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    Process for preparing biphenyls using palladacycles as catalysts
    1.
    发明授权
    Process for preparing biphenyls using palladacycles as catalysts 失效
    使用帕拉达环作为催化剂制备联苯的方法

    公开(公告)号：US5559277A

    公开(公告)日：1996-09-24

    申请号：US496392

    申请日：1995-06-29

    申请人： Matthias Beller ,  Wolfgang A. Herrmann ,  Christoph Brossmer

    发明人： Matthias Beller ,  Wolfgang A. Herrmann ,  Christoph Brossmer

    IPC分类号： B01J31/12 ,  C07B37/04 ,  C07B61/00 ,  C07C1/32 ,  C07C15/14 ,  C07C15/50 ,  C07C17/26 ,  C07C25/18 ,  C07C41/30 ,  C07C43/205 ,  C07C45/68 ,  C07C47/546 ,  C07C49/782 ,  C07C49/784 ,  C07C67/28 ,  C07C67/343 ,  C07C69/12 ,  C07C69/22 ,  C07C69/76 ,  C07C69/773 ,  C07C69/94 ,  C07C253/30 ,  C07C255/49 ,  C07C303/22 ,  C07C309/29 ,  C07C315/04 ,  C07C317/14 ,  C07C255/50

    CPC分类号： C07C253/30 ,  C07B37/04 ,  C07C17/263 ,  C07C41/30 ,  C07C45/68 ,  C07C47/546 ,  C07C49/784

    摘要： The invention relates to a process for preparing biphenyls of the formula (I) ##STR1## where R.sup.1a to R.sup.10a are, independently of one another, hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.1 -C.sub.12 -alkenyl, C.sub.1 -C.sub.12 -alkynyl, alkoxy-(C.sub.1 -C.sub.12), acyloxy-(C.sub.1 -C.sub.12), O-phenyl, aryl, heteroaryl, fluorine, chlorine, OH, NO.sub.2, CN, COOH, CHO, SO.sub.3 H, SO.sub.2 R, SOR, NH.sub.2, NH-alkyl-(C.sub.1 -C.sub.12), N-alkyl.sub.2 -(C.sub.1 -C.sub.12), C-Hal.sub.3, NHCO-alkyl-(C.sub.1 -C.sub.8), CONH-alkyl-(C.sub.1 -C.sub.4), CON-(alkyl).sub.2 -(C.sub.1 -C.sub.4), COO-alkyl-(C.sub.1 -C.sub.12), CONH.sub.2, CO-alkyl-(C.sub.1 -C.sub.12), NHCOH, NHCOO-alkyl-(C.sub.1 -C.sub.8), CO-phenyl, COO-phenyl, CHCHCO.sub.2 -alkyl-(C.sub.1 -C.sub.12), CHCHCO.sub.2 H, PO-phenyl.sub.2, PO-alkyl.sub.2 -(C.sub.1 -C.sub.8), by reaction of haloaromatics or aryl sulfonates of the formula (II) ##STR2## with arylboron derivatives of the formula III ##STR3## where R.sup.1a to R.sup.10a are as defined above and X is bromine, chlorine or OSO.sub.2 CF.sub.3, OSO.sub.2 -aryl, OSO.sub.2 -alkyl and Y is B(OH).sub.2, B(O-alkyl).sub.2, B(O-aryl).sub.2, wherein a palladium compound of the formula (IV) ##STR4## where R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6 are, independently of one another, hydrogen, (C.sub.1 -C.sub.4)-alkyl, (C.sub.5 -C.sub.8)-cycloalkyl, (C.sub.1 -C.sub.4)-alkoxy, fluorine, NH.sub.2, NH-alkyl(C.sub.1 -C.sub.4), N(alkyl).sub.2 -(C.sub.1 -C.sub.4), CO.sub.2 -alkyl-(C.sub.1 -C.sub.4), OCO-alkyl-(C.sub.1 -C.sub.4) or phenyl, or R.sup.1 and R.sup.2, R.sup.2 and R.sup.3, R.sup.3 and R.sup.4, R.sup.5 and R.sup.6 together form an aliphatic or aromatic ring, and R.sup.7, R.sup.8 are (C.sub.1 -C.sub.8)-alkyl, (C.sub.3 -C.sub.12)-cycloalkyl, substituted or unsubstituted aryl and Y is an anion of an inorganic or organic acid, is used as catalyst.

