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1.发明授权In-situ short-circuit protection system and method for high-energy electrochemical cells 有权高能电化学电池原位短路保护系统及方法公开(公告)号：US06548206B1
公开(公告)日：2003-04-15
申请号：US09586218
申请日：2000-06-02
申请人： Michel Gauthier , Michael K. Domroese , Joseph A. Hoffman , David D. Lindeman , Joseph-Robert-Gaétan Noël , Vern E. Radewald , Jean Rouillard , Roger Rouillard , Toshimi Shiota , Jennifer L. Trice
发明人： Michel Gauthier , Michael K. Domroese , Joseph A. Hoffman , David D. Lindeman , Joseph-Robert-Gaétan Noël , Vern E. Radewald , Jean Rouillard , Roger Rouillard , Toshimi Shiota , Jennifer L. Trice
IPC分类号： H01M1050
CPC分类号： H02J7/0026 , H01M2/34 , H01M10/613 , H01M10/647 , H01M10/6554
摘要： An in-situ thermal management system for an energy storage device. The energy storage device includes a plurality of energy storage cells each being coupled in parallel to common positive and negative connections. Each of the energy storage cells, in accordance with the cell's technology, dimensions, and thermal/electrical properties, is configured to have a ratio of energy content-to-contact surface area such that thermal energy produced by a short-circuit in a particular cell is conducted to a cell adjacent the particular cell so as to prevent the temperature of the particular cell from exceeding a breakdown temperature. In one embodiment, a fuse is coupled in series with each of a number of energy storage cells. The fuses are activated by a current spike capacitively produced by a cell upon occurrence of a short-circuit in the cell, thereby electrically isolating the short-circuited cell from the common positive and negative connections.
摘要翻译： 一种用于能量存储装置的原位热管理系统。 能量存储装置包括多个能量存储单元，每个能量存储单元并联耦合到共同的正和负连接。 每个储能电池根据电池的技术，尺寸和热/电特性被配置为具有能量 - 接触表面积的比率，使得由特定的短路产生的热能 将电池传导到与特定电池相邻的电池，以防止特定电池的温度超过击穿温度。 在一个实施例中，熔丝与多个能量存储单元中的每一个串联耦合。 在电池中发生短路时，由电池电容性产生的电流尖峰激活保险丝，从而将短路电池与公共正极和负极连接电隔离。
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2.发明授权
公开(公告)号：US6087036A
公开(公告)日：2000-07-11
申请号：US900566
申请日：1997-07-25
申请人： Roger Rouillard , Michael K. Domroese , Michel Gauthier , Joseph A. Hoffman , David D. Lindeman , Joseph-Robert-Gaetan Noel , Vern E. Radewald , Michel Ranger , Jean Rouillard , Toshimi Shiota , Philippe St-Germain , Anthony Sudano , Jennifer L. Trice , Thomas A. Turgeon
发明人： Roger Rouillard , Michael K. Domroese , Michel Gauthier , Joseph A. Hoffman , David D. Lindeman , Joseph-Robert-Gaetan Noel , Vern E. Radewald , Michel Ranger , Jean Rouillard , Toshimi Shiota , Philippe St-Germain , Anthony Sudano , Jennifer L. Trice , Thomas A. Turgeon
CPC分类号： H01M10/04 , H01M10/0413 , H01M10/0468 , H01M10/613 , H01M10/647 , H01M10/6555 , H01M10/6556 , H01M10/6567 , H01M2/202 , H01M10/052 , H01M2200/103 , H01M6/181 , H01M6/5016
摘要： An improved electrochemical energy storing device includes a number of thin-film electrochemical cells which are maintained in a state of compression through use of an internal or an external pressure apparatus. A thermal conductor, which is connected to at least one of the positive or negative contacts of each electrochemical cell, conducts current into and out of the electrochemical cells and also conducts thermal energy between the electrochemical cells and thermally conductive material disposed on a wall structure adjacent the conductors. The wall structure includes electrically resistive material, such as an anodized coating or a thin film of plastic. The thermal conductors are fabricated to include a spring mechanism which expands and contacts to maintain mechanical contact between the electrochemical cells and the thermally conductive material in the presence of relative movement between the electrochemical cells and the wall structure. An active cooling apparatus may be employed external to a hermetically sealed housing containing the electrochemical cells to enhance the transfer of thermal energy into and out of the electrochemical cells. An integrated interconnect board may be disposed within the housing onto which a number of electrical and electro-mechanical components are mounted. Heat generated by the components is conducted from the interconnect board to the housing using the thermal conductors.
