公开(公告)号：US20120016042A1

公开(公告)日：2012-01-19

申请号：US13180733

申请日：2011-07-12

申请人： Sylvie Maury ,  Christele Legens ,  Loic Sorbier ,  Fabrice Diehl ,  Joseph Lopez ,  Lars Fischer

发明人： Sylvie Maury ,  Christele Legens ,  Loic Sorbier ,  Fabrice Diehl ,  Joseph Lopez ,  Lars Fischer

IPC分类号： C07C1/04 ,  B01J23/755 ,  B01J23/745 ,  B01J23/46 ,  B01J21/04 ,  B01J21/06 ,  B01J23/83 ,  B01J23/63 ,  B01J21/10 ,  B01J23/89 ,  B01J23/882 ,  B01J23/883 ,  B01J23/881 ,  B01J23/652 ,  B01J23/847 ,  B01J23/889 ,  B01J23/656 ,  B01J23/75

CPC分类号： B01J35/002 ,  B01J21/005 ,  B01J21/12 ,  B01J23/005 ,  B01J23/462 ,  B01J23/74 ,  B01J23/75 ,  B01J23/8476 ,  B01J23/882 ,  B01J23/8896 ,  B01J23/89 ,  B01J23/8913 ,  B01J35/008 ,  B01J35/0093 ,  B01J37/0205 ,  B01J37/08 ,  B01J37/088 ,  B01J37/18 ,  C10G2/332 ,  C10G2/333 ,  C10G2300/70

摘要： The present invention concerns a catalyst for carrying out hydrocarbon synthesis starting from a mixture comprising carbon monoxide and hydrogen, the active phase of which comprises at least one metal from group VIII deposited on a support formed by at least one oxide, in which said metal from group VIII is selected from the group constituted by cobalt, nickel, ruthenium or iron, and in which said catalyst has an atomic ratio (Co/Al)not ground/(CO/Al)ground, measured by X-ray photo-emission spectroscopy, in the range 1 to 12.The invention also concerns the catalyst preparation process and its use.

摘要翻译： 本发明涉及一种用于从包含一氧化碳和氢的混合物开始进行烃合成的催化剂，其活性相包含至少一种沉积在由至少一种氧化物形成的载体上的VIII族金属，其中所述金属来自 VIII族选自钴，镍，钌或铁构成的组，其中所述催化剂具有通过X射线光发射光谱测定的未研磨/（CO / Al）原子比（Co / Al） ，在1至12的范围内。本发明还涉及催化剂制备方法及其用途。

公开(公告)号：US09206094B2

公开(公告)日：2015-12-08

申请号：US13813021

申请日：2011-06-24

申请人： Fabrice Diehl ,  Elodie Devers

发明人： Fabrice Diehl ,  Elodie Devers

IPC分类号： C07C5/05 ,  B01J23/652 ,  B01J23/85 ,  B01J23/881 ,  B01J23/882 ,  B01J23/883 ,  B01J23/888 ,  B01J35/10 ,  B01J37/02 ,  B01J37/20 ,  C10G45/38 ,  C10G45/32 ,  C10G45/34 ,  B01J23/70 ,  B01J23/75 ,  B01J23/755 ,  C07C5/02

CPC分类号： C07C5/05 ,  B01J23/652 ,  B01J23/85 ,  B01J23/881 ,  B01J23/882 ,  B01J23/883 ,  B01J23/888 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J37/0201 ,  B01J37/0203 ,  B01J37/20 ,  C10G45/38 ,  C10G2300/104 ,  C10G2300/1044 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2300/4018

摘要： Selective hydrogenation of a gasoline cut containing polyunsaturated hydrocarbons containing at least 2 carbon atoms per molecule and having an end point of 250° C. or less, by bringing said gasoline cut into contact with at least one catalyst the active phase of which comprises at least one metal from group VIII and at least one metal from group VIB deposited on a support.

