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1.发明授权Low application temperature hot melt adhesive comprising ethylene .alpha.-olefin 失效低应用温度的包含乙烯α-烯烃的热熔粘合剂
公开(公告)号：US6107430A
公开(公告)日：2000-08-22
申请号：US981990
申请日：1998-01-08
申请人： Robert A. Dubois , Cynthia L. Rickey , Steven W. Albrecht , Beth M. Eichler , Thomas F. Kauffman , Maynard Lawrence , Thomas H. Quinn
发明人： Robert A. Dubois , Cynthia L. Rickey , Steven W. Albrecht , Beth M. Eichler , Thomas F. Kauffman , Maynard Lawrence , Thomas H. Quinn
IPC分类号： C08L91/06 , C09J123/08 , C08F210/08 , C08F210/14 , C08K5/01 , C08L93/04
CPC分类号： C09J123/0815 , C08L2205/02 , C08L2314/06 , C08L91/06
摘要： Disclosed are hot melt adhesives comprising at least one first homogeneous linear etylene polymer having a particular density and melt viscosity at 350.degree.F. (177.degree.C.), and an optional wax and tackifier. In particular, disclosed is a hot melt adhesive characterized by: a) at least one homogeneous linear or substantially linear interpolymer of ethylene with at least ibe C.sub.2 --C.sub.20 .alpha.-olefin interpolymer having a density from 0.850 g/cm.sup.3 to 0.895 g/cm.sup.3 ; and b) optionally at least one tackifying resin; and c) optionally at least one wax wherein the hot melt adhesive has a viscosity of less than about 5000 cPs (50 grams/cm.second) at 150.degree.C. Preferred hot melt adhesives for use in adhering cardboard or paperboard are disclosed, as well as the resultant adhered products. Also disclosed is a dual reactor process for the preparation of the inventive hot melt adhesives.
摘要翻译： PCT No.PCT / US97 / 12366 Sec。 371日期1998年1月8日 102（e）1998年1月8日PCT PCT 1997年7月21日PCT公布。 公开号WO98 / 03603 日期1998年1月29日公开是包含至少一种在350°F（177℃）下具有特定密度和熔体粘度的第一均匀线型乙烯基聚合物和任选的蜡和增粘剂的热熔粘合剂。 特别地，公开了一种热熔粘合剂，其特征在于：a）至少一种乙烯与至少具有0.850g / cm 3至0.895g / cm 3密度的C 2 -C 20α-烯烃互聚物的均匀直链或基本线性互聚物; 和b）任选的至少一种增粘树脂; 和c）任选的至少一种蜡，其中热熔粘合剂在150℃下具有小于约5000cPs（50克/厘米2）的粘度。用于粘附纸板或纸板的优选热熔粘合剂作为 以及产生的附着产品。 还公开了用于制备本发明的热熔粘合剂的双反应器方法。
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2.发明授权Package comprising low application temperature hot melt adhesive comprising ethylene &agr;-olefin 有权包括包含乙烯α-烯烃的低应用温度热熔粘合剂的包装公开(公告)号：US06319979B1
公开(公告)日：2001-11-20
申请号：US09496973
申请日：2000-02-02
申请人： Robert A. Dubois , Cynthia L. Rickey , Steven W. Albrecht , Thomas F. Kauffman , Beth M. Eichler , Maynard Lawrence , Thomas H. Quinn
发明人： Robert A. Dubois , Cynthia L. Rickey , Steven W. Albrecht , Thomas F. Kauffman , Beth M. Eichler , Maynard Lawrence , Thomas H. Quinn
IPC分类号： C08J2700
CPC分类号： C09J123/0815 , C08F210/16 , C08L91/06 , C08L2205/02 , C08L2666/02 , Y10S206/813 , C08F210/14 , C08F2500/23 , C08F2500/02 , C08F2500/08
摘要： Disclosed are packages, cartons, cases, and trays comprising a hot melt adhesive, in turn comprising at least one first homogenous linear or substantially linear ethylene polymer having a particular density and melt viscosity at 350° F. (177° C.), up to 60 weight percent wax and up to 40 weight percent tackifier. In particular, disclosed are packages, cartons, cases, and trays comprising a hot melt adhesive characterized by: a) at least one homogeneous linear or substantially linear interpolymer of ethylene with at least one C3-C20 &agr;-olefin interpolymer having a density from 0.850 g/cm3 to 0.895 g/cm3; and b) up to 60 weight percent of at least one tackifying resin; and c) up to 40 weight percent of at least one wax, wherein the hot melt adhesive has a viscosity of less than about 5000 cPs (50 grams/(cm.second)) at 150° C.
