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    Self polymerizable phenylquinoxalines, their preparation and use in polyphenylquinoxaline homopolymers and copolymers
    8.
    发明授权
    Self polymerizable phenylquinoxalines, their preparation and use in polyphenylquinoxaline homopolymers and copolymers 失效
    自聚合苯基喹喔啉，它们的制备和在聚苯基喹喔啉均聚物和共聚物中的应用

    公开(公告)号：US5030704A

    公开(公告)日：1991-07-09

    申请号：US368572

    申请日：1989-06-20

    申请人： Frank W. Harris ,  Joseph E. Korleski

    发明人： Frank W. Harris ,  Joseph E. Korleski

    IPC分类号： C08G73/06

    CPC分类号： C08G73/0694

    摘要： A polyphenylquinoxaline which consists of 1 to 100 mole percent of structural elements of the formula (IV) ##STR1## and of 0-99 mole percent of the following repeat unit of formula (V) ##STR2## where R is selected from the group consisting of H, an alkyl group, a carbocyclic aromatic group, a heterocyclic aromatic group, or an alkoxy group, Ar.sub.1 is a carbocyclic aromatic or heterocyclic aromatic group, and B is selected from the representative group consisting of:Ar.sub.2 --Z--Ar.sub.3 (i)where Ar.sub.2 and Ar.sub.3 are the same or different carbocyclic aromatic or heterocyclic aromatic group and Z is selected from the representative group consisting of CO, SO or SO.sub.2 ;Z'--Ar.sub.4 --Z' (ii)where Z' is an activated carbocyclic aromatic or heterocyclic aromatic group and Ar.sub.4 is an aliphatic group, a carbocyclic aromatic or heterocyclic aromatic group. A process for manufacture a self polymerizable phenylquinoxaline subject to polymerization by aromatic nucleophilic substitution. The use of these polyphenylquinoxalines and there copolymers as thermally stable thermal plastics for use in aerospace, high temperature adhesive, microelectronic and membrane (gas and molecular separation membrane) application.

    摘要翻译： 由1至100摩尔％的式（IV）结构元素（IV）和0-99摩尔％的下式（V）Ar1OBO（V）重复单元组成的聚苯基喹喔啉，其中选择R 从由H，烷基，碳环芳基，杂环芳基或烷氧基组成的组中，Ar 1是碳环芳族或杂环芳族基团，B选自以下的代表性基团：Ar 2 -Z -Ar3（i）其中Ar2和Ar3是相同或不同的碳环芳族或杂环芳族基团，Z选自由CO，SO或SO 2组成的代表性基团; Z'-Ar 4 -Z'（ii）其中Z'为活性碳环芳族或杂环芳族基团，Ar 4为脂族基团，碳环芳族或杂环芳族基团。 通过芳族亲核取代制备聚合的自聚合苯基喹喔啉的方法。 使用这些聚苯基喹喔啉和共聚物作为热稳定的热塑性塑料用于航空航天，高温粘合剂，微电子和膜（气体和分子分离膜）应用。