Heat-resistant wire
    2.
    发明授权
    Heat-resistant wire 失效
    耐热丝

    公开(公告)号:US4826726A

    公开(公告)日:1989-05-02

    申请号:US877944

    申请日:1986-06-24

    摘要: A heat-resistnat wire is disclosed which comprises a line of copper or aluminum coated with a shielding material obtained by heating a mixture of: (A) an ethylenic copolymer comprised of ethylene and 0.1 to 20.0 mol % of a monomer of at most 30 carbon atoms having an oxirane group or a hydroxyl group and having at least one double bond; and (B) an ethylenic copolymer comprised of ethylene and 0.1 to 20.0 mol % of a monomer possessing a functional group capable of reacting with oxirane group or hydroxy group in the ethylenic copolymer (A). The wire is excellent not only in heat resistance but also in insulating ability and flexibility.

    摘要翻译: 公开了一种耐热线,其包括涂覆有屏蔽材料的铜或铝线,所述屏蔽材料通过加热以下混合物而获得:(A)由乙烯和0.1至20.0摩尔%的至多30碳的单体组成的乙烯类共聚物 具有环氧乙烷基或羟基并具有至少一个双键的原子; 和(B)在乙烯类共聚物(A)中由乙烯和0.1〜20.0摩尔%的具有能够与环氧乙烷基或羟基反应的官能团的单体组成的乙烯类共聚物。 该电线不仅具有耐热性,而且在绝缘性和柔韧性方面也是优异的。

    Cured product of a modified multiplex ethylene copolymer
    5.
    发明授权
    Cured product of a modified multiplex ethylene copolymer 失效
    改性多元乙烯共聚物的固化产物

    公开(公告)号:US5252675A

    公开(公告)日:1993-10-12

    申请号:US797986

    申请日:1991-11-26

    摘要: Disclosed is a multiplex ethylene copolymer comprising (a) 50 to 94.8 mole % of units derived from ethylene, which are represented by the following formula (I):--CH.sub.2 --CH.sub.2 -- (I)(b) 5 to 45 mole % of units derived from a monomer selected from alkyl acrylates, alkyl methacrylates, vinyl carboxylates and isopropenyl carboxylates, which are represented by the following formula (II): ##STR1## wherein R.sub.1 stands for a hydrogen atom or a methyl group, and X is ##STR2## (in which R.sub.2 and R.sub.3 stand for an alkyl group having 1 to 10 carbon atoms),and (c) 0.2 to 5 mole % of units derived from a monomer having a radical-polymerizable ethylenic double bond and at least one carbon-to-carbon double bond which is different from a double bond of an aromatic nucleus. This ethylene copolymer can be easily cured, and the cured copolymer is a rubber having excellent oil resistance and heat resistance. This multiplex ethylene copolymer can be obtained by copolymerizing a monomer forming the units (a) with a monomer forming the units (b) and (c') a monomer having a radical-polymerizable ethylenic double bond and an acid anhydride group, a carboxyl group and/or an epoxy group, and modifying the obtained copolymer with a low-molecular-weight modifier selected from unsaturated amines and unsaturated alcohols having at least one carbon-to-carbon double bond different from a double bond of an aromatic nucleus (when a radical-polymerizable monomer having an epoxy group is used, the low-molecular-weight modifier may be an unsaturated carboxylic acid having at least one carbon-to-carbon double bond different from a double bond of an aromatic nucleus).

    摘要翻译: 公开了一种多元乙烯共聚物,其包含(a)50至94.8摩尔%的由乙烯衍生的单元,其由下式(I)表示:-CH 2 -CH 2 - (I)(b)5至45摩尔%的单元 衍生自由下式(II)表示的丙烯酸烷基酯,甲基丙烯酸烷基酯,羧酸乙烯酯和异丙烯基羧酸酯的单体:其中R1代表氢原子或甲基,X是 (其中R2和R3代表具有1-10个碳原子的烷基),和(c)0.2-5摩尔%的衍生自具有可自由基聚合的烯属双键和至少一个碳的单体的单元 碳双键,其与芳香核的双键不同。 该乙烯共聚物可以容易地固化,并且固化的共聚物是具有优异的耐油性和耐热性的橡胶。 这种多元乙烯共聚物可以通过使形成单元(a)的单体与形成单元(b)和(c')的单体共聚而获得,该单体具有可自由基聚合的烯属双键和酸酐基的单体,羧基 和/或环氧基,并且用选自不同于芳族核的双键的至少一个碳 - 碳双键的不饱和胺和不饱和醇的低分子量改性剂改性所得共聚物(当a 使用具有环氧基的可自由基聚合的单体,低分子量改性剂可以是具有至少一个与芳香核的双键不同的碳 - 碳双键的不饱和羧酸)。

