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1.发明授权公开(公告)号：US08636959B2
公开(公告)日：2014-01-28
申请号：US12662147
申请日：2010-04-01
申请人： Ryuji Ando , Takashi Hihara , Yasuharu Kanno , Makoto Nagata
发明人： Ryuji Ando , Takashi Hihara , Yasuharu Kanno , Makoto Nagata
IPC分类号： B01D17/038 , B01D53/56
CPC分类号： B01D53/9418 , B01D53/925 , B01D53/9436 , B01D53/944 , B01D53/9468 , B01D2251/2062 , B01D2251/2067 , B01D2255/1021 , B01D2255/1023 , B01D2255/1025 , B01D2255/206 , B01D2255/20707 , B01D2255/20715 , B01D2255/20738 , B01D2255/20776 , B01D2255/2092 , B01D2255/30 , B01D2255/502 , B01D2255/504 , B01D2255/9022 , B01D2255/9027 , B01D2255/91 , B01D2255/911 , B01D2258/012 , B01J21/063 , B01J21/066 , B01J23/42 , B01J23/63 , B01J29/46 , B01J29/7615 , B01J37/0244 , B01J37/0246 , B01J37/0248 , Y02T10/24
摘要： The present invention is an exhaust gas purification catalyst equipment, and a method of use thereof, formed by arranging a selective catalytic reduction type catalyst for purifying nitrogen oxides in exhaust gas exhausted from lean combustion engines using ammonia or urea as a reducing agent, it is provided with a selective catalytic reduction type catalyst, characterized in that said catalyst comprises a lower-layer catalyst layer (A) having an oxidative function for nitrogen monoxide (NO) in exhaust gas and an upper-layer catalyst layer (B) having an adsorbing function for ammonia on the surface of a monolithic structure type carrier (C), and that the lower-layer catalyst layer (A) comprises a noble metal component (i), an inorganic base material constituent (ii) and zeolite (iii), and the upper-layer catalyst layer (B) comprises substantially none of component (i) but the component (iii), in a flow path of exhaust gas, characterized in that a spraying means to supply an urea aqueous solution or an aqueous ammonia solution is arranged in the downstream of the aforementioned oxidation catalyst and in the upstream of aforementioned selective catalytic reduction type catalyst.
摘要翻译： 本发明是一种排气净化催化剂装置及其使用方法，其特征在于，使用氨或尿素作为还原剂，配置用于净化从稀燃燃烧发动机排出的排气中的氮氧化物的选择性催化还原型催化剂， 提供有选择性催化还原型催化剂，其特征在于所述催化剂包括在排气中具有一氧化氮（NO）的氧化功能的下层催化剂层（A）和具有吸附的上层催化剂层（B） 在单体结构型载体（C）的表面上的氨的功能，下层催化剂层（A）包含贵金属组分（i），无机基材成分（ii）和沸石（iii） 并且上层催化剂层（B）在废气流动路径中基本上不包含组分（i）而不包含组分（iii）），其特征在于，提供尿素空气的喷洒装置 在上述氧化催化剂的下游和上述选择性催化还原型催化剂的上游配置氨溶液或氨水溶液。
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公开(公告)号：US08455390B2
公开(公告)日：2013-06-04
申请号：US13002175
申请日：2009-06-23
申请人： Hiroto Kikuchi , Masanori Nakamura , Hironori Wakamatsu , Katsuo Suga , Toshiharu Miyamura , Jun Ikezawa , Tetsuro Naito , Junji Ito
发明人： Hiroto Kikuchi , Masanori Nakamura , Hironori Wakamatsu , Katsuo Suga , Toshiharu Miyamura , Jun Ikezawa , Tetsuro Naito , Junji Ito
CPC分类号： F01N13/16 , B01D53/945 , B01D53/9468 , B01D53/9472 , B01D2255/1021 , B01D2255/1023 , B01D2255/1025 , B01D2255/206 , B01D2255/2063 , B01D2255/2065 , B01D2255/2066 , B01D2255/20715 , B01D2255/2073 , B01D2255/20738 , B01D2255/20746 , B01D2255/20753 , B01D2255/2092 , B01D2255/30 , B01D2255/9022 , B01D2255/9027 , B01D2255/9032 , B01D2255/908 , B01D2255/9202 , B01D2255/9207 , B01J23/63 , B01J23/6562 , B01J23/89 , B01J23/894 , B01J35/006 , B01J35/023 , B01J37/0244 , B01J37/0248 , F01N3/2828 , F01N2510/06 , Y02T10/22
摘要： An exhaust gas purifying catalyst includes a monolithic substrate (2), and a transition metal oxide layer (3) formed in the monolithic substrate (2). The transition metal oxide layer (3) contains transition metal oxide powder including: transition metal oxide particles (10); a first compound (20) on which the transition metal oxide particles (10) are supported; and a second compound (30) that surrounds a single body or an aggregate of the transition metal oxide particles (10) and the first compound (20).