摘要翻译： 改进的电化学能量存储装置包括许多通过使用内部或外部压力装置保持在压缩状态的薄膜电化学电池。 连接到每个电化学电池的正极或负极触点中的至少一个的热导体将电流传导到电化学电池中并流出电化学电池，并且还在电化学电池和设置在相邻的壁结构上的导热材料之间传导热能 导体。 壁结构包括电阻材料，例如阳极氧化涂层或塑料薄膜。 热导体被制造成包括弹簧机构，弹簧机构在电化学电池和壁结构之间的相对运动的存在下膨胀和接触以保持电化学电池和导热材料之间的机械接触。 活性冷却装置可以在包含电化学电池的密封外壳的外部被采用，以增强热能进出电化学电池的能力。 集成的互连板可以设置在壳体内，多个电气和机电部件被安装在该壳体上。 由部件产生的热量使用热导体从互连板传导到壳体。
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3.发明授权In-situ short circuit protection system and method for high-energy electrochemical cells 失效用于高能电化学电池的原位短路保护系统和方法
公开(公告)号：US6099986A
公开(公告)日：2000-08-08
申请号：US900929
申请日：1997-07-25
申请人： Michel Gauthier , Michael K. Domroese , Joseph A. Hoffman , David D. Lindeman , Joseph-Robert-Gaetan Noel , Vern E. Radewald , Jean Rouillard , Roger Rouillard , Toshimi Shiota , Jennifer L. Trice
发明人： Michel Gauthier , Michael K. Domroese , Joseph A. Hoffman , David D. Lindeman , Joseph-Robert-Gaetan Noel , Vern E. Radewald , Jean Rouillard , Roger Rouillard , Toshimi Shiota , Jennifer L. Trice
CPC分类号： H02J7/0026 , H01M2/34 , H01M10/5004 , H01M10/5032 , H01M10/5053
摘要： An in-situ thermal management system for an energy storage device. The energy storage device includes a plurality of energy storage cells each being coupled in parallel to common positive and negative connections. Each of the energy storage cells, in accordance with the cell's technology, dimensions, and thermal/electrical properties, is configured to have a ratio of energy content-to-contact surface area such that thermal energy produced by a short-circuit in a particular cell is conducted to a cell adjacent the particular cell so as to prevent the temperature of the particular cell from exceeding a breakdown temperature. In one embodiment, a fuse is coupled in series with each of a number of energy storage cells. The fuses are activated by a current spike capacitively produced by a cell upon occurrence of a short-circuit in the cell, thereby electrically isolating the short-circuited cell from the common positive and negative connections.
摘要翻译： 一种用于能量存储装置的原位热管理系统。 能量存储装置包括多个能量存储单元，每个能量存储单元并联耦合到共同的正和负连接。 每个储能电池根据电池的技术，尺寸和热/电特性被配置为具有能量 - 接触表面积的比率，使得由特定的短路产生的热能 将电池传导到与特定电池相邻的电池，以防止特定电池的温度超过击穿温度。 在一个实施例中，熔丝与多个能量存储单元中的每一个串联耦合。 在电池中发生短路时，由电池电容性产生的电流尖峰激活保险丝，从而将短路电池与公共正极和负极连接电隔离。
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4.发明授权Process for cutting polymer electrolyte multi-layer batteries and batteries obtained thereby 有权用于切割由其获得的聚合物电解质多层电池和电池的方法公开(公告)号：US06616714B1
公开(公告)日：2003-09-09
申请号：US09393493
申请日：1999-09-10
申请人： Michel Gauthier , Ginette Lessard , Gaston Dussault , Roger Rouillard , Martin Simoneau , Alan Paul Miller
发明人： Michel Gauthier , Ginette Lessard , Gaston Dussault , Roger Rouillard , Martin Simoneau , Alan Paul Miller
IPC分类号： H01M600
CPC分类号： H01M10/0436 , H01M4/13 , H01M6/10 , H01M6/40 , H01M10/052 , H01M10/054 , H01M10/0565 , H01M10/0583 , H01M10/0585 , H01M2004/029 , Y10T29/49108 , Y10T29/49112
摘要： A stacking of battery laminate is prepared, each battery consisting of anode, polymer electrolyte, cathode films and possibly an insulating film, under conditions suitable to constitute a rigid monoblock assembly, in which the films are unitary with one another. The assembly obtained is thereafter cut in predetermined shape by using a mechanical device without macroscopic deformation of the films constituting the assembly and without inducing permanent short circuits. The battery which is obtained after cutting includes at least one end which appears as a uniform cut, the various films constituting the assembly having undergone no macroscopic deformation, the edges of the films of the anode including an electronically insulating passivation film.
