Desulfurizing adsorbent, preparing process and use thereof
    2.
    发明授权
    Desulfurizing adsorbent, preparing process and use thereof 有权
    脱硫吸附剂,制备方法及其用途

    公开(公告)号:US08202816B2

    公开(公告)日:2012-06-19

    申请号:US12468346

    申请日:2009-05-19

    IPC分类号: C10G29/16

    摘要: An adsorbent for desulfurizing cracking gasoline or diesel fuel comprising 1) pillared clay, (2) inorganic oxide binder, (3) an oxide of one or more metals selected from Groups IIB, VB and VIB, and (4) at least one metal accelerant selected from cobalt, nickel, iron and manganese. The adsorbent exhibits excellent abrasion-resistant strength and desulfurization performance.

    摘要翻译: 一种用于脱硫裂化汽油或柴油的吸附剂,包括1)柱撑粘土,(2)无机氧化物粘合剂,(3)选自IIB,VB和VIB族的一种或多种金属的氧化物,和(4)至少一种金属促进剂 选自钴,镍,铁和锰。 吸附剂具有优异的耐磨强度和脱硫性能。

    CATALYST FOR UPGRADING INFERIOR ACID-CONTAINING CRUDE OIL, PROCESS FOR MANUFACTURING THE SAME, AND APPLICATION THEREOF
    7.
    发明申请
    CATALYST FOR UPGRADING INFERIOR ACID-CONTAINING CRUDE OIL, PROCESS FOR MANUFACTURING THE SAME, AND APPLICATION THEREOF 有权
    用于升级含有活性的含酸原油的催化剂,其制备方法及其应用

    公开(公告)号:US20110139682A1

    公开(公告)日:2011-06-16

    申请号:US12993637

    申请日:2009-01-09

    摘要: The present invention relates to a mesopore material of a catalyst for upgrading acid-containing crude oil. Said mesopore material is an amorphous material containing alkaline earth oxide, silica and alumina, and has an anhydrous chemical formula of (0-0.3)Na2O.(1-50)MO.(6-58)Al2O3.(40-92)SiO2, based on the weight percent of the oxides, wherein M is one or more selected from Mg, Ca and Ba. Said mesopore material has a specific surface area of 200-400 m2/g, a pore volume of 0.5-2.0 ml/g, an average pore diameter of 8-20 nm, and a most probable pore size of 5-15 nm. The present invention further relates to a process for manufacturing said mesopore material and the use thereof. The catalyst prepared from the mesopore material provided in the present invention is suitable for the catalytic upgrading of inferior acid-containing crude oil and for the removal of organic acids, carbon residues and metals in the crude oil, and thus has very good economic benefits.

    摘要翻译: 本发明涉及一种用于升级含酸原油的催化剂的中孔材料。 所述中孔材料是含有碱土金属氧化物,二氧化硅和氧化铝的无定形材料,具有无水化学式(0-0.3)Na2O(1-50)MO。(6-58)Al2O3。(40-92)SiO2 ,基于氧化物的重量百分数,其中M是选自Mg,Ca和Ba中的一种或多种。 所述中孔材料的比表面积为200-400m2 / g,孔体积为0.5-2.0ml / g,平均孔径为8-20nm,最可能的孔径为5-15nm。 本发明还涉及一种制造所述中孔材料的方法及其用途。 由本发明提供的中孔材料制备的催化剂适用于劣质含酸原油的催化提质和原油中有机酸,碳残余物和金属的去除,具有非常好的经济效益。

    Zeolite-containing hydrocarbon-converting catalyst, the preparation process thereof, and a process for converting hydrocarbon oils with the catalyst
    8.
    发明授权
    Zeolite-containing hydrocarbon-converting catalyst, the preparation process thereof, and a process for converting hydrocarbon oils with the catalyst 有权
    含沸石的烃转化催化剂,其制备方法以及用催化剂转化烃油的方法

    公开(公告)号:US07923399B2

    公开(公告)日:2011-04-12

    申请号:US11547209

    申请日:2005-03-31

    IPC分类号: B01J29/42

    摘要: A catalyst for converting hydrocarbons includes, based on the weight of the catalyst, 1-60% by weight of a zeolite, 0.1-10% by weight of an assistant catalytic component, 5-98% by weight of a thermotolerant inorganic oxide, and 0-70% by weight of a clay in terms of the oxide. The zeolite is a MFI-structured zeolite-containing phosphor and transition metal(s) or a mixture of the zeolite and a macroporous zeolite, which comprises, based on the weight of the mixture, 75-100% by weight of said MFI-structured zeolite containing phosphor and transition metal(s) and 0-25% by weight of the macroporous zeolite. In terms of the mass of the oxide, the MFI-structured zeolite containing phosphor and transition metal(s) has the following anhydrous chemical formula: (0-0.3)Na2O.(0.3-5.5)Al2O3.(1.0-10)P2O5.(0.7-15)M1xOy.(0.01-5)M2mOn(0-10)RE2O3.(70-97)SiO2  I or (0-0.3)Na2O.(0.3-5)Al2O3.(1.0-10)P2O5.(0.7-15)MpOq.(0-10)RE2O3.(70-98)SiO2  II The assistant catalytic component is one or more selected from the group consisting of the alkali earth metals, Group IVB metals, non-noble metals of Group VIII, and rare earth metals of the Periodic Table of the Elements. This catalyst has a higher ability to convert petroleum hydrocarbons and higher yields for propylene, ethylene, and light aromatics.

    摘要翻译: 用于转化烃的催化剂包括基于催化剂的重量,1-60重量%的沸石,0.1-10重量%的助催化组分,5-98重量%的耐热无机氧化物,和 以氧化物换算0-70重量%的粘土。 沸石是含有MFI结构的含沸石的磷光体和过渡金属或沸石与大孔沸石的混合物,其基于混合物的重量,包含所述MFI结构的75-100重量% 含沸石的磷光体和过渡金属和0-25重量%的大孔沸石。 就氧化物的质量而言,含有荧光粉和过渡金属的MFI结构的沸石具有以下无水化学式:(0-0.3)Na2O(0.3-5.5)Al2O3(1.0-10)P2O5。 (0.7-15)M1xOy(0.01-5)M2mOn(0-10)RE2O3(70-97)SiO2 I或(0-0.3)Na2O(0.3-5)Al2O3(1.0-10)P2O5( 0.7-15)MpOq。(0-10)RE2O3。(70-98)SiO2 II助催化剂组分是选自碱金属,ⅣB族金属,Ⅷ族非贵金属的一种或多种 ,元素周期表中的稀土金属。 该催化剂具有较高的转化石油烃的能力和较高的丙烯,乙烯和轻质芳族化合物的产率。