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公开(公告)号:US20060233690A1
公开(公告)日:2006-10-19
申请号:US11456027
申请日:2006-07-06
申请人: Kiyoshi Taguchi , Takeshi Tomizawa , Kunihiro Ukai , Kimiyasu Honda , Toshiyuki Shono , Kouichiro Kitagawa
发明人: Kiyoshi Taguchi , Takeshi Tomizawa , Kunihiro Ukai , Kimiyasu Honda , Toshiyuki Shono , Kouichiro Kitagawa
IPC分类号: B01D53/62
CPC分类号: B01D53/864 , B01J8/0242 , B01J8/0257 , B01J8/0285 , B01J8/0453 , B01J8/0496 , B01J19/2485 , B01J2208/00044 , B01J2208/00168 , B01J2208/00221 , B01J2208/00309 , C01B3/58 , C01B2203/0435 , C01B2203/047 , H01M8/0662
摘要: A hydrogen purifying apparatus and method are provided for oxidizing and removing carbon monoxide (CO) in a modified gas containing CO in addition to a main component hydrogen gas. The apparatus and method use comprises a catalyst reaction segment having a catalyst layer for oxidizing CO, a material gas supplying segment for supplying the modified gas to the reaction segment via a material gas supply pathway, and an oxidant gas supplying segment for supplying an oxidant gas on the path of the material gas supply pathway. Preferably, the apparatus further comprises means for cooling the catalyst layer at the upstream side and means for heating the catalyst layer at the downstream side.
摘要翻译: 除了主要成分氢气之外,还提供了一种氢净化装置和方法,其用于氧化除去含有CO的改性气体中的一氧化碳(CO)。 该装置和方法的使用包括具有用于氧化CO的催化剂层的催化剂反应段,用于经由原料气体供给路径向反应段供给改性气体的原料气体供给段,以及用于供给氧化剂气体的氧化剂气体供给段 在物料供气路径的路径上。 优选地,该装置还包括用于在上游侧冷却催化剂层的装置和用于在下游侧加热催化剂层的装置。
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公开(公告)号:US06562088B2
公开(公告)日:2003-05-13
申请号:US09392691
申请日:1999-09-09
申请人: Kunihiro Ukai , Kimiyasu Honda , Kiyoshi Taguchi , Takeshi Tomizawa , Kouichiro Kitagawa , Toshiyuki Shono
发明人: Kunihiro Ukai , Kimiyasu Honda , Kiyoshi Taguchi , Takeshi Tomizawa , Kouichiro Kitagawa , Toshiyuki Shono
IPC分类号: C01B300
CPC分类号: B01J8/0492 , B01J8/0242 , B01J8/0278 , B01J8/048 , C01B3/48 , C01B2203/0233 , C01B2203/0261 , C01B2203/0283 , C01B2203/044 , C01B2203/0445 , C01B2203/047 , C01B2203/066 , C01B2203/0811 , C01B2203/0816 , C01B2203/0844 , C01B2203/0866 , C01B2203/0877 , C01B2203/0883 , C01B2203/0894 , C01B2203/1011 , C01B2203/1023 , C01B2203/1029 , C01B2203/1041 , C01B2203/1047 , C01B2203/1052 , C01B2203/1064 , C01B2203/1076 , C01B2203/1082 , C01B2203/1223 , C01B2203/1241 , C01B2203/1247 , C01B2203/1276 , C01B2203/1288 , C01B2203/16 , C01B2203/1609 , C01B2203/1619 , C01B2203/1623 , C01B2203/1628 , C01B2203/1666 , C01B2203/1685 , C01B2203/169 , C01B2203/1695
摘要: A hydrogen generating apparatus comprising a reformer, a heating section, a fuel supply section, a water supply section, a shift reactor with a shift catalyst layer, a first heat exchanger on the downstream side of the shift catalyst layer, and a temperature detector for the shift catalyst layer. The temperature of the downstream portion of the shift catalyst layer is raised by the action of the heat exchanger compared with the temperature of the same before the amount of the reformed gas is increased. And, the temperature of the downstream portion is lowered compared with the temperature of the same before the amount of the reformed gas is reduced when reducing the amount of the reformed gas. Accordingly, regardless whether the generation amount of hydrogen is large or small, the hydrogen generating apparatus can supply a constant concentration hydrogen gas while keeping the concentration of byproduct carbon monoxide low.
