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    SOLID-ACID-CATALYZED SACCHARIFICATION DEVICE AND METHOD
    1.
    发明申请
    SOLID-ACID-CATALYZED SACCHARIFICATION DEVICE AND METHOD 审中-公开
    固体酸催化分离装置及方法

    公开(公告)号：US20120279495A1

    公开(公告)日：2012-11-08

    申请号：US13521630

    申请日：2011-01-18

    申请人： Makoto Kitano ,  Kenji Sato ,  Kentaro Nariai ,  Tatsuya Oka ,  Michikazu Hara ,  Daizo Yamaguchi

    发明人： Makoto Kitano ,  Kenji Sato ,  Kentaro Nariai ,  Tatsuya Oka ,  Michikazu Hara ,  Daizo Yamaguchi

    IPC分类号： C13K13/00 ,  B01J19/18

    CPC分类号： B01F7/18 ,  B01F13/0255 ,  B01J27/053 ,  C13K1/02 ,  C13K13/002

    摘要： A solid-acid-catalyzed saccharification device (A) includes a catalytic reaction vessel (3) configured to contain a polysaccharide feedstock with water and a solid-acid catalyst (X2) as a liquid mixture (X3) to monosaccharify the polysaccharide using the solid-acid catalyst (X2), an agitation device (4) configured to agitate the liquid mixture (X3) in the catalytic reaction vessel (3), an oxidation-reduction electrometer (5) configured to measure the redox potential of the liquid mixture (X3) in the catalytic reaction vessel (3), and a pH meter (6) configured to measure the pH of the liquid mixture (X3) in the catalytic reaction vessel (3). According to the solid-acid-catalyzed saccharification device (A), it is possible to accurately follow the reaction state of a saccharification process of a feedstock using a solid acid catalyst.

    摘要翻译： 固体酸催化糖化装置（A）包括催化反应容器（3），其配置为含有多糖原料与水和固体酸催化剂（X2）作为液体混合物（X3），以使用固体单糖化多糖 - 酸催化剂（X2），用于搅拌催化反应容器（3）中的液体混合物（X3）的搅拌装置（4），配置成测量液体混合物的氧化还原电位的氧化还原静电计（5） X3）和pH计（6），其被配置成测量催化反应容器（3）中的液体混合物（X3）的pH值。 根据固体酸催化的糖化装置（A），可以使用固体酸催化剂精确地跟踪原料的糖化过程的反应状态。

    BIOMASS TREATMENT DEVICE
    2.
    发明申请
    BIOMASS TREATMENT DEVICE 审中-公开
    生物质处理装置

    公开(公告)号：US20120288927A1

    公开(公告)日：2012-11-15

    申请号：US13522602

    申请日：2011-01-18

    申请人： Norimitsu Kaneko ,  Makoto Kitano ,  Kenji Sato ,  Kentaro Nariai ,  Michikazu Hara ,  Daizo Yamaguchi

    发明人： Norimitsu Kaneko ,  Makoto Kitano ,  Kenji Sato ,  Kentaro Nariai ,  Michikazu Hara ,  Daizo Yamaguchi

    IPC分类号： B01J19/00 ,  C12M1/02

    CPC分类号： C13K1/02 ,  C12M45/09 ,  C13K13/002 ,  F28D2021/0077

    摘要： A biomass treatment device (A) includes a hot compressed water reaction device (1) that hydrolyzes a biomass by passing hot compressed water to the biomass to prepare polysaccharides, and a solid-acid catalytic reaction device (2 and 3) that generates monosaccharides from the polysaccharides using a solid-acid catalyst, and the device includes at least one of a first heat exchanger (1b and 1b′) for heating the hot compressed water by the heat of a monosaccharide solution including the monosaccharides delivered from the solid-acid-catalytic reaction device and a second heat exchanger (1c) for heating the hot compressed water by the heat of a polysaccharide solution including the polysaccharides introduced into the solid-acid-catalytic reaction device from the hot compressed water reaction device. According to the biomass treatment device, it is possible to improve the energy efficiency more than the related art.