摘要翻译： 通过使所述汽油切割与至少一种催化剂相接触，含有每分子含有至少2个碳原子并具有250℃或更低终点的多不饱和烃的汽油馏分的选择性氢化，所述催化剂的活性相至少包含 来自VIII族的一种金属和至少一种沉积在载体上的VIB族金属。

公开(公告)号：US20130186806A1

公开(公告)日：2013-07-25

申请号：US13813016

申请日：2011-06-24

申请人： Fabrice Diehl ,  Elodie Devers ,  Karin Marchand ,  Bertrand Guichard

发明人： Fabrice Diehl ,  Elodie Devers ,  Karin Marchand ,  Bertrand Guichard

IPC分类号： B01J27/19 ,  C10G45/10 ,  C10G45/08

CPC分类号： B01J27/19 ,  B01J21/04 ,  B01J23/652 ,  B01J23/85 ,  B01J23/882 ,  B01J23/883 ,  B01J23/94 ,  B01J35/002 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/0203 ,  B01J37/086 ,  B01J37/20 ,  B01J38/14 ,  C10G45/08 ,  C10G45/10 ,  C10G2300/1055 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2400/04

摘要： Preparation of a catalyst having at least one metal from group VIII, at least one metal from group VIB and at least one support; in succession: i) one of i1) contacting a pre-catalyst with metal from group VIII, metal from group VIB and support with a cyclic oligosaccharide naming at least 6 α-(1,4)-bonded glucopyranose subunits; i2) contacting support with a solution containing a precursor of metal from group VIII, a precursor of said metal from group VIB and a cyclic oligosaccharide composed of at least 6 α-(1,4)-bonded glucopyranose subunits; or i3) contacting support with a cyclic oligosaccharide composed of at least 6 α-(1,4)-bonded glucopyranose subunits followed by contacting solid derived therefrom with a precursor of metal from group VIII and a precursor of metal from group VIB.

摘要翻译： 制备具有至少一种来自第VIII族的金属的催化剂，至少一种来自VIB族的金属和至少一种载体; i）i）使预催化剂与VIII族金属，VIB族金属接触，并与至少6个α-（1,4）键的吡喃葡萄糖亚基命名的环状低聚糖进行支持; i2）使载体与含有VIII族金属的前体的溶液接触，所述VIB族的所述金属的前体和由至少6个α-（1,4）键的吡喃葡萄糖亚基组成的环状寡糖; 或i3）使支持物与由至少6个α-（1,4） - 键合的吡喃葡萄糖亚基组成的环状寡糖接触，然后将从其衍生的固体与来自VIII族的金属前体和来自VIB族的金属前体接触。

公开(公告)号：US20130150639A1

公开(公告)日：2013-06-13

申请号：US13812707

申请日：2011-06-24

申请人： Fabrice Diehl ,  Anne Dubreuil ,  Josselin Janvier ,  Cecile Thomazeau

发明人： Fabrice Diehl ,  Anne Dubreuil ,  Josselin Janvier ,  Cecile Thomazeau

IPC分类号： C07C5/02

CPC分类号： C07C5/02 ,  B01J21/04 ,  B01J23/40 ,  B01J23/74 ,  B01J23/755 ,  B01J33/00 ,  B01J37/0203 ,  B01J37/0205 ,  B01J37/20 ,  C07C7/167 ,  C07C2523/755 ,  C10G45/34 ,  C10G45/36 ,  C10G45/52 ,  C10G69/06 ,  C10G2300/1011 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2400/20 ,  C10G2400/22 ,  Y02P20/52 ,  C07C11/02

摘要： Selective hydrogenation of a polyunsaturated hydrocarbon feed containing at least 2 carbon atoms per molecule and having an end point of 250° C. or less, by contacting said feed with a catalyst having an active phase of at least one metal from group VIII deposited on a support formed by at least one oxide, said catalyst being prepared using a process involving at least: i) contacting said support with at least one solution containing at least one precursor of metal from group VIII; ii) contacting said support with at least one organic compound formed from at least one cyclic oligosaccharide composed of at least 6α-(1,4)-bonded glucopyranose subunits; iii) calcining to obtain metal from group VIII in oxide form; i) and ii) possibly being carried out separately, in any order, or simultaneously.

