公开(公告)号：US09283552B2

公开(公告)日：2016-03-15

申请号：US13391727

申请日：2010-08-30

申请人： Kazuaki Hayasaka ,  Hideki Ono ,  Akira Koyama ,  Hideshi Iki

发明人： Kazuaki Hayasaka ,  Hideki Ono ,  Akira Koyama ,  Hideshi Iki

IPC分类号： C07C1/00 ,  B01J29/74 ,  B01J23/883 ,  C10G3/00 ,  C10G45/64 ,  C10L1/04 ,  B01J23/85 ,  B01J29/85

CPC分类号： B01J29/7484 ,  B01J23/85 ,  B01J23/883 ,  B01J29/7461 ,  B01J29/7492 ,  B01J29/85 ,  C10G3/46 ,  C10G3/49 ,  C10G3/50 ,  C10G45/64 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/202 ,  C10G2400/08 ,  C10L1/04 ,  Y02P30/20

摘要： A method for producing an aviation fuel oil base, including: a first step of obtaining a first generated oil by hydrotreating a feedstock by bringing a feedstock which includes an oxygen-containing hydrocarbon compound derived from an animal or vegetable oils and fat into contact with a first dual functional catalyst which has dehydrogenation and hydrogenation functions and which includes a metal of group 6B of the periodic table, a metal of group 8, and an amorphous solid acidic substance, in the presence of hydrogen; and a second step of obtaining a second generated oil including an aviation fuel oil base by hydroisomerizing the first generated oil by bringing the first generated oil into contact with a second dual functional catalyst which has dehydrogenation and hydrogenation functions and which includes a metal of the group 8 of the periodic table and a crystalline solid acidic substance, in the presence of hydrogen.

摘要翻译： 一种生产航空燃料油基料的方法，包括：第一步骤，通过将包含来源于动物或植物油脂的含氧烃化合物的原料与一种原料接触而将原料加氢处理获得第一产生的油 具有脱氢和氢化功能的第一双官能催化剂，其包含周期表第6B族金属，第8族金属和无定形固体酸性物质，在氢的存在下; 以及第二步骤，通过使第一产生的油与具有脱氢和氢化功能的第二双功能催化剂接触，并且包括该组的金属，获得包含航空燃料油基的第二产生的油， 8和结晶固体酸性物质，在氢的存在下。

公开(公告)号：US20120216449A1

公开(公告)日：2012-08-30

申请号：US13391727

申请日：2010-08-30

申请人： Kazuaki Hayasaka ,  Hideki Ono ,  Akira Koyama ,  Hideshi Iki

发明人： Kazuaki Hayasaka ,  Hideki Ono ,  Akira Koyama ,  Hideshi Iki

IPC分类号： C10L1/188

CPC分类号： B01J29/7484 ,  B01J23/85 ,  B01J23/883 ,  B01J29/7461 ,  B01J29/7492 ,  B01J29/85 ,  C10G3/46 ,  C10G3/49 ,  C10G3/50 ,  C10G45/64 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/202 ,  C10G2400/08 ,  C10L1/04 ,  Y02P30/20

摘要： A method for producing an aviation fuel oil base includes obtaining a first generated oil by hydrotreating a feedstock by bringing a feedstock which includes an oxygen-containing hydrocarbon compound derived from an animal or vegetable oils and fat into contact with a first dual functional catalyst which has dehydrogenation and hydrogenation functions and which includes a metal of group 6A of the periodic table, a metal of group 8, and an amorphous solid acidic substance, in the presence of hydrogen; and obtaining a second generated oil including an aviation fuel oil base by hydroisomerizing the first generated oil by bringing the first generated oil into contact with a second dual functional catalyst which has dehydrogenation and hydrogenation functions and which includes a metal of the group 8 of the periodic table and a crystalline solid acidic substance, in the presence of hydrogen.