    摘要翻译： 本发明涉及一种制备式（I）的联苯的方法，其中R 1a至R 10a各自独立地为氢，C 1 -C 12 - 烷基，C 1 -C 12 - 烯基，C 1 -C 12 - 炔基，烷氧基 - （C1-C12），酰氧基 - （C1-C12），O-苯基，芳基，杂芳基，氟，氯，OH，NO2，CN，COOH，CHO，SO3H，SO2R，SOR，NH2， 烷基 - （C1-C12），N-烷基2-（C1-C12），C-Hal3，NHCO-烷基 - （C1-C8），CONH-烷基 - （C1-C4），CON-（烷基） C 1 -C 4烷基 - （C 1 -C 12），CONH 2，CO-烷基 - （C 1 -C 12），NHCOH，NHCOO-烷基 - （C 1 -C 8），CO-苯基，COO-苯基，CHCHCO 2 - 烷基 （II）的卤代芳族化合物或芳基磺酸盐与式III的芳基硼衍生物反应，得到（C1-C12），CHCHCO2H，PO-苯基2，PO-烷基2-（C1-C8） （III）其中R1a至R10a如上定义，X​​为溴，氯或OSO2CF3，OSO2-芳基，OSO2-烷基，Y为B（OH）2，B（O-烷基）2，B（O- 芳基）2，其中式（IV）的化合物（IV）其中R 1，R 2，R 3，R 4，R 5，R 6独立地为 （C 1 -C 4） - 烷基，（C 1 -C 4） - 烷氧基，氟，NH 2，NH-烷基（C 1 -C 4），N（烷基） C4），CO 2烷基 - （C1-C4），OCO-烷基 - （C1-C4）或苯基，或R1和R2，R2和R3，R3和R4，R5和R6一起形成脂族或芳香环， R 7，R 8为（C 1 -C 8） - 烷基，（C 3 -C 12） - 环烷基，取代或未取代的芳基，Y为无机或有机酸的阴离子。

    Reactivation of water-soluble hydroformylation catalysts
    2.
    发明授权
    Reactivation of water-soluble hydroformylation catalysts 失效
    水溶性加氢甲酰化催化剂的再活化

    公开(公告)号：US5466644A

    公开(公告)日：1995-11-14

    申请号：US378861

    申请日：1995-01-19

    申请人： Werner Konkol ,  Helmut Bahrmann ,  Wolfgang A. Herrmann ,  Christian Kohlpaintner

    发明人： Werner Konkol ,  Helmut Bahrmann ,  Wolfgang A. Herrmann ,  Christian Kohlpaintner

    IPC分类号： B01J27/185 ,  B01J27/28 ,  B01J31/24 ,  B01J31/40 ,  B01J38/48 ,  C07B61/00 ,  C07C27/20 ,  C07C27/22 ,  C07C45/50 ,  C07C45/85 ,  C07C47/02 ,  B01J38/62

    CPC分类号： B01J31/4046 ,  B01J31/20 ,  B01J31/2404 ,  B01J31/2447 ,  C07C45/50 ,  C07C45/85 ,  B01J2231/321 ,  B01J2531/822 ,  B01J2531/96 ,  Y02P20/584

    摘要： A process for regenerating a water-soluble hydroformylation catalyst system comprising a coupler rhodium hydrogen-carbonyl complex of rhodium and compounds of the formula ##STR1## wherein Ar.sup.1 and Ar.sup.2 and Ar.sup.3 are individually phenyl or naphthyl, Y.sup.1, Y.sup.2 and Y.sup.3 are individually selected from the group consisting of alkyl and alkoxy of 1 to 4 carbon atoms, halogen, --OH, --CN, --NO.sub.2 and R.sup.1 R.sup.2 N--, R.sup.1 and R.sup.2 are individually alkyl of 1 to 4 carbon atoms, X.sup.1, X.sup.2 and X.sup.3 are individually carboxylate (--COO.sup.-) or sulfonate (--SO.sub.3.sup.-), m.sub.1, m.sub.2 and m.sub.3 are individually integers of 0 to 3, at least one of m.sub.1, m.sub.2 or m.sub.3 being equal to or greater than 1, and n.sub.1, n.sub.2 and n.sub.3 are individually integers of 0 to 5 and if appropriate in excess comprising adding maleic acid, fumaric acid or olefinically unsaturated compounds of formula ##STR2## wherein X is selected from the group consisting of O, S, -- ##STR3## or ##STR4## and R.sup.3, R.sup.4 and R.sup.5 are individually hydrogen, or alkyl or aryl to an aqueous solution of the catalyst system in an amount sufficient to remove sulfonated or carboxylated alkyl-arylphosphanes.

