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    Bi-Sr-Ca-Cu-O superconducting thin film
    2.
    发明授权
    Bi-Sr-Ca-Cu-O superconducting thin film 失效
    Bi-Sr-Ca-Cu-O超导薄膜

    公开(公告)号：US5342826A

    公开(公告)日：1994-08-30

    申请号：US950127

    申请日：1992-09-24

    申请人： Nobuhiko Kubota ,  Tsunemi Sugimoto ,  Kazushi Sugawara ,  Yuh Shiohara

    发明人： Nobuhiko Kubota ,  Tsunemi Sugimoto ,  Kazushi Sugawara ,  Yuh Shiohara

    IPC分类号： H01L39/24 ,  B32B9/00

    CPC分类号： H01L39/2458 ,  Y10S505/701

    摘要： A Bi-Sr-Ca-Cu-O system superconducting thin film formed on a substrate comprising [110] single crystals of an ABO.sub.3 type oxide having a perovskite structure, in which a (119) face is selectively grown relative to a substrate surface. The film is formed on the substrate by chemical vapor deposition process. A method of manufacturing a BiSrCaCuO system superconducting film in which an a-axis is oriented preferentially relative to the surface of a substrate comprising MgO (100) single crystals, wherein the chemical composition ratio (Sr+Ca+Cu)/Bi of the BiSrCaCuO system superconducting film is made not less than 3.5. A Bi-Sr-Ca-Cu-O system superconducting thin film formed on a substrate comprising MgO [110] single crystals, in which a (110) face is selectively grown to the substrate surface. The film is formed on the substrate by a chemical vapor deposition process.

    摘要翻译： 在包含[110]具有钙钛矿结构的ABO 3型氧化物的单晶的衬底上形成的Bi-Sr-Ca-Cu-O系超导薄膜，其中（119）面相对于衬底表面选择性地生长。 该薄膜通过化学气相沉积工艺在基板上形成。 制造BiSrCaCuO系超导膜的方法，其中a轴相对于包含MgO（100）单晶的衬底的表面优先取向，其中BiSrCaCuO的化学组成比（Sr + Ca + Cu）/ Bi 系统超导薄膜不低于3.5。 在包含MgO [110]单晶的基板上形成的Bi-Sr-Ca-Cu-O系超导薄膜，其中（110）面选择性地生长到基板表面。 通过化学气相沉积工艺在基板上形成膜。

    OXIDE SUPERCONDUCTIVITY WIRE MATERIAL AND METHOD OF MANUFACTURING THEREOF
    3.
    发明申请
    OXIDE SUPERCONDUCTIVITY WIRE MATERIAL AND METHOD OF MANUFACTURING THEREOF 审中-公开
    氧化物超导电性材料及其制造方法

    公开(公告)号：US20130217581A1

    公开(公告)日：2013-08-22

    申请号：US13881818

    申请日：2011-10-26

    申请人： Masateru Yoshizumi ,  Koichi Nakaoka ,  Yasuo Takahashi ,  Teruo Izumi ,  Yuh Shiohara ,  Yuji Aoki ,  Katsuhisa Kanbayashi

    发明人： Masateru Yoshizumi ,  Koichi Nakaoka ,  Yasuo Takahashi ,  Teruo Izumi ,  Yuh Shiohara ,  Yuji Aoki ,  Katsuhisa Kanbayashi

    IPC分类号： H01B12/06

    CPC分类号： H01B12/06 ,  H01L39/2425 ,  H01L39/2483 ,  Y10T428/2949

    摘要： Provided is an oxide superconducting wire material, wherein pinning of magnetic flux, under an environment in which magnetic field is applied, can be conducted efficiently towards any magnetic-field applying angle direction, to secure a high superconductive property. The oxide superconducting wire material (100) is provided with a metal substrate (110), an intermediate layer (120) formed upon the metal substrate (110), and a REBaCuO-system superconductive layer (140) formed upon the intermediate layer (120). RE comprises one or more elements selected from Y, Nd, Sm, Eu, Gd, and Ho. Oxide particles including Zr are distributed within the superconductive layer (140) as magnetic-flux pinning points (145), and the mole ratio (y) of Ba included within the superconductive layer (140) is, when the mole ratio of Zr is assumed to be x, within a range of (1.2+ax)≦y≦(1.8+ax), wherein 0.5≦a≦2.