摘要翻译： 公开了包括热熔粘合剂的包装，纸箱，壳体和托盘，其又包含至少一种在350°F（177℃）下具有特定密度和熔体粘度的第一均匀线性或基本线性乙烯聚合物， 至60重量％的蜡和至多40重量％的增粘剂。 特别地，公开了包含热熔粘合剂的包装，纸箱，壳和托盘，其特征在于：a）至少一种乙烯与至少一种具有0.850密度的C 3 -C 20α-烯烃互聚物的均匀线性或基本上线性的互聚物 g / cm 3至0.895g / cm 3; 和b）至多60重量％的至少一种增粘树脂; andc）至多一种蜡的至多40重量％，其中该热熔粘合剂在150℃下具有小于约5000cPs（50克/（cm·sec））的粘度）
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公开(公告)号：US07199180B1
公开(公告)日：2007-04-03
申请号：US08973779
申请日：1997-03-14
申请人： Eugene R. Simmons , William L. Bunnelle , David B. Malcolm , Keith C. Knutson , Thomas F. Kauffman , Mark S. Kroll , Michael S. Keehr , Deepak R. Parikh , Jimmy D. Allen , David R. Speth , Selim Yalvac , Malcolm F. Finlayson , Cynthia L. Rickey
发明人： Eugene R. Simmons , William L. Bunnelle , David B. Malcolm , Keith C. Knutson , Thomas F. Kauffman , Mark S. Kroll , Michael S. Keehr , Deepak R. Parikh , Jimmy D. Allen , David R. Speth , Selim Yalvac , Malcolm F. Finlayson , Cynthia L. Rickey
IPC分类号： B60C1/00
CPC分类号： C08F210/16 , B32B7/12 , C08K5/0008 , C08K5/0016 , C08L23/04 , C08L23/0853 , C08L23/0869 , C08L77/00 , C08L2666/02 , C09J7/35 , C09J123/0815 , C09J2423/00 , C08L2666/04 , C08F210/14 , C08F2500/08 , C08F2500/02 , C08F2500/03 , C08F2500/12
摘要： Disclosed are adhesives and processes for preparing the same, comprising at least one first homogeneous ethylene/α-olefin interpolymer, and optionally at least one tackifier, and optionally at least one plasticizer. The claimed adhesives are useful as adhesives such as are employed in various applications, such as in masking tape, clear office tape, labels, decals, bandages, decorative and protective sheets (such as shelf and drawer liners), floor tiles, sanitary napkin/incontinence device placement strips, sun control films, the joining of gaskets to automobile windows, packaging, bookbinding, construction of nonwoven articles, and insulation bonding.
摘要翻译： 公开了粘合剂及其制备方法，其包括至少一种第一均相乙烯/α-烯烃互聚物和任选的至少一种增粘剂，以及任选的至少一种增塑剂。 所要求保护的粘合剂可用作各种应用中的粘合剂，例如胶带，透明办公带，标签，贴花，绷带，装饰和保护片（例如搁板和抽屉衬里），地砖，卫生巾/ 失禁装置放置条，太阳控制膜，垫圈连接到汽车窗户，包装，装订，非织造制品的构造和绝缘粘合。
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公开(公告)号：US09243173B2
公开(公告)日：2016-01-26
申请号：US14379584
申请日：2013-02-27
申请人： Colin LiPiShan , Cynthia L. Rickey , Alec Y. Wang
发明人： Colin LiPiShan , Cynthia L. Rickey , Alec Y. Wang
IPC分类号： A61K9/16 , C08L53/00 , C09J153/00
CPC分类号： C09J153/00 , C08L23/08
摘要： The invention provides an adhesive formulation comprising an olefin block copolymer comprising hard blocks and soft blocks wherein the hard blocks comprise 4-8 mol % comonomer; and are present in an amount of 20 wt %-45 wt %. This formulation is particularly advantageous for use in hot melt adhesives but may be used in other applications as well.