摘要翻译： 制备电池层叠体的堆叠，每个电池由阳极，聚合物电解质，阴极膜和可能的绝缘膜组成，在适于构成刚性整体组件的条件下，其中膜彼此一体。 然后通过使用不构成组件的膜的宏观变形的机械装置将获得的组件切割成预定形状，并且不引起永久性短路。 在切割后获得的电池包括显示为均匀切口的至少一个端点，构成组件的各种膜不经过宏观变形，阳极膜的边缘包括电绝缘钝化膜。
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5.发明授权Li4Ti5O12, Li(4-α)ZαTi5O12or Li4ZβTi(5-β)O12 particles, processes for obtaining same and their use in electrochemical generators 有权Li4Ti5O12，Li（4-α）ZαTi5O12或Li4Z＆bgr; Ti（5-＆bgr）O12颗粒，其获得方法及其在电化学发生器中的应用公开(公告)号：US09077031B2
公开(公告)日：2015-07-07
申请号：US13360173
申请日：2012-01-27
申请人： Karim Zaghib , Michel Gauthier , Fernand Brochu , Abdelbast Guerfi , Monique Masse , Michel Armand
发明人： Karim Zaghib , Michel Gauthier , Fernand Brochu , Abdelbast Guerfi , Monique Masse , Michel Armand
IPC分类号： B05D5/12 , H01M4/485 , B82Y30/00 , C01G23/00 , H01G9/00 , H01M4/04 , H01M4/131 , H01M4/136 , H01M4/36 , H01M4/58 , H01M4/62 , H01M4/74 , H01M10/0525 , H01M4/02 , H01M4/505 , H01M4/525 , H01M4/66 , H01M10/0562 , H01M10/0565
CPC分类号： H01M4/485 , B82Y30/00 , C01G23/003 , C01G23/005 , C01P2002/77 , C01P2002/88 , C01P2004/03 , C01P2004/64 , C01P2006/40 , H01G9/155 , H01G11/04 , H01G11/46 , H01M4/02 , H01M4/0471 , H01M4/131 , H01M4/136 , H01M4/366 , H01M4/505 , H01M4/525 , H01M4/5825 , H01M4/623 , H01M4/625 , H01M4/661 , H01M4/745 , H01M10/0525 , H01M10/0562 , H01M10/0565 , H01M2300/004 , H01M2300/0082 , H01M2300/0085 , Y02E60/122 , Y02E60/13 , Y02P70/54 , Y10T428/2982
摘要： Synthesis process for new particles of Li4Ti5O12, Li(4-α)ZαTi5O12 or Li4ZβTi(5-β)O12, wherein β is >0 and ≦0.5, α is a number >0 and ≦0.33, Z is a source of at least one metal, preferably chosen from the group made up of Mg, Nb, Al, Zr, Ni, Co. These particles coated with a layer of carbon notably exhibit electrochemical properties that are particularly interesting as components of anodes and/or cathodes in electrochemical generators. The process may involve the steps of a) preparing a dispersion of a mixture of TiOx—LizY-carbon, wherein x is a number between 1 and 2, z is 1 or 2, and Y is a radical chosen among CO3, OH, O and TiO3 or a mixture thereof; and 2) heating of the dispersion, preferably to a temperature of between about 400° C. and about 1000° C.
