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1.发明申请公开(公告)号：US20130008827A1
公开(公告)日：2013-01-10
申请号：US13636182
申请日：2011-03-24
CPC分类号： C10G45/64 , B01J29/7461 , B01J29/7484 , B01J29/7492 , B01J29/7661 , B01J29/7684 , B01J29/7692 , B01J29/7861 , B01J29/7884 , B01J29/7892 , B01J37/0009 , B01J37/0201 , B01J37/18 , B01J37/30 , B01J2229/20 , B01J2229/42 , C07C5/2708 , C07C5/2775 , C10G45/62 , C10G65/043 , C10G2300/1022 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/1081 , C10G2300/30 , C10G2300/70 , C10G2400/10
摘要： The hydroisomerization catalyst of the present invention is a catalyst used for hydroisomerization of a hydrocarbon, including a support including a calcined zeolite modified with at least one metal selected from the group consisting of Na, K, Cs, Mg, Ca, Ba, and K, and having a thermal history that includes heating at 350° C. or more, and at least one inorganic oxide selected from the group consisting of alumina, silica, titania, boria, zirconia, magnesia, ceria, zinc oxide, phosphorus oxide, and a composite oxide containing a combination of at least two or more of these oxides; and at least one metal supported on the support and selected from the group consisting of elements belonging to Groups 8 to 10 of the periodic table, molybdenum and tungsten.
摘要翻译： 本发明的加氢异构化催化剂是用于烃的加氢异构化的催化剂，包括含有由选自Na，K，Cs，Mg，Ca，Ba和K中的至少一种金属改性的煅烧沸石的载体 并且具有包括在350℃以上的加热的热历史，以及选自氧化铝，二氧化硅，二氧化钛，氧化硼，氧化锆，氧化镁，二氧化铈，氧化锌，氧化磷和氧化铝中的至少一种无机氧化物 包含这些氧化物中的至少两种以上的组合的复合氧化物; 以及至少一种负载在载体上并选自元素周期表第8至10族的元素，钼和钨的金属。
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公开(公告)号：US09598650B2
公开(公告)日：2017-03-21
申请号：US13636182
申请日：2011-03-24
IPC分类号： B01J29/06 , C10G45/00 , C07C5/27 , C10G45/64 , C10G45/62 , C10G65/04 , B01J29/76 , B01J29/78 , B01J29/74 , B01J37/02 , B01J37/18 , B01J37/30 , B01J37/00
摘要： The hydroisomerization catalyst of the present invention is a catalyst used for hydroisomerization of a hydrocarbon, including a support including a calcined zeolite modified with at least one metal selected from the group consisting of Na, K, Cs, Mg, Ca, Ba, and K, and having a thermal history that includes heating at 350° C. or more, and at least one inorganic oxide selected from the group consisting of alumina, silica, titania, boria, zirconia, magnesia, ceria, zinc oxide, phosphorus oxide, and a composite oxide containing a combination of at least two or more of these oxides; and at least one metal supported on the support and selected from the group consisting of elements belonging to Groups 8 to 10 of the periodic table, molybdenum and tungsten.
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3.发明授权公开(公告)号：US09458387B2
公开(公告)日：2016-10-04
申请号：US14007396
申请日：2012-03-14
申请人： Yoshiyuki Nagayasu , Hideki Ono , Kazuaki Hayasaka , Mayumi Yokoi
发明人： Yoshiyuki Nagayasu , Hideki Ono , Kazuaki Hayasaka , Mayumi Yokoi
IPC分类号： B01J21/00 , C07C27/00 , C10G2/00 , B01J21/06 , B01J23/00 , B01J23/75 , B01J35/00 , B01J37/18 , B01J21/08
CPC分类号： C10G2/332 , B01J21/066 , B01J21/08 , B01J23/005 , B01J23/75 , B01J35/002 , B01J37/18
摘要： A Fischer-Tropsch synthesis reaction catalyst includes a catalyst support containing a silica and zirconium oxide in an amount of 0.5 to 14% by mass based on the mass of the catalyst support, and cobalt metal and a cobalt oxide supported on the catalyst support in an amount equivalent to 10 to 40% by mass of tricobalt tetroxide based on the mass of the catalyst, wherein the degree of reduction of the cobalt atoms is within a range from 75 to 93%, and the amount of hydrogen gas adsorption per unit mass of the catalyst at 100° C. is within a range from 0.40 to 1.0 ml/g.
