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公开(公告)号：US09604203B2
公开(公告)日：2017-03-28
申请号：US13235858
申请日：2011-09-19
CPC分类号： B01J29/126 , B01J37/0009 , B01J37/10 , B01J2229/16 , B01J2229/20 , B01J2229/36 , B01J2229/42 , C10G35/065 , C10G35/085 , C10G35/09
摘要： Process for the preparation of a catalyst suitable for use in a naphtha reforming process, the process including providing a Y zeolite with an initial SiO2:Al2O3 molar ratio of at least 150, introducing the Y zeolite to a binder to form an intermediate composition, extruding the intermediate composition, reducing the alpha acidity of the extruded composition to provide a low acid composition, and introducing a noble metal to the low acid composition. Processes and systems of converting naphtha to a higher-octane hydrocarbon supply using catalysts, as prepared herein, are also disclosed.
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公开(公告)号：US08546286B2
公开(公告)日：2013-10-01
申请号：US12653511
申请日：2009-12-15
CPC分类号： B01J37/0205 , B01J23/42 , B01J23/44 , B01J29/0325 , B01J29/043 , B01J29/068 , B01J37/0201 , B01J37/0207 , B01J37/088 , B01J37/10 , B01J37/18 , B01J37/28 , B01J2229/18 , B01J2229/186 , B01J2229/20 , B01J2229/36 , B01J2229/37 , B01J2229/42 , C10G45/54 , C10G2300/1096
摘要： In a process for producing a metal containing catalyst composition suitable for effecting hydrocarbon hydrogenation and/or dehydrogenation reactions, a catalyst support comprising a porous crystalline material combined with an amorphous binder is treated with an anchoring material capable of bonding to the surface of the support and to a metal component. In addition, a precursor to the metal component is deposited on the surface of the catalyst support and then the treated catalyst support having the precursor deposited thereon is subjected to conditions effective to convert the precursor to the metal component and to cause the anchoring material to bond to the surface of the support and to the metal component.
摘要翻译： 在适用于进行烃氢化和/或脱氢反应的含金属催化剂组合物的制备方法中，将包含与无定形粘合剂结合的多孔结晶材料的催化剂载体用能够粘合到载体表面的锚定材料进行处理， 到金属部件。 另外，金属组分的前体沉积在催化剂载体的表面上，然后将其上沉积有前体的经处理的催化剂载体进行有效地将前体转化为金属组分并使锚定材料结合 到支撑体的表面和金属部件。
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公开(公告)号：US07553790B2
公开(公告)日：2009-06-30
申请号：US11258440
申请日：2005-10-25
申请人： Jean W. Beeckman , Glenn R. Sweeten , Daria N. Lissy , David L. Stern , Stephen J. McCarthy , Dominick N. Mazzone , Christine N. Elia
发明人： Jean W. Beeckman , Glenn R. Sweeten , Daria N. Lissy , David L. Stern , Stephen J. McCarthy , Dominick N. Mazzone , Christine N. Elia
IPC分类号： B01J29/06
CPC分类号： B01J29/40 , B01J2229/42
摘要： The present invention describes a method to increase the activity of a catalyst by first performing an ion exchange step with a potassium ion, followed by performing an ion-exchange step with an ammonium ion. Specifically, the present invention describes a method to increase the acidity of a zeolite by incorporating a potassium salt ion-exchange prior to an ammonium salt ion-exchange step. Even more specifically, the present invention is drawn to a method of increasing the activity of a zeolite by employing more than one potassium ion exchanges followed by at least one ammonium ion exchange. The present invention also describes a method to reduce the amount of sodium normally found in commercially produced zeolite by employing any of these methods. The present invention is also drawn to the catalysts produced by any of these methods.
摘要翻译： 本发明描述了通过首先用钾离子进行离子交换步骤，然后用铵离子进行离子交换步骤来提高催化剂活性的方法。 具体地，本发明描述了通过在铵盐离子交换步骤之前引入钾盐离子交换来提高沸石的酸度的方法。 更具体地说，本发明涉及通过使用多于一种的钾离子交换，然后进行至少一种铵离子交换来提高沸石的活性的方法。 本发明还描述了一种通过使用任何这些方法来减少通常在商业生产的沸石中发现的钠的量的方法。 本发明还涉及通过任何这些方法制备的催化剂。
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公开(公告)号：US07686949B2
公开(公告)日：2010-03-30
申请号：US11205606
申请日：2005-08-17
申请人： Stephen J. McCarthy , Jean W. Beeckman , Sylvain S. Hantzer , Geoffrey L. Woolery , Glenn R. Sweeten
发明人： Stephen J. McCarthy , Jean W. Beeckman , Sylvain S. Hantzer , Geoffrey L. Woolery , Glenn R. Sweeten
IPC分类号： C07C5/10
CPC分类号： B01J29/043 , B01J29/0308 , B01J29/0325 , B01J29/041 , B01J2229/20 , B01J2229/42 , C07C5/10 , C07C2521/04 , C10G45/62 , C10G45/64 , C10G65/08 , C10G2400/10
摘要： An improved hydrotreating process for use with lube oil boiling range feedstreams utilizing a catalyst comprising a hydrogenation-dehydrogenation component selected from the Group VIII noble metals and mixtures thereof, a mesoporous support, and a binder.
