Atomic Layer Deposition of Hafnium or Zirconium Alloy Films
    4.
    发明申请
    Atomic Layer Deposition of Hafnium or Zirconium Alloy Films 有权
    原子层沉积铪或锆合金膜

    公开(公告)号:US20140231930A1

    公开(公告)日:2014-08-21

    申请号:US14183826

    申请日:2014-02-19

    IPC分类号: H01L21/02 H01L29/78

    摘要: Provided are methods of depositing hafnium or zirconium containing metal alloy films. Certain methods comprise sequentially exposing a substrate surface to alternating flows of an organometallic precursor and a reductant comprising M(BH4)4 to produce a metal alloy film on the substrate surface, wherein M is selected from hafnium and zirconium, and the organometallic precursor contains a metal N. Gate stacks are described comprising a copper barrier layer comprising boron, a first metal M selected from Hf and Zr, and a second metal N selected from tantalum, tungsten, copper, ruthenium, rhodium, cobalt and nickel; and a copper layer overlying the copper barrier seed layer.

    摘要翻译: 提供了沉积含铪或锆的金属合金膜的方法。 某些方法包括将衬底表面依次暴露于有机金属前体和包含M(BH 4)4的还原剂的交替流,以在衬底表面上产生金属合金膜,其中M选自铪和锆,并且有机金属前体含有 描述了包括包含硼的铜阻挡层,选自Hf和Zr的第一金属M和选自钽,钨,铜,钌,铑,钴和镍的第二金属N的栅叠层。 以及覆盖在铜屏障种子层上的铜层。