公开(公告)号：US20070175797A1

公开(公告)日：2007-08-02

申请号：US11626074

申请日：2007-01-23

申请人： Hideshi Iki ,  Kazuaki Hayasaka ,  Shinya Takahashi

发明人： Hideshi Iki ,  Kazuaki Hayasaka ,  Shinya Takahashi

IPC分类号： C10G45/04 ,  C10G45/60 ,  B01J27/00 ,  B01J27/188 ,  B01J27/19 ,  B01J27/182

CPC分类号： C10G45/08 ,  B01J27/19

摘要： The present invention provides a hydrodesulfurization that can attain an extremely high depth of desulfurization to a sulfur content of 10 ppm by mass and maintain such a high desulfurization activity for a long period of time. The catalyst comprises an inorganic porous support containing alumina and phosphorus, at least one active metal selected from the metals of Group 8 of the periodic table, and at least one metal selected from the metals of Group 6A of the periodic table, the Group 8 metal and the Group 6A metal being contained in a molar ratio defined by (oxide of the Group 8 metal)/(oxide of the Group 6A metal) ranging from 0.055 to 0.150, and the content of the Group 6A metal in terms of oxide being in the range of 30 to 40 percent by mass based on the mass of the catalyst.

摘要翻译： 本发明提供一种能够达到非常高的脱硫深度至硫酸含量为10质量ppm的加氢脱硫，并且长期保持如此高的脱硫活性。 催化剂包括含有氧化铝和磷的无机多孔载体，选自元素周期表第8族金属的至少一种活性金属和选自元素周期表第6A族金属中的至少一种金属，第8族金属 并且6A族金属以（由第8族金属的氧化物）/（6A族金属的氧化物）定义的摩尔比包含在0.055〜0.150的范围内，6A族金属的含量以氧化物为单位 相对于催化剂的质量为30〜40质量％的范围。

公开(公告)号：US20120217186A1

公开(公告)日：2012-08-30

申请号：US13391067

申请日：2010-08-06

申请人： Kazuaki Hayasaka ,  Hideki Ono ,  Yoshiyuki Nagayasu ,  Masahiro Taguchi ,  Hideshi Iki

发明人： Kazuaki Hayasaka ,  Hideki Ono ,  Yoshiyuki Nagayasu ,  Masahiro Taguchi ,  Hideshi Iki

IPC分类号： C10G73/38

CPC分类号： C10G65/02 ,  B01J21/066 ,  B01J23/85 ,  B01J23/882 ,  B01J23/883 ,  B01J23/888 ,  B01J29/7484 ,  B01J35/002 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/0009 ,  B01J37/03 ,  C10G45/58 ,  C10G45/60 ,  C10G45/62 ,  C10G45/64 ,  C10G65/043 ,  C10G2300/1022 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2300/302 ,  C10G2300/304 ,  C10G2400/10 ,  C10M101/02 ,  C10M2203/1025 ,  C10M2205/173 ,  C10N2220/026 ,  C10N2220/027 ,  C10N2220/028 ,  C10N2220/031 ,  C10N2230/02 ,  C10N2230/10 ,  C10N2230/43 ,  C10N2240/10 ,  C10N2270/00 ,  C10N2220/022

摘要： A method for producing a lubricant base oil includes contacting feedstock containing normal paraffins having not less than 20 carbon atoms with a first catalyst in the presence of molecular hydrogen to obtain a first produced oil, and contacting the first produced oil with a second catalyst in the presence of molecular hydrogen to obtain a second produced oil. The first catalyst includes a first carrier in which a fraction of an amount of NH3 to be desorbed at 300 to 800° C. based on a total amount of NH3 to be desorbed is 80 to 90% in temperature-programmed desorption of NH3, a first metal selected from metals of Group VI in the periodic table carried on the first carrier, and a second metal selected from metals of Group VIII to Group X in the periodic table carried on the first carrier.

