公开(公告)号：US5126491A

公开(公告)日：1992-06-30

申请号：US562129

申请日：1990-08-03

申请人： Mario G. Clerici ,  Bartolomeo Anfossi ,  Giuseppe Bellussi

发明人： Mario G. Clerici ,  Bartolomeo Anfossi ,  Giuseppe Bellussi

IPC分类号： B01J29/04 ,  B01J29/87 ,  B01J29/88 ,  B01J29/89 ,  C07B61/00 ,  C07C27/12 ,  C07C27/16 ,  C07C29/48 ,  C07C31/125 ,  C07C45/28 ,  C07C49/04

CPC分类号： C07C45/28 ,  C07C29/48 ,  C07C2101/14 ,  Y02P20/582

摘要： Process for oxidating paraffinic compounds in order to yield the corresponding alcoholic and/or ketonic compounds, which process consists of reacting said paraffins with an aqueous solution of hydrogen peroxide, possibly dissolved in a solvent, by operating at a temperature comprised within the range of from 0.degree. C. to 100.degree. C., in the presence of a titanium-silicalite of formulapHMO.sub.2.qTiO.sub.2.SiO.sub.2whereinM is a metal selected from among aluminum, gallium and iron,p is comprised within the range of from 0 to 0.05 andq is comprised within the range of from 0.0001 to 0.04, and the H.sup.+ of HMO.sub.2 can be least partially replaceable or replaced by cations.

公开(公告)号：US5578744A

公开(公告)日：1996-11-26

申请号：US444414

申请日：1995-05-19

申请人： Angela Carati ,  Enrico Davini ,  Mario G. Clerici ,  Giuseppe Bellussi

发明人： Angela Carati ,  Enrico Davini ,  Mario G. Clerici ,  Giuseppe Bellussi

IPC分类号： B01J21/08 ,  B01J23/08 ,  B01J23/14 ,  B01J23/22 ,  B01J27/18 ,  B01J37/00 ,  B01J37/03 ,  C01B33/16 ,  C07B33/00 ,  C07B37/02 ,  C07B61/00 ,  C07C2/10 ,  C07C2/58 ,  C07C2/66 ,  C07C11/02 ,  C07C15/02 ,  C07C37/60 ,  C07C249/04 ,  C07C251/44 ,  C07D301/19 ,  C07D303/04 ,  C07D303/14 ,  C07C2/00 ,  C07C2/12

CPC分类号： C07D301/19 ,  B01J21/08 ,  B01J37/033 ,  C07C2/10 ,  C07C2/66 ,  C07C249/04 ,  C07C37/60 ,  C07D303/04 ,  C07D303/14 ,  C07C2521/08 ,  C07C2523/08 ,  C07C2523/745

摘要： A catalytically active gel is described consisting of a silica matrix with uniform porosity, monomodal pore distribution and high surface area, within which one or metal oxides possessing catalytic activity are dispersed. A process for preparing this catalytic gel is also described.

摘要翻译： 描述了一种催化活性凝胶，其由具有均匀孔隙率，单峰孔分布和高表面积的二氧化硅基质组成，其中分散有一种或具有催化活性的金属氧化物。 还描述了制备该催化凝胶的方法。

公开(公告)号：US4743573A

公开(公告)日：1988-05-10

申请号：US854527

申请日：1986-04-22

申请人： Ugo Romano ,  Mario G. Clerici ,  Giuseppe Bellussi ,  Franco Buonomo

发明人： Ugo Romano ,  Mario G. Clerici ,  Giuseppe Bellussi ,  Franco Buonomo

IPC分类号： B01J29/86 ,  C07C37/08 ,  C07C45/53 ,  B01J29/06

CPC分类号： C07C37/08 ,  B01J29/86 ,  C07C45/53 ,  Y02P20/52

摘要： The present invention relates to a catalyst for the selective decomposition of cumene hydroperoxide, composed of zeolite crystals wherein a portion of the silicon atoms in the crystal lattice of silica is replaced by Al and B. The zeolite crystals are bonded to each other by a siliceous bonding agent which allows the catalyst to assume the shape of mechanically stable microspheres.The invention relates also to a process in which the catalyst is used, and to the related operating conditions.

