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1.发明授权公开(公告)号：US07928180B2
公开(公告)日：2011-04-19
申请号：US11988008
申请日：2006-06-28
IPC分类号： C08G18/08 , C08G18/28 , C08G63/685
CPC分类号： C08G63/91 , C08G63/912 , C08G73/02 , C08G73/0206 , C08G73/028 , C08L101/16 , Y10T442/60
摘要： The problem of the invention is to provide a novel biodegradable polymer without water solubility (hygroscopicity), but with moldability and excellent water disintegratability and biodegradability, a production method thereof, a molded product thereof and applications thereof. The biodegradable polymer of the invention is a biodegradable polymer having one or more imine bonds within a molecule, characterized in that the imine bond constitutes part of a main chain structure of the biodegradable polymer. The biodegradable polymer preferably comprises a biodegradable unit and an imine unit having one or more imine bonds and has a chemical structure, in which the biodegradable units are linked by the imine unit.
摘要翻译： 本发明的问题是提供一种不具有水溶性（吸湿性）但具有成型性和优异的水分解性和生物降解性的新型可生物降解聚合物，其制备方法，其成型产品和应用。 本发明的可生物降解的聚合物是在分子内具有一个或多个亚胺键的可生物降解的聚合物，其特征在于亚胺键构成可生物降解的聚合物的主链结构的一部分。 生物可降解聚合物优选包含可生物降解的单元和具有一个或多个亚胺键并具有化学结构的亚胺单元，其中可生物降解单元通过亚胺单元连接。
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2.发明申请Biodegradable Polymer, Production Method Thereof, Molded Product Thereof, and Use Thereof 有权可生物降解聚合物，其生产方法，其成型产品及其用途公开(公告)号：US20090142982A1
公开(公告)日：2009-06-04
申请号：US11988008
申请日：2006-06-28
CPC分类号： C08G63/91 , C08G63/912 , C08G73/02 , C08G73/0206 , C08G73/028 , C08L101/16 , Y10T442/60
摘要： The problem of the invention is to provide a novel biodegradable polymer without water solubility (hygroscopicity), but with moldability and excellent water disintegratability and biodegradability, a production method thereof, a molded product thereof and applications thereof. The biodegradable polymer of the invention is a biodegradable polymer having one or more imine bonds within a molecule, characterized in that the imine bond constitutes part of a main chain structure of the biodegradable polymer. The biodegradable polymer preferably comprises a biodegradable unit and an imine unit having one or more imine bonds and has a chemical structure, in which the biodegradable units are linked by the imine unit.
摘要翻译： 本发明的问题是提供一种不具有水溶性（吸湿性）但具有成型性和优异的水分解性和生物降解性的新型可生物降解聚合物，其制备方法，其成型产品和应用。 本发明的可生物降解的聚合物是在分子内具有一个或多个亚胺键的可生物降解的聚合物，其特征在于亚胺键构成可生物降解的聚合物的主链结构的一部分。 生物可降解聚合物优选包含可生物降解的单元和具有一个或多个亚胺键并具有化学结构的亚胺单元，其中可生物降解单元通过亚胺单元连接。
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3.发明授权Curing agent composition for epoxy resins, epoxy resin composition and use thereof 有权环氧树脂固化剂组合物，环氧树脂组合物及其应用公开(公告)号：US06911503B2
公开(公告)日：2005-06-28
申请号：US10432368
申请日：2002-09-27
CPC分类号： H01L23/293 , C08G59/621 , C08G59/688 , H01L2924/0002 , H01L2924/00
摘要： An epoxy resin composition comprising an epoxy resin (A), a curing agent (B) and a curing accelerator (C), wherein the curing agent (B) is a phenol compound having two or more hydroxyl functional groups or a compound obtained by esterification of the phenol compound or a mixture of these compounds, and the curing accelerator (C) is a salt of a phosphazenium compound represented by a formula (I): (wherein R1s each represent a hydrogen atom, a linear, branched or cyclic alkyl group having 1 to 10 carbon atoms or an aryl or aralkyl group having 6 to 10 carbon atoms and may be all the same or different from one another; and Z− represents a halogen anion, hydroxy anion, alkoxy anion, aryloxy anion or carboxy anion).