摘要翻译： 一种航空燃料油基料的制造方法，其特征在于，通过使来自动物或植物油脂的含氧烃化合物的原料与第一双官能催化剂接触而进行加氢处理，得到第一产生油， 脱氢和氢化功能，其包括周期表第6A族金属，第8族金属和无定形固体酸性物质，在氢的存在下; 以及通过使第一产生的油与具有脱氢和氢化功能的第二双功能催化剂接触来获得包含航空燃料油基的第二产生的油，该第二双功能催化剂包括周期性的第8族金属 表和结晶固体酸性物质，在氢的存在下。

公开(公告)号：US20120217186A1

公开(公告)日：2012-08-30

申请号：US13391067

申请日：2010-08-06

申请人： Kazuaki Hayasaka ,  Hideki Ono ,  Yoshiyuki Nagayasu ,  Masahiro Taguchi ,  Hideshi Iki

发明人： Kazuaki Hayasaka ,  Hideki Ono ,  Yoshiyuki Nagayasu ,  Masahiro Taguchi ,  Hideshi Iki

IPC分类号： C10G73/38

CPC分类号： C10G65/02 ,  B01J21/066 ,  B01J23/85 ,  B01J23/882 ,  B01J23/883 ,  B01J23/888 ,  B01J29/7484 ,  B01J35/002 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/0009 ,  B01J37/03 ,  C10G45/58 ,  C10G45/60 ,  C10G45/62 ,  C10G45/64 ,  C10G65/043 ,  C10G2300/1022 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2300/302 ,  C10G2300/304 ,  C10G2400/10 ,  C10M101/02 ,  C10M2203/1025 ,  C10M2205/173 ,  C10N2220/026 ,  C10N2220/027 ,  C10N2220/028 ,  C10N2220/031 ,  C10N2230/02 ,  C10N2230/10 ,  C10N2230/43 ,  C10N2240/10 ,  C10N2270/00 ,  C10N2220/022

摘要： A method for producing a lubricant base oil includes contacting feedstock containing normal paraffins having not less than 20 carbon atoms with a first catalyst in the presence of molecular hydrogen to obtain a first produced oil, and contacting the first produced oil with a second catalyst in the presence of molecular hydrogen to obtain a second produced oil. The first catalyst includes a first carrier in which a fraction of an amount of NH3 to be desorbed at 300 to 800° C. based on a total amount of NH3 to be desorbed is 80 to 90% in temperature-programmed desorption of NH3, a first metal selected from metals of Group VI in the periodic table carried on the first carrier, and a second metal selected from metals of Group VIII to Group X in the periodic table carried on the first carrier.

摘要翻译： 一种润滑剂基础油的制造方法，其特征在于，在分子氢存在下，使含有不少于20个碳原子的正链烷烃的原料与第一催化剂接触，得到第一生产油，并将第一生产油与第二催化剂接触 存在分子氢以获得第二产生的油。 第一催化剂包括第一载体，其中在待处理的NH 3的总量的300至800℃下解吸的一部分NH 3的一部分在NH 3的温度程序解吸中为80至90％，a 选自在第一载体上承载的周期表中的VI族的金属的第一种金属和选自第一载体上的周期表中的VIII族至第X族的金属的第二种金属。

公开(公告)号：US09057026B2

公开(公告)日：2015-06-16

申请号：US13391067

申请日：2010-08-06

申请人： Kazuaki Hayasaka ,  Hideki Ono ,  Yoshiyuki Nagayasu ,  Masahiro Taguchi ,  Hideshi Iki

发明人： Kazuaki Hayasaka ,  Hideki Ono ,  Yoshiyuki Nagayasu ,  Masahiro Taguchi ,  Hideshi Iki

IPC分类号： C10G73/38 ,  C10G65/02 ,  B01J21/06 ,  B01J23/85 ,  B01J23/882 ,  B01J23/883 ,  B01J23/888 ,  B01J35/00 ,  B01J35/10 ,  B01J37/00 ,  B01J37/03 ,  C10G45/58 ,  C10G45/60 ,  C10G45/62 ,  C10G45/64 ,  C10G65/04 ,  C10G73/00 ,  C10M101/02 ,  B01J29/74

CPC分类号： C10G65/02 ,  B01J21/066 ,  B01J23/85 ,  B01J23/882 ,  B01J23/883 ,  B01J23/888 ,  B01J29/7484 ,  B01J35/002 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/0009 ,  B01J37/03 ,  C10G45/58 ,  C10G45/60 ,  C10G45/62 ,  C10G45/64 ,  C10G65/043 ,  C10G2300/1022 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2300/302 ,  C10G2300/304 ,  C10G2400/10 ,  C10M101/02 ,  C10M2203/1025 ,  C10M2205/173 ,  C10N2220/026 ,  C10N2220/027 ,  C10N2220/028 ,  C10N2220/031 ,  C10N2230/02 ,  C10N2230/10 ,  C10N2230/43 ,  C10N2240/10 ,  C10N2270/00 ,  C10N2220/022

