公开(公告)号：US5538812A

公开(公告)日：1996-07-23

申请号：US406293

申请日：1995-03-17

申请人： Hung-Sui Lee ,  Lin Geng ,  Terje A. Skotheim

发明人： Hung-Sui Lee ,  Lin Geng ,  Terje A. Skotheim

IPC分类号： C07C317/22 ,  C07C323/20 ,  C07D207/36 ,  C07F1/02 ,  C07F7/18 ,  C08L83/08 ,  C08L83/14 ,  C08L101/02 ,  H01B1/12 ,  H01M10/052 ,  H01M10/0565 ,  H01M10/0568 ,  H01M10/40

CPC分类号： H01M10/0568 ,  C07C317/22 ,  C07D207/36 ,  H01B1/122 ,  H01M10/052 ,  H01M10/0565

摘要： The present invention relates to metal ion salts which can be used in electrolytes for producing electrochemical devices, including both primary and secondary batteries, photoelectrochemical cells and electrochromic displays. The salts have a low energy of dissociation and may be dissolved in a suitable polymer to produce a polymer solid electrolyte or in a polar aprotic liquid solvent to produce a liquid electrolyte. The anion of the salts may be covalently attached to polymer backbones to produce polymer solid electrolytes with exclusive cation conductivity.

摘要翻译： 本发明涉及可用于生产电化学装置的电解质中的金属离子盐，包括一次电池和二次电池，光电化学电池和电致变色显示器。 该盐具有低的解离能，并且可以溶解在合适的聚合物中以产生聚合物固体电解质或在极性非质子液体溶剂中以产生液体电解质。 盐的阴离子可以共价连接到聚合物主链上以产生具有独特阳离子导电性的聚合物固体电解质。

公开(公告)号：US20100104948A1

公开(公告)日：2010-04-29

申请号：US12180379

申请日：2008-07-25

申请人： Terje A. Skotheim ,  Christopher J. Sheehan ,  Yuriy V. Mikhaylik ,  John Affinito

发明人： Terje A. Skotheim ,  Christopher J. Sheehan ,  Yuriy V. Mikhaylik ,  John Affinito

IPC分类号： H01M6/18 ,  H01M6/04 ,  H01M4/36 ,  H01M4/58 ,  H01M4/04

CPC分类号： H01M10/0562 ,  H01M4/02 ,  H01M4/13 ,  H01M4/366 ,  H01M4/38 ,  H01M4/385 ,  H01M4/66 ,  H01M4/661 ,  H01M10/052 ,  H01M10/36 ,  H01M10/4235 ,  H01M2004/021 ,  H01M2004/027 ,  H01M2300/0002 ,  H01M2300/0091

摘要： Provided is an anode for use in electrochemical cells, wherein the anode active layer has a first layer comprising lithium metal and a multi-layer structure comprising single ion conducting layers and polymer layers in contact with the first layer comprising lithium metal or in contact with an intermediate protective layer, such as a temporary protective metal layer, on the surface of the lithium-containing first layer. Another aspect of the invention provides an anode active layer formed by the in-situ deposition of lithium vapor and a reactive gas. The anodes of the current invention are particularly useful in electrochemical cells comprising sulfur-containing cathode active materials, such as elemental sulfur.

摘要翻译： 提供一种用于电化学电池的阳极，其中阳极活性层具有包括锂金属的第一层和包含单一离子传导层和与包含锂金属的第一层接触的聚合物层的多层结构或与 中间保护层，例如临时保护金属层，在含锂的第一层的表面上。 本发明的另一方面提供了通过锂蒸气和反应性气体的原位沉积形成的阳极活性层。 本发明的阳极在包含含硫阴极活性材料如元素硫的电化学电池中特别有用。

公开(公告)号：US06410182B1

公开(公告)日：2002-06-25

申请号：US09641539

申请日：2000-08-18

申请人： Qicong Ying ,  Steven A. Carlson ,  Terje A. Skotheim

发明人： Qicong Ying ,  Steven A. Carlson ,  Terje A. Skotheim

IPC分类号： H01M214

CPC分类号： H01M10/05 ,  H01G11/52 ,  H01M2/16 ,  H01M2/1646 ,  H01M2/1653 ,  H01M2/166 ,  H01M2/1686 ,  H01M6/16 ,  H01M10/052 ,  H01M10/056 ,  H01M10/0585 ,  H01M2300/0094 ,  Y02E60/13

摘要： This invention pertains to separators for electrochemical cells which comprise (i) a microporous pseudo-boehmite layer and (ii) a protective coating layer comprising a polymer; electrolyte elements comprising such separators; electrical current producing cells comprising such separators; and methods of making such separators, electrolyte elements and cells.