    摘要翻译： 一种再生水溶性加氢甲酰化催化剂体系的方法，其包含铑的偶合铑氢 - 羰基络合物和其中Ar1和Ar2和Ar3各自独立地为苯基或萘基，Y1，Y2和Y3的式I化合物的化合物， 由1-4个碳原子的烷基和烷氧基组成的组，卤素，-OH，-CN，-NO 2和R 1 R 2 N - ，R 1和R 2分别是1至4个碳原子的烷基，X 1，X 2和X 3分别是羧酸酯 （-COO-）或磺酸盐（-SO3-），m1，m2和m3分别为0-3的整数，m1，m2或m3中的至少一个等于或大于1，n1，n2和n3分别为 单独的整数为0至5，如果适当，过量包括加入马来酸，富马酸或烯属不饱和的式II化合物，其中X选自O，S， - IMAGE或IMAGE，和 R3，R4和R5分别是氢，或烷基或芳基与催化剂的水溶液 t系统，其量足以除去磺化或羧化的烷基 - 芳基磷烷。

    Ruthenium complexes, process for preparation thereof, and processes for producing open-ring polymer of cycloolefins and hydrogenation products thereof by using the complex as catalyst
    3.
    发明授权
    Ruthenium complexes, process for preparation thereof, and processes for producing open-ring polymer of cycloolefins and hydrogenation products thereof by using the complex as catalyst 失效
    钌络合物，其制备方法以及通过使用络合物作为催化剂制备环烯烃的开环聚合物及其氢化产物的方法

    公开(公告)号：US07084222B2

    公开(公告)日：2006-08-01

    申请号：US10489921

    申请日：2002-09-19

    申请人： Masato Sakamoto ,  Seiji Okada ,  Yasuo Tsunogae ,  Shintaro Ikeda ,  Wolfgang A. Herrmann ,  Karl Oefele

    发明人： Masato Sakamoto ,  Seiji Okada ,  Yasuo Tsunogae ,  Shintaro Ikeda ,  Wolfgang A. Herrmann ,  Karl Oefele

    IPC分类号： C08F4/80 ,  C07F15/00

    CPC分类号： C07D239/04 ,  C07D233/02 ,  C07F15/0046 ,  C08G61/08

    摘要： The present invention relates to ruthenium complex compound wherein a heteroatom-containing carbene compound having a six-membered ring structure is bonded to ruthenium and a process for the preparation thereof; a process for producing ring-opened cyclic olefin polymer by subjecting a cyclic olefin to ring-opening metathesis polymerization in the presence of such a ruthenium complex compound; and a process for producing hydrogenated product of ring-opened cyclic olefin polymers by hydrogenating the carbon-carbon double bonds of the above ring-opened polymers. The invention gives hydrogenated product of ring-opened cyclic olefin polymers having physical properties different from those of hydrogenated product of ring-opened polymers of the prior art. Particularly, the use of dicyclopentadiene can give a hydrogenated product of ring-opened cyclic olefin polymer excellent in heat resistance, and this product can be advantageously used as parts or formed products for medical appliances or electrical components.

    摘要翻译： 本发明涉及具有六元环结构的含杂原子的卡宾化合物与钌结合的钌络合物及其制备方法， 在这种钌络合物的存在下，通过使环状烯烃进行开环易位聚合来制造开环式环烯烃聚合物的方法; 以及通过氢化上述开环聚合物的碳 - 碳双键来制备开环环烯烃聚合物的氢化产物的方法。 本发明提供了具有与现有技术的开环聚合物的氢化产物不同的物理性质的开环环烯烃聚合物的氢化产物。 特别地，二环戊二烯的使用可以得到耐热性优异的开环式环状烯烃聚合物的氢化物，该产品可有利地用作医疗器具或电子部件的部件或成形品。

    Process for the catalytic oxidation of aromatic compounds
    4.
    发明授权
    Process for the catalytic oxidation of aromatic compounds 失效
    芳香族化合物的催化氧化方法

    公开(公告)号：US5616734A

    公开(公告)日：1997-04-01

    申请号：US378231

    申请日：1995-01-25

    申请人： Wolfgang A. Herrmann ,  Joao D. G. Correia ,  Richard Fischer ,  Waldemar Adam ,  Jianhua Lin ,  Chantu R. Saha-Moller ,  Masao Shimizu

    发明人： Wolfgang A. Herrmann ,  Joao D. G. Correia ,  Richard Fischer ,  Waldemar Adam ,  Jianhua Lin ,  Chantu R. Saha-Moller ,  Masao Shimizu