摘要翻译： 改进的加氢处理方法，其利用含有选自第VIII族贵金属及其混合物的氢化 - 脱氢组分的催化剂，中孔载体和粘合剂，用于润滑油沸程进料流。
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公开(公告)号：US07407909B2
公开(公告)日：2008-08-05
申请号：US11228366
申请日：2005-09-16
CPC分类号： B01J29/0325 , B01J23/40 , B01J29/043 , B01J29/064 , B01J35/0013 , B01J35/002 , B01J35/0066 , B01J37/06 , B01J37/14 , B01J37/18 , B01J37/20
摘要： A method of ex-situ activation and dry passivation of supported noble metal catalysts including the steps of reducing in the presence of hydrogen and dry passivation by cooling in an inert atmosphere and exposing to air or by filling the pores of the catalyst with a low sulfur oil before exposing to air.
摘要翻译： 一种负载型贵金属催化剂的原位活化和干法钝化的方法，包括以下步骤：在惰性气氛中冷却并通过在惰性气氛中冷却并且暴露于空气或通过用低硫填充催化剂的孔来减少氢气和干燥钝化 油在暴露于空气之前。
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公开(公告)号：US20110139685A1
公开(公告)日：2011-06-16
申请号：US12653511
申请日：2009-12-15
IPC分类号： C10G45/54 , B01J29/068
CPC分类号： B01J37/0205 , B01J23/42 , B01J23/44 , B01J29/0325 , B01J29/043 , B01J29/068 , B01J37/0201 , B01J37/0207 , B01J37/088 , B01J37/10 , B01J37/18 , B01J37/28 , B01J2229/18 , B01J2229/186 , B01J2229/20 , B01J2229/36 , B01J2229/37 , B01J2229/42 , C10G45/54 , C10G2300/1096
摘要： In a process for producing a metal containing catalyst composition suitable for effecting hydrocarbon hydrogenation and/or dehydrogenation reactions, a catalyst support comprising a porous crystalline material combined with an amorphous binder is treated with an anchoring material capable of bonding to the surface of the support and to a metal component. In addition, a precursor to the metal component is deposited on the surface of the catalyst support and then the treated catalyst support having the precursor deposited thereon is subjected to conditions effective to convert the precursor to the metal component and to cause the anchoring material to bond to the surface of the support and to the metal component.
摘要翻译： 在适用于进行烃氢化和/或脱氢反应的含金属催化剂组合物的制备方法中，将包含与无定形粘合剂结合的多孔结晶材料的催化剂载体用能够粘合到载体表面的锚定材料进行处理， 到金属部件。 另外，金属组分的前体沉积在催化剂载体的表面上，然后将其上沉积有前体的经处理的催化剂载体进行有效地将前体转化为金属组分并使锚定材料结合 到支撑体的表面和金属部件。
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公开(公告)号：US09174206B2
公开(公告)日：2015-11-03
申请号：US12587288
申请日：2009-10-05
申请人： Jean W. Beeckman , Stephen J. McCarthy , Chuansheng Bai , William G. Borghard , Sanket K. Desai , Hyung S. Woo
发明人： Jean W. Beeckman , Stephen J. McCarthy , Chuansheng Bai , William G. Borghard , Sanket K. Desai , Hyung S. Woo
IPC分类号： B01J31/16 , B01J31/04 , B01J23/85 , B01J23/882 , B01J23/883 , B01J31/18 , B01J31/22 , B01J35/10 , B01J37/00 , B01J37/04 , B01J37/08 , B01J37/20 , C10G45/08 , B01J35/00
CPC分类号： B01J31/04 , B01J23/85 , B01J23/882 , B01J23/883 , B01J31/1805 , B01J31/2234 , B01J31/2239 , B01J35/002 , B01J35/1009 , B01J35/1014 , B01J37/0009 , B01J37/04 , B01J37/084 , B01J37/20 , B01J2231/64 , B01J2531/64 , B01J2531/66 , B01J2531/845 , B01J2531/847 , C10G45/08
摘要： Bulk catalysts that include a Group VI metal, a Group VIII metal, and at least 10-60% of an organic compound based component are formed. The bulk catalysts have increased stability through the use of a stabilizer in the organic compound based component, the use of an improved gas phase sulfidation, or a combination thereof. The bulk catalysts are suitable for hydroprocessing of hydrocarbon feeds.
