公开(公告)号：US5428122A

公开(公告)日：1995-06-27

申请号：US243242

申请日：1994-05-16

申请人： Julio A. Abusleme ,  Patrizia Maccone

发明人： Julio A. Abusleme ,  Patrizia Maccone

IPC分类号： C08F2/22 ,  C08F2/20 ,  C08F2/44 ,  C08F14/18 ,  C08F2/00

CPC分类号： C08F14/18

摘要： Fluorinated olefinic monomers, optionally in association with non-fluorinated olefins, are (co)polymerized in aqueous emulsion in the presence of a hydrophilic solvent and of a fluoropolyoxyalkylene having hydrogenated end groups and/or hydrogenated repetitive units. In this way it is possible to obtain high productivities, close to those obtainable using a hydrophilic solvent and a chlorofluorocarbon.

摘要翻译： 任选与非氟化烯烃缔合的氟化烯烃单体在亲水溶剂和具有氢化端基和/或氢化重复单元的氟聚氧亚烷基的存在下在水乳液中共聚合。 以这种方式，可以获得高生产率，接近可使用亲水性溶剂和氯氟烃获得的那些。

公开(公告)号：US5654263A

公开(公告)日：1997-08-05

申请号：US547331

申请日：1995-10-24

申请人： Julio A. Abusleme ,  Rossella Silvani ,  Patrizia Maccone

发明人： Julio A. Abusleme ,  Rossella Silvani ,  Patrizia Maccone

IPC分类号： B08B3/08 ,  C07C31/12 ,  C07C43/12 ,  C11D1/72 ,  C11D3/20 ,  C11D3/44 ,  C11D7/26 ,  C11D7/28 ,  C11D7/50 ,  C23G5/028 ,  C23G5/032

CPC分类号： C11D7/261 ,  C11D7/5018 ,  C23G5/032 ,  C11D7/28

摘要： Ternary mixtures, particularly suitable for removing oily substances having both an hyrogenated and fluorinated or mixed basis, essentially consisting of: (a) water; (b) terbutanol; (c) a fluoropolyoxyalkylene having hydrogenated end groups and/or hydrogenated repetitive units. Such mixtures have high flash point, are non toxic and with null depleting potential of the ozone and show a ternary diagram characterized by a wide monophasic zone, wherein the three components form limpid and stable solutions.

摘要翻译： 三元混合物，特别适用于除去具有氢化和氟化或混合的基础的油性物质，基本上由以下组成：（a）水; （b）叔丁醇; （c）具有氢化端基和/或氢化重复单元的氟代聚氧化烯。 这样的混合物具有高闪点，无毒，臭氧消耗潜力低，并且显示出以宽单相区为特征的三元图，其中三种组分形成清澈和稳定的溶液。

公开(公告)号：US5516863A

公开(公告)日：1996-05-14

申请号：US516685

申请日：1995-08-18

申请人： Julio A. Abusleme ,  Patrizia Maccone ,  Pasqua Colaianna

发明人： Julio A. Abusleme ,  Patrizia Maccone ,  Pasqua Colaianna

IPC分类号： C08F214/18 ,  C08F2/22 ,  C08F2/24 ,  C08F2/38 ,  C08F14/18 ,  C08F2/00

CPC分类号： C08F14/18 ,  C08F2438/01

摘要： Radical (co)polymerization process of fluorinated olefinic monomers, optionally in association with one or more non-fluorinated olefins, in which the monomers are (co)polymerized in aqueous emulsion, in the presence of a hydrogenated chain transfer agent selected from hydrogen, aliphatic hydrocarbons and fluorohydrocarbons C.sub.1 -C.sub.20 and of a branched chain aliphatic alcohol C.sub.3 -C.sub.12 characterized by a ratio between the number of hydroxyl groups and the number of methyl groups lower than or equal to 0.5.

