Metal-Loaded Zeolite Catalysts for the Halogen-Free Conversion of Dimethyl Ether to Methyl Acetate
    96.
    发明申请
    Metal-Loaded Zeolite Catalysts for the Halogen-Free Conversion of Dimethyl Ether to Methyl Acetate 审中-公开
    用于无卤素转化二甲醚至乙酸甲酯的金属负载型沸石催化剂

    公开(公告)号:US20170072388A1

    公开(公告)日:2017-03-16

    申请号:US15168972

    申请日:2016-05-31

    摘要: A catalyst for the carbonylation of dimethyl ether to methyl acetate. The catalyst comprises a zeolite, such as a mordenite zeolite, at least one Group IB metal, such as copper, and/or at least one Group VIII metal, such as iron, and at least one Group IIB metal, such as zinc. Such a catalyst with combined metals provides enhanced catalytic activity, improved stability, and improved selectivity to methyl acetate, and does not require a halogen promoter, as compared to a metal-free or copper only zeolite.

    摘要翻译: 用于将二甲醚羰基化成乙酸甲酯的催化剂。 催化剂包括沸石,例如丝光沸石,至少一种IB族金属如铜,和/或至少一种第Ⅷ族金属,如铁,和至少一种IIB族金属,如锌。 与无金属或仅含铜的沸石相比,这种具有组合金属的催化剂提供增强的催化活性,改进的稳定性和对乙酸甲酯的改善的选择性,并且不需要卤素促进剂。