摘要翻译： 本发明涉及用于选择性分解氢过氧化枯烯的催化剂，其由沸石晶体组成，其中二氧化硅晶格中的一部分硅原子被Al和B代替。沸石晶体通过硅质 粘合剂，其允许催化剂呈现机械稳定的微球的形状。 本发明还涉及使用催化剂和相关操作条件的方法。

公开(公告)号：US5500199A

公开(公告)日：1996-03-19

申请号：US217072

申请日：1994-03-24

申请人： Giuseppe Bellussi ,  Franco Buonomo ,  Antonio Esposito ,  Mario G. Clerici ,  Ugo Romano

发明人： Giuseppe Bellussi ,  Franco Buonomo ,  Antonio Esposito ,  Mario G. Clerici ,  Ugo Romano

IPC分类号： C01B39/00 ,  C01B35/10 ,  C01B39/02 ,  C01B39/04 ,  C01B39/06 ,  C01B39/36 ,  C01B39/38 ,  C01B39/40 ,  C01B39/42 ,  C01B33/26 ,  B01J29/06

CPC分类号： C01B39/026 ,  C01B35/1009

摘要： Zeolites having a pore diameter comprised within the range of from 5 to 12 .ANG. are bonded with amorphous oligomeric silica, by dispersing them in an aqueous solution of silica and alkylammonium hydroxide, and submitting the obtained suspension to a quick drying.

摘要翻译： 通过将其分散在二氧化硅和烷基氢氧化铵的水溶液中，将具有5-12个电极范围的孔径的沸石与无定形低聚二氧化硅结合，并将所得悬浮液快速干燥。

公开(公告)号：US5290533A

公开(公告)日：1994-03-01

申请号：US750240

申请日：1991-08-16

申请人： Giuseppe Bellussi ,  Mario G. Clerici ,  Aldo Giusti ,  Franco Buonomo

发明人： Giuseppe Bellussi ,  Mario G. Clerici ,  Aldo Giusti ,  Franco Buonomo

IPC分类号： B01J29/89 ,  C01B37/00 ,  C07D301/12 ,  C07D303/04 ,  C01B33/34

CPC分类号： C07D303/04 ,  B01J29/89 ,  C01B37/005 ,  C07D301/12 ,  Y10S423/22

摘要： A crystalline, porous, synthetic material is disclosed, together with its related preparation process.Such a material of zeolitic character, containing silicon, titanium and iron oxides, corresponds, in its calcined and anhydrous state, to the following empi rical formulapHFeO.sub.2.qTiO.sub.2.SiO.sub.2wherein p has a value greater than zero and lower than or equal to 0.050, q has a value greater than zero and lower than or equal to 0.025, and the H.sup.+ of HFeO.sub.2 can be at least partly replaceable or replaced by cations.

摘要翻译： 公开了一种结晶多孔合成材料及其相关的制备方法。 这种具有硅，钛和氧化铁的沸石特性的材料在其煅烧和无水状态下对应于以下公式：pHFeO2.qTiO2.SiO2，其中p具有大于零且小于或等于0.050的值 ，q具有大于零且小于或等于0.025的值，并且HFeO 2的H +可以至少部分替代或被阳离子替代。

公开(公告)号：US5235111A

公开(公告)日：1993-08-10

申请号：US730553

申请日：1991-07-16

申请人： Mario G. Clerici ,  Giuseppe Bellussi

发明人： Mario G. Clerici ,  Giuseppe Bellussi

IPC分类号： B01J29/04 ,  B01J29/89 ,  C07B61/00 ,  C07C27/12 ,  C07C29/50 ,  C07C31/02 ,  C07C31/125 ,  C07C45/28 ,  C07C45/33 ,  C07C49/04

CPC分类号： C07C45/33 ,  B01J29/89 ,  C07C29/50 ,  C07C45/28 ,  Y02P20/582

摘要： Process for oxidating paraffinic compounds into their corresponding alcoholic and/or ketonic derivatives, which process consists in causing said paraffins to react, at a temperature comprised within the range of from 0.degree. C. to 100.degree. C., preferably in an acidic medium, with a mixture of oxygen and hydrogen, in the presence of a catalyst on the basis of titanium-silicalite and of a noble metal and/or a derivative of such a metal.

公开(公告)号：US5241119A

公开(公告)日：1993-08-31

申请号：US595665

申请日：1990-10-11

申请人： Mario G. Clerici ,  Giuseppe Bellussi ,  Ugo Romano

发明人： Mario G. Clerici ,  Giuseppe Bellussi ,  Ugo Romano

IPC分类号： B01J29/04

CPC分类号： B01J29/04 ,  Y02P20/582

摘要： Process for the preparation of 4,4'-diaminodiphenylmethane and its derivatives.4,4'-diaminodiphenylmethane and its derivatives are prepared by the condensation of aniline, or its derivative, and aldehyde, or its precursor and/or isomerization of appropriate intermediate products. The reaction proceeds with zeolites acting as catalysts; these catalysts, which are selected in accordance with the reaction to be effected, are preferably zeolites based on Si, Al and B; Si, Al and Ti; Ti and Fe; ZSM-5; or Y zeolites.

