AQUEOUS DISPERSIONS OF CROSS-LINKED, TERTIARY ESTER GROUPS CONTAINING EMULSION POLYMERISATES AND WATER-ABSORBENT MATERIALS ON A CARRIER MATERIAL MADE THEREOF
    1.
    发明申请
    AQUEOUS DISPERSIONS OF CROSS-LINKED, TERTIARY ESTER GROUPS CONTAINING EMULSION POLYMERISATES AND WATER-ABSORBENT MATERIALS ON A CARRIER MATERIAL MADE THEREOF 审中-公开
    含有乳液聚合物和其吸收材料的交联聚合物的季铵盐分散体及其载体材料的分散性

    公开(公告)号:US20100189994A1

    公开(公告)日:2010-07-29

    申请号:US12376797

    申请日:2007-08-06

    摘要: Aqueous dispersions of crosslinked emulsion polymers comprising tertiary ester groups, comprising (a) at least 50% by weight of an ester derived from a tertiary alcohol and an ethylenically unsaturated C3 to C5 carboxylic acid, (b) 0.001% to 5.0% by weight of at least one compound having at least two ethylenically unsaturated double bonds, and (c) 0% to 49.999% by weight of at least one other monoethylenically unsaturated compound in interpolymerized form and having an average particle size of not more than 1000 nm, and water-absorbing materials obtainable by coating a backing material with the aqueous dispersion described of crosslinked emulsion polymers comprising tertiary ester groups, drying and heating the thus treated backing material to a temperature of at least 140° C. to form carboxyl groups from the tertiary ester groups of the emulsion polymer and at least partly neutralizing the carboxyl groups, and also the use of the water-absorbing materials as an absorbent for water and aqueous fluids.

    摘要翻译: 包含叔酯基团的交联乳液聚合物的水分散体,包含(a)至少50重量%的衍生自叔醇和烯属不饱和C3至C5羧酸的酯,(b)0.001重量%至5.0重量% 至少一种具有至少两个烯键式不饱和双键的化合物,和(c)0〜49.999%重量的至少一种互聚形式的平均粒径不大于1000nm的其它单烯属不饱和化合物,以及水 - 通过用包含叔酯基团的交联乳液聚合物描述的水性分散体涂覆背衬材料获得的吸收材料,干燥并将由此处理的背衬材料加热至至少140℃的温度以从叔酯基团形成羧基 的乳液聚合物并且至少部分中和羧基,并且还使用吸水材料作为水的吸收剂 d含水流体。

    ASSOCIATIVE THICKENER COMPRISING ACID MONOMER, ASSOCIATIVE MONOMER AND NONIONIC MONOMER
    4.
    发明申请
    ASSOCIATIVE THICKENER COMPRISING ACID MONOMER, ASSOCIATIVE MONOMER AND NONIONIC MONOMER 有权
    包含酸性单体,相关单体和非离子单体的相关增稠剂

    公开(公告)号:US20110189487A1

    公开(公告)日:2011-08-04

    申请号:US13018777

    申请日:2011-02-01

    摘要: As associative thickener obtainable by free radical polymerization, the preparation thereof and the use thereof in paper coating slips are described. The associative thickener is formed from (a) acid monomers selected from ethylenically unsaturated C3- to C8-carboxylic acids, (b) associative monomers of the general formula H2C═CR1—COO(EO)n—(PO)m—R2, in which R1 is hydrogen or methyl, n is a number of at least two, m is a number from zero to 50, EO is an ethylene oxide group, PO is a propylene oxide group and R2 is a C8-C30-alkyl group or a C8-C30-alkaryl group, and (c) nonionic, copolymerizable monomers differing from a) and b), the reaction product having been reacted, after the polymerization, with initiators forming nonionic radicals.

    摘要翻译: 作为通过自由基聚合获得的缔合增稠剂,其制备方法及其在纸张涂布纸上的用途被描述。 缔合增稠剂由(a)选自烯属不饱和C 3 -C 8羧酸的酸单体形成,(b)通式为H 2 C = CR 1 -COO(EO)n - (PO)m -R 2的缔合单体, 其中R1为氢或甲基,n为至少两个数,m为0至50的数,EO为环氧乙烷基,PO为环氧丙烷基,R 2为C 8 -C 30 - 烷基或 C8-C30-烷芳基,(c)不同于a)和b)的非离子型可共聚单体,聚合后反应产物与形成非离子基的引发剂反应。

    PAPER AND CARDBOARD PACKAGING WITH BARRIER COATING OF A POLYMER MIXTURE
    5.
    发明申请
    PAPER AND CARDBOARD PACKAGING WITH BARRIER COATING OF A POLYMER MIXTURE 有权
    用聚合物混合物涂布纸和纸板包装

    公开(公告)号:US20120308749A1

    公开(公告)日:2012-12-06

    申请号:US13483762

    申请日:2012-05-30

    IPC分类号: B32B29/06 B05D7/24 B32B1/02

    摘要: Paper or cardboard packaging produced from recycled paper contaminated by mineral oil, where the packaging includes a barrier layer obtained by applying an aqueous polymeric dispersion containing a mixture of at least two polymers A and B. Polymer A is obtained by emulsion polymerization of C1-C4 alkyl(meth)acrylates, acid monomers, e.g., acrylic acid or methacrylic acid, 0-20 wt % of acrylonitrile and 0-10 wt % of further monomers, where the glass transition temperature of copolymer A is greater than +45° C. and the glass transition temperature of polymer B is less than +10° C. The mean value calculated from the glass transition temperatures of the individual polymers is +10 to +45° C. The barrier layer may be situated on one of the surfaces of the packaging or form one of multiple layers of a multilayered packaging coating or be situated as a coating on one side of an inner bag situated within the packaging.