    摘要翻译： 一种生物质处理装置（A）包括热压缩水反应装置（1），其通过将热的压缩水通过生物质水解生物质以制备多糖;以及固体酸催化反应装置（2和3），其从 使用固体酸催化剂的多糖，并且该装置包括用于通过单糖溶液的热量加热热压缩水的第一热交换器（1b和1b'）中的至少一种，所述单糖溶液包括从固体酸 - 催化反应装置和第二热交换器（1c），用于通过包含从热压缩水反应装置引入固体酸催化反应装置的多糖的多糖溶液的热量加热热压缩水。 根据生物质处理装置，与现有技术相比，能够提高能量效率。

    SYSTEM AND METHOD FOR TREATING BIOMASS
    3.
    发明申请
    SYSTEM AND METHOD FOR TREATING BIOMASS 审中-公开
    用于处理生物量的系统和方法

    公开(公告)号：US20120232264A1

    公开(公告)日：2012-09-13

    申请号：US13497983

    申请日：2010-09-24

    申请人： Kenji Sato ,  Kentaro Nariai ,  Makoto Kitano ,  Norimitsu Kaneko ,  Michikazu Hara ,  Daizo Yamaguchi

    发明人： Kenji Sato ,  Kentaro Nariai ,  Makoto Kitano ,  Norimitsu Kaneko ,  Michikazu Hara ,  Daizo Yamaguchi

    IPC分类号： C07H1/00 ,  B01J10/00

    CPC分类号： C13K1/02 ,  C12M21/12 ,  C12M45/06 ,  C13K13/00 ,  C13K13/002

    摘要： A biomass treatment apparatus (A) is constituted by a pressurized hot water reaction apparatus (1) in which pressurized hot water is used, biomass is hydrolyzed under first reaction conditions that provide for decomposition of hemicellulose so as to generate a first polysaccharide solution including xylooligosaccharides, and then the biomass is hydrolyzed under second reaction conditions that provide for decomposition of cellulose to generate a second polysaccharide solution including cellooligosaccharides, a first catalysis apparatus (2) in which the first polysaccharide solution that flows out from the pressurized hot water reaction apparatus (1) is hydrolyzed using a solid acid catalyst so as to generate a first monosaccharide solution including xylose, and a second catalysis apparatus (3) in which the second polysaccharide solution that flows out from the pressurized hot water reaction apparatus (1) is hydrolyzed using a solid acid catalyst so as to generate a second monosaccharide solution including glucose.

    摘要翻译： 生物质处理装置（A）由使用加压热水的加压热水反应装置（1）构成，生物质在提供半纤维素分解的第一反应条件下水解，生成含有低聚木糖的第一多糖溶液 然后在提供纤维素分解以产生包含低聚果糖的第二多糖溶液的第二反应条件下水解生物质，第一催化装置（2），其中从加压热水反应装置流出的第一多糖溶液（ 1）使用固体酸催化剂水解，以产生包含木糖的第一单糖溶液和第二催化装置（3），其中从加压热水反应装置（1）流出的第二多糖溶液水解，使用 固体酸催化剂，以产生第二单糖 溶液包括葡萄糖。

    Metal oxynitride electrode catalyst
    5.
    发明授权
    Metal oxynitride electrode catalyst 有权
    金属氮氧化物电极催化剂

    公开(公告)号：US07670712B2

    公开(公告)日：2010-03-02

    申请号：US10581210

    申请日：2004-11-30

    申请人： Kenichiro Ota ,  Nobuyuki Kamiya ,  Shigenori Mitsushima ,  Akimitsu Ishihara ,  Kazunari Doumen ,  Michikazu Hara

    发明人： Kenichiro Ota ,  Nobuyuki Kamiya ,  Shigenori Mitsushima ,  Akimitsu Ishihara ,  Kazunari Doumen ,  Michikazu Hara

    IPC分类号： H01M4/90

    CPC分类号： H01M4/90 ,  B01J27/24 ,  H01M4/9016 ,  H01M8/086

    摘要： An electrode catalyst that maintains catalytic activity under conditions of an electrode potential as high as 0.4 V or above and exhibits improved stability. The metal oxynitride electrode catalyst is composed of an oxynitride containing at least one transition metal element selected from the group consisting of La, Ta, Nb, Ti, and Zr, the metal oxynitride electrode catalyst being used at a potential of 0.4 V or higher relative to the reversible hydrogen electrode potential in an acidic electrolyte. The metal oxynitride electrode catalyst is useful as an electrode catalyst for electrochemical systems used in acidic electrolytes in the fields of water electrolysis, organic electrolysis, fuel cells, etc.