摘要翻译： 废气净化催化剂包括单片基板（2）和形成在整体式基板（2）中的过渡金属氧化物层（3）。 过渡金属氧化物层（3）含有过渡金属氧化物粉末，其包括：过渡金属氧化物颗粒（10）; 负载有过渡金属氧化物粒子（10）的第一化合物（20） 和包围过渡金属氧化物颗粒（10）和第一化合物（20）的单体或聚集体的第二化合物（30）。
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公开(公告)号：US07906449B2
公开(公告)日：2011-03-15
申请号：US12149575
申请日：2008-05-05
申请人： Ryuji Ando , Takashi Hihara , Yasuharu Kanno , Makoto Nagata
发明人： Ryuji Ando , Takashi Hihara , Yasuharu Kanno , Makoto Nagata
IPC分类号： B01J29/06
CPC分类号： B01D53/9468 , B01D53/9413 , B01D53/9436 , B01D53/9477 , B01D2251/2062 , B01D2251/2067 , B01D2255/1021 , B01D2255/1023 , B01D2255/1025 , B01D2255/206 , B01D2255/20707 , B01D2255/20715 , B01D2255/20738 , B01D2255/20776 , B01D2255/2092 , B01D2255/30 , B01D2255/502 , B01D2255/504 , B01D2255/9022 , B01D2255/9027 , B01D2255/91 , B01D2258/012 , B01J21/06 , B01J21/063 , B01J23/42 , B01J23/63 , B01J29/46 , B01J29/7615 , B01J37/0244 , B01J37/0246 , B01J37/0248
摘要： The present invention is a selective catalytic reduction type catalyst for purifying nitrogen oxides in exhaust gas exhausted from lean combustion engines using ammonia or urea as a reducing agent, it is provided with a selective catalytic reduction type catalyst The catalyst comprises a lower-layer catalyst layer (A) having an oxidative function for nitrogen monoxide (NO) in exhaust gas and an upper-layer catalyst layer (B) having an adsorbing function for ammonia on the surface of a monolithic structure type carrier (C), and that the lower-layer catalyst layer (A) comprises a noble metal component (i), an inorganic base material constituent (ii) and zeolite (iii), and the upper-layer catalyst layer (B) comprises substantially none of component (i) but the component (iii).
摘要翻译： 本发明是一种选择性催化还原型催化剂，其中使用氨或尿素作为还原剂来净化从稀燃燃烧机排出的废气中的氮氧化物，其具有选择性催化还原型催化剂。催化剂包括下层催化剂层 （A）在排气中具有一氧化氮（NO）的氧化功能，在单体结构型载体（C）的表面具有氨吸附功能的上层催化剂层（B） 层状催化剂层（A）包含贵金属成分（i），无机基材成分（ii）和沸石（iii），上层催化剂层（B）基本上不含有成分（i），但成分 （iii）。
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公开(公告)号：US20080226514A1
公开(公告)日：2008-09-18
申请号：US12037362
申请日：2008-02-26
CPC分类号： B01J35/04 , B01D53/945 , B01D2255/1021 , B01D2255/1023 , B01D2255/1025 , B01D2255/204 , B01D2255/206 , B01D2255/20715 , B01D2255/2092 , B01D2255/407 , B01D2255/9027 , B01D2255/908 , B01D2255/9207 , B01J23/40 , B01J23/58 , B01J23/63 , B01J37/0244 , B01J37/0248 , Y02A50/2324 , Y02T10/22
摘要： Provided are an exhaust treatment catalyst and an exhaust article containing the catalyst. The catalyst comprises a carrier; a first layer deposited on the carrier, said first layer comprising substantially only at least one refractory metal oxide; a second layer deposited on the first layer, said second layer comprising substantially only at least one oxygen storage component and at least one binder therefore; and a third layer deposited on the second layer, said third layer comprising at least one layer of one or more platinum group metal components supported on a refractory metal oxide support.