摘要翻译： 本发明涉及用于电化学电池的隔板，其包括（i）微孔假勃姆石层和（ii）包含聚合物的保护涂层; 包括这种分离器的电解质元件; 包括这种分离器的电流产生电池; 以及制造这种分离器，电解质元件和电池的方法。

公开(公告)号：US5089112A

公开(公告)日：1992-02-18

申请号：US463540

申请日：1990-01-11

申请人： Terje A. Skotheim ,  Yoshiyuki Okamoto ,  Paul D. Hale

发明人： Terje A. Skotheim ,  Yoshiyuki Okamoto ,  Paul D. Hale

IPC分类号： C12Q1/00 ,  G01N27/416

CPC分类号： C12Q1/004 ,  Y10S435/817

摘要： The present invention relates to an electrochemical enzyme biosensor for use in liquid mixtures of components for detecting the presence of, or measuring the amount of, one or more select components. The enzyme electrode of the present invention is comprised of an enzyme, an artificial redox compound covalently bound to a flexible polymer backbone and an electron collector.

摘要翻译： 本发明涉及用于检测一种或多种选择组分的存在或测量量的组分的液体混合物中的电化学酶生物传感器。 本发明的酶电极由酶，与弹性聚合物骨架共价结合的人造氧化还原化合物和电子收集体构成。

公开(公告)号：US4190950A

公开(公告)日：1980-03-04

申请号：US889688

申请日：1978-03-24

申请人： Terje A. Skotheim

发明人： Terje A. Skotheim

IPC分类号： H01L31/07 ,  B01J17/00

CPC分类号： H01L31/07 ,  H01L51/4226 ,  Y02E10/542 ,  Y02E10/549

摘要： A low-cost dye-sensitized Schottky barrier solar cell comprised of a substrate of semiconductor with an ohmic contact on one face, a sensitizing dye adsorbed onto the opposite face of the semiconductor, a transparent thin-film layer of a reducing agent over the dye, and a thin-film layer of metal over the reducing agent. The ohmic contact and metal layer constitute electrodes for connection to an external circuit and one or the other or both are made transparent to permit light to penetrate to the dye and be absorbed therein for generating electric current. The semiconductor material chosen to be the substrate is one having a wide bandgap and which therefore is transparent; the dye selected is one having a ground state within the bandgap of the semiconductor to generate carriers in the semiconductor, and a first excited state above the conduction band edge of the semiconductor to readily conduct electrons from the dye to the semiconductor; the reducing agent selected is one having a ground state above the ground state of the sensitizer to provide a plentiful source of electrons to the dye during current generation and thereby enhance the generation; and the metal for the thin-film layer of metal is selected to have a Fermi level in the vicinity of or above the ground state of the reducing agent to thereby amply supply electrons to the reducing agent.

摘要翻译： 一种低成本染料敏化肖特基势垒太阳能电池，由一面上具有欧姆接触的半导体衬底，吸附在半导体的相对面上的敏化染料，在染料上的还原剂的透明薄膜层 和还原剂上的金属薄膜层。 欧姆接触和金属层构成用于连接到外部电路的电极，并且一个或另一个或两者均为透明的，以允许光穿透染料并被吸收以产生电流。 选择为基板的半导体材料是具有宽带隙的半导体材料，因此是透明的; 选择的染料是在半导体的带隙内具有基态以在半导体中产生载流子的染料，并且在半导体的导带边缘之上的第一激发态能够容易地将电子从染料导入半导体; 选择的还原剂是具有高于敏化剂的基态的基态的电荷，在电流产生期间向染料提供充足的电子源，从而增强产生; 并且金属薄膜层的金属被选择为在还原剂的基态附近或高于还原剂的基态具有费米能级，从而向还原剂供应电子。

