摘要:
Disclosed is a catalyst, preferably for use in selective catalytic reduction (SCR), said catalyst comprising one or more zeolites of the MFI structure type, and one or more zeolites of the BEA structure type, wherein at least part of the one or more zeolites of the MFI structure type and at least part of the one or more zeolites of the BEA structure type respectively contain iron (Fe). Furthermore, an exhaust gas treatment system is described, comprising said catalyst as well as a process for the treatment of a gas stream comprising NOx using said catalyst as well.
摘要:
The present invention relates to a technology to purify nitrogen oxides contained in exhaust gas exhausted from lean combustion engines such as diesel engine with ammonia and a selective catalytic reduction type catalyst, and an object of the present invention is to provide a selective catalytic reduction type catalyst which can effectively purify nitrogen oxides even at a low temperature as well as inhibit leak of ammonia, and an exhaust gas purification equipment and a purifying process of exhaust gas using the same.The present invention is a selective catalytic reduction type catalyst for purifying nitrogen oxides in exhaust gas exhausted from lean combustion engines using ammonia or urea as a reducing agent, it is provided with a selective catalytic reduction type catalyst, characterized in that said catalyst comprises a lower-layer catalyst layer (A) having an oxidative function for nitrogen monoxide (NO) in exhaust gas and an upper-layer catalyst layer (B) having an adsorbing function for ammonia on the surface of a monolithic structure type carrier (C), and that the lower-layer catalyst layer (A) comprises a noble metal component (i), an inorganic base material constituent (ii) and zeolite (iii), and the upper-layer catalyst layer (B) comprises substantially none of component (i) but the component (iii).
摘要:
The present invention is an exhaust gas purification catalyst equipment, and a method of use thereof, formed by arranging a selective catalytic reduction type catalyst for purifying nitrogen oxides in exhaust gas exhausted from lean combustion engines using ammonia or urea as a reducing agent, it is provided with a selective catalytic reduction type catalyst, characterized in that said catalyst comprises a lower-layer catalyst layer (A) having an oxidative function for nitrogen monoxide (NO) in exhaust gas and an upper-layer catalyst layer (B) having an adsorbing function for ammonia on the surface of a monolithic structure type carrier (C), and that the lower-layer catalyst layer (A) comprises a noble metal component (i), an inorganic base material constituent (ii) and zeolite (iii), and the upper-layer catalyst layer (B) comprises substantially none of component (i) but the component (iii), in a flow path of exhaust gas, characterized in that a spraying means to supply an urea aqueous solution or an aqueous ammonia solution is arranged in the downstream of the aforementioned oxidation catalyst and in the upstream of aforementioned selective catalytic reduction type catalyst.
摘要:
An exhaust gas purification method which is capable of purifying nitrogen oxide to be included in exhaust gas from a lean burn engine such as a boiler, a gas turbine or a lean-burn-type gasoline engine, a diesel engine, effectively, in particular, even at low temperature, with spray-supplying an aqueous solution of urea as the reducing component to the selective reduction catalyst.The exhaust gas purification method for reducing selectively NOx in exhaust gas, which is exhausted from a lean burn engine, with a selective reduction catalyst and ammonia, characterized in that an aqueous solution of urea is spray-supplied to the selective reduction catalyst, comprising at least the following zeolite (A) and the hydrolysis promotion component of urea (B), and it is contacted at 150 to 600° C., and ammonia is generated in a ratio of [NH3/NOx=0.5 to 1.5] to NOx in exhaust gas, as converted to ammonia, and a nitrogen oxide is decomposed into nitrogen and water. zeolite (A): zeolite comprising an iron element hydrolysis promotion component (B): a complex oxide comprising at least one kind selected from titania or titanium, zirconium, tungsten, silicon or alumina
摘要翻译:一种排气净化方法,其特征在于,能够从诸如锅炉,燃气轮机或稀燃型汽油发动机的柴油发动机,柴油发动机中净化包含在废气中的氮氧化物, 即使在低温下也可以向选择还原催化剂喷雾供应尿素水溶液作为还原组分。 一种废气净化方法,用于选择性还原催化剂和氨,从贫燃发动机排出的废气中选择性地还原NOx,其特征在于向选择性还原催化剂喷射供给尿素水溶液, 至少以下的沸石(A)和尿素(B)的水解促进成分,并且在150〜600℃下接触,以[NH 3 / NO x = 0.5〜1.5]的比例生成氨与NOx 废气转化为氨,氮氧化物分解成氮和水。 沸石(A):包含铁元素水解促进组分的沸石(B):包含选自二氧化钛或钛,锆,钨,硅或氧化铝中的至少一种的复合氧化物
摘要:
The present invention is an exhaust gas purification catalyst equipment, and a method of use thereof, formed by arranging a selective catalytic reduction type catalyst for purifying nitrogen oxides in exhaust gas exhausted from lean combustion engines using ammonia or urea as a reducing agent, it is provided with a selective catalytic reduction type catalyst, characterized in that said catalyst comprises a lower-layer catalyst layer (A) having an oxidative function for nitrogen monoxide (NO) in exhaust gas and an upper-layer catalyst layer (B) having an adsorbing function for ammonia on the surface of a monolithic structure type carrier (C), and that the lower-layer catalyst layer (A) comprises a noble metal component (i), an inorganic base material constituent (ii) and zeolite (iii), and the upper-layer catalyst layer (B) comprises substantially none of component (i) but the component (iii), in a flow path of exhaust gas, characterized in that a spraying means to supply an urea aqueous solution or an aqueous ammonia solution is arranged in the downstream of the aforementioned oxidation catalyst and in the upstream of aforementioned selective catalytic reduction type catalyst.