摘要翻译: 一种氢生成装置,包括重整器,加热部,燃料供给部,供水部,变速催化剂层的变换反应器,变换催化剂层的下游侧的第一热交换器,以及温度检测器 换档催化剂层。 换热催化剂层的下游部分的温度通过热交换器的作用与在重整气体量增加之前的温度相比升高。 并且,在减少重整气体的量时,在重整气体量减少之前,下游部分的温度与其温度相比降低。 因此,无论氢的产生量是大还是小,氢生成装置都可以在保持副产物一氧化碳浓度低的同时供给恒定浓度的氢气。
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公开(公告)号:US06846475B1
公开(公告)日:2005-01-25
申请号:US09549918
申请日:2000-04-14
IPC分类号: C01B3/58 , B01J23/42 , B01J23/58 , B01J23/60 , B01J23/62 , B01J23/63 , B01J23/648 , B01J23/652 , B01J23/89 , B01J29/12 , B01J29/22 , B01J29/44 , B01J29/74 , C01B3/16 , C01B3/48 , B01J8/02
CPC分类号: C01B3/16 , C01B3/48 , C01B2203/0233 , C01B2203/0283 , C01B2203/044 , C01B2203/047 , C01B2203/066 , C01B2203/0811 , C01B2203/1011 , C01B2203/1023 , C01B2203/1052 , C01B2203/1064 , C01B2203/107 , C01B2203/1082 , C01B2203/1223 , C01B2203/1241 , C01B2203/1247 , C01B2203/16 , C01B2203/1604 , C01B2203/1609 , C01B2203/1619 , C01B2203/1623 , Y02P20/52
摘要: The present specification disclosed a hydrogen refinement apparatus comprising a reformed gas feeding part containing at least a hydrogen gas and water vapor, and a reaction chamber equipped with a carbon monoxide shifting catalyst body downstream said reformed gas feeding part, wherein said carbon monoxide shifting catalyst body comprises a carrier supporting Pt, the carrier being composed of at least one metal oxide having a BET specific surface area of 10 m2/g or more, and a method for operating the apparatus. The present invention provides improved heat-resistance of the CO shifting catalyst body, and can operate stably even if the apparatus is activated and stopped repeatedly.
摘要翻译: 本说明书公开了一种氢精制装置,其包括至少含有氢气和水蒸汽的重整气体供给部,以及在所述重整气体供给部下游配备有一氧化碳转换催化剂体的反应室,其中,所述一氧化碳转化催化剂体 包括负载Pt的载体,载体由至少一种BET比表面积为10m 2 / g以上的金属氧化物构成,以及操作该装置的方法。 本发明提供了CO转化催化剂体的改进的耐热性,并且即使重新启动和停止该装置也能够稳定地运行。
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公开(公告)号:US06607703B1
公开(公告)日:2003-08-19
申请号:US09577364
申请日:2000-05-23
IPC分类号: B01D100
CPC分类号: C01B3/323 , B01J8/02 , B01J8/0278 , B01J8/0285 , B01J2208/00212 , B01J2208/00504 , B01J2219/00155 , B01J2219/185 , C01B3/384 , C01B2203/0811 , Y02P20/129
摘要: The present specification discloses a hydrogen generator for generating a hydrogen gas, comprising at least a fuel supply part for supplying a hydrocarbon type fuel, a fuel combustion part, a water supply part, a gas, mixing part for mixing the fuel and a water, and a reforming part filled with the reforming catalyst, wherein at least one of the gas mixing part and the reforming part is heated by an exhaust gas generated in the combustion part. The hydrogen generator according to the present invention aims to improve the heat efficiency, reducing the heat loss from the apparatus with a simple constitution and collecting the waste heat for an effective use thereof.
摘要翻译: 本说明书公开了一种用于产生氢气的氢发生器,至少包括用于供给烃类燃料的燃料供给部,燃料燃烧部,供水部,气体,混合燃料和水的混合部, 以及填充有重整催化剂的重整部分,其中气体混合部分和重整部分中的至少一个被在燃烧部分中产生的废气加热。 根据本发明的氢发生器旨在提高热效率,以简单的结构减少来自设备的热损失并收集废热用于其有效的应用。
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公开(公告)号:US20050252083A1
公开(公告)日:2005-11-17
申请号:US11187949
申请日:2005-07-25
IPC分类号: C01B3/38 , B01J38/04 , B01J38/06 , C01B3/32 , C01B3/40 , C10G11/02 , C10G11/20 , C10G25/00 , C10G45/00 , C10G55/06 , C10G69/04
CPC分类号: C01B3/326 , B01J38/04 , B01J38/06 , C01B3/40 , C01B2203/1052 , C01B2203/1064 , Y02P20/52 , Y02P20/584
摘要: The fuel reforming apparatus according to the present invention comprises a reforming unit having a reforming catalyst for steam-reforming a raw material of a hydrocarbon and a heater for heating the reforming unit to generate a hydrogen gas by heating the reforming unit while supplying the raw material and water to the heated reforming unit. This fuel reforming apparatus can recover the activity of the reforming catalyst by heating the reforming catalyst in a reducing atmosphere and, therefore, the present invention eliminates the need for replacing the poisoned reforming catalyst and makes it possible to recover with ease the decreased activity of the reforming catalyst.