摘要翻译： Li4Ti5O12，Li（4-α）ZαTi5O12或Li4Z＆bgr; Ti（5-＆bgr）O12的新颗粒的合成工艺，其中＆bgr; 是> 0和＆nlE; 0.5，α是数> 0和＆nlE; 0.33，Z是至少一种金属的源，优选选自由Mg，Nb，Al，Zr，Ni，Co组成的组。 涂覆有碳层的颗粒特别表现出电化学特性，其特别令人感兴趣的是作为电化学发生器中阳极和/或阴极的组分。 该方法可以包括以下步骤：a）制备TiOx-LizY-碳的混合物的分散体，其中x是1和2之间的数，z是1或2，Y是选自CO 3，OH，O 和TiO 3或其混合物; 和2）分散体的加热，优选至约400℃至约1000℃的温度
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6.发明授权Polymers obtained from monomers allowing a sequential polymerization, and their use for preparing ionic conductors 有权从允许顺序聚合的单体获得的聚合物及其用于制备离子导体的用途公开(公告)号：US08512899B2
公开(公告)日：2013-08-20
申请号：US12118483
申请日：2008-05-09
CPC分类号： C08F226/06 , C07C43/15 , C08G65/14 , C08G65/16 , C08G65/20 , C08G65/22 , C08G65/337 , H01B1/122 , H01M4/131 , H01M4/133 , H01M4/136 , H01M4/1393 , H01M4/1397 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/5815 , H01M4/5825 , H01M6/164 , H01M10/052 , H01M10/0525 , H01M10/0565 , Y10S525/901 , Y10S525/919
摘要： The present invention concerns polymers obtained by anionic initiation and bearing functions that can be activated by cationic initiations that are not reactive in the presence of anionic polymerization initiators. The presence of such cationic initiation functions allow an efficient cross-linking of the polymer after molding, particularly in the form of a thin film. It is thus possible to obtain polymers with well-defined properties in terms of molecular weight and cross-linking density. The polymers of the present invention are capable of dissolving ionic compounds inducing a conductivity for the preparation of solid electrolytes.
摘要翻译： 本发明涉及通过阴离子引发而获得的聚合物，并且可通过在阴离子聚合引发剂存在下不具有反应性的阳离子引发而活化。 这种阳离子引发功能的存在允许聚合物在模制之后，特别是薄膜形式的有效交联。 因此，可以获得在分子量和交联密度方面具有明确特性的聚合物。 本发明的聚合物能够溶解诱导用于制备固体电解质的导电性的离子化合物。
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7.发明授权Process for preparing electroactive insertion compounds and electrode materials obtained therefrom 有权制备电活性插入化合物的方法和由其获得的电极材料公开(公告)号：US08273481B2
公开(公告)日：2012-09-25
申请号：US13217719
申请日：2011-08-25
CPC分类号： C01B25/45 , C01B25/37 , H01M4/136 , H01M4/1397 , H01M4/366 , H01M4/525 , H01M4/5825 , H01M4/625 , H01M10/052 , H01M2004/028
摘要： A process for preparing an at least partially lithiated transition metal oxyanion-based lithium-ion reversible electrode material, which includes providing a precursor of said lithium-ion reversible electrode material, heating said precursor, melting same at a temperature sufficient to produce a melt including an oxyanion containing liquid phase, cooling said melt under conditions to induce solidification thereof and obtain a solid electrode that is capable of reversible lithium ion deinsertion/insertion cycles for use in a lithium battery. Also, lithiated or partially lithiated oxyanion-based-lithium-ion reversible electrode materials obtained by the aforesaid process.
摘要翻译： 一种制备至少部分锂化的过渡金属氧阴离子的锂离子可逆电极材料的方法，其包括提供所述锂离子可逆电极材料的前体，加热所述前体，在足以产生熔体的温度下熔化，包括 含有氧阴离子的液相，在条件下冷却所述熔体以诱导其固化，并获得能够在锂电池中使用的可逆锂离子去插入/插入循环的固体电极。 而且，通过上述方法获得的锂化或部分锂化的氧阴离子 - 锂离子可逆电极材料。
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8.发明申请公开(公告)号：US20120028121A1
公开(公告)日：2012-02-02
申请号：US13217719
申请日：2011-08-25
CPC分类号： C01B25/45 , C01B25/37 , H01M4/136 , H01M4/1397 , H01M4/366 , H01M4/525 , H01M4/5825 , H01M4/625 , H01M10/052 , H01M2004/028
摘要： A process for preparing an at least partially lithiated transition metal oxyanion-based lithium-ion reversible electrode material, which includes providing a precursor of said lithium-ion reversible electrode material, heating said precursor, melting same at a temperature sufficient to produce a melt including an oxyanion containing liquid phase, cooling said melt under conditions to induce solidification thereof and obtain a solid electrode that is capable of reversible lithium ion deinsertion/insertion cycles for use in a lithium battery. Also, lithiated or partially lithiated oxyanion-based-lithium-ion reversible electrode materials obtained by the aforesaid process.