摘要翻译： 提供了含有催化剂的废气处理催化剂和排气制品。 催化剂包括载体; 沉积在载体上的第一层，所述第一层基本上仅包含至少一种难熔金属氧化物; 沉积在第一层上的第二层，所述第二层基本上仅包含至少一种氧存储组分和至少一种粘合剂; 以及沉积在所述第二层上的第三层，所述第三层包含至少一层负载在难熔金属氧化物载体上的一种或多种铂族金属组分。
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公开(公告)号：US07374729B2
公开(公告)日：2008-05-20
申请号：US10812542
申请日：2004-03-30
CPC分类号： B01J35/04 , B01D53/945 , B01D2255/1021 , B01D2255/1023 , B01D2255/1025 , B01D2255/204 , B01D2255/206 , B01D2255/20715 , B01D2255/2092 , B01D2255/407 , B01D2255/9027 , B01D2255/908 , B01D2255/9207 , B01J23/40 , B01J23/58 , B01J23/63 , B01J37/0244 , B01J37/0248 , Y02A50/2324 , Y02T10/22
摘要： Provided are an exhaust treatment catalyst and an exhaust article containing the catalyst. The catalyst comprises: (a) a carrier; (b) a first layer deposited on the carrier, said first layer comprising substantially only at least one refractive metal oxide; (c) a second layer deposited on the first layer, said second layer comprising substantially only at least one oxygen storage component and at least one binder therefor; and (d) a third layer deposited on the second layer, said third layer comprising at least one layer of one or more platinum group metal components supported on a refractory metal oxide support. Optionally, a fourth layer is deposited on the third layer wherein the fourth layer comprises one or more platinum group metal components supported on a refractory metal oxide support. As a further option, an overcoat layer may be deposited on the third or fourth layer wherein the overcoat layer comprises a catalyst poison sorbent. Also provided are methods for preparing the catalyst and methods for monitoring the exhaust storage capacity of an exhaust article containing the catalyst.
摘要翻译： 提供了含有催化剂的废气处理催化剂和排气制品。 催化剂包括：（a）载体; （b）沉积在载体上的第一层，所述第一层基本上仅包含至少一种折射金属氧化物; （c）沉积在第一层上的第二层，所述第二层基本上仅包含至少一个储氧部件和至少一个粘合剂; 和（d）沉积在第二层上的第三层，所述第三层包含负载在难熔金属氧化物载体上的至少一层一种或多种铂族金属组分。 任选地，第四层沉积在第三层上，其中第四层包含负载在难熔金属氧化物载体上的一种或多种铂族金属组分。 作为另外的选择，外涂层可沉积在第三层或第四层上，其中外涂层包含催化剂毒物吸附剂。 还提供了制备催化剂的方法和用于监测含有催化剂的排气制品的排气存储容量的方法。
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公开(公告)号：US11666861B2
公开(公告)日：2023-06-06
申请号：US17361395
申请日：2021-06-29
申请人： Ralph J. Mancini , Cem E. Celik , Matthias Grahl , Arthur C. Selover , Sesha Hari Vemuri , Helko Schneider
发明人： Ralph J. Mancini , Cem E. Celik , Matthias Grahl , Arthur C. Selover , Sesha Hari Vemuri , Helko Schneider
CPC分类号： B01D53/869 , B01D53/0407 , B01D53/261 , B01D53/28 , B01D53/864 , B01D53/8671 , B01J20/08 , B01J20/18 , B01J23/8892 , B01D2253/104 , B01D2253/108 , B01D2253/25 , B01D2255/2073 , B01D2255/20761 , B01D2255/40 , B01D2255/9022 , B01D2255/9025 , B01D2255/9027 , B01D2257/108 , B01D2257/502 , B01D2257/504 , B01D2257/80
摘要： A system and method of pre-purification of a feed gas stream is provided that is particularly suitable for pre-purification of a feed air stream in cryogenic air separation unit. The disclosed pre-purification systems and methods are configured to remove substantially all of the hydrogen, carbon monoxide, water, and carbon dioxide impurities from a feed air stream and is particularly suitable for use in a high purity or ultra-high purity nitrogen plant. The pre-purification systems and methods preferably employ two or more separate layers of hopcalite catalyst with the successive layers of the hopcalite separated by a zeolite adsorbent layer that removes water and carbon dioxide produced in the hopcalite layers.