    摘要翻译： 提供了一种氧化物超导线材，其中在施加磁场的环境下磁通的钉扎可以有效地向任何磁场施加角度方向传导，以确保高的超导性能。 氧化物超导线材（100）设置有金属基板（110），形成在金属基板（110）上的中间层（120）和形成在中间层（120）上的REBaCuO系超导层（140） ）。 RE包括选自Y，Nd，Sm，Eu，Gd和Ho中的一种或多种元素。 包含Zr的氧化物粒子作为磁通钉扎点（145）分布在超导层（140）内，并且当考虑Zr的摩尔比时，超导层（140）中包含的Ba的摩尔比（y）为 在（1.2 + ax）@ y @（1.8 + ax）的范围内为x，其中0.5 @ a @ 2。

    RE1Ba2Cu3O7-z SUPERCONDUCTOR
    5.
    发明申请
    RE1Ba2Cu3O7-z SUPERCONDUCTOR 审中-公开
    RE1Ba2Cu3O7-z超导体

    公开(公告)号：US20120035055A1

    公开(公告)日：2012-02-09

    申请号：US13154684

    申请日：2011-06-07

    申请人： Masataka IWAKUMA ,  Akira Ibi ,  Teruo Izumi ,  Yuh Shiohara

    发明人： Masataka IWAKUMA ,  Akira Ibi ,  Teruo Izumi ,  Yuh Shiohara

    IPC分类号： H01L39/12 ,  H01F6/00

    CPC分类号： H01L39/126 ,  H01L39/2483

    摘要： Problem: To provide an REBCO superconductor which has electromagnetic properties of an extremely small magnetization in a DC magnetic field or an extremely small pinning loss in a fluctuating magnetic field and thereby enable production of a REBCO superconducting wire with an extremely small magnetization and pinning loss.Solution to Problem: A RE1Ba2Cu3O7-z superconductor characterized by having a magnetization-zero-region on its magnetization curve, wherein in the magnetization-zero-region a rate of change of magnetization remains at about zero near zero magnetization, the magnetization curve is formed when an external magnetic field turns from an increase to a decrease or from a decrease to an increase, and RE is one or more of Y, Gd, Nd, Sm, Eu, Yb, Pr, and Ho.

    摘要翻译： 问题：提供一种REBCO超导体，该超导体在直流磁场中具有非常小的磁化强度的电磁特性，或者在波动的磁场中具有非常小的钉扎损耗，从而能够制造具有非常小的磁化强度和钉扎损耗的REBCO超导线材。 解决问题的方法：一种RE1Ba2Cu3O7-z超导体，其特征在于在其磁化曲线上具有磁化 - 零区域，其中在磁化零区域中磁化变化率在零磁化附近保持在约零，形成磁化曲线 当外部磁场从增加转变为降低或从降低到增加时，RE是Y，Gd，Nd，Sm，Eu，Yb，Pr和Ho中的一种或多种。

    Method of manufacturing a metal substrate for an oxide superconducting wire
    6.
    发明授权
    Method of manufacturing a metal substrate for an oxide superconducting wire 有权
    制造氧化物超导线金属基板的方法

    公开(公告)号：US07431868B2

    公开(公告)日：2008-10-07

    申请号：US11239204

    申请日：2005-09-30

    申请人： Toshihiko Maeda ,  Toru Izumi ,  Katsuya Hasegawa ,  Shigenobu Asada ,  Teruo Izumi ,  Yuh Shiohara

    发明人： Toshihiko Maeda ,  Toru Izumi ,  Katsuya Hasegawa ,  Shigenobu Asada ,  Teruo Izumi ,  Yuh Shiohara

    IPC分类号： H01B12/00 ,  H01L39/24 ,  B05D5/12

    CPC分类号： H01L39/2454 ,  Y10T29/49014

    摘要： A metal substrate for an oxide superconducting wire, which comprises a polycrystalline metal substrate with a rolled aggregate structure having a {100} plane which is parallel to the rolled surface and a axis which is parallel to the rolling direction, and an oxide crystal layer comprising an oxide of the polycrystalline metal and formed on a surface of the polycrystalline metal substrate, wherein at least 90% of grain boundaries in the oxide crystal layer have an inclination of 10° or less, and at least 90% of the {100} plane of the oxide crystal layer make an angle of 10° or less with the surface of the polycrystalline metal substrate.