公开(公告)号：US08415054B2

公开(公告)日：2013-04-09

申请号：US11452445

申请日：2006-06-13

申请人： Terje A. Skotheim ,  Christopher J. Sheehan ,  Yuriy V. Mikhaylik ,  John Affinito

发明人： Terje A. Skotheim ,  Christopher J. Sheehan ,  Yuriy V. Mikhaylik ,  John Affinito

IPC分类号： H01M2/16

CPC分类号： H01M4/628 ,  H01M2/1673 ,  H01M4/04 ,  H01M4/0404 ,  H01M4/0421 ,  H01M4/0426 ,  H01M4/134 ,  H01M4/136 ,  H01M4/1395 ,  H01M4/366 ,  H01M4/38 ,  H01M4/382 ,  H01M4/387 ,  H01M4/581 ,  H01M4/5815 ,  H01M4/625 ,  H01M6/14 ,  H01M6/18 ,  H01M6/40 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/056 ,  H01M10/0585 ,  H01M10/4235 ,  H01M2004/021 ,  H01M2004/027 ,  H01M2220/30 ,  Y02E60/122 ,  Y02P70/54

摘要： Provided is an anode for use in electrochemical cells, wherein the anode active layer has a first layer comprising lithium metal and a multi-layer structure comprising single ion conducting layers and polymer layers in contact with the first layer comprising lithium metal or in contact with an intermediate protective layer, such as a temporary protective metal layer, on the surface of the lithium-containing first layer. Another aspect of the invention provides an anode active layer formed by the in-situ deposition of lithium vapor and a reactive gas. The anodes of the current invention are particularly useful in electrochemical cells comprising sulfur-containing cathode active materials, such as elemental sulfur.

公开(公告)号：US06936382B2

公开(公告)日：2005-08-30

申请号：US10390516

申请日：2003-03-17

申请人： Yuriy V. Mikhaylik ,  Terje A. Skotheim ,  Boris A. Trofimov

发明人： Yuriy V. Mikhaylik ,  Terje A. Skotheim ,  Boris A. Trofimov

IPC分类号： H01M6/16 ,  B41J2/365 ,  H01M4/06 ,  H01M4/134 ,  H01M4/136 ,  H01M4/38 ,  H01M4/40 ,  H01M4/58 ,  H01M4/60 ,  H01M10/052 ,  H01M10/0567 ,  H01M10/36 ,  H01M10/42 ,  H01M10/40

CPC分类号： H01M10/4235 ,  B41J2/3555 ,  B41J2/365 ,  H01M4/134 ,  H01M4/136 ,  H01M4/38 ,  H01M4/5815 ,  H01M4/60 ,  H01M4/602 ,  H01M6/168 ,  H01M10/052 ,  H01M10/0567 ,  Y10T29/49108

摘要： Provided is a lithium battery in which the cathode comprises an electroactive sulfur-containing material and the electrolyte comprises a lithium salt, a non-aqueous solvent, and one or more capacity-enhancing reactive components. Suitable reactive components include electron transfer mediators. Also are provided methods for making the lithium battery.

摘要翻译： 提供了一种锂电池，其中阴极包含电活性含硫材料，电解质包含锂盐，非水溶剂和一种或多种增强能量的反应性组分。 合适的反应性组分包括电子转移介质。 还提供了制造锂电池的方法。

公开(公告)号：US06406814B1

公开(公告)日：2002-06-18

申请号：US09703348

申请日：2000-10-31

申请人： Alexander Gorkovenko ,  Terje A. Skotheim ,  Zhe-Sheng Xu ,  Leonid I. Boguslavsky ,  Zhongyi Deng ,  Shyama P. Mukherjee

发明人： Alexander Gorkovenko ,  Terje A. Skotheim ,  Zhe-Sheng Xu ,  Leonid I. Boguslavsky ,  Zhongyi Deng ,  Shyama P. Mukherjee