    Method of producing resin composition containing inorganic filler
    6.
    发明授权
    Method of producing resin composition containing inorganic filler 失效
    含有无机填料的树脂组合物的制造方法

    公开(公告)号:US5932634A

    公开(公告)日:1999-08-03

    申请号:US836913

    申请日:1997-05-23

    CPC分类号: C08K7/00 C08K9/04

    摘要: A method of producing a resin composition containing an inorganic filler is disclosed, wherein organic cations having a steric hindrance structure are brought into contact with a layered mineral with an equivalent area per unit charge on the layer surface of 40-150 .ANG..sup.2 /charge, then brought into contact with a thermoplastic resin having a solubility parameter of at least 9.5 �cal/cm.sup.3 !.sup.1/2, so as to disperse the layered mineral inside the resin at the molecular level. The resin compositions obtained by this production method have excellent rigidity, heat resistance and impact resistance, and are suitable for use in fields such as, for example, automobiles, household electronic parts, construction materials and industrial materials.

    摘要翻译: PCT No.PCT / JP96 / 02754 Sec。 371日期1997年5月23日 102(e)日期1997年5月23日PCT提交1996年9月25日PCT公布。 公开号WO97 / 11998 日本1997年4月3日公开了含有无机填料的树脂组合物的制造方法,其中具有空间位阻结构的有机阳离子与层表面上的每单位电荷的等效面积接触40-150 ANGSTROM 2 /充电,然后与溶解度参数为至少9.5 [cal / cm3] + E,fra 1/2 + EE的热塑性树脂接触,以便将层状矿物分散在树脂中的分子水平 。 通过该制造方法获得的树脂组合物具有优异的刚性,耐热性和耐冲击性,并且适用于例如汽车,家用电子部件,建筑材料和工业材料等领域。

    Multiplex ethylene copolymer, process for preparation thereof and cured
product thereof
    8.
    发明授权
    Multiplex ethylene copolymer, process for preparation thereof and cured product thereof 失效
    复合乙烯共聚物,其制备方法和其固化产物

    公开(公告)号:US5093429A

    公开(公告)日:1992-03-03

    申请号:US480382

    申请日:1990-02-15

    摘要: Disclosed is a multiplex ethylene coplymer comprising (a) 50 to 94.8 mole % of units derived from ethylene, which are represented by the following formula (I):--CH.sub.2 --CH.sub.2 -- (I)(b) 5 to 45 mole % of units derived from a monomer selected from alkyl acrylates, alkyl methacrylates, vinyl carboxylates and isopropenyl carboxylates, which are represented by the following formula (II): ##STR1## wherein R.sub.1 stands for a hydrogen atom or a methyl group, and X is ##STR2## in which R.sub.2 and R.sub.3 stand for an alkyl group having 1 to 10 carbon atoms), and (c) 0.2 to 5 mole % of units derived from a monomer having a radical-polymerizable ethylenic double bond and at least one carbon-to-carbon double bond which is different from a double bond of an aromatic nucleus. This ethylene copolymer can be easily cured, and the cured copolymer is a rubber having excellent oil resistance and heat resistance.This multiplex ethylene copolymer can be obtained by copolymerizing a monomer forming the units (a) with a monomer forming the units (b) and (c') a monomer having a radical-polymerizable ethylenic double bond and an acid anhydride group, a carboxyl group and/or an epoxy group, and modifying the obtained copolymer with a low-molecular-weight modifier selected from unsaturated amines and unsaturated alcohols having at least one carbon-to-carbon double bond different from a double bond of an aromatic nucleus (when a radical-polymerizable monomer having an epoxy group is used, the low-molecular-weight modifier may be an unsaturated carboxylic acid having at least one carbon-to-carbon double bond different from a double bond of an aromatic nucleus).

