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    Preparation of additive mixtures for mineral oils and mineral oil distillates
    94.
    发明申请
    Preparation of additive mixtures for mineral oils and mineral oil distillates 有权
    矿物油和矿物油馏分添加剂混合物的制备

    公开(公告)号：US20040065004A1

    公开(公告)日：2004-04-08

    申请号：US10676962

    申请日：2003-10-01

    Applicant: Clariant GmbH

    Inventor： Matthias Krull ,  Gerhard Bettermann ,  Curd-Werner Adams ,  Werner Reimann

    IPC: C10L010/00 ,  C08K003/00

    CPC classification number: C08K3/00 ,  C10L1/146 ,  C10L1/1641 ,  C10L1/1955 ,  C10L1/1963 ,  C10L1/1966 ,  C10L1/1973 ,  C10L1/1981 ,  C10L1/1985

    Abstract: The present invention provides a continuous process for preparing additive mixtures for mineral oils and mineral oil distillates, comprising A) a cold flow improver for middle distillates, and at least one further component selected from B) and C): B) a further cold flow improver, C) an organic solvent, which comprises mixing cold flow improver and optionally solvent by means of a static mixer, the temperature of the additive mixture at the outlet of the static mixer being from 0null C. to 100null C.

    Abstract translation: 本发明提供了用于制备用于矿物油和矿物油馏出物的添加剂混合物的连续方法，其包括A）用于中间馏分的冷流改进剂和至少一种选自B）和C）的另外的组分：B）另外的冷流 改进剂，C）有机溶剂，其包括通过静态混合器将冷流改进剂和任选溶剂混合，静态混合器出口处的添加剂混合物的温度为0℃至100℃

    Copolymer blends and their use as additives for improving the cold flow properties of middle distillates
    97.
    发明授权
    Copolymer blends and their use as additives for improving the cold flow properties of middle distillates 失效
    共聚物共混物及其用作改善中间馏分冷流特性的添加剂

    公开(公告)号：US06593426B2

    公开(公告)日：2003-07-15

    申请号：US09808481

    申请日：2001-03-14

    Applicant: Matthias Krull ,  Thomas Volkmer ,  Werner Reimann

    Inventor： Matthias Krull ,  Thomas Volkmer ,  Werner Reimann

    IPC: C08L118

    CPC classification number: C10L1/195 ,  C10L1/146 ,  C10L1/1963 ,  C10L1/1966 ,  C10L1/1973 ,  C10L1/2364

    Abstract: The invention relates to additives for improving the cold flow properties of middle distillates, containing from 10 to 95% by weight of copolymers A), from 5 to 90% by weight of copolymers B) and, if required, from 0 to 70% by weight of copolymers C), which correspond to the following formulae: A) copolymers of lower olefins and vinyl esters, B) copolymers comprising B1) from 40 to 60 mol % of bivalent structural units of the formula  where X is O or N—R4 and in which a and b are 0 or 1 and a +b=1, and B2) from 60 to 40 mol % of bivalent structural units of the formula —H2C—CR11R5—  B2 and, if required, B3) from 0 to 20 mol % of bivalent structural units which are derived from polyolefins, the polyolefins being derivable from monoolefins having 3 to 5 carbon atoms, and in which a) R4 is an alkyl or alkenyl radical having 10 to 40 carbon atoms or an alkoxyalkyl radical having 1 to 100 alkoxy units and 1 to 30 carbon atoms in the alkyl radical, and b) R5 is a radical of the formula OCOR12 or COOR12, in which R12 is C1-to C3-alkyl, and c) the number of carbon atoms of the polyolefin molecules on which the structural units B3) are based is from 35 to 350, and d) R11 is hydrogen or methyl, and, if required, C) a further copolymer differing from A) and B) and comprising ethylene and one or more vinyl esters or acrylates, which by itself is effective as a cold flow improver for middle distillates.

    Abstract translation: 本发明涉及用于改善中间馏分的冷流动性的添加剂，其含有10至95重量％的共聚物A），5至90重量％的共聚物B），如果需要，0至70重量％ 共聚物C）的重量，其对应于下式：A）低级烯烃和乙烯基酯的共聚物，B）包含B1至40摩尔％的下式的二价结构单元的共聚物，其中X为O或N-R 4， 其中a和b分别为0或1，a + b = 1，B 2）为60至40摩尔％的二价结构单元，如果需要，B3）0至20摩尔％的二价结构单元衍生 聚烯烃可以衍生自具有3至5个碳原子的单烯烃，并且其中a）R4是具有10至40个碳原子的烷基或烯基或具有1至100个烷氧基单元和1至30个碳原子的烷氧基烷基 在烷基中，和b）R 5是式OCOR 12或COOR 12的基团，其中R 1 2是C1-C3烷基，c）结构单元B3）所基于的聚烯烃分子的碳原子数为35〜350，d）R 11为氢或甲基，如果需要， C）与A）和B）不同的另外的共聚物，并且包含乙烯和一种或多种乙烯基酯或丙烯酸酯，其本身作为中间馏分的冷流改进剂是有效的。

    Ethylene polymers with &agr;-olefins
    99.
    发明授权
    Ethylene polymers with &agr;-olefins 失效
    乙烯聚合物与α-烯烃

    公开(公告)号：US06278032B1

    公开(公告)日：2001-08-21

    申请号：US09328881

    申请日：1999-06-09

    Applicant: Paolo Falchi

    Inventor： Paolo Falchi

    IPC: C08F21016

    CPC classification number: C10L1/165 ,  C10L1/143 ,  C10L1/1641 ,  C10L1/1658 ,  C10L1/1666 ,  C10L1/1963 ,  C10L1/1966 ,  C10L1/1973 ,  C10L1/224

    Abstract: Ethylene copolymers with octene and/or ethylene terpolymers with alpha-olefins from 3 to 12 carbon atoms, optionally in the presence of other comonomers containing more than one unsaturation, usable as additives to increase the gas oil properties at low temperatures, obtainable by polymerization of the monomers in the presence of catalysts comprising: a bis-cyclopentadienyl derivative having the general formula: (Cp1Cp2)—M—(L2L3) containing groups with oxygen bound to the transition metal, wherein M is a metal from the IIIb group to the Vb group or of the lanthanide series of the Element Periodic Table; Cp1 and Cp2, equal to or different from each other, represent cyclopentadienyls bound to M with delocalized &pgr; bonds.

    Abstract translation: 具有辛烯和/或乙烯三元共聚物的乙烯共聚物与3至12个碳原子的α-烯烃，任选在含有多于一个不饱和基团的其它共聚单体存在下，可用作增加低温下的瓦斯油性能的添加剂，可通过 催化剂存在下的单体，其包含：具有以下通式的双环戊二烯基衍生物：含有与过渡金属结合的氧的基团，其中M是从IIIb族基团至Vb基团的金属或元素周期的镧系元素 表; Cp1和Cp2彼此相同或不同，表示与离子化π键结合的M的环戊二烯基。

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