摘要翻译： 费 - 托合成反应催化剂包括基于催化剂载体的质量含有0.5至14质量％的二氧化硅和氧化锆的催化剂载体，以及负载在催化剂载体上的钴金属和氧化钴 相对于催化剂的质量，相当于四氧化四铁的10〜40质量％，钴原子的还原度为75〜93％，每单位质量的氢气吸附量 在100℃下的催化剂在0.40至1.0ml / g的范围内。
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4.发明申请ACTIVATED FISCHER-TROPSCH SYNTHESIS REACTION CATALYST AND METHOD FOR PRODUCING HYDROCARBONS 有权活性螯合剂 - 催化剂合成反应催化剂和生产烃类的方法公开(公告)号：US20140018454A1
公开(公告)日：2014-01-16
申请号：US14007396
申请日：2012-03-14
申请人： Yoshiyuki Nagayasu , Hideki Ono , Kazuaki Hayasaka , Mayumi Yokoi
发明人： Yoshiyuki Nagayasu , Hideki Ono , Kazuaki Hayasaka , Mayumi Yokoi
CPC分类号： C10G2/332 , B01J21/066 , B01J21/08 , B01J23/005 , B01J23/75 , B01J35/002 , B01J37/18
摘要： A Fischer-Tropsch synthesis reaction catalyst includes a catalyst support containing a silica and zirconium oxide in an amount of 0.5 to 14% by mass based on the mass of the catalyst support, and cobalt metal and a cobalt oxide supported on the catalyst support in an amount equivalent to 10 to 40% by mass of tricobalt tetroxide based on the mass of the catalyst, wherein the degree of reduction of the cobalt atoms is within a range from 75 to 93%, and the amount of hydrogen gas adsorption per unit mass of the catalyst at 100° C. is within a range from 0.40 to 1.0 ml/g.
摘要翻译： 费 - 托合成反应催化剂包括基于催化剂载体的质量含有0.5至14质量％的二氧化硅和氧化锆的催化剂载体，以及负载在催化剂载体上的钴金属和氧化钴 相对于催化剂的质量，相当于四氧化四铁的10〜40质量％，钴原子的还原度为75〜93％，每单位质量的氢气吸附量 在100℃下的催化剂在0.40至1.0ml / g的范围内。
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5.发明申请公开(公告)号：US20120322899A1
公开(公告)日：2012-12-20
申请号：US13581948
申请日：2011-02-14
申请人： Hideki Ono , Yoshiyuki Nagayasu , Kazuaki Hayasaka
发明人： Hideki Ono , Yoshiyuki Nagayasu , Kazuaki Hayasaka
CPC分类号： B01J37/18 , B01J23/462 , B01J23/75 , B01J23/8913 , B01J23/94 , B01J23/96 , B01J35/1061 , B01J37/10 , B01J38/02 , B01J38/06 , B01J38/10 , C10G2/332 , C10G2/333
摘要： A method for producing a regenerated Fischer-Tropsch synthesis catalyst obtained by regenerating a spent catalyst used in a Fischer-Tropsch synthesis reaction, comprising a steaming step of bringing the above spent catalyst into contact with a mixed gas comprising 1 to 30% by volume of steam and an inert gas at a pressure of atmospheric pressure to 5 MPa and a temperature of 150 to 350° C., the above spent catalyst being a spent catalyst in which cobalt and/or ruthenium is supported on a carrier comprising silica with an average pore diameter measured by a nitrogen adsorption method of 4 to 25 nm, and of which activity represented by an initial carbon monoxide conversion is 40 to 95%, based on the activity of a corresponding unused catalyst.
摘要翻译： 一种生产通过再生费 - 托合成反应中使用的废催化剂而获得的再生费 - 托合成催化剂的方法，包括使上述废催化剂与含有1〜30体积％ 蒸汽和惰性气体，在大气压至5MPa的压力和150至350℃的温度下，上述废催化剂是废催化剂，其中钴和/或钌负载在包含二氧化硅的载体上，平均 基于相应的未使用的催化剂的活性，通过4〜25nm的氮吸附法测定的孔径，其初始一氧化碳转化率表示的活性为40〜95％。
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公开(公告)号：US20120217186A1
公开(公告)日：2012-08-30
申请号：US13391067
申请日：2010-08-06
IPC分类号： C10G73/38
CPC分类号： C10G65/02 , B01J21/066 , B01J23/85 , B01J23/882 , B01J23/883 , B01J23/888 , B01J29/7484 , B01J35/002 , B01J35/1061 , B01J35/108 , B01J37/0009 , B01J37/03 , C10G45/58 , C10G45/60 , C10G45/62 , C10G45/64 , C10G65/043 , C10G2300/1022 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/202 , C10G2300/301 , C10G2300/302 , C10G2300/304 , C10G2400/10 , C10M101/02 , C10M2203/1025 , C10M2205/173 , C10N2220/026 , C10N2220/027 , C10N2220/028 , C10N2220/031 , C10N2230/02 , C10N2230/10 , C10N2230/43 , C10N2240/10 , C10N2270/00 , C10N2220/022
摘要： A method for producing a lubricant base oil includes contacting feedstock containing normal paraffins having not less than 20 carbon atoms with a first catalyst in the presence of molecular hydrogen to obtain a first produced oil, and contacting the first produced oil with a second catalyst in the presence of molecular hydrogen to obtain a second produced oil. The first catalyst includes a first carrier in which a fraction of an amount of NH3 to be desorbed at 300 to 800° C. based on a total amount of NH3 to be desorbed is 80 to 90% in temperature-programmed desorption of NH3, a first metal selected from metals of Group VI in the periodic table carried on the first carrier, and a second metal selected from metals of Group VIII to Group X in the periodic table carried on the first carrier.
