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    Synthesis of cyclic organic compounds and metallocenes
    1.
    发明授权
    Synthesis of cyclic organic compounds and metallocenes 有权

    公开(公告)号：US11479573B2

    公开(公告)日：2022-10-25

    申请号：US17159791

    申请日：2021-01-27

    申请人： Univation Technologies, LLC

    发明人： Angela I. Padilla-Acevedo ,  Roger L. Kuhlman

    IPC分类号： C07F17/00 ,  C08F4/6592 ,  C08F210/16 ,  C07C45/48 ,  C08F4/76 ,  C08F10/02 ,  C07C45/45

    摘要： A method comprising synthesizing a cyclic organic compound via reaction of an unsubstituted or substituted cyclopentene with an unsubstituted or substituted acrylic acid in the presence of phosphoric and/or sulfonic acid reagent to make the cyclic organic compound. Also, a method of synthesizing a ligand for a transition metal, and a related substituted ligand-metal complex and catalyst, from the unsubstituted or substituted cyclopentene and unsubstituted or substituted acrylic acid. Also, the cyclic organic compound, ligand, and substituted ligand-metal complex and catalyst synthesized thereby. Also a method of polymerizing an olefin with the catalyst to give a polyolefin, and the polyolefin made thereby.

    METHOD OF PRODUCING HIGHER ALKANONES, PREFERABLY 6-UNDECANONE, AND DERIVATIVES THEREOF
    2.
    发明申请
    METHOD OF PRODUCING HIGHER ALKANONES, PREFERABLY 6-UNDECANONE, AND DERIVATIVES THEREOF 有权

    公开(公告)号：US20210395179A1

    公开(公告)日：2021-12-23

    申请号：US17292857

    申请日：2019-11-19

    申请人： Evonik Operations GmbH

    发明人： Thomas HAAS ,  Christian RICHTER ,  Uwe PAULMANN ,  Anja HECKER

    IPC分类号： C07C45/48 ,  C07C51/50 ,  C12P7/40 ,  C12P7/62

    摘要： A method of producing higher alkanones, preferably 6-undecanone, from ethanol and/or acetate, may include: (a) contacting the ethanol and/or acetate with at least one microorganism capable of carrying out carbon chain elongation to produce hexanoic acid and/or an ester thereof from the ethanol and/or acetate; (b) extracting the hexanoic acid and/or ester thereof from the contacting (a) using at least one extractant in an aqueous medium, the extractant including at least one alkyl-phosphine oxide and at least one C12+ alkane; or at least one trialkylamine and at least one C12+ alkane; and (c) contacting the extracted hexanoic acid and/or ester thereof from (b) with at least one ketonization catalyst and eventually a further C1 to C22 alkanoic acid under suitable reaction conditions for chemical ketonization of hexanoic acid and eventually the further alkanoic acid to a higher alkanone, preferably 6-undecanone.

    Ether lubricants from fatty acids
    5.
    发明授权
    Ether lubricants from fatty acids 有权
    来自脂肪酸的醚润滑剂

    公开(公告)号：US09193653B1

    公开(公告)日：2015-11-24

    申请号：US14540459

    申请日：2014-11-13

    申请人： Sven Ivar Hommeltoft

    发明人： Sven Ivar Hommeltoft

    IPC分类号： C07C43/00 ,  C07C41/01 ,  C07C41/09 ,  C07C41/06 ,  C07C45/48 ,  C07C29/145

    CPC分类号： C07C29/145 ,  C07C41/01 ,  C07C41/06 ,  C07C41/09 ,  C07C45/48 ,  Y02P20/582 ,  C07C49/04 ,  C07C31/02 ,  C07C43/04

    摘要： Processes for producing long chain ethers from long chain secondary alcohols using fatty acid containing feedstocks. In an embodiment, a long chain secondary alcohol may be reacted with a primary alcohol, a secondary alcohol, or an olefin to form a long chain ether. In another embodiment, a long chain secondary alcohol or the corresponding alkoxide may be reacted with an alkyl halide to form a long chain ether. In yet a further embodiment, a long chain secondary alcohol may be converted to a halide, and the halide may be reacted with a second alcohol or the corresponding alkoxide to form a long chain ether. Long chain ether compositions of matter are also disclosed.

    摘要翻译： 使用含脂肪酸的原料从长链仲醇生产长链醚的方法。 在一个实施方案中，长链仲醇可以与伯醇，仲醇或烯烃反应形成长链醚。 在另一个实施方案中，长链仲醇或相应的醇盐可与烷基卤反应形成长链醚。 在又一个实施方案中，长链仲醇可以转化为卤化物，并且卤化物可以与第二醇或相应的醇盐反应形成长链醚。 还公开了物质的长链醚组合物。

    Preparation of cyclic ketones
    8.
    发明授权
    Preparation of cyclic ketones 失效
    环酮的制备

    公开(公告)号：US5426235A

    公开(公告)日：1995-06-20

    申请号：US251041

    申请日：1994-06-01

    申请人： Juergen Schroeder ,  Klaus Ebel ,  Charles Schommer

    发明人： Juergen Schroeder ,  Klaus Ebel ,  Charles Schommer

    IPC分类号： C07C45/00 ,  C07C45/48

    CPC分类号： C07C45/00

    摘要： Cyclic ketones of the general formula I ##STR1## where n is an integer from 4 to 6, are prepared by reacting aliphatic dicarbonitriles of the general formula IINC--(CH.sub.2).sub.n --CN (II),where n has the abovementioned meaning, in the gas phase in the presence of water at from 250.degree. to 500.degree. C. on solid oxide catalysts.

    摘要翻译： 通式II NC-（CH 2）n -CN（II）的脂族二腈通过使通式II NC-（CH2）n-CN（II）的脂肪族二腈反应来制备通式I的环酮，其中n是4-6的整数，其中n具有 在固体氧化物催化剂上，在250〜500℃的水存在下，在气相中。