摘要:
A method for producing a lubricant base oil, the method comprising a first step of fractionating, from a hydrocarbon oil containing a base oil fraction and a heavy fraction that is heavier than the base oil fraction, the base oil fraction and the heavy fraction, and a second step of obtaining a dewaxed oil by isomerization and dewaxing of the base oil fraction fractionated in the first step, wherein a hydrocracked oil obtained by hydrocracking the heavy fraction fractionated in the first step is returned to the first step.
摘要:
A method for producing a lubricating base oil, comprising: performing a 13C-NMR analysis regarding an oil to be treated and selecting the oil based on a value for dividing an integrated value of a peak for a tertiary carbon atom by an integrated value of all peaks at 0 to 50 ppm, a value for dividing an integrated value of a peak for a carbon atom constituting a main chain by the integrated value of all peaks at 0 to 50 ppm, and a value for dividing an integrated value of a peak for a branched CH3 bonded to a fifth or the following carbon atom from a terminal carbon atom in the main chain by an integrated value of all peaks at 10 to 25 ppm, and obtaining a dewaxed oil by isomerization dewaxing of the oil selected in the first step, is disclosed.
摘要:
A process for producing a Fischer-Tropsch synthesis catalyst according to the present invention comprises a step of calcining a carrier precursor containing silica calcined at a temperature T1 and a zirconium compound at a temperature T2 to obtain a carrier; and a step of calcining a catalyst precursor containing the carrier and a cobalt compound and/or a ruthenium compound at a temperature T3, wherein the content of the zirconium compound in the carrier precursor is 0.01 to 7% by mass in terms of zirconium oxide based on the total mass of the catalyst, and T1, T2, and T3 satisfy conditions represented by expressions (1) to (3): T1≧T3 (1) 250° C.≦T2≦450° C. (2) 250° C.≦T3≦450° C. (3).
摘要:
A method for producing a lubricant base oil which comprises a first step of carrying out isomerization dewaxing by contacting, in the presence of hydrogen, a hydrocarbon oil containing normal paraffin having a boiling point of 360° C. or higher, with a hydroisomerization catalyst under conditions such that a cracking rate defined in the following formula (1) is 10 mass % or less, and a second step of carrying out the above isomerization dewaxing by temporarily switching the above conditions to conditions such that the cracking rate is 13 mass % or more. Cracking rate (mass %)=[(C1−C2)/C1]×100 (1) wherein C1 represents the mass ratio of a fraction having a boiling point of 360° C. or higher in the above hydrocarbon oil, and C2 represents the mass ratio of the fraction having a boiling point of 360° C. or higher in the above hydrocarbon oil after the isomerization dewaxing.
摘要:
A method for producing a lubricant base oil, the method comprising a first step of fractionating, from a hydrocarbon oil containing a base oil fraction and a heavy fraction that is heavier than the base oil fraction, the base oil fraction and the heavy fraction, and a second step of obtaining a dewaxed oil by isomerization and dewaxing of the base oil fraction fractionated in the first step, wherein a hydrocracked oil obtained by hydrocracking the heavy fraction fractionated in the first step is returned to the first step.
摘要:
A method for producing a hydroisomerization catalyst includes a first step of preparing a support precursor by heating a mixture containing an ion-exchanged zeolite and a binder, the ion-exchanged zeolite being prepared by ion-exchanging an organic template-containing zeolite which contains an organic template and has a one-dimensional pore structure including a 10-membered ring in a solution containing ammonium ions and/or protons, at a temperature of 250 to 350° C. under N2 atmosphere, and a second step of preparing a hydroisomerization catalyst, which is prepared by calcining a catalyst precursor, the catalyst precursor being prepared based on the support precursor containing a platinum salt and/or a palladium salt, at a temperature of 350 to 400° C. in an atmosphere containing molecular oxygen, the hydroisomerization catalyst containing a support which includes a zeolite and carries platinum and/or palladium.
摘要:
A method for producing a hydroisomerization catalyst includes a first step of preparing a support precursor by heating a mixture containing an ion-exchanged zeolite and a binder, the ion-exchanged zeolite being prepared by ion-exchanging an organic template-containing zeolite which contains an organic template and has a one-dimensional pore structure including a 10-membered ring in a solution containing ammonium ions and/or protons, at a temperature of 250 to 350° C. under N2 atmosphere, and a second step of preparing a hydroisomerization catalyst, which is prepared by calcining a catalyst precursor, the catalyst precursor being prepared based on the support precursor containing a platinum salt and/or a palladium salt, at a temperature of 350 to 400° C. in an atmosphere containing molecular oxygen, the hydroisomerization catalyst containing a support which includes a zeolite and carries platinum and/or palladium.
摘要:
A method for producing a lubricant base oil which comprises a first step of carrying out isomerization dewaxing by contacting, in the presence of hydrogen, a hydrocarbon oil containing normal paraffin having a boiling point of 360° C. or higher, with a hydroisomerization catalyst under conditions such that a cracking rate defined in the following formula (1) is 10 mass % or less, and a second step of carrying out the above isomerization dewaxing by temporarily switching the above conditions to conditions such that the cracking rate is 13 mass % or more. Cracking rate (mass %)=[(C1−C2)/C1]×100 (1) wherein C1 represents the mass ratio of a fraction having a boiling point of 360° C. or higher in the above hydrocarbon oil, and C2 represents the mass ratio of the fraction having a boiling point of 360° C. or higher in the above hydrocarbon oil after the isomerization dewaxing.