AMIDE COMPOUND AND USE THEREOF FOR CONTROLLING PLANT DISEASES
    94.
    发明申请
    AMIDE COMPOUND AND USE THEREOF FOR CONTROLLING PLANT DISEASES 失效
    酰胺化合物及其用于控制​​植物病害的用途

    公开(公告)号:US20100105647A1

    公开(公告)日:2010-04-29

    申请号:US12451115

    申请日:2008-04-25

    摘要: Disclosed is an amide compound represented by the following formula (1). (1) (In the formula, X1 represents a fluorine atom or a methoxy group; X2 represents a hydrogen atom, a halogen atom, a C1-C4 alkyl group or the like; Z represents an oxygen atom or a sulfur atom; and A represents an A1-CR6R7R8 group, an A2-Cy1 group or an A3-Cy2 group, wherein A1 represents a CH2 group or the like, A2 represents a single bond, a CH2 group or the like, Cy1 represents a C3-C6 cycloalkyl group substituted with a C1-C6 alkoxy group or the like, Cy2 represents a C3-C6 cycloalkyl group which may be substituted with at least one halogen atom or the like, R6 and R7 independently represent a C1-C4 alkyl group, and R8 represents a halogen atom, a hydroxyl group or the like.) The amide compound has excellent plant disease controlling activity.

    摘要翻译: 公开了由下式(1)表示的酰胺化合物。 (1)(式中,X1表示氟原子或甲氧基; X2表示氢原子,卤素原子,C1-C4烷基等; Z表示氧原子或硫原子,A表示 表示A1-CR6R7R8基团,A2-Cy1基团或A3-Cy2基团,其中A1表示CH2基团等,A2表示单键,CH2基团等,Cy1表示C3-C6环烷基 被C 1 -C 6烷氧基等取代,Cy 2表示可以被至少一个卤素原子等取代的C 3〜C 6环烷基,R 6和R 7分别表示C 1〜C 4烷基,R 8表示 卤素原子,羟基等)。酰胺化合物具有优异的植物病害控制活性。

    Reactor having titanium silicate recycling
    96.
    发明申请
    Reactor having titanium silicate recycling 有权
    反应器具有硅酸钛回收

    公开(公告)号:US20100063323A1

    公开(公告)日:2010-03-11

    申请号:US12207169

    申请日:2008-09-09

    摘要: The invention relates to a plant for carrying out chemical reactions, having a reactor (1), the reaction space of which contains hydrogen peroxide (H2O2) and titanium silicalite (TS-1). The object of the invention is to improve such a plant such that continuous separation and recycling of the active catalyst to the reaction space is possible with a long filter service life. This is achieved in that the reaction space contains a solid silicon source, in that the plant comprises a water takeoff line (3) which is set up for drawing off water in addition to components which are dissolved and/or dispersed therein from the reaction space, in that the water takeoff line (3) leads to a filter (4) which separates off the components which are dissolved and/or dispersed in the water, and in that the plant has a return line (5) which is set up for recirculating to the reaction space components which are separated off by means of the filter (4).

    摘要翻译: 本发明涉及一种用于进行化学反应的设备,其具有反应器(1),其反应空间含有过氧化氢(H 2 O 2)和钛硅沸石(TS-1)。 本发明的目的是改进这种设备,使得活性催化剂在反应空间的连续分离和循环是可能的,并具有长的过滤器使用寿命。 这是通过反应空间包含固体硅源实现的,因为该设备包括除了从反应空间溶解和/或分散在其中的组分除去水以外的水引出线(3) 因为水引出线(3)通过一个过滤器(4),该过滤器(4)将溶解和/或分散在水中的组分分离出来,并且该设备具有一个回流管线(5) 再循环到通过过滤器(4)分离的反应空间部件。

    Coammoxidation of Ketones
    97.
    发明申请
    Coammoxidation of Ketones 有权
    酮的辅酶氧化

    公开(公告)号:US20080249300A1

    公开(公告)日:2008-10-09

    申请号:US10572594

    申请日:2004-08-02

    IPC分类号: C07C249/04 C07D223/10

    摘要: The invention relates to a method for the coammoxidation, i.e. for the simultaneous ammoxidation of ketones, especially of cyclic ketones such as cyclododecanone and cyclohexanone. The ammoxidatian method of the invention relates to the production of oximes from ketones or aldehydes using hydrogen peroxide and amnmonia and further using a catalyst that substantially consists of silicon, titanium and oxygen, such as for example titanium silicalite.

    摘要翻译: 本发明涉及一种辅助氧化反应的方法,即用于同时氨基酮化,特别是环状酮如环十二酮和环己酮的氨基氧化。 本发明的氨氧化方法涉及使用过氧化氢和亚麻酸从酮或醛生产肟,并进一步使用基本上由硅,钛和氧组成的催化剂,例如钛硅沸石。

    Method for synthesis of oximes
    100.
    发明授权
    Method for synthesis of oximes 有权
    肟的合成方法

    公开(公告)号:US06927308B2

    公开(公告)日:2005-08-09

    申请号:US10733278

    申请日:2003-12-12

    摘要: An oxime is synthesized by ammoximation of a carbonyl compound. In stage (i) of the process, a carbonyl compound containing 6 to 20 C atoms is reacted with ammonia and hydrogen peroxide in the presence of a) an organic solvent that is a1) at least partly water-soluble, a2) stable under ammoximation conditions, a3) has a boiling point of higher than 100° C. and/or is capable of forming a two-phase azeotrope with water, and b) a titanium-containing heterogeneous catalyst. After the reaction, the catalyst is separated from the reaction mixture. The oxime is crystallized and separated from the reaction mixture. Water is removed from the remaining mother liquor, provided the mother liquor is a two-phase system in which one of the phases is an aqueous phase. Water or a water-containing two-phase azeotrope is distilled off from the mother liquor, while the distillation bottoms and, optionally, the predominantly organic phase of the azeotrope are recycled to stage (i).

    摘要翻译: 通过羰基化合物的肟化合成肟。 在该方法的阶段(i)中,在a)至少部分水溶性的有机溶剂存在下,使含有6-20个碳原子的羰基化合物与氨和过氧化氢反应,a2)在氨肟化下稳定 条件a3)的沸点高于100℃,和/或能够与水形成两相共沸物,和b)含钛的非均相催化剂。 反应后,将催化剂与反应混合物分离。 将肟结晶并与反应混合物分离。 如果母液是其中一相是水相的两相系统,则从剩余的母液中除去水。 从母液中蒸馏掉水或含水的两相共沸物,同时将蒸馏塔底物和任选的共沸物的主要有机相再循环至阶段(i)。