IPC分类号： H01M404

CPC分类号： H01M4/136 ,  H01M4/0485 ,  H01M4/137 ,  H01M4/36 ,  H01M4/40 ,  H01M4/581 ,  H01M4/5815 ,  H01M4/583 ,  H01M4/587 ,  H01M4/60 ,  H01M4/602 ,  H01M4/62 ,  H01M4/622 ,  H01M4/623 ,  H01M4/624 ,  H01M10/052 ,  H01M10/3909 ,  H01M2004/027 ,  H01M2004/028 ,  Y10S977/753 ,  Y10S977/948 ,  Y10T29/49108

摘要： The present invention pertains to solid composite cathodes which comprise (a) an electroactive sulfur-containing cathode material which, in its oxidized state, comprises a polysulfide moiety of the formula, —Sm—, wherein m is an integer from 3 to 10; and (b) a non-electroactive particulate material having a strong adsorption of soluble polysulfides. The present invention also pertains to electric current producing cells comprising such solid composite cathodes, and methods of making such solid composite cathodes and electric current producing cells.

摘要翻译： 本发明涉及固体复合阴极，其包含（a）电活性含硫阴极材料，其在其氧化态中包含下式的多硫化物部分-Sm-，其中m为3至10的整数; 和（b）具有强吸附可溶性多硫化物的非电活性颗粒材料。 本发明还涉及包含这种固体复合阴极的电流产生电池，以及制备这种固体复合阴极和电流产生电池的方法。

公开(公告)号：US06306545B1

公开(公告)日：2001-10-23

申请号：US09215112

申请日：1998-12-17

申请人： Steven A. Carlson ,  Qicong Ying ,  Zhongyi Deng ,  Terje A. Skotheim

发明人： Steven A. Carlson ,  Qicong Ying ,  Zhongyi Deng ,  Terje A. Skotheim

IPC分类号： H01M216

CPC分类号： H01M10/0525 ,  B01D71/025 ,  H01M2/16 ,  H01M2/1646 ,  H01M2/1673 ,  H01M4/136 ,  H01M6/14 ,  H01M10/05 ,  H01M10/052 ,  H01M10/0563 ,  H01M10/0565 ,  H01M2300/0017 ,  H01M2300/0068 ,  Y10T29/49115

摘要： This invention pertains to separators for electrochemical cells which comprise a microporous pseudo-boehmite layer; electrolyte elements comprising such separators; electrical current producing cells comprising such separators; and methods of making such separators, electrolyte elements and cells.

摘要翻译： 本发明涉及包含微孔假勃姆石层的电化学电池隔板; 包括这种分离器的电解质元件; 包括这种分离器的电流产生电池; 以及制造这种分离器，电解质元件和电池的方法。

公开(公告)号：US06277514B1

公开(公告)日：2001-08-21

申请号：US09447901

申请日：1999-11-23

申请人： Qicong Ying ,  Steven A. Carlson ,  Terje A. Skotheim

发明人： Qicong Ying ,  Steven A. Carlson ,  Terje A. Skotheim

IPC分类号： H01M214

CPC分类号： H01M2/166 ,  H01M2/16 ,  H01M2/1646 ,  H01M2/1653 ,  H01M2/1686 ,  H01M6/16 ,  H01M10/052 ,  H01M10/056 ,  H01M10/0585 ,  H01M2300/0094

摘要： This invention pertains to separators for use in electrochemical cells which comprise at least one microporous pseudo-boehmite layer, which separator is in contact with at least one protective coating layer positioned on the anode-facing side of the separator opposite from the cathode active layer in the cell; electrolyte elements comprising such separators; electrical current producing cells comprising such separators; and methods of making such separators, electrolyte elements and cells.

摘要翻译： 本发明涉及用于电化学电池的分离器，其包含至少一个微孔假勃姆石层，该分离器与位于与阴极活性层相对的隔板的面向阳极侧的至少一个保护涂层接触， 细胞; 包括这种分离器的电解质元件; 包括这种分离器的电流产生电池; 以及制造这种分离器，电解质元件和电池的方法。