摘要翻译： 一种润滑剂基础油的制造方法，其特征在于，在分子氢存在下，使含有不少于20个碳原子的正链烷烃的原料与第一催化剂接触，得到第一生产油，并将第一生产油与第二催化剂接触 存在分子氢以获得第二产生的油。 第一催化剂包括第一载体，其中在待处理的NH 3的总量的300至800℃下解吸的一部分NH 3的一部分在NH 3的温度程序解吸中为80至90％，a 选自在第一载体上承载的周期表中的VI族的金属的第一种金属和选自第一载体上的周期表中的VIII族至第X族的金属的第二种金属。
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公开(公告)号：US09057026B2
公开(公告)日：2015-06-16
申请号：US13391067
申请日：2010-08-06
IPC分类号： C10G73/38 , C10G65/02 , B01J21/06 , B01J23/85 , B01J23/882 , B01J23/883 , B01J23/888 , B01J35/00 , B01J35/10 , B01J37/00 , B01J37/03 , C10G45/58 , C10G45/60 , C10G45/62 , C10G45/64 , C10G65/04 , C10G73/00 , C10M101/02 , B01J29/74
CPC分类号： C10G65/02 , B01J21/066 , B01J23/85 , B01J23/882 , B01J23/883 , B01J23/888 , B01J29/7484 , B01J35/002 , B01J35/1061 , B01J35/108 , B01J37/0009 , B01J37/03 , C10G45/58 , C10G45/60 , C10G45/62 , C10G45/64 , C10G65/043 , C10G2300/1022 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/202 , C10G2300/301 , C10G2300/302 , C10G2300/304 , C10G2400/10 , C10M101/02 , C10M2203/1025 , C10M2205/173 , C10N2220/026 , C10N2220/027 , C10N2220/028 , C10N2220/031 , C10N2230/02 , C10N2230/10 , C10N2230/43 , C10N2240/10 , C10N2270/00 , C10N2220/022
摘要： A method for producing a lubricant base oil includes contacting feedstock containing normal paraffins having not less than 20 carbon atoms with a first catalyst in the presence of molecular hydrogen to obtain a first produced oil, and contacting the first produced oil with a second catalyst in the presence of molecular hydrogen to obtain a second produced oil. The first catalyst includes a first carrier in which a fraction of an amount of NH3 to be desorbed at 300 to 800° C. based on a total amount of NH3 to be desorbed is 80 to 90% in temperature-programmed desorption of NH3, a first metal selected from metals of Group VI in the periodic table carried on the first carrier, and a second metal selected from metals of Group VIII to Group X in the periodic table carried on the first carrier.
摘要翻译： 一种润滑剂基础油的制造方法，其特征在于，在分子氢存在下，使含有不少于20个碳原子的正链烷烃的原料与第一催化剂接触，得到第一生产油，并将第一生产油与第二催化剂接触 存在分子氢以获得第二产生的油。 第一催化剂包括第一载体，其中在待处理的NH 3的总量的300至800℃下解吸的一部分NH 3的一部分在NH 3的温度程序解吸中为80至90％，a 选自在第一载体上承载的周期表中的VI族的金属的第一种金属和选自第一载体上的周期表中的VIII族至第X族的金属的第二种金属。
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8.发明授权公开(公告)号：US08557879B2
公开(公告)日：2013-10-15
申请号：US13580239
申请日：2011-01-06
申请人： Yoshiyuki Nagayasu , Kazuaki Hayasaka , Hideki Ono
发明人： Yoshiyuki Nagayasu , Kazuaki Hayasaka , Hideki Ono
CPC分类号： B01J35/023 , B01J21/066 , B01J21/08 , B01J23/75 , B01J23/8913 , B01J35/1061 , B01J37/009 , B01J37/0207 , B01J37/088 , B01J37/14 , B01J37/18 , B01J37/343 , C10G2/33 , C10G2300/4006 , C10G2300/703
摘要： A method for producing an activated Fischer-Tropsch synthesis catalyst comprising a hydrogen reduction step of subjecting a catalyst comprising 3 parts by mass to 50 parts by mass, as a metal atom, of a cobalt compound and/or a ruthenium compound, based on 100 parts by mass of a carrier containing a porous inorganic oxide, supported on the carrier, to reduction in a gas containing molecular hydrogen at a temperature of 300° C. to 600° C.; and a CO reduction step of subjecting the catalyst to reduction in a gas containing carbon monoxide and containing no molecular hydrogen at a temperature of 200° C. to 400° C.