摘要翻译： 氟化烯烃单体的自由基（共）聚合方法，任选与一种或多种非氟化烯烃缔合，其中单体在水乳液中共聚合，在氢化链转移剂存在下，选自氢，脂族 碳氢化合物和氟代烃C1-C20和支链脂族醇C3-C12，其特征在于羟基数与甲基数之比小于或等于0.5。

公开(公告)号：US5498680A

公开(公告)日：1996-03-12

申请号：US447636

申请日：1995-05-23

申请人： Julio A. Abusleme ,  Patrizia Maccone

发明人： Julio A. Abusleme ,  Patrizia Maccone

IPC分类号： C08F2/22 ,  C08F2/00 ,  C08F2/20 ,  C08F2/44 ,  C08F14/18 ,  C08J3/03

CPC分类号： C08F14/18 ,  C08J3/03 ,  C08J2371/00

摘要： In a process of (co)polymerization in aqueous emulsion of fluorinated olefinic monomers it is added to the reaction medium a microemulsion of fluoropolyoxyalkylenes having hydrogenated end groups and/or hydrogenated repetitive units. A remarkable reduction in the reaction induction period is so obtained, with formation of a product with improved mechanical properties and higher thermal and chemical resistance.

摘要翻译： 在氟化烯烃单体的水性乳液中（共）聚合的过程中，向反应介质中加入具有氢化端基和/或氢化重复单元的氟代聚氧化烯的微乳液。 通过形成具有改进的机械性能和更高的耐热和耐化学性的产品，可以获得反应诱导期的显着减少。

公开(公告)号：US11441007B2

公开(公告)日：2022-09-13

申请号：US14131747

申请日：2012-07-10

申请人： Stefano Mortara ,  Julio A. Abusleme

发明人： Stefano Mortara ,  Julio A. Abusleme

IPC分类号： C08K3/22 ,  C08F214/22 ,  C08F20/06 ,  B29C48/21 ,  C09D127/16 ,  C08F14/22 ,  C08L27/16 ,  B32B27/30 ,  B32B27/36 ,  C08K3/30

摘要： The invention pertains to a composition (C1) comprising: at least one (meth)acrylic modified VDF polymer [polymer (A)] comprising recurring units derived from comprising recurring units derived from vinylidene fluoride (VDF) monomer and at least one hydrophilic (meth)acrylic monomer (MA) of formula (I), wherein each of R1, R2, R3, equal or different from each other, is independently a hydrogen atom or a C1-C3 hydrocarbon group, and ROH is a hydrogen or a C1-C5 hydrocarbon moiety comprising at least one hydroxyl group; at least one inorganic UV blocker compound in an amount not exceeding 5% wt, with respect to the weight of polymer (A), to multilayer assemblies comprising one layer made from said composition (C1), to a method for manufacturing said multilayer assemblies and to the use of the same in different field of use, including protection of PV modules.

公开(公告)号：US09382362B2

公开(公告)日：2016-07-05

申请号：US13638425

申请日：2011-03-31

申请人： Julio A. Abusleme ,  Riccardo Pieri ,  Ivan Pagin

发明人： Julio A. Abusleme ,  Riccardo Pieri ,  Ivan Pagin

IPC分类号： C08F20/06 ,  C08F214/18 ,  C08F8/00 ,  C09D127/16 ,  C08J5/00 ,  C08J5/22 ,  B01D67/00 ,  B01D69/14 ,  B82Y30/00 ,  C08F220/06 ,  C08F220/20 ,  C08F214/22 ,  C08F214/24 ,  C08K3/34 ,  H01M2/14 ,  H01M2/16 ,  H01M8/10 ,  B01D71/02 ,  B01D71/34 ,  B01D71/70

CPC分类号： C08F214/18 ,  B01D67/0079 ,  B01D69/148 ,  B01D71/022 ,  B01D71/027 ,  B01D71/34 ,  B01D71/70 ,  B01D2323/38 ,  B82Y30/00 ,  C08F8/00 ,  C08F214/182 ,  C08F214/186 ,  C08F214/225 ,  C08F214/245 ,  C08F220/06 ,  C08F220/20 ,  C08F2800/10 ,  C08F2810/20 ,  C08F2810/50 ,  C08J5/005 ,  C08J5/2281 ,  C08J2333/10 ,  C08K3/346 ,  C09D127/16 ,  H01M2/145 ,  H01M2/166 ,  H01M8/1046 ,  Y02P70/56 ,  C08F8/12 ,  C08F8/42 ,  C08F210/02 ,  C08K3/36