    摘要翻译： 一种电极催化剂，其在电极电位高达0.4V或更高的条件下保持催化活性并表现出改进的稳定性。 金属氧氮化物电极催化剂由含有选自La，Ta，Nb，Ti和Zr中的至少一种过渡金属元素的氧氮化物组成，金属氧氮化物电极催化剂以0.4V或更高的电位使用 到酸性电解质中的可逆氢电极电位。 金属氮氧化物电极催化剂可用作在水电解，有机电解，燃料电池等领域中用于酸性电解质的电化学体系的电极催化剂。

    Carbon-Based Solid Acid, Catalyst Comprising the Solid Acid, and Reaction Using the Solid Acid as Catalyst
    6.
    发明申请
    Carbon-Based Solid Acid, Catalyst Comprising the Solid Acid, and Reaction Using the Solid Acid as Catalyst 有权
    碳固体酸，包含固体酸的催化剂和使用固体酸作为催化剂的反应

    公开(公告)号：US20090099345A1

    公开(公告)日：2009-04-16

    申请号：US12282253

    申请日：2007-03-08

    申请人： Shinichirou Yanagawa ,  Hidesato Kondo ,  Michikazu Hara

    发明人： Shinichirou Yanagawa ,  Hidesato Kondo ,  Michikazu Hara

    IPC分类号： C07G1/00 ,  C08B1/00 ,  C07C41/01 ,  C07C5/02 ,  C07C67/00 ,  C08B33/00

    CPC分类号： C07C29/04 ,  B01J21/18 ,  B01J27/02 ,  B01J31/10 ,  B01J37/084 ,  C01B32/05 ,  C07C41/06 ,  C07C67/08 ,  C07C69/54 ,  C07C69/14 ,  C07C31/10 ,  C07C43/046

    摘要： A carbon-based solid acid which has high activity and high thermal stability and is useful as an acid catalyst for various reactions such as hydration of olefins.The carbon-based solid acid for use as a catalyst is obtained by carbonization and sulfonation of an organic substance, which has a reduction rate of 10 mol % or less of acid content as measured by immersing the solid acid in hot water at 120° C. for 2 hours, is used as the acid catalyst.The organic substance to be used as the raw material for preparing the solid acid is preferably a saccharide having β1-4 glycosidic bond (e.g. cellulose) or lignin. Amylose is also suitable as the raw material. Examples of the reaction for which the solid catalyst can be used include hydration of olefins, etherification of olefins, and acid/alcohol esterification.

    摘要翻译： 一种具有高活性和高热稳定性的碳基固体酸，可用作各种反应（如烯烃水合）的酸催化剂。 用作催化剂的碳系固体酸通过将固体酸浸渍在120℃的热水中而测定的有机物质的还原率为10摩尔％以下的有机物质进行碳化和磺化， 使用2小时作为酸催化剂。 用作制备固体酸的原料的有机物质优选是具有β1-4糖苷键（例如纤维素）或木质素的糖。 直链淀粉也适合作为原料。 可以使用固体催化剂的反应的实例包括烯烃的水合，烯烃的醚化和酸/醇的酯化。

    Polycyclic aromatic carbon based solid strong acid
    7.
    发明授权
    Polycyclic aromatic carbon based solid strong acid 有权
    多环芳烃基固体强酸

    公开(公告)号：US07335790B2

    公开(公告)日：2008-02-26

    申请号：US10544402

    申请日：2003-09-08

    申请人： Kazunari Domen ,  Michikazu Hara

    发明人： Kazunari Domen ,  Michikazu Hara

    IPC分类号： C07C309/38

    CPC分类号： B01J31/06 ,  B01J31/0225 ,  B01J37/20 ,  B01J2231/40 ,  C07C309/38 ,  C07C309/62

    摘要： A composite solid strong acid comprising, a solid acid and a carbon material, wherein said solid acid is obtained by heat treating of polycyclic aromatic hydrocarbons or polycyclic aromatic hydrocarbons to which the carbon material is blended in concentrated sulfuric acid or fuming sulfuric acid, transforming said polycyclic aromatic hydrocarbons to a solid acid which is insoluble in a polar solvent by condensation and sulfonation further compositing with said carbon material.

    摘要翻译： 一种复合固体强酸，其包含固体酸和碳材料，其中所述固体酸是通过热处理多碳芳族烃或多碳芳烃而得到的，所述多环芳烃或多环芳烃是在浓硫酸或发烟硫酸中混合的碳材料，将所述 多环芳香烃与固体酸反应，该固体酸通过与所述碳材料进行缩合和磺化进一步合成而不溶于极性溶剂。