Styrene separation from ethylbenzene
    2.
    发明授权
    Styrene separation from ethylbenzene 失效
    苯乙烯分离苯乙烯

    公开(公告)号:US3801664A

    公开(公告)日:1974-04-02

    申请号:US3801664D

    申请日:1973-03-16

    申请人: SHELL OIL CO

    发明人: BLYTAS G

    IPC分类号: C01G3/08 C07C7/156 C07C7/16

    CPC分类号: C01G3/08 C07C7/156 C07C15/46

    摘要: STYRENE IS SEPARATED FROM ETHYLBENZENE IN HIGH YIELD AND PURITY BY A PROCESS WHICH COMPRISES (A) EXTRACTION WITH A TWO - -PHASE SOLVENT SYSTEM IN WHICH THE EXTRACTING PHASE IS A CONCENTRATED ANHYDROUS CUPROUS NITRATE/ PROPIONITRILE SOLUTION, WHEREIN THE STYRENE IS SELECTIVELY COMPLEXED WITH THE CUPROUS ION, AND THE ETHYLBENZENE COUNTER SOLVENT IS A C5-C18 PARAFFIN; (B) SEPARATION OF THE PROPIONITRILE SOLUTION PHASE CONTAINING THE STYRENECUPROUS ION COMPLEX FROM THE PARAFFIN PHASE AND (C) DECOMPOSING THE STYRENE-CUPROUS ION COMPLEX TO RECOVER THE STYRENE THEREFROM.

    Catalyst
    6.
    发明授权
    Catalyst 失效
    催化剂

    公开(公告)号:US4600704A

    公开(公告)日:1986-07-15

    申请号:US652052

    申请日:1984-09-19

    申请人: James R. Jennings

    发明人: James R. Jennings

    CPC分类号: C22B15/0073 Y02P10/236

    摘要: A substantially iron-free copper nitrate solution is made by dissolving a copper-containing solid catalyst composition such as a used copper-zinc oxide-alumina methanol synthesis catalyst in nitric acid and controlling the acid concentration at a level such that any iron oxide present in the composition remains substantially undissolved. The acid concentration during dissolution is preferably under 4 molar. Alternatively or additionally the terminal pH is greater than 1.0. The resulting solution is pure enough for reconversion to catalyst by co-precipitation.

    摘要翻译: 通过将诸如使用的铜 - 氧化锌 - 氧化铝 - 甲醇合成催化剂的含铜固体催化剂组合物溶解在硝酸中来制备基本上无铁的硝酸铜溶液,并将酸浓度控制在使得存在于 该组合物基本上未溶解。 溶解期间的酸浓度优选为4摩尔以下。 或者或另外,末端pH大于1.0。 所得溶液足够纯以通过共沉淀重新转化为催化剂。

    Concentrated cuprous nitrate/propionitrile solutions as complexing agents for olefin separations
    7.
    发明授权
    Concentrated cuprous nitrate/propionitrile solutions as complexing agents for olefin separations 失效
    浓缩的硝酸铵/丙酮溶液作为烯烃分离的复合剂

    公开(公告)号:US3801666A

    公开(公告)日:1974-04-02

    申请号:US3801666D

    申请日:1973-03-16

    申请人: SHELL OIL CO

    发明人: BLYTAS G

    IPC分类号: C01G3/08 C07C7/156 C07C11/00

    CPC分类号: C01G3/08 C07C7/156

    摘要: ANHYDROUS CUPROUS NITRATE/PROPIONITRILE SOLUTIONS HAVING HIGH CONCENTRATIONS OF CUPROUS ION, E.G., 15-26% BY WEIGHT CUPROUS ION, AND CORRESPONDINGLY LOW CONCENTRATIONS OF CUPRIC ION, E.G., 2-5% BY WEIGHT CUPRIC ION, AND THE PREPARATION THEREOF BY (1) CONTACTING QUANTITIES OF CUPRIC NITRATE AND METALLIC COPPER SUFFICIENT TO YIELD NO MORE THAN ABOUT 4% CUPROUS ION IN PROPIONITRILE SOLVENT AT ELEVATED TEMPERATURES TO PRODUCE A DILUTE PROPIONITRILE SOLVEN SOLUTION WHEREIN THE COPPER IS PRESENT SUBSTANTIALLY IN THE CUPROUS FORM AND (2) CONCENTRATING THE DILUTE/PROPIONITRILE SOLUTION. THE CONCENTRATED CUPROUS NITRATE/PROPIONITRILE SOLUTIONS, THUSLY PREPARED, ARE USEFUL IN AFFECTING THE SEPARATION OF OLEFINICALLY UNSATURATED HYDROCARBONS FROM HYDROCARBONS OF LESSER DEGREES OF UNSATURATION.