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    SELECTIVE HYDROGENATION OF ALDEHYDES WITH RU/BIDENTATE LIGANDS COMPLEXES
    4.
    发明申请
    SELECTIVE HYDROGENATION OF ALDEHYDES WITH RU/BIDENTATE LIGANDS COMPLEXES 有权
    具有RU / BIDENTATE LIGANDS复合物的ALDEHYDES的选择性加氢

    公开(公告)号：US20160039853A1

    公开(公告)日：2016-02-11

    申请号：US14777502

    申请日：2014-03-06

    申请人： FIRMENICH SA

    发明人： Philippe DUPAU ,  Lucia BONOMO ,  Laurent KERMORVAN

    IPC分类号： C07F15/00 ,  C07C29/14

    CPC分类号： C07F15/0046 ,  C07C29/14 ,  C07C29/157 ,  C07C33/12

    摘要： The present invention relates to processes for the reduction by hydrogenation, using molecular H2, of a C5-C20 substrate containing one or two aldehydes functional groups into the corresponding alcohols or diol, characterized in that said process is carried out in the presence of—at least one catalyst or pre-catalyst in the form of a ruthenium complex having a coordination sphere of the N1P3O2, wherein the coordinating atom N and one coordinating atom P are provided by a first bidentate ligand, and the two other coordinating atoms P2 are provided by a second bidentate ligand and the coordinating atoms O2 are provided by two non-linear carboxylate ligands; and—optionally of an acidic additive.

    摘要翻译： 本发明涉及通过使用分子H 2将含有一个或两个醛官能团的C5-C20底物氢化还原成相应的醇或二醇的方法，其特征在于所述方法在-a 具有N1P3O2配位球的钌络合物形式的至少一种催化剂或预催化剂，其中配位原子N和一个配位原子P由第一二齿配体提供，另外两个配位原子P2由 第二个二齿配位体和配位原子O2由两个非线性羧酸盐配体提供; 和任选的酸性添加剂。

    Process for production of hexamethylenediamine from carbohydrate-containing materials and intermediates therefor
    6.
    发明授权
    Process for production of hexamethylenediamine from carbohydrate-containing materials and intermediates therefor 有权
    由含碳水化合物的材料及其中间体生产六亚甲基二胺的方法

    公开(公告)号：US09035109B2

    公开(公告)日：2015-05-19

    申请号：US14290869

    申请日：2014-05-29

    申请人： Rennovia, Inc.

    发明人： Eric L. Dias ,  James A. W. Shoemaker ,  Thomas R. Boussie ,  Vincent J. Murphy

    IPC分类号： C07C209/16 ,  C07C29/141 ,  C07D307/50 ,  C07C29/132 ,  C07D307/48 ,  C07C29/17 ,  C07C29/157

    CPC分类号： C07C29/157 ,  C07C29/132 ,  C07C29/141 ,  C07C29/175 ,  C07C209/16 ,  C07D307/46 ,  C07D307/48 ,  C07D307/50 ,  C07C31/20 ,  C07C31/22 ,  C07C211/12

    摘要： Processes are disclosed for the conversion of a carbohydrate source to hexamethylenediamine (HMDA) and to intermediates useful for the production of hexamethylenediamine and other industrial chemicals. HMDA is produced by direct reduction of a furfural substrate to 1,6-hexanediol in the presence of hydrogen and a heterogeneous reduction catalyst comprising Pt or by indirect reduction of a furfural substrate to 1,6-hexanediol wherein 1,2,6-hexanetriol is produced by reduction of the furfural substrate in the presence of hydrogen and a catalyst comprising Pt and 1,2,6-hexanediol is then converted by hydrogenation in the presence of a catalyst comprising Pt to 1,6 hexanediol, each process then proceeding to the production of HMDA by known routes, such as amination of the 1,6 hexanediol. Catalysts useful for the direct and indirect production of 1,6-hexanediol are also disclosed.

    摘要翻译： 公开了用于将碳水化合物源转化为六亚甲基二胺（HMDA）的方法和用于生产六亚甲基二胺和其它工业化学品的中间体。 HMDA通过在氢存在下将糠醛底物直接还原为1,6-己二醇和通过Pt的多相还原催化剂或通过将糠醛底物间接还原成1,6-己二醇来制备，其中1,2,6-己三醇 通过在氢气存在下还原糠醛底物而制备，然后在包含Pt至1,2,6-己二醇的催化剂存在下，通过氢化将包含Pt和1,2,6-己二醇的催化剂转化，然后进行到 通过已知途径生产HMDA，如1,6己糖胺的胺化。 还公开了用于直接和间接生产1,6-己二醇的催化剂。

    Method for producing alcohol by hydrogenating lactone and carboxylic acid ester in liquid phase
    8.
    发明授权
    Method for producing alcohol by hydrogenating lactone and carboxylic acid ester in liquid phase 有权
    通过在液相中氢化内酯和羧酸酯来生产醇的方法

    公开(公告)号：US08013193B2

    公开(公告)日：2011-09-06

    申请号：US12594577

    申请日：2008-04-02

    申请人： Hirofumi Maeda ,  Kenji Inoue ,  Takaji Matsumoto ,  Izuru Nagasaki ,  Ryoji Noyori ,  Susumu Saito

    发明人： Hirofumi Maeda ,  Kenji Inoue ,  Takaji Matsumoto ,  Izuru Nagasaki ,  Ryoji Noyori ,  Susumu Saito