摘要翻译： 包含环氧树脂（A），固化剂（B）和固化促进剂（C）的环氧树脂组合物，其中固化剂（B）是具有两个或多个羟基官能团的酚化合物或通过酯化获得的化合物 的酚化合物或这些化合物的混合物，固化促进剂（C）是式（I）表示的磷氮杂鎓化合物的盐：（其中R 1〜4各自表示氢原子 ，具有1至10个碳原子的直链，支链或环状烷基或具有6至10个碳原子的芳基或芳烷基，并且可以彼此相同或不同;且Z代表 卤素阴离子，羟基阴离子，烷氧基阴离子，芳氧基阴离子或羧基阴离子）。
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4.发明授权Polar group-containing olefin copolymer, process for preparing the same, thermoplastic resin composition containing the copolymer, and uses thereof 有权含极性基团的烯烃共聚物，其制备方法，含有共聚物的热塑性树脂组合物及其用途公开(公告)号：US07393907B2
公开(公告)日：2008-07-01
申请号：US10713278
申请日：2003-11-17
申请人： Junichi Imuta , Norio Kashiwa , Seiji Ota , Satoru Moriya , Tadahito Nobori , Kazumi Mizutani
发明人： Junichi Imuta , Norio Kashiwa , Seiji Ota , Satoru Moriya , Tadahito Nobori , Kazumi Mizutani
IPC分类号： C08F232/08
CPC分类号： C08F297/02 , C08F4/65912 , C08F4/6592 , C08F210/00 , C08F210/02 , C08F210/06 , C08F210/08 , C08F210/14 , C08F210/16 , C08J5/18 , C08J2351/06 , C08J2371/02 , C08J2387/00 , C08L53/00 , C08L2666/02 , C09J153/00 , C08F4/65927 , C08F222/06 , C08F2500/03 , C08F2500/12 , C08F2500/09 , C08F216/00
摘要： The present invention is a polar group-containing olefin copolymer having excellent adhesion properties to metals or polar resins and excellent compatibility therewith. A process for preparing the copolymer, a thermoplastic resin composition containing the copolymer, and uses thereof are also described. The polar group-containing olefin copolymer comprises a constituent unit derived from an α-olefin of 2 to 20 carbon atoms, and a constituent unit derived from a straight-chain, branched or cyclic polar group-containing monomer having at the end a polar group such as a hydroxyl group or an epoxy group and/or a constituent unit derived from a macromonomer having at the end a polymer segment obtained by anionic polymerization, ring-opening polymerization or polycondensation. The polar group-containing olefin copolymer and the thermoplastic resin composition containing the copolymer are used for films, sheets, modifiers, building/civil engineering materials, automobile exterior trim, electric/electronic parts, coating bases, compatibilizing agents, etc.
摘要翻译： 本发明是对金属或极性树脂具有优异的粘附性的极性基团的烯烃共聚物，与其相容性优异。 还描述了制备共聚物的方法，含有共聚物的热塑性树脂组合物及其用途。 含有极性基团的烯烃共聚物包含衍生自2-20个碳原子的α-烯烃的构成单元和衍生自具有极性基团的直链，支链或环状极性基团单体的构成单元 例如羟基或环氧基和/或衍生自大分子单体的结构单元，其末端具有通过阴离子聚合，开环聚合或缩聚获得的聚合物链段。 含有极性基团的烯烃共聚物和含有共聚物的热塑性树脂组合物用于薄膜，片材，改性剂，建筑/土木工程材料，汽车外饰件，电气/电子部件，涂料基料，相容剂等。
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公开(公告)号：US06297332B1
公开(公告)日：2001-10-02
申请号：US09295592
申请日：1999-04-22
IPC分类号： C08F28300
CPC分类号： H01B3/40 , C08G59/688 , Y10T428/12528
摘要： An epoxy-resin composition comprising (A) an at least bifunctional epoxy compound and/or an at least bifunctional epoxy resin, (B) a curing agent, and (C) an accelerating agent, the accelerating agent essentially containing a phosphine oxide represented by general formula (1); where R1 to R6 all of which may be the same or not are hydrogen, straight, branched or cyclic alkyl having 1 to 10 carbons or aryl or aralkyl having 6 to 10 carbons.
摘要翻译： 一种环氧树脂组合物，其包含（A）至少双官能环氧化合物和/或至少双官能环氧树脂，（B）固化剂和（C）促进剂，所述促进剂基本上含有由 通式（1）;其中R 1至R 6全部可以相同或不同，为氢，具有1至10个碳的直链，支链或环状烷基或具有6至10个碳的芳基或芳烷基。
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公开(公告)号：US6153794A
公开(公告)日：2000-11-28
申请号：US348586
申请日：1999-07-07
申请人： Katsuhiko Funaki , Isao Hara , Takaomi Hayashi , Shinji Kiyono , Atsushi Shibahara , Kazumi Mizutani , Tadahito Nobori , Usaji Takaki
发明人： Katsuhiko Funaki , Isao Hara , Takaomi Hayashi , Shinji Kiyono , Atsushi Shibahara , Kazumi Mizutani , Tadahito Nobori , Usaji Takaki
CPC分类号： C07F9/224 , C07F9/065 , C08G65/2675
摘要： An organic compound which is basic and soluble in an organic solvent, does not have a problem in preparation or handling and exhibits catalytic activity as a basic compound, i.e., a phosphine sulfide represented by formula (1), and a manufacturing process therefor, i.e., manufacturing a phosphine sulfide represented by formula (1), by reacting one molecule of thiophosphoryl chloride with three molecules of a phosphorane represented by formula (2). The phosphine sulfide can be used in a process for effectively manufacturing a poly(alkylene oxide) by polymerizing an alkylene oxide in the presence of the phosphine sulfide or of the phosphine sulfide and an active hydrogen compound selected from water and organic compounds having a partial structure of --OH or --NH--; and 2) a process for manufacturing a 1,2-dioxyethane derivative from an epoxy compound, i.e, manufacturing a 1,2-dioxyethane derivative by reacting an epoxy compound with a carboxylate, carboxylic anhydride, carbonate or phenol compound, respectively, in the presence of the phosphine sulfide.
