Aluminum nitride powder and thermally conductive grease composition
using the same
    2.
    发明授权
    Aluminum nitride powder and thermally conductive grease composition using the same 有权
    氮化铝粉末和使用其的导热油脂组合物

    公开(公告)号:US6136758A

    公开(公告)日:2000-10-24

    申请号:US209455

    申请日:1998-12-11

    摘要: An aluminum nitride powder having the surface treated with an organosilane represented by formula, R.sup.I.sub.a R.sup.II.sub.b SiY.sub.4-1-b, and/or a partial hydrolysis condensate thereof to acquire excellent moisture-proof, wherein R.sup.I represents a 6-20C alkyl group or a group formed by substituting halogen atom or atoms for part or all of the hydrogen atoms attached to carbon atoms of the 6-20C alkyl group, R.sup.II represents a 1-20C hydrocarbon group or a group formed by substituting halogen atom or atoms for part or all of the hydrogen atoms attached to carbon atoms of the 1-20C hydrocarbon group, Y represents a hydrolyzable group, a is an integer of 1 to 3 and b is an integer of 0 to 2, provided that a+b is an integer of 1 to 3; and a thermally conductive grease composition comprising (A) 50-95 weight % of the aforementioned surface-treated aluminum nitride powder and (B) 5 to 50 weight % of at least one base oil selected from the group consisting of liquid silicones, liquid hydrocarbons and fluorohydrocarbon oils, and further, if desired, (C) 0-30 weight % of a thicknener selected from the group consisting of zinc oxide, alumina, boron nitride and silicon carbide powders.

    摘要翻译: 具有用式表示的有机硅烷表面处理的氮化铝粉末,RIaRIIbSiY4-1-b和/或其部分水解缩合物,以获得优异的防湿性,其中RI表示6-20C烷基或由 用卤原子或原子取代与6-20C烷基的碳原子连接的部分或全部氢原子,RII表示1-20C的烃基或通过用卤原子或原子取代部分或全部氢 附着于1-20C烃基的碳原子的原子,Y表示可水解基团,a表示1〜3的整数,b表示0〜2的整数,条件是a + b为1〜3的整数。 和导热性润滑脂组合物,其包含(A)50-95重量%的上述表面处理的氮化铝粉末和(B)5至50重量%的至少一种基础油,其选自液体硅酮,液体烃 和氟代烃油,并且如果需要,(C)0-30重量%的选自氧化锌,氧化铝,氮化硼和碳化硅粉末的增稠剂。

    Thermally conductive silicone composition
    3.
    发明授权
    Thermally conductive silicone composition 有权
    导热硅胶组合物

    公开(公告)号:US6114429A

    公开(公告)日:2000-09-05

    申请号:US153334

    申请日:1998-09-15

    IPC分类号: C08L83/04 H01B1/04

    摘要: A thermally conductive silicone composition which comprises (A) 5 to 30 weight % of a liquid silicone, (B) 50 to 94.98 weight % of at least one thickener selected from the group consisting of a zinc oxide powder, an aluminum powder, an aluminum nitride powder, a boron nitride powder and a silicon carbide powder, (C) 0.01 to 10 weight % of an organopolysiloxane having at least one per molecule of hydroxyl group attached directly to a silicon atom, and (D) 0.01 to 10 weight % of an alkoxysilane, thereby retainining satisfactory thermal conductive properties and hardly causing oil bleeding over a long time.