    摘要翻译: 公开了一种多元乙烯共聚物,其包含(a)50至94.8摩尔%的衍生自乙烯的单元,其由下式(I)表示:-CH 2 -CH 2 - (I)(b)5至45摩尔%的单元 衍生自由下式(II)表示的丙烯酸烷基酯,甲基丙烯酸烷基酯,羧酸乙烯酯和异丙烯基羧酸酯的单体:其中R1代表氢原子或甲基,X是 其中R 2和R 3代表具有1至10个碳原子的烷基),和(c)0.2至5摩尔%的衍生自具有自由基聚合性烯键式双键的单体和至少一种碳 - 与芳香族核的双键不同的碳 - 碳双键。 该乙烯共聚物可以容易地固化,并且固化的共聚物是具有优异的耐油性和耐热性的橡胶。 这种多元乙烯共聚物可以通过使形成单元(a)的单体与形成单元(b)和(c')的单体共聚而获得,该单体具有可自由基聚合的烯属双键和酸酐基的单体,羧基 和/或环氧基,并且用选自不同于芳族核的双键的至少一个碳 - 碳双键的不饱和胺和不饱和醇的低分子量改性剂改性所得共聚物(当a 使用具有环氧基的可自由基聚合的单体,低分子量改性剂可以是具有至少一个与芳香核的双键不同的碳 - 碳双键的不饱和羧酸)。

    Crosslinkable polymer composition
    9.
    发明授权
    Crosslinkable polymer composition 失效
    可交联聚合物组合物

    公开(公告)号:US4855363A

    公开(公告)日:1989-08-08

    申请号:US096431

    申请日:1987-09-15

    申请人: Yoshihiro Moteki

    发明人: Yoshihiro Moteki

    摘要: A crosslinkable polymer composition comprising:(I) 1% to 99% by weight of at least one olefin copolymer selected from the group consisting of:(A) copolymers composed of (i) .alpha.-olefins, (ii) unsaturated dicarboxylic acid anhydrides, and (iii) at least one compound selected from the group consisting of unsaturated carboxylic acid esters, and vinyl esters;(B) copolymers at least composed of olefins and unsaturated monocarboxylic acids;(C) copolymers obtained by saponifying and neutralizing olefin copolymers at least composed of olefins and unsaturated carboxylic esters; and(D) copolymers at least composed of olefins and unsaturated dicarboxylic acids or the half esters thereof; and(II) 99% to 1% by weight of at least one olefin copolymer selected from the group consisting of:(A) copolymers at least composed of olefins and glycidyl alkyl (meth) acrylates; and(B) copolymers composed of (i) at least one .alpha.-olefin, (ii) at least one compound selected from unsaturated carboxylic acid esters and vinyl esters, and (iii) at least one compound having a hydroxyl group or primary or secondary amino group in the side chain.The resultant crosslinkable polymer composition has excellent molding and processing characteristics and can provide crosslinked products having excellent heat resistance and adhesion properties.

    摘要翻译: 一种可交联聚合物组合物,其包含:(I)1重量%至99重量%的至少一种选自以下的烯烃共聚物:(A)由(i)α-烯烃,(ii)不饱和二羧酸酐, 和(iii)至少一种选自不饱和羧酸酯和乙烯基酯的化合物; (B)至少由烯烃和不饱和一元羧酸组成的共聚物; (C)通过皂化和中和至少由烯烃和不饱和羧酸酯组成的烯烃共聚物而获得的共聚物; 和(D)至少由烯烃和不饱和二羧酸或其半酯组成的共聚物; 和(II)99重量%至1重量%的至少一种选自以下的烯烃共聚物:(A)至少由烯烃和缩水甘油基(甲基)丙烯酸烷基酯组成的共聚物; 和(B)由(i)至少一种α-烯烃,(ii)至少一种选自不饱和羧酸酯和乙烯基酯的化合物组成的共聚物,和(iii)至少一种具有羟基或一级或二级 侧链上的氨基。 所得的交联性聚合物组合物具有优异的成型加工特性,能够提供耐热性和粘合性优异的交联体。