摘要翻译： 碱性且可溶于有机溶剂的有机化合物在制备或处理中没有问题，并且表现出作为碱性化合物的催化活性，即由式（1）表示的硫化膦及其制备方法，即 制备由式（1）表示的硫化膦，通过使一分子的硫代磷酰氯与由式（2）表示的三价分子的三分子反应。 所述硫化膦可用于通过在硫化膦或硫化氢存在下聚合烯化氧和选自水和具有部分结构的有机化合物的活性氢化合物来有效制造聚（环氧烷）的方法 的-OH或-NH-; 和2）由环氧化合物制造1,2-二氧乙烷衍生物的方法，即分别通过使环氧化合物与羧酸酯，羧酸酐，碳酸酯或酚化合物反应制备1,2-二氧乙烷衍生物 硫化磷的存在。
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7.发明授权Process for preparing an organic compound from an oxirane-containing compound in the presence of a tris(triaminophosphoranylideneamino)phosphine oxide 有权在三（三氨基亚正膦基氨基）氧化膦存在下由含环氧乙烷的化合物制备有机化合物的方法
公开(公告)号：US6130346A
公开(公告)日：2000-10-10
申请号：US289989
申请日：1999-04-13
申请人： Tadahito Nobori , Takaomi Hayashi , Isao Hara , Shinji Kiyono , Atsushi Shibahara , Katsuhiko Funaki , Tatsuhiro Urakami , Keisuke Takuma , Usaji Takaki
发明人： Tadahito Nobori , Takaomi Hayashi , Isao Hara , Shinji Kiyono , Atsushi Shibahara , Katsuhiko Funaki , Tatsuhiro Urakami , Keisuke Takuma , Usaji Takaki
IPC分类号： C07B41/04 , C07C41/03 , C07C67/26 , C07C68/06 , C07C303/26 , C07C309/66 , C07C309/73 , C07C319/14 , C07C323/17 , C07C68/00
CPC分类号： C07C319/14 , C07B41/04 , C07C303/26 , C07C41/03 , C07C67/26 , C07C68/06 , C07C2101/14 , C07C2102/42
摘要： A process for preparing an organic compound, comprising conducting an organic reaction in the presence of a phosphine oxide represented by formula (1); ##STR1## where R.sup.1 is the same or different and each represents a hydrogen or hydrocarbon group with 1 to 10 carbon atoms, and x is the amount of water as a molar ratio which is 0 to 5.0, exhibiting a high catalytic performance especially in an organic reaction involving an alkylene oxide.
摘要翻译： 一种制备有机化合物的方法，包括在由式（1）表示的氧化膦存在下进行有机反应; 其中R1相同或不同，并且各自表示氢或具有1-10个碳原子的烃基，x是摩尔比为0至5.0的水的量，表现出高的催化性能，特别是在涉及 环氧烷。
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8.发明申请NOVEL PHOSPHAZENE-SUPPORTED CATALYST, NOVEL COMPOUND THEREOF AND USE THEREOF 审中-公开新型磷酸盐载体催化剂，其新颖化合物及其用途公开(公告)号：US20110288240A1
公开(公告)日：2011-11-24
申请号：US13198397
申请日：2011-08-04
申请人： Naritoshi YOSHIMURA , Shinji Kiyono , Kazumi Mizutani , Isao Hara , Takaomi Hayashi , Tadahito Nobori , Yoshihiro Yamamoto , Miyuki Konno , Yoshihisa Inoue , Akira Matsuura , Tuneyuki Ohkubo
发明人： Naritoshi YOSHIMURA , Shinji Kiyono , Kazumi Mizutani , Isao Hara , Takaomi Hayashi , Tadahito Nobori , Yoshihiro Yamamoto , Miyuki Konno , Yoshihisa Inoue , Akira Matsuura , Tuneyuki Ohkubo
CPC分类号： C08G63/823 , B01J31/0265 , B01J2231/12 , C07F9/065 , C07F9/224
摘要： A phosphazene-supported catalyst in which a support is bonded to a group represented by the general formula (1): wherein n, Zn−, a, b, c, d, R, R1 and D are all defined. The phosphazene-supported catalyst is highly effective to catalyze various organic reactions, and further has no reduction of activity even after recovery and reuse of the catalyst, thus it being economically advantageous. In addition, the polymerization of cyclic monomers, substitution of substituents, carbon-carbon bond forming reactions and the like can be conducted with extremely high efficiency.