    摘要翻译： 一种用于氧化物超导线的金属基底，其包括具有平行于轧制表面的{100}平面和平行于轧制方向的<001>轴的轧制骨料结构的多晶金属基体和氧化物 所述多晶金属的氧化物形成在所述多晶金属基板的表面上，所述氧化物晶层中的至少90％的晶界倾斜度为10°以下，所述{ 100}面与多晶金属基板的表面成10°以下的角度。

    Method of retaining melt of oxide
    7.
    发明授权
    Method of retaining melt of oxide 失效
    保留氧化物熔体的方法

    公开(公告)号：US5632811A

    公开(公告)日：1997-05-27

    申请号：US420519

    申请日：1995-04-12

    申请人： Yasuo Namikawa ,  Yasuji Yamada ,  Satoshi Koyama ,  Yuh Shiohara ,  Shoji Tanaka

    发明人： Yasuo Namikawa ,  Yasuji Yamada ,  Satoshi Koyama ,  Yuh Shiohara ,  Shoji Tanaka

    IPC分类号： C30B9/00 ,  C30B15/00 ,  C30B15/12 ,  C30B29/22 ,  H01B13/00 ,  H01L21/208 ,  C30B29/16

    CPC分类号： C30B29/225 ,  C30B15/12 ,  C30B9/00

    摘要： In order to stably retain an oxide-based melt consisting essentially of yttrium or a lanthanoid element, barium, copper and oxygen at a prescribed temperature with no impurity contamination thereby preparing a large oxide crystal of high quality from the melt, an oxide melt consisting essentially of yttrium or a lanthanoid element, barium, copper and oxygen is stored in a first crucible, which in turn is held in a second crucible. The first crucible is made of a material which is an oxide of at least one element forming the melt having a melting point higher by at least 10.degree. C. than a melt retention temperature and causing no structural phase transition up to a temperature higher by 10.degree. C. than the aforementioned prescribed temperature, with solubility of not more than 5 atomic percent with respect to the melt in a temperature range from the room temperature to a temperature higher by 10.degree. C. than the melt retention temperature. The second crucible is made of a material substantially causing neither melting nor chemical reaction with respect to the oxide-based melt, which can retain the melt more stably than the first material. Even if the melt overflows the first crucible, this overflow is suppressed by the second crucible. It is possible to prepare a crystal of an oxide superconductor such as YBa.sub.2 Cu.sub.3 O.sub.7-x (0.ltoreq.X.ltoreq.1) by the pulling method from the melt which is stored in the first crucible.

    摘要翻译： 为了稳定地保持基本上由钇或镧系元素，钡，铜和氧组成的氧化物基熔体，在规定的温度下没有杂质污染，从而从熔体制备高质量的大的氧化物晶体，基本上由 的钇或镧系元素，钡，铜和氧储存在第一坩埚中，第一坩埚又保持在第二坩埚中。 第一坩埚由至少一种形成熔体的元素的氧化物的材料制成，其熔点比熔融保持温度高至少10℃，并且不会导致结构相变达到高于10℃的温度 ℃以上的规定温度，相对于熔体，在室温至高于熔融保持温度10℃的温度范围内的溶解度为5原子％以下。 第二坩埚由相对于基于氧化物的熔体基本上不熔化和化学反应的材料制成，其可以比第一材料更稳定地保持熔体。 即使熔体溢出第一坩埚，这种溢流被第二坩埚抑制。 可以通过从存储在第一坩埚中的熔体的拉伸方法制备氧化物超导体的晶体，例如YBa2Cu3O7-x（0≤X1）。

    Composite material and method of preparing same
    8.
    发明授权
    Composite material and method of preparing same 失效
    复合材料及其制备方法

    公开(公告)号：US5536704A

    公开(公告)日：1996-07-16

    申请号：US240067

    申请日：1994-05-09

    申请人： Yasuji Yamada ,  Minoru Tagami ,  Masaru Nakamura ,  Hideki Sakai ,  Koichi Uehara ,  Yuh Shiohara ,  Shoji Tanaka