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公开(公告)号：US20180221857A1
公开(公告)日：2018-08-09
申请号：US15513812
申请日：2015-09-22
CPC分类号： B01J23/63 , B01D53/945 , B01D2255/1021 , B01D2255/1023 , B01D2255/1025 , B01D2255/2065 , B01D2255/20715 , B01D2255/50 , B01D2255/902 , B01D2255/9022 , B01D2255/9025 , B01D2255/9027 , B01D2258/01 , B01D2258/012 , B01J35/04 , B01J35/108 , B01J37/0215 , F01N3/08 , F01N3/2803 , F01N2330/06 , F01N2370/02 , Y02T10/22
摘要： A catalytic module, containing a solid support, and a stack including at least the following layers arranged in the following order, taking the solid support as a base: a first porous layer containing CeO2 and deposited by chemical vapour deposition, a first catalytic layer containing at least one metal and/or at least one alloy of metals selected from, for example, Pt, Pd, Rh.
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公开(公告)号：US20180141031A1
公开(公告)日：2018-05-24
申请号：US15358827
申请日：2016-11-22
发明人： Zahra Nazarpoor , Stephen J. Golden
IPC分类号： B01J35/04 , B01J23/00 , B01J23/40 , B01J23/889 , B01J23/89 , B01J23/58 , B01J23/44 , B01J23/46 , B01J35/00 , B01D53/94 , F01N3/28
CPC分类号： B01J35/04 , B01D53/945 , B01D53/9468 , B01D53/9472 , B01D2255/1023 , B01D2255/1025 , B01D2255/2042 , B01D2255/2065 , B01D2255/20707 , B01D2255/20715 , B01D2255/2073 , B01D2255/20738 , B01D2255/20761 , B01D2255/2092 , B01D2255/40 , B01D2255/405 , B01D2255/9025 , B01D2255/9027 , B01D2255/9032 , B01D2255/908 , B01J23/005 , B01J23/40 , B01J23/44 , B01J23/464 , B01J23/58 , B01J23/8892 , B01J23/8986 , B01J35/0006 , B01J2523/00 , F01N3/101 , F01N2510/068 , F01N2510/0682 , F01N2510/0684 , Y02T10/22 , B01J2523/3712 , B01J2523/822 , B01J2523/842
摘要： Multi-zoned synergized-platinum group metals (SPGM) catalysts with significant catalytic capabilities are disclosed. The multi-zoned SPGM catalysts are produced according to catalyst configurations including OC layers of ultra-low PGM loadings, alone or in combination with a base metal oxide, which are deposited onto either mixtures of doped ZrO2 and oxygen storage materials (OSM) or OSM alone. Further, the multi-zoned SPGM catalysts further include zoned impregnation layers with PGM, alone or in combination with Ba loadings. Additionally, three-zoned SPGM catalysts are produced including front and back zone catalysts that include binary spinel oxide compositions. Conversion performance of the aged SPGM catalysts and an aged PGM-based OEM catalyst are tested employing TWC low perturbation isothermal oscillating, isothermal steady-state sweep, and light-off test methodologies. Test results confirm the SPGM catalysts including ultra-low PGM loadings and spinel-based ZPGM WC layer are capable of providing significant conversion performance that is comparable to high PGM-based OEM catalyst.