    摘要翻译: 由矿物油污染的再生纸生产的纸或纸板包装,其中包装包含通过施加含有至少两种聚合物A和B的混合物的水性聚合物分散体获得的阻隔层。聚合物A通过C1-C4的乳液聚合 烷基(甲基)丙烯酸酯,酸单体,例如丙烯酸或甲基丙烯酸,0-20重量%的丙烯腈和0-10重量%的其它单体,其中共聚物A的玻璃化转变温度大于+ 45℃。 聚合物B的玻璃化转变温度低于+ 10℃。由各聚合物的玻璃化转变温度计算出的平均值为+ 10〜+ 45℃。阻挡层可以位于 包装或形成多层包装涂料的多层之一,或者作为涂层位于位于包装内的内袋的一侧上。

    USE OF POLYELECTROLYTE COMPLEXES FOR PRODUCING POLYMER FOILS WITH OXYGEN-BARRIER PROPERTIES
    6.
    发明申请
    USE OF POLYELECTROLYTE COMPLEXES FOR PRODUCING POLYMER FOILS WITH OXYGEN-BARRIER PROPERTIES 有权
    用于生产具有氧阻挡性能的聚合物箔的聚电解质复合材料的应用

    公开(公告)号:US20120148855A1

    公开(公告)日:2012-06-14

    申请号:US13389680

    申请日:2010-08-17

    摘要: The use of polyelectrolyte complexes is described, for providing an oxygen barrier to packaging materials made of polymer foils. Polymeric components of the polyelectrolyte complex are applied in polymerized form to the polymer foil. The polymer foil is either coated with an aqueous dispersion comprising a dispersed polyelectrolyte complex previously produced by water-in-water emulsion polymerization, or is coated with a composition comprising a polyelectrolyte complex produced from anionic polymer and from cationic surfactant, or the polymer foil is coated with at least three alternating layers, where respectively one of two adjacent layers comprises an anionic polyelectrolyte component and the other of two adjacent layers comprises a cationic polyelectrolyte component, and polyelectrolyte complexes form at the opposite, adjacent interfaces of the alternating layers.

    摘要翻译: 描述了使用聚电解质络合物,用于为由聚合物箔制成的包装材料提供氧阻隔。 将聚电解质复合物的聚合物组分以聚合形式施加到聚合物箔上。 聚合物箔片涂覆有预先由水包水乳液聚合制备的分散的聚电解质络合物的水性分散体,或涂覆有包含由阴离子聚合物和阳离子表面活性剂产生的聚电解质络合物的组合物,或聚合物箔是 涂覆有至少三个交替层,其中两个相邻层中的一个分别包含阴离子聚电解质组分,并且两个相邻层中的另一个包含阳离子聚电解质组分,并且在交替层的相对的相邻界面处形成聚电解质络合物。

    Use of polyelectrolyte complexes for producing polymer foils with oxygen-barrier properties
    9.
    发明授权
    Use of polyelectrolyte complexes for producing polymer foils with oxygen-barrier properties 有权
    使用聚电解质复合物制备具有阻氧性能的聚合物薄膜

    公开(公告)号:US08980437B2

    公开(公告)日:2015-03-17

    申请号:US13389680

    申请日:2010-08-17

    IPC分类号: B32B27/08 B05D7/00 B05D5/00

    摘要: The use of polyelectrolyte complexes is described, for providing an oxygen barrier to packaging materials made of polymer foils. Polymeric components of the polyelectrolyte complex are applied in polymerized form to the polymer foil. The polymer foil is either coated with an aqueous dispersion comprising a dispersed polyelectrolyte complex previously produced by water-in-water emulsion polymerization, or is coated with a composition comprising a polyelectrolyte complex produced from anionic polymer and from cationic surfactant, or the polymer foil is coated with at least three alternating layers, where respectively one of two adjacent layers comprises an anionic polyelectrolyte component and the other of two adjacent layers comprises a cationic polyelectrolyte component, and polyelectrolyte complexes form at the opposite, adjacent interfaces of the alternating layers.

    摘要翻译: 描述了使用聚电解质络合物,用于为由聚合物箔制成的包装材料提供氧阻隔。 将聚电解质复合物的聚合物组分以聚合形式施加到聚合物箔上。 聚合物箔片涂覆有预先由水包水乳液聚合制备的分散的聚电解质络合物的水性分散体,或涂覆有包含由阴离子聚合物和阳离子表面活性剂产生的聚电解质络合物的组合物,或聚合物箔是 涂覆有至少三个交替层,其中两个相邻层中的一个分别包含阴离子聚电解质组分,并且两个相邻层中的另一个包含阳离子聚电解质组分,并且在交替层的相对的相邻界面处形成聚电解质络合物。