摘要翻译: 根据本发明的燃料重整装置包括:重整单元,其具有用于烃的原料的蒸汽重整的重整催化剂和用于加热重整单元的加热器,以在供应原料的同时加热重整单元产生氢气 和水加热到重整单元。 该燃料重整装置能够通过在还原气氛中加热重整催化剂来回收重整催化剂的活性,因此,本发明不需要更换中毒的重整催化剂,并且能够容易地回收活性降低 重整催化剂。
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公开(公告)号:US06733552B1
公开(公告)日:2004-05-11
申请号:US09524160
申请日:2000-03-13
IPC分类号: B01J802
CPC分类号: C01B3/58 , C01B3/48 , C01B2203/0233 , C01B2203/0261 , C01B2203/0283 , C01B2203/04 , C01B2203/044 , C01B2203/0465 , C01B2203/047 , C01B2203/066 , C01B2203/0811 , C01B2203/0816 , C01B2203/0866 , C01B2203/1023 , C01B2203/1029 , C01B2203/1041 , C01B2203/1052 , C01B2203/1064 , C01B2203/1076 , C01B2203/1082 , C01B2203/1205 , C01B2203/1223 , C01B2203/1241 , C01B2203/1247 , C01B2203/1276 , C01B2203/147 , C01B2203/1604 , C01B2203/1609 , C01B2203/1619 , C01B2203/1623 , C01B2203/1633 , C01B2203/1676 , C01B2203/1695
摘要: A hydrogen generating apparatus having a fuel feeding part, a water feeding part for fuel reforming, an oxidant gas feeding part, a reforming catalyst body, a heating part for the reforming catalyst, a CO shifting catalyst body and a CO purification catalyst body is provided wherein the reforming catalyst body, the CO shifting catalyst body and the CO purification catalyst body are sequentially ordered from the fuel feeding part toward the downstream side, and wherein a shifting catalyst of the shifting catalyst body contains as one component at least a platinum group-type catalyst. A fuel and water are fed to the reforming part which has been heated, and an oxidant gas from the oxidant gas feeding part is nixed with each of a reformed gas introduced into the shifting part and a shifted gas obtained in the shifting part and introduced into the purification part, wherein at least a part of the reformed gas and at least a part of the shifted gas are oxidized, respectively, in the shifting part and the purification part.
摘要翻译: 具有燃料供给部,燃料重整用供水部,氧化剂气体供给部,重整催化剂体,重整催化剂用加热部,CO转化催化剂体以及CO净化催化剂体的氢生成装置 其中所述重整催化剂体,所述CO转化催化剂体和所述CO净化催化剂体从所述燃料供给部朝向下游侧依次排列,并且其中所述变换催化剂体的换档催化剂至少含有铂族 - 型催化剂。 将燃料和水供给到已经被加热的重整部分,并且将来自氧化剂气体供给部分的氧化剂气体与引入变速部分的重整气体和在变速部分中获得的换流气体混合并被引入 净化部分,其中至少一部分重整气体和至少一部分位移气体分别在换档部分和净化部分中被氧化。
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公开(公告)号:US07674445B2
公开(公告)日:2010-03-09
申请号:US11456027
申请日:2006-07-06
申请人: Kiyoshi Taguchi , Takeshi Tomizawa , Kunihiro Ukai , Kimiyasu Honda , Toshiyuki Shono , Kouchiro Kitagawa
发明人: Kiyoshi Taguchi , Takeshi Tomizawa , Kunihiro Ukai , Kimiyasu Honda , Toshiyuki Shono , Kouchiro Kitagawa
IPC分类号: B01D53/62
CPC分类号: B01D53/864 , B01J8/0242 , B01J8/0257 , B01J8/0285 , B01J8/0453 , B01J8/0496 , B01J19/2485 , B01J2208/00044 , B01J2208/00168 , B01J2208/00221 , B01J2208/00309 , C01B3/58 , C01B2203/0435 , C01B2203/047 , H01M8/0662
摘要: A hydrogen purifying apparatus and method are provided for oxidizing and removing carbon monoxide (CO) in a modified gas containing CO in addition to a main component hydrogen gas. The apparatus and method use comprises a catalyst reaction segment having a catalyst layer for oxidizing CO, a material gas supplying segment for supplying the modified gas to the reaction segment via a material gas supply pathway, and an oxidant gas supplying segment for supplying an oxidant gas on the path of the material gas supply pathway. Preferably, the apparatus further comprises means for cooling the catalyst layer at the upstream side and means for heating the catalyst layer at the downstream side.