摘要翻译： 一种润滑剂基础油的制造方法，其特征在于，在分子氢存在下，使含有不少于20个碳原子的正链烷烃的原料与第一催化剂接触，得到第一生产油，并将第一生产油与第二催化剂接触 存在分子氢以获得第二产生的油。 第一催化剂包括第一载体，其中在待处理的NH 3的总量的300至800℃下解吸的一部分NH 3的一部分在NH 3的温度程序解吸中为80至90％，a 选自在第一载体上承载的周期表中的VI族的金属的第一种金属和选自第一载体上的周期表中的VIII族至第X族的金属的第二种金属。

公开(公告)号：US20120216449A1

公开(公告)日：2012-08-30

申请号：US13391727

申请日：2010-08-30

申请人： Kazuaki Hayasaka ,  Hideki Ono ,  Akira Koyama ,  Hideshi Iki

发明人： Kazuaki Hayasaka ,  Hideki Ono ,  Akira Koyama ,  Hideshi Iki

IPC分类号： C10L1/188

CPC分类号： B01J29/7484 ,  B01J23/85 ,  B01J23/883 ,  B01J29/7461 ,  B01J29/7492 ,  B01J29/85 ,  C10G3/46 ,  C10G3/49 ,  C10G3/50 ,  C10G45/64 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/202 ,  C10G2400/08 ,  C10L1/04 ,  Y02P30/20

摘要： A method for producing an aviation fuel oil base includes obtaining a first generated oil by hydrotreating a feedstock by bringing a feedstock which includes an oxygen-containing hydrocarbon compound derived from an animal or vegetable oils and fat into contact with a first dual functional catalyst which has dehydrogenation and hydrogenation functions and which includes a metal of group 6A of the periodic table, a metal of group 8, and an amorphous solid acidic substance, in the presence of hydrogen; and obtaining a second generated oil including an aviation fuel oil base by hydroisomerizing the first generated oil by bringing the first generated oil into contact with a second dual functional catalyst which has dehydrogenation and hydrogenation functions and which includes a metal of the group 8 of the periodic table and a crystalline solid acidic substance, in the presence of hydrogen.

摘要翻译： 一种航空燃料油基料的制造方法，其特征在于，通过使来自动物或植物油脂的含氧烃化合物的原料与第一双官能催化剂接触而进行加氢处理，得到第一产生油， 脱氢和氢化功能，其包括周期表第6A族金属，第8族金属和无定形固体酸性物质，在氢的存在下; 以及通过使第一产生的油与具有脱氢和氢化功能的第二双功能催化剂接触来获得包含航空燃料油基的第二产生的油，该第二双功能催化剂包括周期性的第8族金属 表和结晶固体酸性物质，在氢的存在下。

公开(公告)号：US07429550B2

公开(公告)日：2008-09-30

申请号：US11567374

申请日：2006-12-06

申请人： Hideshi Iki ,  Kazuaki Hayasaka ,  Kazuo Fukazawa

发明人： Hideshi Iki ,  Kazuaki Hayasaka ,  Kazuo Fukazawa

IPC分类号： B01J21/12 ,  B01J27/18 ,  C10G47/18 ,  C10G47/20 ,  C10G45/12

CPC分类号： C10G49/04 ,  B01J23/85 ,  B01J23/882 ,  B01J23/883 ,  B01J27/182 ,  B01J27/19 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1038 ,  B01J37/0009 ,  B01J37/0203 ,  B01J37/03 ,  C10G49/08

摘要： A hydrogenation catalyst for a hydrocarbon oil, includes an inorganic porous support composed of at least the oxides of aluminum, phosphorus, and silicon, and supporting at least one active metal selected from the metals of Group 8 of the periodic table, at least one active metal selected from the metals of Group 6 of the periodic table, and phosphorus, the phosphorus chemical shift value of the inorganic support determined by 31P-CPMAS-NMR having the peak within the range of 0 to −20 ppm. The catalyst can achieve an extremely high level of hydrogenation wherein the hydrocarbon is decreased in sulfur content to 10 ppm by mass or less and in nitrogen content to 3 ppm by mass or less.

摘要翻译： 用于烃油的氢化催化剂包括至少由铝，磷和硅的氧化物组成的无机多孔载体，并且支持选自元素周期表第8族金属中的至少一种活性金属，至少一种活性 选自元素周期表第6族金属的金属和磷，由POD-NMR-NMR确定的无机载体的磷化学位移值，峰值在0至 - 20 ppm。 催化剂可以实现极高的氢化水平，其中烃的含量降低到10质量ppm以下，氮含量降低到3质量ppm以下。