    IPC分类号： B01J31/12 ,  C07B61/00 ,  C07C27/00 ,  C07C37/60 ,  C07C39/07 ,  C07C39/225 ,  C07C46/04 ,  C07C46/06 ,  C07C50/02 ,  C07C50/10 ,  C07C50/28 ,  C07C51/285 ,  C07C63/331 ,  C07D311/74 ,  C07C50/04

    CPC分类号： C07C46/04 ,  C07C37/60 ,  C07C46/06 ,  C07C50/10

    摘要： The invention relates to the use of compounds of the formula IR.sup.1.sub.a Re.sub.b O.sub.c (I),where a is from 1 to 6, b is from 1 to 4 and c is from 1 to 14 and the sum of a, b and c is in accordance with the valence of from 5 to 7 of the rhenium, with the proviso that c is not greater than 3.multidot.b, and where R.sup.1 is identical or different and is an aliphatic hydrocarbon radical having from 1 to 10 carbon atoms, an aromatic hydrocarbon radical having from 6 to 10 carbon atoms or an arylalkyl radical having from 7 to 9 carbon atoms, with the radicals R.sup.1 being able, if desired, to be identically or differently substituted independently of one another and, in the case of .sigma.-bonded radicals, at least one hydrogen atom still being bonded to the carbon atom in the .alpha. position, as catalysts for the oxidation of electron-rich aromatic compounds and their derivatives and to a process for the oxidation of electron-rich aromatic compounds which comprises oxidizing electron-rich C.sub.6 -C.sub.22 -aryl compounds and their derivatives in the presence of a catalyst of the formula I and a peroxide-containing compound.

    摘要翻译： 本发明涉及式Ⅰ化合物R1aRebOc（Ⅰ）的用途，其中a为1至6，b为1至4，c为1至14，a，b和c的和为 铼的价数为5至7，条件是c不大于3xb，并且其中R1相同或不同，是具有1至10个碳原子的脂族烃基，具有从 6至10个碳原子或具有7至9个碳原子的芳基烷基，如果需要，基团R1能够彼此相同或不同地取代，并且在σ-键合基团的情况下，至少 一个氢原子仍然与α位上的碳原子键合，作为用于氧化富含电子的芳族化合物及其衍生物的催化剂，以及氧化富含电子的芳族化合物的方法，其包括将富含电子的C6- C22-芳基化合物及其衍生物 在式I催化剂和含过氧化物的化合物存在下进行。

    Complexes of lanthanides with heterocyclic carbenes
    9.
    发明授权
    Complexes of lanthanides with heterocyclic carbenes 失效
    镧系元素与杂环碳烯的络合物

    公开(公告)号：US5705619A

    公开(公告)日：1998-01-06

    申请号：US581398

    申请日：1995-12-29

    申请人： Wolfgang A. Herrmann

    发明人： Wolfgang A. Herrmann

    IPC分类号： C07C45/46 ,  C07F5/00 ,  C07F7/10

    CPC分类号： C07F5/00 ,  C07C45/46

    摘要： A complex of the formula �L.sub.a Ln.sub.b X.sub.c !.sup.n (A).sub.n wherein Ln is an ion in the oxidation state of 2, 3 or 4 of the lanthanide elements having the atomic numbers 21, 39 and from 57 to 71 in the Periodic Table of the Elements, with the exception of europium and promethium, as central atom, X.sup.(S) are monodentate or multidentate, charged or uncharged ligands bound to the central atom and L is a monocarbene or dicarbene ligand likewise bound to the central atom and which are derived from imidazole and/or pyrazole, A is a singly charged anion or the chemical equivalent of a multiple charged anion, b is an integer from 1 to 4, a is an integer from 1 to 4 . b and c is zero or an integer from 1 to 4.b and n is zero or an integer from 1 to 3.b having catalytic activity.

    摘要翻译： 式[LaLnbXc] n（A）n的络合物，其中Ln是氧化态的2,3或4族的镧系元素的离子，所述镧系元素在元素周期表中具有原子序数21,39和57至71 元素除了铕和ium之外，作为中心原子，X（S）是与中心原子结合的单齿或多齿，带电荷或不带电的配体，L是同样与中心原子结合的单碳烯或二烯属配体， A是单电荷阴离子或多电荷阴离子的化学等价物，b为1〜4的整数，a为1〜4的整数。 b和c为0或1至4.b的整数，n为0或具有催化活性的1至3b的整数。