摘要:
The hydroisomerization catalyst of the present invention is a catalyst used for hydroisomerization of a hydrocarbon, including a support including a calcined zeolite modified with at least one metal selected from the group consisting of Na, K, Cs, Mg, Ca, Ba, and K, and having a thermal history that includes heating at 350° C. or more, and at least one inorganic oxide selected from the group consisting of alumina, silica, titania, boria, zirconia, magnesia, ceria, zinc oxide, phosphorus oxide, and a composite oxide containing a combination of at least two or more of these oxides; and at least one metal supported on the support and selected from the group consisting of elements belonging to Groups 8 to 10 of the periodic table, molybdenum and tungsten.
摘要:
The hydroisomerization catalyst of the present invention is a catalyst used for hydroisomerization of a hydrocarbon, including a support including a calcined zeolite modified with at least one metal selected from the group consisting of Na, K, Cs, Mg, Ca, Ba, and K, and having a thermal history that includes heating at 350° C. or more, and at least one inorganic oxide selected from the group consisting of alumina, silica, titania, boria, zirconia, magnesia, ceria, zinc oxide, phosphorus oxide, and a composite oxide containing a combination of at least two or more of these oxides; and at least one metal supported on the support and selected from the group consisting of elements belonging to Groups 8 to 10 of the periodic table, molybdenum and tungsten.
摘要:
A Fischer-Tropsch synthesis reaction catalyst includes a catalyst support containing a silica and zirconium oxide in an amount of 0.5 to 14% by mass based on the mass of the catalyst support, and cobalt metal and a cobalt oxide supported on the catalyst support in an amount equivalent to 10 to 40% by mass of tricobalt tetroxide based on the mass of the catalyst, wherein the degree of reduction of the cobalt atoms is within a range from 75 to 93%, and the amount of hydrogen gas adsorption per unit mass of the catalyst at 100° C. is within a range from 0.40 to 1.0 ml/g.
摘要:
A Fischer-Tropsch synthesis reaction catalyst includes a catalyst support containing a silica and zirconium oxide in an amount of 0.5 to 14% by mass based on the mass of the catalyst support, and cobalt metal and a cobalt oxide supported on the catalyst support in an amount equivalent to 10 to 40% by mass of tricobalt tetroxide based on the mass of the catalyst, wherein the degree of reduction of the cobalt atoms is within a range from 75 to 93%, and the amount of hydrogen gas adsorption per unit mass of the catalyst at 100° C. is within a range from 0.40 to 1.0 ml/g.
摘要:
A method for producing a regenerated Fischer-Tropsch synthesis catalyst obtained by regenerating a spent catalyst used in a Fischer-Tropsch synthesis reaction, comprising a steaming step of bringing the above spent catalyst into contact with a mixed gas comprising 1 to 30% by volume of steam and an inert gas at a pressure of atmospheric pressure to 5 MPa and a temperature of 150 to 350° C., the above spent catalyst being a spent catalyst in which cobalt and/or ruthenium is supported on a carrier comprising silica with an average pore diameter measured by a nitrogen adsorption method of 4 to 25 nm, and of which activity represented by an initial carbon monoxide conversion is 40 to 95%, based on the activity of a corresponding unused catalyst.
摘要:
A method for producing a lubricant base oil includes contacting feedstock containing normal paraffins having not less than 20 carbon atoms with a first catalyst in the presence of molecular hydrogen to obtain a first produced oil, and contacting the first produced oil with a second catalyst in the presence of molecular hydrogen to obtain a second produced oil. The first catalyst includes a first carrier in which a fraction of an amount of NH3 to be desorbed at 300 to 800° C. based on a total amount of NH3 to be desorbed is 80 to 90% in temperature-programmed desorption of NH3, a first metal selected from metals of Group VI in the periodic table carried on the first carrier, and a second metal selected from metals of Group VIII to Group X in the periodic table carried on the first carrier.
摘要:
A method for producing an activated Fischer-Tropsch synthesis catalyst comprising a hydrogen reduction step of subjecting a catalyst comprising 3 parts by mass to 50 parts by mass, as a metal atom, of a cobalt compound and/or a ruthenium compound, based on 100 parts by mass of a carrier containing a porous inorganic oxide, supported on the carrier, to reduction in a gas containing molecular hydrogen at a temperature of 300° C. to 600° C.; and a CO reduction step of subjecting the catalyst to reduction in a gas containing carbon monoxide and containing no molecular hydrogen at a temperature of 200° C. to 400° C.
摘要:
A method for producing a regenerated Fischer-Tropsch synthesis catalyst obtained by regenerating a spent catalyst used in a Fischer-Tropsch synthesis reaction, comprising a steaming step of bringing the above spent catalyst into contact with a mixed gas comprising 1 to 30% by volume of steam and an inert gas at a pressure of atmospheric pressure to 5 MPa and a temperature of 150 to 350° C., the above spent catalyst being a spent catalyst in which cobalt and/or ruthenium is supported on a carrier comprising silica with an average pore diameter measured by a nitrogen adsorption method of 4 to 25 nm, and of which activity represented by an initial carbon monoxide conversion is 40 to 95%, based on the activity of a corresponding unused catalyst.
摘要:
A method for producing a lubricant base oil includes contacting feedstock containing normal paraffins having not less than 20 carbon atoms with a first catalyst in the presence of molecular hydrogen to obtain a first produced oil, and contacting the first produced oil with a second catalyst in the presence of molecular hydrogen to obtain a second produced oil. The first catalyst includes a first carrier in which a fraction of an amount of NH3 to be desorbed at 300 to 800° C. based on a total amount of NH3 to be desorbed is 80 to 90% in temperature-programmed desorption of NH3, a first metal selected from metals of Group VI in the periodic table carried on the first carrier, and a second metal selected from metals of Group VIII to Group X in the periodic table carried on the first carrier.
摘要:
The hydroisomerization catalyst of the present invention is a catalyst used for hydroisomerization of a hydrocarbon, including a support including a calcined zeolite modified with at least one metal selected from the group consisting of Na, K, Cs, Mg, Ca, Ba, and K, and having a thermal history that includes heating at 350° C. or more, and at least one inorganic oxide selected from the group consisting of alumina, silica, titania, boria, zirconia, magnesia, ceria, zinc oxide, phosphorus oxide, and a composite oxide containing a combination of at least two or more of these oxides; and at least one metal supported on the support and selected from the group consisting of elements belonging to Groups 8 to 10 of the periodic table, molybdenum and tungsten.