    IPC分类号： C07C29/149

    CPC分类号： C07B53/00 ,  C07B2200/07 ,  C07C29/157 ,  C07C213/00 ,  C07C231/12 ,  C07C269/06 ,  C07C31/20 ,  C07C33/20 ,  C07C31/207 ,  C07C31/22 ,  C07C31/205 ,  C07C33/22 ,  C07C33/26 ,  C07C215/28 ,  C07C233/73 ,  C07C271/16

    摘要： Disclosed is a method for producing an alcohol from a lactone or a carboxylic acid ester, which enables to produce an alcohol from a lactone or a carboxylic acid ester under relatively mild conditions with high yield and high catalytic efficiency. This method also enables to produce an optically active alcohol from an optically active lactone or an optically active carboxylic acid ester. Specifically disclosed is a method for producing an alcohol by hydrogen reducing a lactone or a carboxylic acid ester in the presence of a catalyst containing ruthenium and a phosphine compound represented by the following general formula (1): wherein R1 represents a spacer; R2, R3, R4, R5, R6 and R7 independently represent a hydrogen atom, an alkyl group having 1-12 carbon atoms, an aryl group or a heterocyclic group; and R8, R9, R10, R11, R12 and R13 independently represent an alkyl group having 1-12 carbon atoms, an aryl group or a heterocyclic group.

    摘要翻译： 公开了一种从内酯或羧酸酯制备醇的方法，其能够在相对温和的条件下以高产率和高催化效率从内酯或羧酸酯制备醇。 该方法还能够从光学活性的内酯或光学活性的羧酸酯制备光学活性的醇。 具体公开的是通过在含有钌的催化剂和由以下通式（1）表示的膦化合物的存在下氢还原内酯或羧酸酯来制备醇的方法：其中R1表示间隔基; R2，R3，R4，R5，R6和R7独立地表示氢原子，具有1-12个碳原子的烷基，芳基或杂环基; 并且R 8，R 9，R 10，R 11，R 12和R 13独立地表示具有1-12个碳原子的烷基，芳基或杂环基。

    Novel process and catalyst for carbon dioxide conversion to energy generating products
    9.
    发明申请
    Novel process and catalyst for carbon dioxide conversion to energy generating products 审中-公开
    二氧化碳转化为能源产品的新工艺和催化剂

    公开(公告)号：US20080287555A1

    公开(公告)日：2008-11-20

    申请号：US11751026

    申请日：2007-05-20

    申请人： Syed Tajammul Hussain ,  Mohammad Mazhar ,  Muhammad Hasib-ur-Rehman

    发明人： Syed Tajammul Hussain ,  Mohammad Mazhar ,  Muhammad Hasib-ur-Rehman

    IPC分类号： C07C27/06

    CPC分类号： C07C29/157 ,  C07C1/12 ,  C07C2523/84 ,  C07C11/22 ,  C07C31/04

    摘要： A catalytic process and a nano material for the conversion of moist carbon dioxide into methanol, propyne and oxygen have been developed. In the process invented, hydrogen is produced from water in a catalytic reaction, when the moist carbon dioxide enters into the catalytic reactor, resulting in C—O and H—OH bond breakage at a relatively low temperature and at atmospheric pressure in a single step using a combination of catalytic materials comprising at least three metals dispersed on a catalyst support, preferably anatase form of titanium dioxide, to induce a multifunctional surface chemical reaction for the production of oxygenated products such as hydrocarbons of different chain lengths.

    摘要翻译： 已经开发了用于将湿二氧化碳转化成甲醇，丙炔和氧气的催化方​​法和纳米材料。 在所发明的方法中，当催化反应中产生氢气时，当潮湿的二氧化碳进入催化反应器时，在相对较低的温度和大气压下在单个步骤中导致CO和H-OH键断裂，使用 包含分散在催化剂载体上的至少三种金属的催化材料的组合，优选锐钛矿形式的二氧化钛，以诱导用于生产不同链长的烃的氧化产物的多功能表面化学反应。

    Hydrogenation of carbon monoxide using sulfide catalysts
    10.
    发明授权
    Hydrogenation of carbon monoxide using sulfide catalysts 失效
    使用硫化物催化剂氢化一氧化碳

    公开(公告)号：US06534553B1

    公开(公告)日：2003-03-18

    申请号：US09986905

    申请日：2001-11-13

    申请人： Muneyoshi Yamada ,  Naoto Koizumi

    发明人： Muneyoshi Yamada ,  Naoto Koizumi

    IPC分类号： C07C2700

    CPC分类号： C07C29/157 ,  Y02P20/52 ,  C07C31/04

    摘要： A method of producing synthetic fuels by hydrogenating carbon monoxide comprising contacting a feed gas containing carbon monoxide and hydrogen with a catalyst comprising: (1) a supported metal sulfide comprising Pd and at least one promoter selected from the group consisting of alkali metal, alkaline earth metal, and rare earth elements, and optionally (2) solid acid.

    摘要翻译： 一种通过氢化一氧化碳生产合成燃料的方法，包括使含有一氧化碳和氢气的进料气体与催化剂接触，所述催化剂包括：（1）负载金属硫化物，其包含Pd和至少一种选自碱金属，碱土金属 金属和稀土元素，和任选的（2）固体酸。