公开(公告)号：US09283552B2

公开(公告)日：2016-03-15

申请号：US13391727

申请日：2010-08-30

申请人： Kazuaki Hayasaka ,  Hideki Ono ,  Akira Koyama ,  Hideshi Iki

发明人： Kazuaki Hayasaka ,  Hideki Ono ,  Akira Koyama ,  Hideshi Iki

IPC分类号： C07C1/00 ,  B01J29/74 ,  B01J23/883 ,  C10G3/00 ,  C10G45/64 ,  C10L1/04 ,  B01J23/85 ,  B01J29/85

CPC分类号： B01J29/7484 ,  B01J23/85 ,  B01J23/883 ,  B01J29/7461 ,  B01J29/7492 ,  B01J29/85 ,  C10G3/46 ,  C10G3/49 ,  C10G3/50 ,  C10G45/64 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/202 ,  C10G2400/08 ,  C10L1/04 ,  Y02P30/20

摘要： A method for producing an aviation fuel oil base, including: a first step of obtaining a first generated oil by hydrotreating a feedstock by bringing a feedstock which includes an oxygen-containing hydrocarbon compound derived from an animal or vegetable oils and fat into contact with a first dual functional catalyst which has dehydrogenation and hydrogenation functions and which includes a metal of group 6B of the periodic table, a metal of group 8, and an amorphous solid acidic substance, in the presence of hydrogen; and a second step of obtaining a second generated oil including an aviation fuel oil base by hydroisomerizing the first generated oil by bringing the first generated oil into contact with a second dual functional catalyst which has dehydrogenation and hydrogenation functions and which includes a metal of the group 8 of the periodic table and a crystalline solid acidic substance, in the presence of hydrogen.

摘要翻译： 一种生产航空燃料油基料的方法，包括：第一步骤，通过将包含来源于动物或植物油脂的含氧烃化合物的原料与一种原料接触而将原料加氢处理获得第一产生的油 具有脱氢和氢化功能的第一双官能催化剂，其包含周期表第6B族金属，第8族金属和无定形固体酸性物质，在氢的存在下; 以及第二步骤，通过使第一产生的油与具有脱氢和氢化功能的第二双功能催化剂接触，并且包括该组的金属，获得包含航空燃料油基的第二产生的油， 8和结晶固体酸性物质，在氢的存在下。

公开(公告)号：US09057026B2

公开(公告)日：2015-06-16

申请号：US13391067

申请日：2010-08-06

申请人： Kazuaki Hayasaka ,  Hideki Ono ,  Yoshiyuki Nagayasu ,  Masahiro Taguchi ,  Hideshi Iki

发明人： Kazuaki Hayasaka ,  Hideki Ono ,  Yoshiyuki Nagayasu ,  Masahiro Taguchi ,  Hideshi Iki

IPC分类号： C10G73/38 ,  C10G65/02 ,  B01J21/06 ,  B01J23/85 ,  B01J23/882 ,  B01J23/883 ,  B01J23/888 ,  B01J35/00 ,  B01J35/10 ,  B01J37/00 ,  B01J37/03 ,  C10G45/58 ,  C10G45/60 ,  C10G45/62 ,  C10G45/64 ,  C10G65/04 ,  C10G73/00 ,  C10M101/02 ,  B01J29/74

CPC分类号： C10G65/02 ,  B01J21/066 ,  B01J23/85 ,  B01J23/882 ,  B01J23/883 ,  B01J23/888 ,  B01J29/7484 ,  B01J35/002 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/0009 ,  B01J37/03 ,  C10G45/58 ,  C10G45/60 ,  C10G45/62 ,  C10G45/64 ,  C10G65/043 ,  C10G2300/1022 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2300/302 ,  C10G2300/304 ,  C10G2400/10 ,  C10M101/02 ,  C10M2203/1025 ,  C10M2205/173 ,  C10N2220/026 ,  C10N2220/027 ,  C10N2220/028 ,  C10N2220/031 ,  C10N2230/02 ,  C10N2230/10 ,  C10N2230/43 ,  C10N2240/10 ,  C10N2270/00 ,  C10N2220/022

摘要： A method for producing a lubricant base oil includes contacting feedstock containing normal paraffins having not less than 20 carbon atoms with a first catalyst in the presence of molecular hydrogen to obtain a first produced oil, and contacting the first produced oil with a second catalyst in the presence of molecular hydrogen to obtain a second produced oil. The first catalyst includes a first carrier in which a fraction of an amount of NH3 to be desorbed at 300 to 800° C. based on a total amount of NH3 to be desorbed is 80 to 90% in temperature-programmed desorption of NH3, a first metal selected from metals of Group VI in the periodic table carried on the first carrier, and a second metal selected from metals of Group VIII to Group X in the periodic table carried on the first carrier.