摘要翻译: 除了主要成分氢气之外,还提供了一种氢净化装置和方法,其用于氧化除去含有CO的改性气体中的一氧化碳(CO)。 该装置和方法的使用包括具有用于氧化CO的催化剂层的催化剂反应段,用于经由原料气体供给路径向反应段供给改性气体的原料气体供给段,以及用于供给氧化剂气体的氧化剂气体供给段 在物料供气路径的路径上。 优选地,该装置还包括用于在上游侧冷却催化剂层的装置和用于在下游侧加热催化剂层的装置。
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公开(公告)号:US06797420B2
公开(公告)日:2004-09-28
申请号:US09914376
申请日:2001-12-03
申请人: Kunihiro Ukai , Takeshi Tomizawa , Kiyoshi Taguchi , Toshiyuki Shono , Koichiro Kitagawa , Tomonori Asou , Masataka Ozeki , Shinji Miyauchi , Akira Maenishi , Yutaka Yoshida
发明人: Kunihiro Ukai , Takeshi Tomizawa , Kiyoshi Taguchi , Toshiyuki Shono , Koichiro Kitagawa , Tomonori Asou , Masataka Ozeki , Shinji Miyauchi , Akira Maenishi , Yutaka Yoshida
IPC分类号: H01M804
CPC分类号: H01M8/04425 , B01J8/0457 , B01J2208/00061 , B01J2208/00309 , B01J2208/00504 , B01J2208/00548 , B01J2219/00157 , B01J2219/002 , B01J2219/00213 , B01J2219/00231 , C01B3/323 , C01B3/38 , C01B3/48 , C01B3/583 , C01B2203/0233 , C01B2203/0283 , C01B2203/0288 , C01B2203/044 , C01B2203/0445 , C01B2203/047 , C01B2203/0495 , C01B2203/066 , C01B2203/0811 , C01B2203/0816 , C01B2203/0822 , C01B2203/0827 , C01B2203/0844 , C01B2203/0866 , C01B2203/0877 , C01B2203/0883 , C01B2203/1011 , C01B2203/1023 , C01B2203/1041 , C01B2203/1047 , C01B2203/1064 , C01B2203/107 , C01B2203/1076 , C01B2203/1082 , C01B2203/1223 , C01B2203/1241 , C01B2203/1247 , C01B2203/1288 , C01B2203/146 , C01B2203/1604 , C01B2203/1609 , C01B2203/1619 , C01B2203/1638 , C01B2203/1657 , C01B2203/1685 , C01B2203/169 , C01B2203/1695 , H01M8/04014 , H01M8/04022 , H01M8/04373 , H01M8/04738 , H01M8/04776 , H01M8/0612 , H01M8/0662 , Y02P20/128
摘要: The present invention relates to an electric power generator and its operation method, which electric power generator is equipped with a hydrogen generator, a polymer electrolyte fuel cell for generating electric power using hydrogen rich gas from the hydrogen generator, a burner for heating the hydrogen generator, a flow rate controller for controlling the supply amount of a burning fuel to the burner, a communicating pathway connecting the flow rate controller and the burner, a joint where at least a residual fuel gas from a fuel electrode of the fuel cell and/or an incompletely generated gas from the hydrogen generator are combined into the communicating pathway, and a pressure-transferring pipe for releasing the pressure between the joint and the flow rate controller into the flow rate controller; the flow rate controller controls the supply amount of the burning fuel on the basis of the above-mentioned pressure.