    摘要翻译: 一种导热硅氧烷组合物,其包含(A)5至30重量%的液体硅氧烷,(B)50至94.98重量%的至少一种增稠剂,其选自氧化锌粉末,铝粉末,铝 氮化物粉末,氮化硼粉末和碳化硅粉末,(C)0.01〜10重量%的每分子羟基至少一个羟基直接与硅原子连接的有机聚硅氧烷,(D)0.01〜10重量% 烷氧基硅烷,从而保持令人满意的导热性能,并且长时间难以引起油渗出。

    Silicone grease composition
    5.
    发明授权
    Silicone grease composition 有权
    硅油组合物

    公开(公告)号:US06255257B1

    公开(公告)日:2001-07-03

    申请号:US09453469

    申请日:1999-12-02

    IPC分类号: C10M10750

    摘要: A silicone grease composition having high thermal conductivity, comprising (A) 50 to 95 weight % of a mixture of an aluminum nitride powder &agr; having an average particle size of 0.5 to 5 &mgr;m and an aluminum nitride powder &bgr; having an average particle size of 6 to 20 &mgr;m, wherein the aluminum nitride powders &agr; and &bgr; are mixed so that the &agr;/(&agr;+&bgr;) ratio by weight is from 0.1 to 0.9 and the average particle size after mixing is from 1 to 10 &mgr;m, (B) 5 to 15 weight % of organopolysiloxanes having a viscosity of from 50 to 50,000 cs at 25° C. and represented by formula R1aSiO(4−a)/2, wherein R1 represents at least one group selected from saturated or unsaturated univalent hydrocarbon groups containing 1 to 18 carbon atoms and 1.8≦a≦2.2, and (C) 0 to 35 weight % of at least one inorganic compound powder having an average particle size of 0.5 to 100 &mgr;m selected from the group consisting of zinc oxide, alumina, boron nitride and silicon carbide powders.

    摘要翻译: 一种具有高导热性的硅氧烷润滑脂组合物,其包含(A)50至95重量%的平均粒度为0.5至5μm的氮化铝粉末α和平均粒径为6的氮化铝粉末β的混合物 至20微米,其中将氮化铝粉末α和β混合,使得α/(α+β)重量比为0.1至0.9,混合后的平均粒度为1至10微米,(B)5 至15重量%的有机聚硅氧烷,其在25℃下具有50至50,000cs的粘度并由式R 1a SiO(4-a)/ 2表示,其中R 1表示选自饱和或不饱和的一价烃基中的至少一个基团, 至18个碳原子和1.8 <= a <= 2.2,和(C)0-35重量%的至少一种平均粒度为0.5-100微米的无机化合物粉末,选自氧化锌,氧化铝, 氮化硼和碳化硅粉末。

    Thermally conductive silicone grease composition
    10.
    发明授权
    Thermally conductive silicone grease composition 有权
    导热硅油组合物

    公开(公告)号:US08383005B2

    公开(公告)日:2013-02-26

    申请号:US13282797

    申请日:2011-10-27

    摘要: A thermally conductive silicone grease composition comprising: (A) an organopolysiloxane having at least two alkenyl groups in one molecule and having a kinetic viscosity of 5,000 to 100,000 mm2/s at 25° C.; (B) a hydrolyzable methylpolysiloxane having a trifunctional termination at one end and represented by the following general formula (2): wherein R2 represents an alkyl group having 1 to 6 carbon atoms and b is an integer of 5 to 100; (C) a thermally conductive filler having a thermal conductivity of at least 10 W/m·° C.; (D) an organohydrogenpolysiloxane containing from 2 to 5 hydrogen atoms in one molecule directly bound to silicon atoms (Si—H groups); (E) a bonding aid having a triazine ring and at least one alkenyl group in one molecule; and (F) a catalyst selected from the group consisting of platinum and platinum compounds.

    摘要翻译: 一种导热硅脂组合物,其包含:(A)在一个分子中具有至少两个烯基的有机聚硅氧烷,其在25℃下的动力学粘度为5,000至100,000mm 2 / s; (B)在一端具有三官能终止并由以下通式(2)表示的可水解甲基聚硅氧烷:其中R2表示碳原子数1〜6的烷基,b为5〜100的整数。 (C)具有至少10W / m·℃的导热率的导热填料; (D)在一个直接与硅原子结合的分子(Si-H基)中含有2至5个氢原子的有机氢聚硅氧烷; (E)在一个分子中具有三嗪环和至少一个烯基的键合助剂; 和(F)选自铂和铂化合物的催化剂。