摘要： A method for producing a lubricant base oil includes contacting feedstock containing normal paraffins having not less than 20 carbon atoms with a first catalyst in the presence of molecular hydrogen to obtain a first produced oil, and contacting the first produced oil with a second catalyst in the presence of molecular hydrogen to obtain a second produced oil. The first catalyst includes a first carrier in which a fraction of an amount of NH3 to be desorbed at 300 to 800° C. based on a total amount of NH3 to be desorbed is 80 to 90% in temperature-programmed desorption of NH3, a first metal selected from metals of Group VI in the periodic table carried on the first carrier, and a second metal selected from metals of Group VIII to Group X in the periodic table carried on the first carrier.

摘要翻译： 一种润滑剂基础油的制造方法，其特征在于，在分子氢存在下，使含有不少于20个碳原子的正链烷烃的原料与第一催化剂接触，得到第一生产油，并将第一生产油与第二催化剂接触 存在分子氢以获得第二产生的油。 第一催化剂包括第一载体，其中在待处理的NH 3的总量的300至800℃下解吸的一部分NH 3的一部分在NH 3的温度程序解吸中为80至90％，a 选自在第一载体上承载的周期表中的VI族的金属的第一种金属和选自第一载体上的周期表中的VIII族至第X族的金属的第二种金属。

公开(公告)号：US07429550B2

公开(公告)日：2008-09-30

申请号：US11567374

申请日：2006-12-06

申请人： Hideshi Iki ,  Kazuaki Hayasaka ,  Kazuo Fukazawa

发明人： Hideshi Iki ,  Kazuaki Hayasaka ,  Kazuo Fukazawa

IPC分类号： B01J21/12 ,  B01J27/18 ,  C10G47/18 ,  C10G47/20 ,  C10G45/12

CPC分类号： C10G49/04 ,  B01J23/85 ,  B01J23/882 ,  B01J23/883 ,  B01J27/182 ,  B01J27/19 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1038 ,  B01J37/0009 ,  B01J37/0203 ,  B01J37/03 ,  C10G49/08

摘要： A hydrogenation catalyst for a hydrocarbon oil, includes an inorganic porous support composed of at least the oxides of aluminum, phosphorus, and silicon, and supporting at least one active metal selected from the metals of Group 8 of the periodic table, at least one active metal selected from the metals of Group 6 of the periodic table, and phosphorus, the phosphorus chemical shift value of the inorganic support determined by 31P-CPMAS-NMR having the peak within the range of 0 to −20 ppm. The catalyst can achieve an extremely high level of hydrogenation wherein the hydrocarbon is decreased in sulfur content to 10 ppm by mass or less and in nitrogen content to 3 ppm by mass or less.

摘要翻译： 用于烃油的氢化催化剂包括至少由铝，磷和硅的氧化物组成的无机多孔载体，并且支持选自元素周期表第8族金属中的至少一种活性金属，至少一种活性 选自元素周期表第6族金属的金属和磷，由POD-NMR-NMR确定的无机载体的磷化学位移值，峰值在0至 - 20 ppm。 催化剂可以实现极高的氢化水平，其中烃的含量降低到10质量ppm以下，氮含量降低到3质量ppm以下。

公开(公告)号：US20070175797A1

公开(公告)日：2007-08-02

申请号：US11626074

申请日：2007-01-23

申请人： Hideshi Iki ,  Kazuaki Hayasaka ,  Shinya Takahashi

发明人： Hideshi Iki ,  Kazuaki Hayasaka ,  Shinya Takahashi

IPC分类号： C10G45/04 ,  C10G45/60 ,  B01J27/00 ,  B01J27/188 ,  B01J27/19 ,  B01J27/182

CPC分类号： C10G45/08 ,  B01J27/19

摘要： The present invention provides a hydrodesulfurization that can attain an extremely high depth of desulfurization to a sulfur content of 10 ppm by mass and maintain such a high desulfurization activity for a long period of time. The catalyst comprises an inorganic porous support containing alumina and phosphorus, at least one active metal selected from the metals of Group 8 of the periodic table, and at least one metal selected from the metals of Group 6A of the periodic table, the Group 8 metal and the Group 6A metal being contained in a molar ratio defined by (oxide of the Group 8 metal)/(oxide of the Group 6A metal) ranging from 0.055 to 0.150, and the content of the Group 6A metal in terms of oxide being in the range of 30 to 40 percent by mass based on the mass of the catalyst.