摘要翻译： 一种活性费 - 托合成催化剂的制造方法，其特征在于，具有氢还原工序，该催化剂以钴化合物和/或钌化合物为基准，含有3质量份〜50质量份作为金属原子的催化剂， 在载体上承载含有多孔无机氧化物的载体的质量份，以在300℃至600℃的温度下还原含有分子氢的气体。 以及在200℃至400℃的温度下使催化剂还原含有一氧化碳并且不含分子氢的CO的还原步骤。
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9.发明授权Method for manufacturing a regenerated Fischer-Tropsch synthesis catalyst, and hydrocarbon manufacturing method 有权再生费 - 托合成催化剂的制造方法以及烃制造方法公开(公告)号：US08557725B2
公开(公告)日：2013-10-15
申请号：US13581948
申请日：2011-02-14
申请人： Hideki Ono , Yoshiyuki Nagayasu , Kazuaki Hayasaka
发明人： Hideki Ono , Yoshiyuki Nagayasu , Kazuaki Hayasaka
CPC分类号： B01J37/18 , B01J23/462 , B01J23/75 , B01J23/8913 , B01J23/94 , B01J23/96 , B01J35/1061 , B01J37/10 , B01J38/02 , B01J38/06 , B01J38/10 , C10G2/332 , C10G2/333
摘要： A method for producing a regenerated Fischer-Tropsch synthesis catalyst obtained by regenerating a spent catalyst used in a Fischer-Tropsch synthesis reaction, comprising a steaming step of bringing the above spent catalyst into contact with a mixed gas comprising 1 to 30% by volume of steam and an inert gas at a pressure of atmospheric pressure to 5 MPa and a temperature of 150 to 350° C., the above spent catalyst being a spent catalyst in which cobalt and/or ruthenium is supported on a carrier comprising silica with an average pore diameter measured by a nitrogen adsorption method of 4 to 25 nm, and of which activity represented by an initial carbon monoxide conversion is 40 to 95%, based on the activity of a corresponding unused catalyst.
摘要翻译： 一种生产通过再生费 - 托合成反应中使用的废催化剂而获得的再生费 - 托合成催化剂的方法，包括使上述废催化剂与含有1〜30体积％ 蒸汽和惰性气体，在大气压至5MPa的压力和150至350℃的温度下，上述废催化剂是废催化剂，其中钴和/或钌负载在包含二氧化硅的载体上，平均 基于相应的未使用的催化剂的活性，通过4〜25nm的氮吸附法测定的孔径，其初始一氧化碳转化率表示的活性为40〜95％。
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公开(公告)号：US09637692B2
公开(公告)日：2017-05-02
申请号：US13636182
申请日：2011-03-24
IPC分类号： B01J29/06 , C10G45/00 , C07C5/27 , C10G45/64 , C10G45/62 , C10G65/04 , B01J29/76 , B01J29/78 , B01J29/74 , B01J37/02 , B01J37/18 , B01J37/30 , B01J37/00
CPC分类号： C10G45/64 , B01J29/7461 , B01J29/7484 , B01J29/7492 , B01J29/7661 , B01J29/7684 , B01J29/7692 , B01J29/7861 , B01J29/7884 , B01J29/7892 , B01J37/0009 , B01J37/0201 , B01J37/18 , B01J37/30 , B01J2229/20 , B01J2229/42 , C07C5/2708 , C07C5/2775 , C10G45/62 , C10G65/043 , C10G2300/1022 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/1081 , C10G2300/30 , C10G2300/70 , C10G2400/10
摘要： The hydroisomerization catalyst of the present invention is a catalyst used for hydroisomerization of a hydrocarbon, including a support including a calcined zeolite modified with at least one metal selected from the group consisting of Na, K, Cs, Mg, Ca, Ba, and K, and having a thermal history that includes heating at 350° C. or more, and at least one inorganic oxide selected from the group consisting of alumina, silica, titania, boria, zirconia, magnesia, ceria, zinc oxide, phosphorus oxide, and a composite oxide containing a combination of at least two or more of these oxides; and at least one metal supported on the support and selected from the group consisting of elements belonging to Groups 8 to 10 of the periodic table, molybdenum and tungsten.
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