摘要翻译： 一种制备至少部分锂化的过渡金属氧阴离子的锂离子可逆电极材料的方法，其包括提供所述锂离子可逆电极材料的前体，加热所述前体，在足以产生熔体的温度下熔化，包括 含有氧阴离子的液相，在条件下冷却所述熔体以诱导其固化，并获得能够在锂电池中使用的可逆锂离子去插入/插入循环的固体电极。 而且，通过上述方法获得的锂化或部分锂化的氧阴离子 - 锂离子可逆电极材料。
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9.发明申请公开(公告)号：US20110062380A1
公开(公告)日：2011-03-17
申请号：US12953077
申请日：2010-11-23
CPC分类号： C01B25/45 , C01B25/37 , H01M4/136 , H01M4/1397 , H01M4/366 , H01M4/525 , H01M4/5825 , H01M4/625 , H01M10/052 , H01M2004/028
摘要： A process for preparing an at least partially lithiated transition metal oxyanion-based lithium−ion reversible electrode material, which includes providing a precursor of said lithium−ion reversible electrode material, heating said precursor, melting same at a temperature sufficient to produce a melt including an oxyanion containing liquid phase, cooling said melt under conditions to induce solidification thereof and obtain a solid electrode that is capable of reversible lithium ion deinsertion/insertion cycles for use in a lithium battery. Also, lithiated or partially lithiated oxyanion-based-lithium−ion reversible electrode materials obtained by the aforesaid process.
摘要翻译： 一种制备至少部分锂化的过渡金属氧阴离子的锂离子可逆电极材料的方法，其包括提供所述锂离子可逆电极材料的前体，加热所述前体，在足以产生熔体的温度下熔化，包括 含有氧阴离子的液相，在条件下冷却所述熔体以诱导其固化，并获得能够在锂电池中使用的可逆锂离子去插入/插入循环的固体电极。 而且，通过上述方法获得的锂化或部分锂化的氧阴离子 - 锂离子可逆电极材料。
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10.发明申请Polymers Obtained From Monomers Allowing A Sequential Polymerization, And Their Use For Preparing Ionic Conductors 有权从单体获得的聚合物允许顺序聚合，以及它们用于制备离子导体的用途公开(公告)号：US20080213661A1
公开(公告)日：2008-09-04
申请号：US12118483
申请日：2008-05-09
CPC分类号： C08F226/06 , C07C43/15 , C08G65/14 , C08G65/16 , C08G65/20 , C08G65/22 , C08G65/337 , H01B1/122 , H01M4/131 , H01M4/133 , H01M4/136 , H01M4/1393 , H01M4/1397 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/5815 , H01M4/5825 , H01M6/164 , H01M10/052 , H01M10/0525 , H01M10/0565 , Y10S525/901 , Y10S525/919
摘要： The present invention concerns polymers obtained by anionic initiation and bearing functions that can be activated by cationic initiations that are not reactive in the presence of anionic polymerization initiators. The presence of such cationic initiation functions allow an efficient cross-linking of the polymer after moulding, particularly in the form of a thin film. It is thus possible to obtain polymers with well-defined properties in terms of molecular weight and cross-linking density. The polymers of the present invention are capable of dissolving ionic compounds inducing a conductivity for the preparation of solid electrolytes.
摘要翻译： 本发明涉及通过阴离子引发而获得的聚合物，并且可通过在阴离子聚合引发剂存在下不具有反应性的阳离子引发而活化。 这种阳离子引发功能的存在允许聚合物在模制之后，特别是薄膜形式的有效交联。 因此，可以获得在分子量和交联密度方面具有明确特性的聚合物。 本发明的聚合物能够溶解诱导用于制备固体电解质的导电性的离子化合物。
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