摘要:
The present invention is a selective catalytic reduction type catalyst for purifying nitrogen oxides in exhaust gas exhausted from lean combustion engines using ammonia or urea as a reducing agent, it is provided with a selective catalytic reduction type catalyst The catalyst comprises a lower-layer catalyst layer (A) having an oxidative function for nitrogen monoxide (NO) in exhaust gas and an upper-layer catalyst layer (B) having an adsorbing function for ammonia on the surface of a monolithic structure type carrier (C), and that the lower-layer catalyst layer (A) comprises a noble metal component (i), an inorganic base material constituent (ii) and zeolite (iii), and the upper-layer catalyst layer (B) comprises substantially none of component (i) but the component (iii).
摘要:
The selective reduction-type catalyst (SROC) has a lower catalyst layer (A) and an upper catalyst layer (B) at the surface of an integral structure-type carrier (C). the lower catalyst layer (A) contains the following components (i) a noble metal component, component (ii) alumina, titania, silica, zirconia, tungsten oxide, a transition metal oxide, a rare earth oxide, and a complex oxide thereof, and component (iii) zeolite. The upper catalyst layer (B) does not substantially contain the following component (i) and contains the following component (iii). The component (i) of the lower catalyst layer (A1) of the selective reduction-type catalyst (SROC1) at the forward stage contains a platinum component of 90% by weight or more in metal equivalent. The component (i) of the lower catalyst layer (A2) of the selective reduction-type catalyst (SROC2) at the backward stage contains a palladium component of 40% or more in metal equivalent.
摘要:
A denitrification catalyst and a honeycomb structure type denitrification catalyst which are used for efficiently removing nitrogen oxides through reduction from exhaust gases discharged from, e.g., boilers and internal combustion engines such as a gasoline engine and diesel engine; and a method of denitrification using either of these catalysts. The denitrification catalyst is for use in reducing nitrogen oxides contained in an exhaust gas with an ammonia source and comprises zeolite as the main ingredient, and is characterized in that not only iron element and cerium element but tin element and/or gallium element has been deposited on the zeolite. The honeycomb structure type denitrification catalyst comprises the denitrification catalyst and a honeycomb structure support whose surface has been covered therewith. The denitrification method is characterized by adding ammonia or urea as a reducing agent to an exhaust gas containing nitrogen oxides and bringing the mixture into contact with the denitrification catalyst or honeycomb structure type denitrification catalyst at a temperature in the range of 170-550° C.
摘要:
The present invention provides an exhaust gas purification catalyst for automobile which is capable of raising temperature of exhaust gas exhausted from combustion engines such as diesel engine cars and converting NO in the exhaust gas to NO2, in addition, an exhaust gas purification catalyst system to purify soot, soluble organic component and NOx component exhausted from diesel engines, and a purifying process of exhaust gas.The present invention is an exhaust gas purification catalyst composition to oxidize NO in automobile exhaust gas comprising a catalyst composition in which a noble metal catalyst component (A) is supported on a heat-resistant inorganic oxide (B), and an exhaust gas purification catalyst composition etc. for automobile characterized in that the noble metal catalyst component (A) comprises platinum (Pt) existing in a state of elemental substance in the catalyst composition and platinum-palladium (Pt—Pd) existing in a state of alloy in the catalyst composition are provided.
摘要翻译:本发明提供一种汽车排气净化催化剂,其能够提高从诸如柴油机车辆的内燃机排出的废气的温度,并将排气中的NO转化为NO 2,另外, 用于净化从柴油发动机排出的烟灰,可溶性有机成分和NO x X成分的废气净化催化剂体系,以及废气净化处理。 本发明是将贵金属催化剂成分(A)负载在耐热性无机氧化物(B)上的催化剂组合物和排气净化催化剂(A)的废气净化催化剂组合物, 用于汽车的组合物等,其特征在于贵金属催化剂组分(A)包含以催化剂组合物中元素状态存在的铂(Pt)和在催化剂中以合金状态存在的铂 - 钯(Pt-Pd) 提供组合物。
摘要:
An oxidation catalyst for exhaust gas purification, comprising a carrier containing titania and zeolite, and a noble metal supported on the carrier, wherein the quantity of the zeolite is within a range from 35 to 50% by weight relative to the catalyst. This oxidation catalyst for exhaust gas purification exhibits favorable SOF removal performance, particularly superior CO and HC removal performance, and favorable resistance to sulfur poisoning, and is consequently ideal for the purification of an exhaust gas emitted from an internal combustion engine such as a diesel engine that uses a fuel containing sulfur.