摘要： A process for manufacturing a fluoropolymer hybrid organic/inorganic composite comprising: (i) mixing at least one fluoropolymer comprising recurring units derived from at least one (meth)acrylic monomer [monomer (MA)] of formula: at least one metal compound [compound (M)] of formula: X4-mAYm, wherein each of R1, R2, R3, equal or different from each other, is independently a hydrogen atom or a C1-C3 hydrocarbon group, and ROH is a hydrogen atom or a C1-C5 hydrocarbon moiety comprising at least one hydroxyl group [polymer (F)]; wherein m is an integer from 1 to 4, A is a metal selected from the group consisting of Si, Ti and Zr, Y is a hydrolysable group, X is a hydrocarbon group comprising one or more functional groups; (ii) reacting at least a fraction of hydroxyl groups of the ROH groups of said monomer (MA) of said polymer (F) with at least a fraction of said compound (M), to obtain a grafted polymer comprising pendant —Ym-1AX4-m groups, with m, Y, A and X having same meaning as above; and (iii) hydrolyzing and/or polycondensing compound (M) and/or pendant —Ym-1AX4-m groups as above. The invention also disclose the fluoropolymer hybrid organic/inorganic composites obtained therefrom and the method of the use of the same.

公开(公告)号：US08642702B2

公开(公告)日：2014-02-04

申请号：US13643339

申请日：2011-04-26

申请人： Julio A. Abusleme ,  Stefano Mortara

发明人： Julio A. Abusleme ,  Stefano Mortara

IPC分类号： C08F8/00 ,  C08L23/04

CPC分类号： C08J5/18 ,  C08J2327/16 ,  C08L27/16 ,  C08L27/12 ,  C08L23/0892

摘要： The invention pertains to a thermoplastic VDF polymer composition comprising: at least one thermoplastic vinylidene fluoride (VDF) polymer comprising at least 85% by moles of recurring units derived from VDF; and at least one ethylene/chlorotrifluoroethylene (ECTFE) polymer, wherein said ECTFE polymer possesses a melting point of less than 210° C. and it is comprised in an amount of from 0.1 to 20% wt with respect to the total weight of VDF polymer and ECTFE polymer. The invention also pertains to a process for making the VDF polymer and to the uses thereof for manufacturing films, in particular transparent films.

摘要翻译： 本发明涉及一种热塑性VDF聚合物组合物，其包含：至少一种包含至少85％摩尔衍生自VDF的重复单元的热塑性偏二氟乙烯（VDF）聚合物; 和至少一种乙烯/氯三氟乙烯（ECTFE）聚合物，其中所述ECTFE聚合物具有小于210℃的熔点，并且其含量相对于VDF聚合物的总重量为0.1-20重量％ 和ECTFE聚合物。 本发明还涉及制备VDF聚合物的方法及其用于制造膜，特别是透明膜的用途。

公开(公告)号：US20130192755A1

公开(公告)日：2013-08-01

申请号：US13877792

申请日：2011-10-12

申请人： Serena Carella ,  Mattia Bassi ,  Stefano Mortara ,  Paolo Toniolo ,  Julio A. Abusleme

发明人： Serena Carella ,  Mattia Bassi ,  Stefano Mortara ,  Paolo Toniolo ,  Julio A. Abusleme

IPC分类号： B32B27/08

CPC分类号： B32B27/08 ,  B32B27/20 ,  B32B27/304 ,  B32B2250/03 ,  B32B2250/246 ,  B32B2250/40 ,  B32B2264/102 ,  B32B2307/412 ,  B32B2307/71 ,  B32B2307/712 ,  B32B2457/12 ,  H01L31/0481 ,  Y02E10/50 ,  Y10T156/10 ,  Y10T428/257 ,  Y10T428/259 ,  Y10T428/265 ,  Y10T428/31544

摘要： A multilayer assembly comprising a first inner layer (L1) made from a first composition (C1), said first composition (C1) comprising at least one polymer comprising recurring units derived from ethylene (E) and from chlorotrifluoroethylene (CTFE), and at least one Ti compound; and a second outer layer (L2) made from a second composition, said second composition (C2) being free from TiO2-containing additives, said second composition (C2) comprising at least one semi-crystalline polymer (A) comprising recurring units derived from ethylene and from at least one fluoromonomer selected from chlorotrifluoroethylene (CTFE), tetrafluoroethylene (TFE) and mixtures thereof, said semi-crystalline polymer (A) having a heat of fusion of at least 35 J/g.