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9.发明授权Substrate having porous sheet(s) for treating exhaust gases of combustion engines 有权具有用于处理内燃机废气的多孔板的基板公开(公告)号：US08337762B2
公开(公告)日：2012-12-25
申请号：US13109514
申请日：2011-05-17
申请人： Aulis Vakkilainen , Reijo Lylykangas , Ritva Heikkinen , Teuvo Maunula , Matti Harkonen , Ari Lievonen
发明人： Aulis Vakkilainen , Reijo Lylykangas , Ritva Heikkinen , Teuvo Maunula , Matti Harkonen , Ari Lievonen
CPC分类号： B01J35/04 , B01D53/865 , B01D2255/104 , B01D2255/106 , B01D2255/2063 , B01D2255/2065 , B01D2255/207 , B01D2255/9027 , B01D2255/9202 , B01J23/10 , B01J29/126 , B01J29/44 , B01J29/7007 , B01J29/7415 , B01J29/7615 , B01J37/0246 , B01J2229/186 , B01J2229/42 , F01N3/0222 , F01N3/035 , F01N3/281 , F01N2330/12 , F01N2330/38 , Y10T29/49345 , Y10T29/49826
摘要： The object of the invention is a porous sheet(s) for treating exhaust gases of combustion engines in open channels. According to the invention at least part of the porous sheet has a covering support having pores over 10 nm and coarse particles over 1.4 μm.
摘要翻译： 本发明的目的是用于在开放通道中处理内燃机的废气的多孔板。 根据本发明，多孔片材的至少一部分具有覆盖载体，其具有超过10nm的孔和超过1.4μm的粗颗粒。
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公开(公告)号：US20110094211A1
公开(公告)日：2011-04-28
申请号：US13002175
申请日：2009-06-23
申请人： Hiroto Kikuchi , Masanori Nakamura , Hironori Wakamatsu , Katsuo Suga , Toshiharu Miyamura , Jun Ikezawa , Tetsuro Naito , Junji Ito
发明人： Hiroto Kikuchi , Masanori Nakamura , Hironori Wakamatsu , Katsuo Suga , Toshiharu Miyamura , Jun Ikezawa , Tetsuro Naito , Junji Ito
IPC分类号： F01N3/28
CPC分类号： F01N13/16 , B01D53/945 , B01D53/9468 , B01D53/9472 , B01D2255/1021 , B01D2255/1023 , B01D2255/1025 , B01D2255/206 , B01D2255/2063 , B01D2255/2065 , B01D2255/2066 , B01D2255/20715 , B01D2255/2073 , B01D2255/20738 , B01D2255/20746 , B01D2255/20753 , B01D2255/2092 , B01D2255/30 , B01D2255/9022 , B01D2255/9027 , B01D2255/9032 , B01D2255/908 , B01D2255/9202 , B01D2255/9207 , B01J23/63 , B01J23/6562 , B01J23/89 , B01J23/894 , B01J35/006 , B01J35/023 , B01J37/0244 , B01J37/0248 , F01N3/2828 , F01N2510/06 , Y02T10/22
摘要： An exhaust gas purifying catalyst includes a monolithic substrate (2), and a transition metal oxide layer (3) formed in the monolithic substrate (2). The transition metal oxide layer (3) contains transition metal oxide powder including: transition metal oxide particles (10); a first compound (20) on which the transition metal oxide particles (10) are supported; and a second compound (30) that surrounds a single body or an aggregate of the transition metal oxide particles (10) and the first compound (20).
摘要翻译： 废气净化催化剂包括单片基板（2）和形成在整体式基板（2）中的过渡金属氧化物层（3）。 过渡金属氧化物层（3）含有过渡金属氧化物粉末，其包括：过渡金属氧化物颗粒（10）; 负载有过渡金属氧化物粒子（10）的第一化合物（20） 和包围过渡金属氧化物颗粒（10）和第一化合物（20）的单体或聚集体的第二化合物（30）。
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