摘要翻译: 发电机及其运行方法技术领域本发明涉及一种发电机及其运行方法,该发电机配备有氢发生器,使用来自氢发生器的富氢气体发电的聚合物电解质型燃料电池,用于加热氢发生器的燃烧器 用于控制向燃烧器燃烧燃料的供给量的流量控制器,连接流量控制器和燃烧器的连通路径,至少来自燃料电池的燃料电极的残留燃料气体和/或 来自氢发生器的不完全产生的气体被组合到连通通道中,以及用于将接头和流量控制器之间的压力释放到流量控制器中的压力传递管; 流量控制器基于上述压力控制燃烧燃料的供给量。
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公开(公告)号:US06972119B2
公开(公告)日:2005-12-06
申请号:US10168854
申请日:2000-12-27
申请人: Kiyoshi Taguchi , Takeshi Tomizawa , Kunihiro Ukai , Toshiyuki Shono , Koichiro Kitagawa , Tetsuya Ueda , Seiji Fujihara , Yutaka Yoshida
发明人: Kiyoshi Taguchi , Takeshi Tomizawa , Kunihiro Ukai , Toshiyuki Shono , Koichiro Kitagawa , Tetsuya Ueda , Seiji Fujihara , Yutaka Yoshida
IPC分类号: B01J8/04 , B01J19/24 , B01J23/40 , B01J23/63 , B01J23/72 , B01J35/00 , C01B3/16 , C01B3/48 , C01B3/58 , C10K3/04 , H01M8/06 , B01J3/00
CPC分类号: H01M8/0631 , B01J8/0453 , B01J8/0457 , B01J8/0488 , B01J8/0496 , B01J19/2485 , B01J23/40 , B01J23/63 , B01J23/72 , B01J35/0006 , B01J2208/00061 , B01J2208/00194 , B01J2208/00504 , B01J2208/00716 , B01J2219/0004 , B01J2219/00198 , B01J2219/002 , B01J2219/00202 , B01J2219/00213 , B01J2219/00231 , C01B3/16 , C01B3/48 , C01B3/583 , C01B3/586 , C01B2203/0233 , C01B2203/0283 , C01B2203/0288 , C01B2203/044 , C01B2203/0445 , C01B2203/047 , C01B2203/066 , C01B2203/0811 , C01B2203/0816 , C01B2203/085 , C01B2203/0866 , C01B2203/0877 , C01B2203/0883 , C01B2203/0894 , C01B2203/1023 , C01B2203/1041 , C01B2203/1064 , C01B2203/107 , C01B2203/1076 , C01B2203/1082 , C01B2203/1223 , C01B2203/1241 , C01B2203/1247 , C01B2203/1604 , C01B2203/1609 , C01B2203/1619 , C01B2203/1661 , C01B2203/169 , C01B2203/1695 , C01B2203/82 , C10K3/04 , Y02P20/52
摘要: A hydrogen producing apparatus comprising: a reforming section having a reforming catalyst which causes a reaction between a carbon-containing organic compound as a feedstock and water; a feedstock supply section for supplying the feedstock to the reforming section; a water supply section for supplying water to the reforming section; a heating section for heating the reforming catalyst; a shifting section having a shift catalyst which causes a shift reaction between carbon monoxide and water contained in a reformed gas supplied from the reforming section; and a purifying section having a purifying catalyst which causes oxidation or methanation of carbon monoxide contained in a gas supplied from the shifting section, wherein the shift catalyst comprises a platinum group metal and a metal oxide.
摘要翻译: 一种制氢装置,其特征在于,包括:重整部,其具有使作为原料的含碳有机化合物与水发生反应的重整催化剂; 原料供给部,用于将原料供给至重整部; 供水部,其向所述重整部供给水; 用于加热所述重整催化剂的加热部分; 具有变换催化剂的换档部分,其引起从重整部分供应的重整气体中包含的一氧化碳和水之间的转化反应; 以及净化部,其具有使从所述变速部供给的气体中含有的一氧化碳发生氧化或甲烷化的净化催化剂,所述变换催化剂含有铂族金属和金属氧化物。
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公开(公告)号:US4523994A
公开(公告)日:1985-06-18
申请号:US508578
申请日:1983-06-28
申请人: Toshiyuki Shono , Keiichi Kimura , Takumi Maeda
发明人: Toshiyuki Shono , Keiichi Kimura , Takumi Maeda
IPC分类号: A61B5/145 , A61B5/1468 , C07D323/00 , G01N27/333 , C08J5/22 , C08K5/15
CPC分类号: C07D323/00 , G01N27/3335
摘要: Bis-crown-ether derivatives having such configuration that the two crown rings may easily overlap spatially, holding a potassium or the like ion between them, and ion-selective membranes used for said bis-crown-ether derivatives as neutral carrier, which are useful as an ion sensor and are superior to the ion-selective membrane containing valinomycin.
摘要翻译: 具有这样构造的双冠醚衍生物,其两个冠环可以容易地在空间上重叠,在它们之间保持钾等离子,以及用于所述双冠醚衍生物的离子选择性膜作为中性载体,这是有用的 作为离子传感器,并且优于含有缬氨霉素的离子选择性膜。
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