摘要翻译： 形成包括第Ⅵ族金属，第Ⅷ族金属和至少10-60％有机化合物基成分的散装催化剂。 本体催化剂通过在基于有机化合物的组分中使用稳定剂，使用改进的气相硫化或其组合来提高稳定性。 本体催化剂适用于烃进料的加氢处理。
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公开(公告)号：US20100093522A1
公开(公告)日：2010-04-15
申请号：US12587288
申请日：2009-10-05
申请人： Jean W. Beeckman , Stephen J. McCarthy , Chuansheng Bai , William G. Borghard , Sanket K. Desai , Hyung S. Woo
发明人： Jean W. Beeckman , Stephen J. McCarthy , Chuansheng Bai , William G. Borghard , Sanket K. Desai , Hyung S. Woo
IPC分类号： B01J21/18 , B01J27/049 , B01J23/24
CPC分类号： B01J31/04 , B01J23/85 , B01J23/882 , B01J23/883 , B01J31/1805 , B01J31/2234 , B01J31/2239 , B01J35/002 , B01J35/1009 , B01J35/1014 , B01J37/0009 , B01J37/04 , B01J37/084 , B01J37/20 , B01J2231/64 , B01J2531/64 , B01J2531/66 , B01J2531/845 , B01J2531/847 , C10G45/08
摘要： Bulk catalysts that include a Group VI metal, a Group VIII metal, and at least 10-60% of an organic compound based component are formed. The bulk catalysts have increased stability through the use of a stabilizer in the organic compound based component, the use of an improved gas phase sulfidation, or a combination thereof. The bulk catalysts are suitable for hydroprocessing of hydrocarbon feeds.
摘要翻译： 形成包括第Ⅵ族金属，第Ⅷ族金属和至少10-60％有机化合物基成分的散装催化剂。 本体催化剂通过在基于有机化合物的组分中使用稳定剂，使用改进的气相硫化或其组合来提高稳定性。 本体催化剂适用于烃进料的加氢处理。
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9.发明授权Process to hydrogenate aromatics present in lube oil boiling range feedstreams 有权氢化存在于润滑油沸腾范围的原料流中的芳烃的方法公开(公告)号：US07682502B2
公开(公告)日：2010-03-23
申请号：US11205642
申请日：2005-08-17
CPC分类号： B01J29/043 , B01J29/0325 , B01J2229/42 , C10G45/52 , C10G2400/10
摘要： An improved hydrogenation process for lube oil boiling range feedstreams utilizing a catalyst comprising at least one Group VIII noble metal selected from Pt, Pd, and mixtures thereof having an average pore diameter of about 15 to less than about 40 Å.
摘要翻译： 利用包含平均孔径为约15至小于约的至少一种选自Pt，Pd及其混合物的第Ⅷ族贵金属的催化剂，用于润滑油沸程的进料流的改进的氢化方法。
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公开(公告)号：US20090182183A1
公开(公告)日：2009-07-16
申请号：US12014406
申请日：2008-01-15
申请人： Michael J. Keenan , Ramzi Y. Saleh , James C. Vartuli , Robert C. Lemon , Jean W. Beeckman , Christopher C. Boyer , Mitchell E. Loescher
发明人： Michael J. Keenan , Ramzi Y. Saleh , James C. Vartuli , Robert C. Lemon , Jean W. Beeckman , Christopher C. Boyer , Mitchell E. Loescher
IPC分类号： C07C2/24
CPC分类号： C07C2/10 , C07C2521/06 , C07C2523/30 , Y02P20/52
摘要： A process for the oligomerization of propylene is disclosed wherein a tungstated zirconia catalyst prepared as a distillation structure is used in a reaction distillation zone under conditions of temperature and pressure to concurrently react the propylene to produce oligomers thereof and separate the oligomer products from unreacted propylene by fractional distillation in a distillation column reactor. Compared to the prior art tubular or plug flow reactors, lower temperatures and pressures are used to produce higher conversions and selectivities to preferred isomeric forms useful for preparing neo acids.
摘要翻译： 公开了一种用于丙烯低聚的方法，其中在反应蒸馏区中在温度和压力条件下使用制备为蒸馏结构的钨酸氧化锆催化剂，以同时使丙烯反应生成其低聚物，并将低聚物产物与未反应的丙烯分离 在蒸馏塔反应器中进行分馏。 与现有技术的管状或活塞式流动反应器相比，使用较低的温度和压力来产生较高的转化率和选择性，以用于制备新酸的优选异构形式。
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