摘要翻译： 本发明提供一种包含含有硬嵌段和软嵌段的烯烃嵌段共聚物的粘合剂制剂，其中硬嵌段包含4-8mol％共聚单体; 并且以20重量％-45重量％的量存在。 该配方对于用于热熔粘合剂中特别有利，但也可用于其它应用中。
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5.发明授权Adhesive and marking compositions made from interpolymers of ethylene/α-olefins 有权由乙烯/α-烯烃的互聚物制成的粘合剂和标记组合物公开(公告)号：US07989543B2
公开(公告)日：2011-08-02
申请号：US11908950
申请日：2006-03-15
IPC分类号： A61K9/16
CPC分类号： C09J153/00 , C08F4/659 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F10/14 , C08F110/02 , C08F210/16 , C08F295/00 , C08F297/08 , C08F297/083 , C08F297/086 , C08F2410/01 , C08L23/0815 , C08L23/10 , C08L53/00 , C08L53/005 , C08L2205/02 , C08L2205/025 , C08L2314/06 , C08L2666/02 , C08L2666/06 , C09D153/00 , C09J123/0815 , C08F210/14 , C08F2500/03 , C08F2500/20 , C08F2500/12 , C08F2500/11 , C08F2500/21 , C08F4/65904 , C08L2666/04 , C08F2500/09 , C08F210/08
摘要： An adhesive composition comprises: (i) at least one ethylene/α-olefin interpolymer, (ii) at least one tackifÊer; and (iii) optionally at least one additive, such as a plasticizer, wax and antioxidant. Preferably, the ethylene/α-olefin interpolymer has a Mw/Mn from about 1.7 to about 3.5, at least one melting point, Tm, in degrees Celsius, and a density, d, in grams/cubic centimeter, wherein the numerical values of Tm and d correspond to the relationship: Tm≧858.91−1825.3(d)+1112.8(d)2. The composition has relatively higher SAFT temperature and can be used in hot melt adhesives pressure-sensitive adhesives, and thermoplastic marking paints.
摘要翻译： 粘合剂组合物包含：（i）至少一种乙烯/α-烯烃互聚物，（ii）至少一种增粘剂; 和（iii）任选的至少一种添加剂，例如增塑剂，蜡和抗氧化剂。 优选地，乙烯/α-烯烃互聚物的Mw / Mn为约1.7至约3.5，至少一个熔点Tm，摄氏度，密度d（克/立方厘米），其中数值 Tm和d对应关系：Tm≥858.91-1825.3（d）+1112.8（d）2。 该组合物具有相对较高的SAFT温度，并且可用于热熔粘合剂压敏粘合剂和热塑性标记涂料中。
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6.发明申请FUNCTIONALIZED OLEFIN INTERPOLYMERS, COMPOSITIONS AND ARTICLES PREPARED THEREFROM, AND METHODS FOR MAKING THE SAME 有权官能化的烯烃嵌段共聚物，其制备的组合物和制品及其制备方法公开(公告)号：US20100160497A1
公开(公告)日：2010-06-24
申请号：US12299490
申请日：2007-06-11
CPC分类号： C09J151/003 , C08F8/00 , C08F255/00 , C08F255/02 , C08J5/00 , C08J2351/06 , C08J2451/06 , C08K3/01 , C08K5/0008 , C08L51/06 , C08L2205/02 , C08L2666/02 , C08L2666/04 , C09J151/06 , C08F210/02
摘要： The invention provides compositions containing at least one functionalized polyolefin, and in particular, to compositions containing at least one functionalized ethylene interpolymer, which has a melt viscosity less than 50,000 cP at 350° F. (177° C.) and a molecular weight distribution (Mw/Mn) from about 1 to 5. The invention also provides adhesive formulations containing the same. The invention also relates to the preparation of the functionalized interpolymers, by reacting, for example, such an ethylene interpolymer with the following: a) at least one unsaturated compound, containing at least one heteroatom, and b) at least one initiator.