    发明人： Yasuji Yamada ,  Minoru Tagami ,  Masaru Nakamura ,  Hideki Sakai ,  Koichi Uehara ,  Yuh Shiohara ,  Shoji Tanaka

    IPC分类号： C01G1/00 ,  C30B15/00 ,  C30B29/22 ,  H01L39/02 ,  H01L39/24 ,  C30B19/02

    CPC分类号： C30B29/225 ,  C30B15/00 ,  H01L39/2461 ,  Y10S505/729

    摘要： A composite material comprising a bulky substrate of a Y-series 123 metal oxide crystal, and at least one layer provided on a surface of the substrate and formed of a crystal of a Y-series 123 metal oxide. The substrate may be produced by immersing a seed material in a liquid phase which comprises components constituting the metal oxide. The liquid phase contains a solid phase located at a position different from the position at which the seed material contacts the liquid phase. The solid phase provides the liquid phase with solutes which constitute the Y-series 123 metal oxide so that the solutes are transported to the position at which the seed material and the liquid phase contact, thereby permitting the Y-series 123 metal oxide to grow on the seed material as primary crystals and to obtain the bulky substrate. The layer of a Y-series 123 metal oxide may be formed on the substrate by a sputtering method, a vacuum deposition method, a laser abrasion method, a CVD method or a liquid phase epitaxy method.

    摘要翻译： 一种复合材料，其特征在于，包括Y系123金属氧化物晶体的体积大的基板，以及设置在所述基板的表面上的由Y系123金属氧化物晶体形成的至少一层。 基材可以通过将种子材料浸入包含构成金属氧化物的组分的液相中来制备。 液相含有位于与种子材料接触液相的位置不同的位置的固相。 固相为构成Y系123金属氧化物的溶质提供液相，使得溶质被输送到种子材料和液相接触的位置，从而允许Y系列123金属氧化物生长 种子材料作为主要晶体并获得体积大的底物。 可以通过溅射法，真空沉积法，激光磨蚀法，CVD法或液相外延法在基板上形成Y系123金属氧化物层。

    Re-type oxide superconducting wire and process for producing the same
    10.
    发明授权
    Re-type oxide superconducting wire and process for producing the same 有权
    再生氧化物超导线及其制造方法

    公开(公告)号：US08326387B2

    公开(公告)日：2012-12-04

    申请号：US12811141

    申请日：2008-12-17

    申请人： Masashi Miura ,  Tatsuhisa Nakanishi ,  Yasunori Sutoh ,  Teruo Izumi ,  Yuh Shiohara

    发明人： Masashi Miura ,  Tatsuhisa Nakanishi ,  Yasunori Sutoh ,  Teruo Izumi ,  Yuh Shiohara

    IPC分类号： H01L39/24

    CPC分类号： H01L39/2425 ,  H01L39/126 ,  H01L39/2483 ,  Y10T29/49014

    摘要： A RE-type oxide superconducting wire having excellent angular dependence for magnetic field of Jc is obtained by finely dispersing magnetic flux pinning centers into a superconductor. A mixed solution which comprises a metal-organic complex solution including a metal element which composes a RE-type oxide superconductor whose Ba content is reduced and a metal-organic complex solution including at least one or more kinds of metals which are selected from Zr, Ce, Sn, or Ti which has a larger affinity for Ba is coated onto an intermediate layer of a composite substrate, and the assembly is then calcined to disperse artificially and finely oxide particles (magnetic flux pinning centers) including Zr. Thus, the angular dependence for magnetic field (Jc,min/Jc,max) of Jc can be remarkably improved.

    摘要翻译： 通过将磁通钉扎中心精细地分散到超导体中，获得对Jc的磁场具有优异的角度依赖性的RE型氧化物超导线。 一种混合溶液，其包含含有金属元素的金属有机络合物溶液，所述金属有机络合物溶液中含有Ba含量减少的RE型氧化物超导体和含有选自Zr， 对Ba具有较大亲合力的Ce，Sn或Ti涂覆在复合衬底的中间层上，然后将该组件煅烧以分散包括Zr的人造和细小氧化物颗粒（磁通钉扎中心）。 因此，Jc的磁场的角度依赖性（Jc，min / Jc，max）可以显着提高。