摘要翻译： 制备4,4'-二氨基二苯甲烷及其衍生物的方法。 4,4'-二氨基二苯基甲烷及其衍生物通过苯胺或其衍生物与醛或其前体的缩合和/或合适的中间产物的异构化来制备。 反应进行作为催化剂的沸石; 根据要进行的反应选择的这些催化剂优选基于Si，Al和B的沸石; Si，Al和Ti; Ti和Fe; ZSM-5; 或Y沸石。

公开(公告)号：US4895988A

公开(公告)日：1990-01-23

申请号：US110329

申请日：1987-10-20

申请人： Mario G. Clerici ,  Giuseppe Bellussi

发明人： Mario G. Clerici ,  Giuseppe Bellussi

IPC分类号： B01J29/04 ,  B01J27/00 ,  B01J29/86 ,  B01J29/88 ,  B01J29/89 ,  B01J39/14 ,  C07B31/00 ,  C07B37/04 ,  C07B61/00 ,  C07C1/00 ,  C07C2/86 ,  C07C15/12 ,  C07C15/16 ,  C07C27/00 ,  C07C37/16 ,  C07C37/20 ,  C07C39/16 ,  C07C41/00 ,  C07C41/30 ,  C07C43/205 ,  C07C67/00 ,  C07C39/12

CPC分类号： C07C41/30 ,  B01J29/86 ,  B01J29/89 ,  C07C37/115 ,  C07C37/20 ,  Y02P20/582

摘要： The mutual condensation of aromatic and carbonylic compounds is carried out with zeolitic materials derived from silicalite by replacing a portion of silicon with B and Al, Al and Ti, Ti and Fe, and with ZSM-5, to yield diaryl-alkanes.

摘要翻译： 芳烃和羰基化合物的相互缩合通过用B和Al，Al和Ti，Ti和Fe以及ZSM-5代替一部分硅来产生硅沸石的沸石材料进行，得到二芳基烷烃。

公开(公告)号：US5409876A

公开(公告)日：1995-04-25

申请号：US37344

申请日：1993-03-25

申请人： Mario G. Clerici ,  Giuseppe Bellussi

发明人： Mario G. Clerici ,  Giuseppe Bellussi

IPC分类号： B01J29/04 ,  B01J29/89 ,  C07B61/00 ,  C07C27/12 ,  C07C29/50 ,  C07C31/02 ,  C07C31/125 ,  C07C45/28 ,  C07C45/33 ,  C07C49/04 ,  B01J21/06 ,  B01J23/38

CPC分类号： C07C45/33 ,  B01J29/89 ,  C07C29/50 ,  C07C45/28 ,  Y02P20/582

摘要： Process for oxidating paraffinic compounds into their corresponding alcoholic and/or ketonic derivatives, which process consists in causing said paraffins to react, at a temperature comprised within the range of from 0.degree. C. to 100.degree. C., preferably in an acidic medium, with a mixture of oxygen and hydrogen, in the presence of a catalyst on the basis of titanium-silicalite and of a noble metal and/or a derivative of such a metal.

摘要翻译： 将链烷烃化合物氧化成其相应的醇和/或酮衍生物的方法，该方法包括在0℃至100℃范围内，优选在酸性介质中使所述链烷烃反应， 在钛 - 硅沸石和贵金属和/或这种金属的衍生物的催化剂存在下，用氧和氢的混合物。

公开(公告)号：US5049536A

公开(公告)日：1991-09-17

申请号：US345142

申请日：1989-04-28

申请人： Giuseppe Bellussi ,  Mario G. Clerici ,  Angela Carati ,  Fabrizio Cavani

发明人： Giuseppe Bellussi ,  Mario G. Clerici ,  Angela Carati ,  Fabrizio Cavani

IPC分类号： B01J21/12 ,  B01J37/00 ,  C01B33/12 ,  C01B33/26 ,  C07B61/00 ,  C07C1/00 ,  C07C2/10 ,  C07C2/58 ,  C07C5/25 ,  C07C11/02 ,  C07C67/00

CPC分类号： B01J21/12 ,  C07C2/10 ,  C07C2521/12

摘要： A silica and alumina gel is disclosed, which is amorphous at X-rays, has a molar ratio of SiO.sub.2 /Al.sub.2 O.sub.3 comprised within the range of from 30/1 to 500/1, a surface area comprised within the range of from 500 to 1000 m.sup.2 /g, a total volume of pores comprised within the range of from 0.3 to 0.6 ml/g, an average diameter of the pores of the order of magnitude of 10 .ANG. or less and which is free, or substantially free, from pores having a diameter larger than 30 .ANG..Such a silica and alumina gel is catalytically active in reactions of conversion of the hydrocarbons, such as: oligomerization, alkylation, isomerization and dewaxing.Also a process for preparing such a silica and alumina gel is disclosed.