摘要翻译： 通过使所述进料与具有活性相的催化剂选择氢化，每分子含有至少2个碳原子，每个分子具有250℃或更低的终点，所述催化剂具有沉积在 由至少一种氧化物形成的载体，所述催化剂使用至少涉及以下方法制备的方法：i）使所述载体与至少一种含有至少一种第VIII族金属前体的溶液接触; ii）使所述载体与至少一种由至少一种由至少6α-（1,4） - 键合的吡喃葡萄糖亚基组成的环状寡糖形成的有机化合物接触; iii）煅烧以获得氧化物形式的VIII族金属; i）和ii）可能以任何顺序或同时单独进行。

公开(公告)号：US09328039B2

公开(公告)日：2016-05-03

申请号：US13812707

申请日：2011-06-24

申请人： Fabrice Diehl ,  Anne Claire Dubreuil ,  Josselin Janvier ,  Cecile Thomazeau

发明人： Fabrice Diehl ,  Anne Claire Dubreuil ,  Josselin Janvier ,  Cecile Thomazeau

IPC分类号： C10G45/36 ,  C10G45/34 ,  B01J23/755 ,  C07C5/02 ,  B01J33/00 ,  B01J37/02 ,  B01J37/20 ,  C07C7/167 ,  C10G45/52 ,  C10G69/06 ,  C10G45/32 ,  B01J23/70 ,  B01J23/75 ,  B01J21/04 ,  B01J23/40 ,  B01J23/74

CPC分类号： C07C5/02 ,  B01J21/04 ,  B01J23/40 ,  B01J23/74 ,  B01J23/755 ,  B01J33/00 ,  B01J37/0203 ,  B01J37/0205 ,  B01J37/20 ,  C07C7/167 ,  C07C2523/755 ,  C10G45/34 ,  C10G45/36 ,  C10G45/52 ,  C10G69/06 ,  C10G2300/1011 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2400/20 ,  C10G2400/22 ,  Y02P20/52 ,  C07C11/02

摘要： Selective hydrogenation of a polyunsaturated hydrocarbon feed containing at least 2 carbon atoms per molecule and having an end point of 250° C. or less, by contacting said feed with a catalyst having an active phase of at least one metal from group VIII deposited on a support formed by at least one oxide, said catalyst being prepared using a process involving at least: i) contacting said support with at least one solution containing at least one precursor of metal from group VIII; ii) contacting said support with at least one organic compound formed from at least one cyclic oligosaccharide composed of at least 6 α-(1,4)-bonded glucopyranose subunits; iii) calcining to obtain metal from group VIII in oxide form; i) and ii) possibly being carried out separately, in any order, or simultaneously.

摘要翻译： 通过使所述进料与具有活性相的催化剂选择氢化，每分子含有至少2个碳原子，每个分子具有250℃或更低的终点，所述催化剂具有沉积在 由至少一种氧化物形成的载体，所述催化剂使用至少涉及以下方法制备的方法：i）使所述载体与至少一种含有至少一种第VIII族金属前体的溶液接触; ii）使所述载体与至少一种由至少一种由至少6个α-（1,4）键的吡喃葡萄糖亚基组成的环状寡糖形成的有机化合物接触; iii）煅烧以获得氧化物形式的VIII族金属; i）和ii）可能以任何顺序或同时单独进行。

公开(公告)号：US20130184361A1

公开(公告)日：2013-07-18

申请号：US13812701

申请日：2011-06-24

申请人： Fabrice Diehl ,  Anne Griboval-Constant ,  Andrei Khodakov ,  Alan Jean-Marie ,  Eric Monflier

发明人： Fabrice Diehl ,  Anne Griboval-Constant ,  Andrei Khodakov ,  Alan Jean-Marie ,  Eric Monflier

IPC分类号： C07C1/04

CPC分类号： C07C1/0445 ,  B01J21/005 ,  B01J21/04 ,  B01J21/12 ,  B01J23/005 ,  B01J23/75 ,  B01J23/8913 ,  B01J31/065 ,  B01J35/006 ,  B01J35/023 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0201 ,  B01J37/0203 ,  B01J37/0205 ,  B01J37/0226 ,  B01J37/12 ,  B01J2231/641 ,  B01J2231/648 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/12 ,  C07C2523/10 ,  C07C2523/74 ,  C07C2523/75 ,  C07C2531/02 ,  C10G2/331 ,  C10G2/332 ,  C10G2/333 ,  C07C9/14

摘要： C5+ hydrocarbon synthesis by contracting a synthesis gas with a catalyst naming at least one metal from group VIII deposited on a support formed by at least one oxide, said catalyst being prepared using a process of at least: i) contracting at least the support with at least one solution containing at least one precursor of metal from group VIII; ii) contracting at least the support with at least one organic compound formed from at least one cyclic oligosaccharide composed of at least 6 α-(1,4)-bonded glucopyranose subunits; iii) at least one calcining to obtain at least the metal from group VIII in the oxide form; i) and ii) being carried out separately, in any order, or simultaneously.