摘要翻译： 一种润滑剂基础油的制造方法，其特征在于，在分子氢存在下，使含有不少于20个碳原子的正链烷烃的原料与第一催化剂接触，得到第一生产油，并将第一生产油与第二催化剂接触 存在分子氢以获得第二产生的油。 第一催化剂包括第一载体，其中在待处理的NH 3的总量的300至800℃下解吸的一部分NH 3的一部分在NH 3的温度程序解吸中为80至90％，a 选自在第一载体上承载的周期表中的VI族的金属的第一种金属和选自第一载体上的周期表中的VIII族至第X族的金属的第二种金属。

公开(公告)号：US20060211900A1

公开(公告)日：2006-09-21

申请号：US10548313

申请日：2004-03-05

申请人： Hideshi Iki ,  Yukihiro Sugiura ,  Yuichi Tanaka ,  Shinya Takahashi

发明人： Hideshi Iki ,  Yukihiro Sugiura ,  Yuichi Tanaka ,  Shinya Takahashi

IPC分类号： C07C1/00

CPC分类号： B01J23/85 ,  B01J23/883 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/20 ,  C10G2400/06

摘要： The gas oil fraction hydrotreatment process of the invention is characterized by using a gas oil fraction with a sulfur content of 0.8-2% by mass and a total aromatic content of 20-35% by volume as the feed oil and subjecting the feed oil to hydrotreatment in the presence of a hydrogenation catalyst comprising at least one metal from among Group 6A metals and at least one metal from among Group 8 metals as active metals, and under reaction conditions with a reaction temperature of 330-390° C., a hydrogen partial pressure of 12-20 MPa and a liquid hourly space velocity of 0.1-1 h−1, to obtain an ultralow sulfur and low- aromatic gas oil fraction having a sulfur content of not greater than 1 ppm by mass and a total aromatic content of not greater than 1% by volume. This hydrotreatment process allows production of a “zero sulfur” and “zero aromatic” gas oil fraction in an efficient and reliable manner without provision of special operating conditions or equipment investment.

摘要翻译： 本发明的粗柴油馏分加氢处理方法的特征在于，使用硫含量为0.8〜2质量％，总芳烃含量为20〜35体积％的粗柴油馏分作为原料油， 在包含至少一种金属的6A族金属和至少一种金属作为活性金属的第8族金属中进行加氢处理，在反应温度为330-390℃的反应条件下，加氢处理 12-20MPa的分压和0.1-1小时-1的液时空速，得到硫含量不大于1ppm的超低硫和低芳烃瓦斯油馏分 并且总芳族含量不大于1体积％。 该加氢处理方法允许以有效和可靠的方式生产“零硫”和“零芳烃”瓦斯油馏分，而不需要特殊的操作条件或设备投资。

公开(公告)号：US07776784B2

公开(公告)日：2010-08-17

申请号：US10888972

申请日：2004-07-13

申请人： Hideshi Iki ,  Shigeto Hatanaka ,  Eitaro Morita ,  Shinya Takahashi

发明人： Hideshi Iki ,  Shigeto Hatanaka ,  Eitaro Morita ,  Shinya Takahashi

IPC分类号： B01J23/00 ,  B01J21/00 ,  B01J20/00 ,  B01J29/00

CPC分类号： B01J37/0009 ,  B01J23/88 ,  B01J23/885 ,  B01J23/8871 ,  B01J23/8873 ,  B01J35/1019 ,  B01J35/1038 ,  B01J37/0207 ,  B01J37/20 ,  C10G45/08

摘要： A hydrodesulfurization catalyst used for hydrodesulfurization of catalytically cracked gasoline comprises a support composed mainly of alumina modified with an oxide of at least one metal selected from the group consisting of iron, chromium, cobalt, nickel, copper, zinc, yttrium, scandium and lanthanoid-based metals, with at least one metal selected from the group consisting of Group 6A and Group 8 metals loaded as an active metal on the support. Hydrogenation of olefins generated as by-products during hydrodesulfurization of the catalytically cracked gasoline fraction, as an important constituent base of gasoline, can be adequately inhibited to maintain the octane number, while sufficiently reducing the sulfur content of the hydrodesulfurized catalytically cracked gasoline fraction.