摘要翻译： 本发明提供一种能够达到非常高的脱硫深度至硫酸含量为10质量ppm的加氢脱硫，并且长期保持如此高的脱硫活性。 催化剂包括含有氧化铝和磷的无机多孔载体，选自元素周期表第8族金属的至少一种活性金属和选自元素周期表第6A族金属中的至少一种金属，第8族金属 并且6A族金属以（由第8族金属的氧化物）/（6A族金属的氧化物）定义的摩尔比包含在0.055〜0.150的范围内，6A族金属的含量以氧化物为单位 相对于催化剂的质量为30〜40质量％的范围。

公开(公告)号：US20130008827A1

公开(公告)日：2013-01-10

申请号：US13636182

申请日：2011-03-24

申请人： Yoshiyuki Nagayasu ,  Kazuaki Hayasaka ,  Hideki Ono ,  Takaya Matsumoto

发明人： Yoshiyuki Nagayasu ,  Kazuaki Hayasaka ,  Hideki Ono ,  Takaya Matsumoto

IPC分类号： B01J29/74 ,  C10G49/00 ,  C10G65/02

CPC分类号： C10G45/64 ,  B01J29/7461 ,  B01J29/7484 ,  B01J29/7492 ,  B01J29/7661 ,  B01J29/7684 ,  B01J29/7692 ,  B01J29/7861 ,  B01J29/7884 ,  B01J29/7892 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/18 ,  B01J37/30 ,  B01J2229/20 ,  B01J2229/42 ,  C07C5/2708 ,  C07C5/2775 ,  C10G45/62 ,  C10G65/043 ,  C10G2300/1022 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/1081 ,  C10G2300/30 ,  C10G2300/70 ,  C10G2400/10

摘要： The hydroisomerization catalyst of the present invention is a catalyst used for hydroisomerization of a hydrocarbon, including a support including a calcined zeolite modified with at least one metal selected from the group consisting of Na, K, Cs, Mg, Ca, Ba, and K, and having a thermal history that includes heating at 350° C. or more, and at least one inorganic oxide selected from the group consisting of alumina, silica, titania, boria, zirconia, magnesia, ceria, zinc oxide, phosphorus oxide, and a composite oxide containing a combination of at least two or more of these oxides; and at least one metal supported on the support and selected from the group consisting of elements belonging to Groups 8 to 10 of the periodic table, molybdenum and tungsten.

摘要翻译： 本发明的加氢异构化催化剂是用于烃的加氢异构化的催化剂，包括含有由选自Na，K，Cs，Mg，Ca，Ba和K中的至少一种金属改性的煅烧沸石的载体 并且具有包括在350℃以上的加热的热历史，以及选自氧化铝，二氧化硅，二氧化钛，氧化硼，氧化锆，氧化镁，二氧化铈，氧化锌，氧化磷和氧化铝中的至少一种无机氧化物 包含这些氧化物中的至少两种以上的组合的复合氧化物; 以及至少一种负载在载体上并选自元素周期表第8至10族的元素，钼和钨的金属。

公开(公告)号：US09598650B2

公开(公告)日：2017-03-21

申请号：US13636182

申请日：2011-03-24

申请人： Yoshiyuki Nagayasu ,  Kazuaki Hayasaka ,  Hideki Ono ,  Takaya Matsumoto

发明人： Yoshiyuki Nagayasu ,  Kazuaki Hayasaka ,  Hideki Ono ,  Takaya Matsumoto

IPC分类号： B01J29/06 ,  C10G45/00 ,  C07C5/27 ,  C10G45/64 ,  C10G45/62 ,  C10G65/04 ,  B01J29/76 ,  B01J29/78 ,  B01J29/74 ,  B01J37/02 ,  B01J37/18 ,  B01J37/30 ,  B01J37/00