摘要翻译： C5 +烃合成通过用催化剂收缩合成气，催化剂命名至少一种沉积在由至少一种氧化物形成的载体上的VIII族金属，所述催化剂使用以下方法制备，所述方法至少包括：i）至少在载体上收缩载体 含有至少一种来自VIII族金属的前体的至少一种溶液; ii）至少由至少一种由至少6个α-（1,4）键的吡喃葡萄糖亚基组成的环状低聚糖形成的有机化合物至少包含载体; iii）至少一种煅烧以至少获得氧化物形式的VIII族金属; i）和ii）以任何顺序或同时单独进行。

公开(公告)号：US20130168292A1

公开(公告)日：2013-07-04

申请号：US13812711

申请日：2011-06-24

申请人： Fabrice Diehl ,  Elodie Devers

发明人： Fabrice Diehl ,  Elodie Devers

IPC分类号： C10G45/08 ,  C10G45/10

CPC分类号： C10G45/08 ,  B01J23/85 ,  B01J23/882 ,  B01J27/1853 ,  B01J27/1856 ,  B01J27/188 ,  B01J27/19 ,  B01J31/0201 ,  B01J31/2208 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1042 ,  B01J37/0203 ,  B01J37/0205 ,  B01J37/20 ,  C07C1/321 ,  C10G45/10 ,  C10G2300/104 ,  C10G2300/1044 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2300/4018

摘要： Hydrodesulphurization of a gasoline cut containing hydrocarbons containing at least 2 carbon atoms per molecule and having an end point of 250° C. or less, by contacting the gasoline cut with at least one catalyst having an active phase of at least one metal from group VIII and at least one metal from group VIB deposited on a support, said catalyst being prepared using a process of: i) contacting support with precursors of group VIII and group VIB metals; ii) contacting support with at least one organic compound formed from at least one cyclic oligosaccharide composed of at least 6 α-(1,4)-bonded glucopyranose subunits; iii) drying to obtain at least said metal from group VIII and at least said metal from group VIB in the oxide form; then iv) sulphurization such that said active phase is in the sulphide form; i) and ii) being carried out separately, in any order, or simultaneously.

摘要翻译： 通过使汽油馏分与至少一种具有至少一种来自第VIII族的金属的活性相的催化剂接触，将每个分子含有至少2个碳原子的烃并且终点为250℃或更低的汽油馏分加氢脱硫 和至少一种来自组VIB的金属沉积在载体上，所述催化剂使用以下方法制备：i）使载体与第VIII族和第VIB族金属的前体接触; ii）使支持物与至少一种由至少一种由至少6个α-（1,4）键的吡喃葡萄糖亚基组成的环状寡糖形成的有机化合物接触; iii）干燥以从氧化物形式获得至少来自第VIII族的金属和至少所述VIB族金属; 然后iv）硫化使得所述活性相为硫化物形式; i）和ii）以任何顺序或同时单独进行。

公开(公告)号：US20070155618A1

公开(公告)日：2007-07-05

申请号：US11715949

申请日：2007-03-09

申请人： Fabrice Diehl ,  Christophe Bouchy ,  Tivadar Cseri ,  Slavik Kasztelan

发明人： Fabrice Diehl ,  Christophe Bouchy ,  Tivadar Cseri ,  Slavik Kasztelan

IPC分类号： B01J31/00

CPC分类号： C10G45/10 ,  B01J21/12 ,  B01J23/85 ,  B01J23/88 ,  B01J23/882 ,  B01J27/1802 ,  B01J31/0254 ,  B01J37/0203 ,  B01J37/20 ,  B01J2231/645 ,  C10G45/08

摘要： A hydrotreating catalyst that contains at least one element of group VIB and/or group VIII of the periodic table and optionally phosphorus and/or silicon, with an organic compound as an additive that contains at least one nitrogen atom, is used for the transformation of hydrocarbon-containing fractions, in particular the hydrodesulfurization, the hydrodenitrification, the hydrodemetallization, the hydrogenation of various petroleum fractions, such as residues, vacuum distillates, gas oils and gasolines, and the hydroconversion of vacuum distillates.