摘要翻译： 载体与由通式（1）表示的基团键合的磷腈担载催化剂：其中n，Zn-，a，b，c，d，R，R1和D全部定义。 磷腈担载的催化剂对于催化各种有机反应是非常有效的，即使在回收和再利用催化剂之后也不会降低活性，因此在经济上是有利的。 此外，可以极高效率进行环状单体的聚合，取代基的取代，碳 - 碳键形成反应等。
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公开(公告)号：US06255537B1
公开(公告)日：2001-07-03
申请号：US09289990
申请日：1999-04-13
申请人： Takaomi Hayashi , Katsuhiko Funaki , Atsushi Shibahara , Kazumi Mizutani , Isao Hara , Shinji Kiyono , Tadahito Nobori , Usaji Takaki
发明人： Takaomi Hayashi , Katsuhiko Funaki , Atsushi Shibahara , Kazumi Mizutani , Isao Hara , Shinji Kiyono , Tadahito Nobori , Usaji Takaki
IPC分类号： C07C4313
CPC分类号： C08G65/2675 , C08G65/10 , C08G65/2663
摘要： There is provided a process for preparing a poly(alkylene oxide) by using a polymerization initiator which does not cause any problem on preparing and handling in the preparation of the polyalkylene oxide by polymerizing an alkylene oxide compound and does not require a special treatment before the initiation of the polymerization. That is, it is a process of polymerizing the alkylene oxide compound in the presence of a phosphine oxide compound represented by the formula (1): wherein R is the same or different and each represents a hydrocarbon group having 1 to 10 carbon atoms, and x represents an amount of water molecules contained in terms of a molar ratio and is within a range from 0 to 5.0, or in the presence of said phosphine oxide compound and an active hydrogen compound selected from water or an organic compound having a partial structural formula —OH or —NH—.
摘要翻译： 提供了一种通过使用聚合引发剂制备聚（环氧烷）的方法，该聚合引发剂在通过聚合烯化氧化合物制备聚环氧烷的制备和处理中不会引起任何问题，并且不需要在 引发聚合。 也就是说，它是在式（1）表示的氧化膦化合物存在下使烯化氧化合物聚合的方法：其中R相同或不同，各自代表具有1-10个碳原子的烃基，和 x表示以摩尔比表示的水分子的含量，在0〜5.0的范围内，或在所述氧化膦化合物和活性氢化合物存在下，选自水或具有部分结构式的有机化合物 -OH或-NH-。
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公开(公告)号：US6063825A
公开(公告)日：2000-05-16
申请号：US136307
申请日：1998-08-19
申请人： Masahiro Isobe , Kazuhiko Ohkubo , Seijiro Sakai , Usaji Takaki , Tadahito Nobori , Tsukuru Izukawa , Satoshi Yamasaki
发明人： Masahiro Isobe , Kazuhiko Ohkubo , Seijiro Sakai , Usaji Takaki , Tadahito Nobori , Tsukuru Izukawa , Satoshi Yamasaki
IPC分类号： C08G18/40 , C08G18/63 , C08G18/66 , C08G65/26 , C08L71/02 , C08J9/00 , C08F8/30 , C08G18/00 , C08K3/20 , C08L75/00
CPC分类号： C08G65/2672 , C08G18/4072 , C08G18/632 , C08G18/667 , C08L71/02 , C08G2101/0008 , C08G2101/0058 , C08G2101/0083
摘要： A flexible polyurethane foam prepared by reacting polyisocyanate with polyol and/or polymer polyol containing dispersed polymer microparticles obtained by polymerizing an unsaturated compound, water, catalyst, surfactant and, when needed, crosslinking agent and other auxiliary agents, wherein a portion or the whole of the polyol and/or the polymer polyol is prepared in the presence of a compound having a nitrogen-phosphorus double bond as a catalyst, have excellent wet compression set, fatigue by constant-load pounding and dynamic durability.
摘要翻译： 一种柔性聚氨酯泡沫，其通过使多异氰酸酯与多元醇和/或聚合物多元醇反应制备，所述多元醇和/或聚合物多元醇含有通过聚合不饱和化合物，水，催化剂，表面活性剂和（如果需要的话）交联剂和其它助剂而获得的分散的聚合物微粒， 在具有氮磷双键作为催化剂的化合物的存在下制备多元醇和/或聚合物多元醇，具有优异的湿压缩永久变形，通过恒定负荷冲击的疲劳和动态耐久性。
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