摘要翻译： 本发明提供含有至少一种官能化聚烯烃的组合物，特别是含有至少一种官能化乙烯互聚物的组合物，其在350°F（177℃）下的熔体粘度小于50,000cP，分子量分布 （Mw / Mn）为约1〜5。本发明还提供含有该组合物的粘合剂制剂。 本发明还涉及官能化互聚物的制备，例如使这种乙烯互聚物与下列物质反应：a）至少一种含有至少一个杂原子的不饱和化合物，和b）至少一种引发剂。
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7.发明授权Low molecular weight ethylene interpolymers, methods of making, and uses thereof 有权低分子量乙烯互聚物，制备方法及其应用公开(公告)号：US08034878B2
公开(公告)日：2011-10-11
申请号：US12159514
申请日：2006-12-12
CPC分类号： C08F10/00 , C08F10/02 , C08F210/16 , C08L23/0815 , C08L51/06 , C08L2205/02 , C08L2205/025 , C08L2308/00 , C08L2314/06 , C08F4/64 , C08L2666/24 , C08L2666/06 , C08F210/14 , C08F2500/02 , C08F2500/03 , C08F2500/20 , C08F2500/17 , C08F2500/01 , C08F4/64079 , C08F4/64013
摘要： The invention provides a comprising one or more ethylene interpolymers, and wherein the interpolymers, or the composition, has a melt viscosity from 1 to 30,000 cP at 177° C., and wherein at least one ethylene interpolymer has an Rv from 0.3 to 0.99. The invention further provides a composition comprising at least one low molecular weight (LMW) ethylene interpolymer, and at least one high molecular weight (HMW) ethylene interpolymer, and wherein the composition has a melt viscosity from 1 to 30,000 cP at 177° C., and wherein the sum of the Rv from the low molecular weight interpolymer and the high molecular weight interpolymer is from 0.3 to 2. The invention further provides for processes of making such compositions, processes for functionalizing the interpolymer(s) of such compositions, and articles comprising at least one component prepared from an inventive composition.
摘要翻译： 本发明提供包含一种或多种乙烯互聚物，并且其中互聚物或组合物在177℃下的熔体粘度为1至30,000cP，并且其中至少一种乙烯互聚物的Rv为0.3-0.99。 本发明还提供包含至少一种低分子量（LMW）乙烯互聚物和至少一种高分子量（HMW）乙烯互聚物的组合物，并且其中该组合物在177℃具有1至30,000cP的熔体粘度 ，并且其中来自低分子量互聚物和高分子量互聚物的Rv的总和为0.3至2.本发明还提供了制备这种组合物的方法，使这种组合物的互聚物官能化的方法，以及 包含由本发明组合物制备的至少一种组分的制品。
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公开(公告)号：US20110144240A1
公开(公告)日：2011-06-16
申请号：US13031339
申请日：2011-02-21
申请人： William J. Harris , John D. Weaver , Brian W. Walther , Stephen F. Hahn , Yunwa W. Cheung , Pankaj Gupta , Thoi H. Ho , Kenneth N. Reichek , Selim Yalvac , Teresa P. Karjala , Benjamin R. Rozenblat , Cynthia L. Rickey
发明人： William J. Harris , John D. Weaver , Brian W. Walther , Stephen F. Hahn , Yunwa W. Cheung , Pankaj Gupta , Thoi H. Ho , Kenneth N. Reichek , Selim Yalvac , Teresa P. Karjala , Benjamin R. Rozenblat , Cynthia L. Rickey
IPC分类号： C08L23/26 , C08F299/00 , C08F230/08 , C08L29/04 , C08L75/04 , C08L27/04 , C08L33/20 , C08L31/04 , C08L47/00 , C08K7/02
CPC分类号： B32B27/327 , B32B27/06 , B32B27/32 , C08F4/659 , C08F4/65908 , C08F4/65912 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08F10/14 , C08F110/02 , C08F210/14 , C08F210/16 , C08F295/00 , C08F297/00 , C08F297/08 , C08F297/083 , C08F297/086 , C08F2410/01 , C08F2410/04 , C08F2420/02 , C08L23/02 , C08L23/06 , C08L23/0815 , C08L23/0853 , C08L23/10 , C08L53/00 , C08L53/005 , Y10T428/24942 , Y10T428/24992 , Y10T428/2826 , Y10T428/31573 , Y10T428/31587 , C08F2/38 , C08F4/65904 , C08L2666/06 , C08F2500/09 , C08F2500/03 , C08F4/64148 , C08F4/64193 , C08F4/64048 , C08F4/6411 , C08F4/64144 , C08F2500/08 , C08F4/64113 , C08L2666/02 , C08L2666/04 , C08F2500/12 , C08F2500/20 , C08F210/08 , C08F2500/11 , C08F2500/21 , C08F210/02 , C08F212/08 , C08F232/02 , C08F232/08
摘要： The invention relates to functionalized interpolymers derived from base olefin interpolymers, which are prepared by polymerizing one or more monomers or mixtures of monomers, such as ethylene and one or more comonomers, to form an interpolymer products having unique physical properties. The functionalized olefin interpolymers contain two or more differing regions or segments (blocks), resulting in unique processing and physical properties.