摘要： The hydroisomerization catalyst of the present invention is a catalyst used for hydroisomerization of a hydrocarbon, including a support including a calcined zeolite modified with at least one metal selected from the group consisting of Na, K, Cs, Mg, Ca, Ba, and K, and having a thermal history that includes heating at 350° C. or more, and at least one inorganic oxide selected from the group consisting of alumina, silica, titania, boria, zirconia, magnesia, ceria, zinc oxide, phosphorus oxide, and a composite oxide containing a combination of at least two or more of these oxides; and at least one metal supported on the support and selected from the group consisting of elements belonging to Groups 8 to 10 of the periodic table, molybdenum and tungsten.

公开(公告)号：US09458387B2

公开(公告)日：2016-10-04

申请号：US14007396

申请日：2012-03-14

申请人： Yoshiyuki Nagayasu ,  Hideki Ono ,  Kazuaki Hayasaka ,  Mayumi Yokoi

发明人： Yoshiyuki Nagayasu ,  Hideki Ono ,  Kazuaki Hayasaka ,  Mayumi Yokoi

IPC分类号： B01J21/00 ,  C07C27/00 ,  C10G2/00 ,  B01J21/06 ,  B01J23/00 ,  B01J23/75 ,  B01J35/00 ,  B01J37/18 ,  B01J21/08

CPC分类号： C10G2/332 ,  B01J21/066 ,  B01J21/08 ,  B01J23/005 ,  B01J23/75 ,  B01J35/002 ,  B01J37/18

摘要： A Fischer-Tropsch synthesis reaction catalyst includes a catalyst support containing a silica and zirconium oxide in an amount of 0.5 to 14% by mass based on the mass of the catalyst support, and cobalt metal and a cobalt oxide supported on the catalyst support in an amount equivalent to 10 to 40% by mass of tricobalt tetroxide based on the mass of the catalyst, wherein the degree of reduction of the cobalt atoms is within a range from 75 to 93%, and the amount of hydrogen gas adsorption per unit mass of the catalyst at 100° C. is within a range from 0.40 to 1.0 ml/g.

摘要翻译： 费 - 托合成反应催化剂包括基于催化剂载体的质量含有0.5至14质量％的二氧化硅和氧化锆的催化剂载体，以及负载在催化剂载体上的钴金属和氧化钴 相对于催化剂的质量，相当于四氧化四铁的10〜40质量％，钴原子的还原度为75〜93％，每单位质量的氢气吸附量 在100℃下的催化剂在0.40至1.0ml / g的范围内。

公开(公告)号：US20140018454A1

公开(公告)日：2014-01-16

申请号：US14007396

申请日：2012-03-14

申请人： Yoshiyuki Nagayasu ,  Hideki Ono ,  Kazuaki Hayasaka ,  Mayumi Yokoi

发明人： Yoshiyuki Nagayasu ,  Hideki Ono ,  Kazuaki Hayasaka ,  Mayumi Yokoi

IPC分类号： C10G2/00 ,  B01J23/75

CPC分类号： C10G2/332 ,  B01J21/066 ,  B01J21/08 ,  B01J23/005 ,  B01J23/75 ,  B01J35/002 ,  B01J37/18

摘要： A Fischer-Tropsch synthesis reaction catalyst includes a catalyst support containing a silica and zirconium oxide in an amount of 0.5 to 14% by mass based on the mass of the catalyst support, and cobalt metal and a cobalt oxide supported on the catalyst support in an amount equivalent to 10 to 40% by mass of tricobalt tetroxide based on the mass of the catalyst, wherein the degree of reduction of the cobalt atoms is within a range from 75 to 93%, and the amount of hydrogen gas adsorption per unit mass of the catalyst at 100° C. is within a range from 0.40 to 1.0 ml/g.

摘要翻译： 费 - 托合成反应催化剂包括基于催化剂载体的质量含有0.5至14质量％的二氧化硅和氧化锆的催化剂载体，以及负载在催化剂载体上的钴金属和氧化钴 相对于催化剂的质量，相当于四氧化四铁的10〜40质量％，钴原子的还原度为75〜93％，每单位质量的氢气吸附量 在100℃下的催化剂在0.40至1.0ml / g的范围内。