摘要翻译： 用于催化裂化汽油加氢脱硫的加氢脱硫催化剂包括主要由氧化物组成的载体，该氧化铝用选自铁，铬，钴，镍，铜，锌，钇，钪和镧系元素中的至少一种金属的氧化物， 具有至少一种选自负载作为活性金属的6A族和第8族金属的金属在载体上。 作为汽油的重要成分基的催化裂化汽油馏分的加氢脱硫期间作为副产物生成的烯烃的氢化可以充分地抑制维持辛烷值，同时充分降低加氢脱硫催化裂化汽油馏分的硫含量。

公开(公告)号：US20050023192A1

公开(公告)日：2005-02-03

申请号：US10888972

申请日：2004-07-13

申请人： Hideshi Iki ,  Shigeto Hatanaka ,  Eitaro Morita ,  Shinya Takahashi

发明人： Hideshi Iki ,  Shigeto Hatanaka ,  Eitaro Morita ,  Shinya Takahashi

IPC分类号： B01J23/88 ,  B01J23/885 ,  B01J23/887 ,  B01J35/10 ,  B01J37/00 ,  B01J37/02 ,  B01J37/20 ,  C10G45/08 ,  C10G45/04

CPC分类号： B01J37/0009 ,  B01J23/88 ,  B01J23/885 ,  B01J23/8871 ,  B01J23/8873 ,  B01J35/1019 ,  B01J35/1038 ,  B01J37/0207 ,  B01J37/20 ,  C10G45/08

摘要： A hydrodesulfurization catalyst used for hydrodesulfurization of catalytically cracked gasoline comprises a support composed mainly of alumina modified with an oxide of at least one metal selected from the group consisting of iron, chromium, cobalt, nickel, copper, zinc, yttrium, scandium and lanthanoid-based metals, with at least one metal selected from the group consisting of Group 6A and Group 8 metals loaded as an active metal on the support. Hydrogenation of olefins generated as by-products during hydrodesulfurization of the catalytically cracked gasoline fraction, as an important constituent base of gasoline, can be adequately inhibited to maintain the octane number, while sufficiently reducing the sulfur content of the hydrodesulfurized catalytically cracked gasoline fraction.

摘要翻译： 用于催化裂化汽油加氢脱硫的加氢脱硫催化剂包括主要由氧化物组成的载体，该氧化铝用至少一种选自铁，铬，钴，镍，铜，锌，钇，钪和镧系元素的金属的氧化物， 具有至少一种选自负载作为活性金属的6A族和第8族金属的金属在载体上。 作为汽油的重要成分基的催化裂化汽油馏分的加氢脱硫期间作为副产物生成的烯烃的氢化可以充分地抑制维持辛烷值，同时充分降低加氢脱硫催化裂化汽油馏分的硫含量。

公开(公告)号：US20060260983A1

公开(公告)日：2006-11-23

申请号：US10548315

申请日：2004-03-05

申请人： Hideshi Iki ,  Yukihiro Sugiura ,  Yuichi Tanaka

发明人： Hideshi Iki ,  Yukihiro Sugiura ,  Yuichi Tanaka

IPC分类号： C07C37/00 ,  C10G45/04 ,  C10G25/00 ,  C10G45/60

CPC分类号： C10G45/44 ,  B01J29/126 ,  C10G2300/1059 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2400/06

摘要： The gas oil fraction hydrotreatment process of the invention is characterized by using a hydrorefined petroleum-based hydrocarbon oil with a sulfur content of 5-15 ppm by mass, a total aromatic content of 10-25% by volume and a boiling point range of 150-380° C. as the feed oil and subjecting the feed oil to hydrotreatment in the presence of a hydrogenation catalyst to obtain an ultralow sulfur and low aromatic gas oil fraction having a sulfur content of not greater than 1 ppm by mass and a total aromatic content of not greater than 1% by volume. This hydrotreatment process allows production of a “zero sulfur” and “zero aromatic” gas oil fraction in an efficient and reliable manner without provision of special operating conditions or equipment investment.

摘要翻译： 本发明的粗柴油馏分加氢处理方法的特征在于使用硫含量为5〜15质量ppm的加氢精制石油基烃油，总芳族化合物含量为10〜25体积％，沸点范围为150 -380℃作为原料油，并在进料油在氢化催化剂存在下进行加氢处理，得到硫含量不大于1质量ppm的超低硫和低芳烃馏分，总芳烃 含量不超过1％（体积）。 该加氢处理方法允许以有效和可靠的方式生产“零硫”和“零芳烃”瓦斯油馏分，而不需要特殊的操作条件或设备投资。