摘要翻译： 一种多层组件，包括由第一组合物（C1）制成的第一内层（L1），所述第一组合物（C1）包含至少一种包含衍生自乙烯（E）和氯三氟乙烯（CTFE）的重复单元的聚合物，并且至少 一钛化合物 和由第二组合物制成的第二外层（L2），所述第二组合物（C2）不含TiO 2添加剂，所述第二组合物（C2）包含至少一种半结晶聚合物（A），其包含衍生自 乙烯和至少一种选自三氟氯乙烯（CTFE），四氟乙烯（TFE）及其混合物的含氟单体，所述半结晶聚合物（A）具有至少35J / g的熔化热。

公开(公告)号：US07985790B2

公开(公告)日：2011-07-26

申请号：US12095798

申请日：2006-12-04

申请人： Fabio Polastri ,  Tiziana Poggio ,  Julio A. Abusleme

发明人： Fabio Polastri ,  Tiziana Poggio ,  Julio A. Abusleme

IPC分类号： C08K5/05

CPC分类号： C09D127/12 ,  C08K5/04 ,  C08K5/05 ,  C08K5/053 ,  C08K5/06 ,  C09D127/16 ,  C09D127/18 ,  Y10T428/3154 ,  C08L27/12

摘要： A fluoropolymer composition comprising: at least one thermoplastic partially fluorinated fluoropolymer [polymer (F)]; water; less than 15% wt (based on total weight of composition) of a water-soluble solvent mixture [mixture (M)] comprising: at least one alcohol solvent [solvent (A)]; at least one glycol derivative solvent having a boiling point of at least 100° C. [solvent (GD)], wherein the solvent (GD) is a derivative of a compound comprising at least two hydroxyl groups, wherein at least one of the hydroxyl group has been derivatized to yield an ether or an ester bond.

摘要翻译： 含氟聚合物组合物，其包含：至少一种热塑性部分氟化含氟聚合物[聚合物（F）]; 水; 包含：至少一种醇溶剂[溶剂（A）];小于15重量％（基于组合物的总重量）的水溶性溶剂混合物[混合物（M） 至少一种沸点为至少100℃的二醇衍生物溶剂[溶剂（GD）]，其中溶剂（GD）是包含至少两个羟基的化合物的衍生物，其中至少一个羟基 已经衍生化得到醚或酯键。

公开(公告)号：US20090326154A1

公开(公告)日：2009-12-31

申请号：US12516086

申请日：2005-11-29

申请人： Julio A. Abusleme ,  Marco Avataneo ,  Giancarlo Perfetti

发明人： Julio A. Abusleme ,  Marco Avataneo ,  Giancarlo Perfetti

IPC分类号： C08F214/24

CPC分类号： C08L23/0892 ,  C08L23/00 ,  C08L27/00 ,  C08L51/08 ,  C08L53/00 ,  C08L71/02 ,  C08L2666/24 ,  C08L2666/22

摘要： Polymeric compositions comprising: 1) at least one thermoprocessable semicrystalline halo-polymer; 2) an additive in amounts between 0.01 and 10% by weight of 1) one or more (per)fluoropolyether polymers of formula: Q-O-[A-B]z-[A-B′]z′-A-Q′ (I) wherein: A=—(X)a—O-A′-(X′)b— wherein A′ is a perfluoropolyether chain; X, X′=—CF2—, —CF2CF2—, —CF(CF3)—; a, b=0 or 1; B derives from one or more olefins, of which at least one homopolymerizable by radical way, of formula: —[(CR1R2—CR3R4)j(CR5R6—CR7R8)j′]— (Ia) wherein j=1-30, j′=0-29, with the proviso that 2

摘要翻译： 聚合物组合物包括：1）至少一种热可加工半结晶卤代聚合物; 2）0.01至10重量％的添加剂，1）一种或多种式（Q） - [AB] z- [A-B'] z'-AQ'（I）的（全）氟聚醚聚合物，其中： A = - （X）aO-A' - （X'）b-其中A'是全氟聚醚链; X，X'= -CF 2 - ， - CF 2 CF 2 - ， - CF（CF 3） - ; a，b = 0或1; B衍生自一种或多种烯烃，其中至少一种可通过自由基方式可通过以下通式共聚合： - [（CR1R2-CR3R4）j（CR5R6-CR7R8）j'] - （Ia）其中j = 1-30，j' = 0-29，条件是2 <（j + j'）<30; R 1 -R 8 =卤素，H，C 1 -C 6（全）卤代烷基，C 1 -C 6烷基或C 1 -C 6氧基（全）氟烷基; B'=（Ia），但R 1 -R 8中的至少一个具有与B不同的含义，并且2 <=（j + j'）<30; z> = 2; z'为0或整数; z，z'使得（I）的数均分子量在500和500,000之间; Q，Q'= C1-C3全氟烷基; C1-C6烷基; 或功能性端基。