Bimodal emulsion and its method of preparation
    4.
    发明授权
    Bimodal emulsion and its method of preparation 失效
    双峰乳液及其制备方法

    公开(公告)号:US5419852A

    公开(公告)日:1995-05-30

    申请号:US801472

    申请日:1991-12-02

    摘要: A stable, low viscosity bimodal oil in water emulsion having an emulsifier, a continuous water phase and a discontinuous oil phase having an oil:water ratio of from about 70:30 to about 85:15 by weight, the discontinuous oil phase being characterized by two distinct oil droplet sizes D.sub.L and D.sub.S wherein D.sub.L is about 10 to 40 microns and D.sub.S is less than or equal to 5 microns, the ratio of D.sub.L /D.sub.S is greater than or equal to 4 and about 45 to 85% by weight of the oil is in oil droplet size D.sub.L.

    摘要翻译: 稳定的低粘度双峰水包油乳液,其具有乳化剂,连续水相和不连续油相,其油 - 水比为约70:30至约85:15重量比,不连续油相的特征在于 两种不同的油滴尺寸DL和DS,其中DL为约10至40微米,DS小于或等于5微米,DL / DS的比例大于或等于4且约45至85重量% 油是油滴尺寸DL。

    Recirculating a portion of high internal phase emulsions prepared in a
continuous process
    8.
    发明授权
    Recirculating a portion of high internal phase emulsions prepared in a continuous process 失效
    循环连续过程中制备的一部分高内相乳液

    公开(公告)号:US5827909A

    公开(公告)日:1998-10-27

    申请号:US716510

    申请日:1996-09-17

    摘要: An improvement in a continuous process for making high internal phase emulsions that are typically polymerized to provide microporous, open-celled polymeric foam materials capable of absorbing aqueous fluids, especially aqueous body fluids such as urine. The improvement involves recirculating a portion (about 50% or less) of the emulsion withdrawn from the dynamic mixing zone of this continuous process. This increases the uniformity of the emulsion ultimately obtained from this continuous process in terms of having the water droplets homogeneously dispersed in the oil phase. This also improves the stability of the HIPE and expands the temperature range for pouring and curing this HIPE during subsequent emulsion polymerization. The improvement also eliminates the need for a static mixer outside the dynamic mixing zone, and allows for processing where relatively low pressure drops are required across the mixing zone.

    摘要翻译: 用于制备高内相乳液的连续方法的改进,其通常被聚合以提供能够吸收含水流体,特别是尿液体液等微孔,开孔聚合物泡沫材料。 该改进涉及将从该连续过程的动态混合区抽出的乳液的一部分(约50%或更少)再循环。 这就增加了从这个连续过程中最终获得的乳液的均匀性,就是使水滴均匀地分散在油相中。 这也提高了HIPE的稳定性,并扩大了在随后的乳液聚合过程中倾倒和固化该HIPE的温度范围。 该改进也消除了在动态混合区之外的静态混合器的需要,并且允许在混合区域需要相对低的压降的处理。

    Preparation of emulsions
    9.
    发明授权
    Preparation of emulsions 失效
    乳液的制备

    公开(公告)号:US4746460A

    公开(公告)日:1988-05-24

    申请号:US800959

    申请日:1985-11-22

    申请人: Spencer E. Taylor

    发明人: Spencer E. Taylor

    摘要: An HIPR emulsion of oil in water is prepared by a method comprising the steps of (a) generating a foam by beating a gas into an aqueous solution of a surfactant and (b) dispersing the foam into the oil under low shear conditions in the range 10 to 1,000 reciprocal seconds in such manner that an emulsion is formed comprising distorted oil droplets having mean droplet diameters in the range 2 to 50 microns, separated by aqueous films, 70 to 98% by volume of the liquid content of the emulsion being oil.The method is applicable to both high and low viscosity oils.Depending on the nature of the oil, the emulsions can be used in the food, drug, cosmetics and petroleum industries.

    摘要翻译: 通过包括以下步骤的方法制备油中水的HIPR乳液:(a)通过将气体喷射到表面活性剂的水溶液中产生泡沫,和(b)在低剪切条件下将泡沫分散到油中, 以形成乳液的方式形成10至1,000个倒数秒,其中包含具有2至50微米范围内的平均液滴直径的变形油滴,由水膜分离,乳液的液体含量为油的70至98体积%。 该方法适用于高粘度和低粘度的油。 根据油的性质,乳液可用于食品,药物,化妆品和石油工业。

    Emulsion of viscous hydrocarbon in aqueous buffer solution and method
for preparing same
    10.
    发明授权
    Emulsion of viscous hydrocarbon in aqueous buffer solution and method for preparing same 失效
    缓冲溶液中粘性烃的乳液及其制备方法

    公开(公告)号:US5622920A

    公开(公告)日:1997-04-22

    申请号:US403185

    申请日:1995-03-13

    摘要: A method for forming a stable emulsion of a viscous hydrocarbon in an aqueous buffer solution includes the steps of: providing a viscous hydrocarbon containing an inactive natural surfactant and having a salt content by weight of less than or equal to about 15 ppm and having a water content by weight of less than or equal to about 0.1%; forming a solution of a buffer additive in an aqueous solution to provide a basic aqueous buffer solution, the buffer additive being operative to extract and activate the inactive natural surfactant from the viscous hydrocarbon; and mixing the viscous hydrocarbon with the aqueous buffer solution at a rate sufficient to provide an emulsion of the viscous hydrocarbon in the aqueous buffer solution, whereby the buffer additive extracts the inactive natural surfactant from the viscous hydrocarbon into the aqueous buffer solution and activates the inactive natural surfactant so as to stabilize the emulsion. According to the invention, the buffer additive is a water soluble amine. The inactive natural surfactant contained in the viscous hydrocarbon includes carboxylic acids, phenols, esters, and mixtures thereof. Bimodal emulsions, having two distinct droplet size distributions, are also formed according to the method of the present invention and have improved viscosity characteristics.

    摘要翻译: 在缓冲溶液水溶液中形成粘性烃的稳定乳液的方法包括以下步骤:提供含有惰性天然表面活性剂并且盐含量小于或等于约15ppm并具有水的粘性烃 重量含量小于或等于约0.1%; 在水溶液中形成缓冲添加剂的溶液以提供碱性缓冲水溶液,所述缓冲添加剂可操作以从粘性烃提取和活化无活性天然表面活性剂; 并且以足以提供缓冲溶液中粘性烃的乳液的速率将粘性烃与缓冲水溶液混合,由此缓冲添加剂将无活性天然表面活性剂从粘性烃中提取到缓冲水溶液中并激活非活性的 天然表面活性剂以稳定乳液。 根据本发明,缓冲添加剂是水溶性胺。 包含在粘性烃中的惰性天然表面活性剂包括羧酸,酚,酯及其混合物。 具有两个不同液滴尺寸分布的双峰乳液也根据本发明的方法形成并具有改进的粘度特性。