摘要翻译： 本发明涉及衍生自基础烯烃互聚物的官能化互聚物，其通过聚合一种或多种单体或单体混合物如乙烯和一种或多种共聚单体而制备，以形成具有独特物理性质的互聚物产物。 官能化的烯烃互聚物含有两个或多个不同的区域或链段（嵌段），产生独特的加工和物理性能。
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9.发明授权Adhesive and marking compositions made from interpolymers of ethylene/α-olefins 有权由乙烯/α-烯烃的互聚物制成的粘合剂和标记组合物公开(公告)号：US07524911B2
公开(公告)日：2009-04-28
申请号：US11376957
申请日：2006-03-15
CPC分类号： A61L27/34 , A61L15/58 , C08L2666/02 , C09J123/0815 , C08L23/08
摘要： An adhesive composition comprises: (i) at least one ethylene/α-olefin interpolymer, (ii) at least one tackifier; and (iii) optionally at least one additive, such as a plasticizer, wax and antioxidant. Preferably, the ethylene/α-olefin interpolymer has a Mw/Mn from about 1.7 to about 3.5, at least one melting point, Tm, in degrees Celsius, and a density, d, in grams/cubic centimeter, wherein the numerical values of Tm and d correspond to the relationship: Tm≧858.91−1825.3(d)+1112.8(d)2. The composition has relatively higher SAFT temperature and can be used in hot melt adhesives pressure-sensitive adhesives, and thermoplastic marking paints.
摘要翻译： 粘合剂组合物包含：（i）至少一种乙烯/α-烯烃互聚物，（ii）至少一种增粘剂; 和（iii）任选的至少一种添加剂，例如增塑剂，蜡和抗氧化剂。 优选地，乙烯/α-烯烃互聚物的Mw / Mn为约1.7至约3.5，至少一个熔点Tm，摄氏度，密度d（克/立方厘米），其中数值 Tm和d对应关系：Tm> = 858.91-1825.3（d）+1112.8（d）2。 该组合物具有相对较高的SAFT温度，并且可用于热熔粘合剂压敏粘合剂和热塑性标记涂料中。
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公开(公告)号：US20110152437A1
公开(公告)日：2011-06-23
申请号：US13031406
申请日：2011-02-21
申请人： William J. Harris , John D. Weaver , Brian W. Walther , Stephen F. Hahn , Yunwa W. Cheung , Pankaj Gupta , Thoi H. Ho , Kenneth N. Reichek , Selim Yalvac , Teresa P. Karjala , Benjamin R. Rozenblat , Cynthia L. Rickey
发明人： William J. Harris , John D. Weaver , Brian W. Walther , Stephen F. Hahn , Yunwa W. Cheung , Pankaj Gupta , Thoi H. Ho , Kenneth N. Reichek , Selim Yalvac , Teresa P. Karjala , Benjamin R. Rozenblat , Cynthia L. Rickey
IPC分类号： C08L53/00 , C08F255/02 , C08F8/14 , C08F8/00
CPC分类号： C08F297/086 , C08F210/16 , C08F295/00 , C08F297/083 , C08L23/08 , C08F210/14 , C08F2500/03 , C08F2500/20 , C08F2500/12 , C08F2500/11 , C08F2500/21
摘要： The invention relates to functionalized interpolymers derived from base olefin interpolymers, which are prepared by polymerizing one or more monomers or mixtures of monomers, such as ethylene and one or more comonomers, to form an interpolymer products having unique physical properties. The functionalized olefin interpolymers contain two or more differing regions or segments (blocks), resulting in unique processing and physical properties.
摘要翻译： 本发明涉及衍生自基础烯烃互聚物的官能化互聚物，其通过聚合一种或多种单体或单体混合物如乙烯和一种或多种共聚单体而制备，以形成具有独特物理性质的互聚物产物。 官能化的烯烃互聚物含有两个或多个不同的区域或链段（嵌段），产生独特的加工和物理性能。
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