公开(公告)号：US08618182B2

公开(公告)日：2013-12-31

申请号：US13812701

申请日：2011-06-24

申请人： Fabrice Diehl ,  Anne Griboval-Constant ,  Andrei Khodakov ,  Alan Jean-Marie ,  Eric Monflier

发明人： Fabrice Diehl ,  Anne Griboval-Constant ,  Andrei Khodakov ,  Alan Jean-Marie ,  Eric Monflier

IPC分类号： C07C27/00

CPC分类号： C07C1/0445 ,  B01J21/005 ,  B01J21/04 ,  B01J21/12 ,  B01J23/005 ,  B01J23/75 ,  B01J23/8913 ,  B01J31/065 ,  B01J35/006 ,  B01J35/023 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0201 ,  B01J37/0203 ,  B01J37/0205 ,  B01J37/0226 ,  B01J37/12 ,  B01J2231/641 ,  B01J2231/648 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/12 ,  C07C2523/10 ,  C07C2523/74 ,  C07C2523/75 ,  C07C2531/02 ,  C10G2/331 ,  C10G2/332 ,  C10G2/333 ,  C07C9/14

摘要： C5+ hydrocarbon synthesis by contracting a synthesis gas with a catalyst naming at least one metal from group VIII deposited on a support formed by at least one oxide, said catalyst being prepared using a process of at least: i) contracting at least the support with at least one solution containing at least one precursor of metal from group VIII; ii) contracting at least the support with at least one organic compound formed from at least one cyclic oligosaccharide composed of at least 6 α-(1,4)-bonded glucopyranose subunits; iii) at least one calcining to obtain at least the metal from group VIII in the oxide form; i) and ii) being carried out separately, in any order, or simultaneously.

摘要翻译： C5 +烃合成通过用催化剂收缩合成气，催化剂命名至少一种沉积在由至少一种氧化物形成的载体上的VIII族金属，所述催化剂使用以下方法制备，所述方法至少包括：i）至少在载体上收缩载体 含有至少一种来自VIII族金属的前体的至少一种溶液; ii）至少由至少一种由至少6个α-（1,4）键的吡喃葡萄糖亚基组成的环状低聚糖形成的有机化合物至少包含载体; iii）至少一种煅烧以至少获得氧化物形式的VIII族金属; i）和ii）以任何顺序或同时单独进行。

公开(公告)号：US08071655B2

公开(公告)日：2011-12-06

申请号：US11721923

申请日：2005-11-17

申请人： Fabrice Diehl ,  François Hugues ,  Marie-Claire Marion ,  Denis Uzio

发明人： Fabrice Diehl ,  François Hugues ,  Marie-Claire Marion ,  Denis Uzio

IPC分类号： C07C27/00 ,  B01J23/00 ,  B01J21/00 ,  B01J20/00

CPC分类号： B01J21/12 ,  B01J23/005 ,  B01J23/462 ,  B01J23/745 ,  B01J23/75 ,  B01J23/755 ,  B01J23/8913 ,  B01J29/405 ,  B01J29/7049 ,  B01J29/7088 ,  B01J29/7092 ,  B01J29/90 ,  B01J37/08 ,  C10G2/332 ,  Y10S502/524

摘要： A catalyst applicable to the synthesis gas conversions especially E-T slurry processes, said catalyst comprising: a) a support containing at least a first aluminate element of mixed spinel structure of formula MxM′(1−x)Al2O4/Al2O3.SiO2, x ranging between and excluding 0 and 1, or of simple spinel structure of formula MAl2O4/Al2O3.SiO2, said support being calcined in an at least partly oxidizing atmosphere, at a temperature ranging between 850° C. and 900° C., and b) an active phase deposited on said support, which contains one or more group VIII metals, selected from among cobalt, nickel, ruthenium or iron. Said catalyst is used in a fixed bed or suspended in a three-phase reactor for hydrocarbon synthesis from a CO, H2 mixture.

摘要翻译： 一种适用于合成气转化尤其是ET淤浆法的催化剂，所述催化剂包括：a）至少含有式M x M'（1-x）Al 2 O 4 / Al 2 O 3 -SiO 2的混合尖晶石结构的第一铝酸盐元素的载体， 并且不包括0和1，或者简单的尖晶石结构式为MA1204 / Al2O3.SiO2，所述载体在至少部分氧化的气氛中在850℃和900℃之间的温度下煅烧，和b） 活性相沉积在所述载体上，其含有一种或多种选自钴，镍，钌或铁的第VIII族金属。 所述催化剂用于固定床或悬浮在三相反应器中，用于从CO，H 2混合物合成碳氢化合物。