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    PROCESSES FOR PREPARING AMINOSILANE FUNCTIONALIZED POLYMERS
    92.
    发明申请
    PROCESSES FOR PREPARING AMINOSILANE FUNCTIONALIZED POLYMERS 审中-公开
    制备氨基硅烷官能化聚合物的方法

    公开(公告)号：US20160152756A1

    公开(公告)日：2016-06-02

    申请号：US15014620

    申请日：2016-02-03

    申请人： Bridgestone Corporation

    发明人： David F. Lawson ,  Terrence E. Hogan ,  Christine Rademacher ,  David M. Roggeman ,  Fuminori Ota

    IPC分类号： C08F236/10

    CPC分类号： C08C19/25 ,  B60C1/00 ,  C08C19/22 ,  C08C19/44 ,  C08F4/48 ,  C08F8/42 ,  C08F36/04 ,  C08F36/06 ,  C08F236/10 ,  C08L15/00 ,  C08L19/006 ,  Y02T10/862

    摘要： Disclosed herein are metallated aminosilane compounds for use as functional initiators in anionic polymerizations and processes for producing an aminosilane-functionalized polymer using the metallated aminosilane compounds to initiate anionic polymerization of at least one type of anionically polymerizable monomer. Preferred use of the metallated aminosilane compounds results in rubber compositions for use in tires comprising an aminosilane functionalized polymer. A telechelic polymer may result from use of the metallated aminosilane compound and a functional terminator.

    摘要翻译： 本文公开了用作阴离子聚合中的官能引发剂的金属化氨基硅烷化合物和使用金属化氨基硅烷化合物制备氨基硅烷官能化聚合物以引发至少一种类型的阴离子聚合性单体的阴离子聚合的方法。 优选使用金属化的氨基硅烷化合物产生用于包含氨基硅烷官能化聚合物的轮胎的橡胶组合物。 使用金属化氨基硅烷化合物和功能性终止剂可产生遥爪聚合物。

    LOW VINYL STYRENE-BUTADIENE POLYMERS AND METHODS OF MAKING THE SAME
    96.
    发明申请
    LOW VINYL STYRENE-BUTADIENE POLYMERS AND METHODS OF MAKING THE SAME 有权

    公开(公告)号：US20160096912A1

    公开(公告)日：2016-04-07

    申请号：US14966856

    申请日：2015-12-11

    申请人： TRINSEO EUROPE GMBH

    发明人： Silvia VALENTI ,  Evemarie HAMANN

    IPC分类号： C08F236/10

    CPC分类号： C08F236/10 ,  C08F212/08 ,  C08L9/06 ,  C08F4/48

    摘要： The invention provides a process for the continuous polymerization of a polymer comprising monomeric units derived from styrene and 1,3-butadiene, said process comprising: polymerizing the monomers in the presence of an initiator, and at least one polar agent selected from Formula 1; wherein R1 and R2 are each independently an alkyl, and preferably a C1-C4 alkyl; R3, R4, R5, R6, R7 and R8 are each independently selected from hydrogen or an alkyl, and preferably hydrogen or a C1-C4 alkyl; and wherein a 1,2-diene is added to the polymerization, and the 1,2-diene to active initiator (active for polymerization) molar ratio is from 0.1 to 1.0, preferably from 0.1 to 0.9, and more preferably from 0.1 to 0.85; and wherein the polar agent to the active initiator molar ratio is from 0.05 to 0.6, preferably from 0.1 to 0.5, more preferably from 0.15 to 0.3. The invention also provides a composition comprising a polymer comprising monomeric units derived from styrene and 1,3-butadiene, and wherein the polymer has at least the following characteristics: A) vinyl content from 12 to 40 weight percent, based on the weight of polymerized butadiene in the polymer, B) block styrene content less than 8 weight percent, based on the weight of styrene in the polymer, and C) a styrene content from 10 to 50 weight percent, based on the weight of the polymer.

    Low vinyl styrene-butadiene polymers and methods of making the same
    99.
    发明授权
    Low vinyl styrene-butadiene polymers and methods of making the same 有权
    低乙烯基苯乙烯 - 丁二烯聚合物及其制备方法

    公开(公告)号：US09243099B2

    公开(公告)日：2016-01-26

    申请号：US13702685

    申请日：2011-06-15

    申请人： Silvia Valenti ,  Evemarie Hamann

    发明人： Silvia Valenti ,  Evemarie Hamann

    IPC分类号： C08L9/06 ,  C08F236/10 ,  C08F212/08

    CPC分类号： C08F236/10 ,  C08F212/08 ,  C08L9/06 ,  C08F4/48

    摘要： The invention provides a process for the continuous polymerization of a polymer comprising monomeric units derived from styrene and 1,3-butadiene, said process comprising: polymerizing the monomers in the presence of an initiator, and at least one polar agent selected from Formula 1; wherein R1 and R2 are each independently an alkyl, and preferably a C1-C4 alkyl; R3, R4, R5, R6, R7 and R8 are each independently selected from hydrogen or an alkyl, and preferably hydrogen or a C1-C4 alkyl; and wherein a 1,2-diene is added to the polymerization, and the 1,2-diene to active initiator (active for polymerization) molar ratio is from 0.1 to 1.0, preferably from 0.1 to 0.9, and more preferably from 0.1 to 0.85; and wherein the polar agent to the active initiator molar ratio is from 0.05 to 0.6, preferably from 0.1 to 0.5, more preferably from 0.15 to 0.3. The invention also provides a composition comprising a polymer comprising monomeric units derived from styrene and 1,3-butadiene, and wherein the polymer has at least the following characteristics: A) vinyl content from 12 to 40 weight percent, based on the weight of polymerized butadiene in the polymer, B) block styrene content less than 8 weight percent, based on the weight of styrene in the polymer, and C) a styrene content from 10 to 50 weight percent, based on the weight of the polymer.

    摘要翻译： 本发明提供了包含衍生自苯乙烯和1,3-丁二烯的单体单元的聚合物的连续聚合的方法，所述方法包括：在引发剂存在下聚合单体和至少一种选自式1的极性试剂; 其中R 1和R 2各自独立地为烷基，优选为C 1 -C 4烷基; R 3，R 4，R 5，R 6，R 7和R 8各自独立地选自氢或烷基，优选氢或C 1 -C 4烷基; 并且其中在聚合中加入1,2-二烯，1,2-二烯与活性引发剂（聚合活性）的摩尔比为0.1〜1.0，优选为0.1〜0.9，更优选为0.1〜0.85 ; 并且其中所述极性试剂与所述活性引发剂的摩尔比为0.05至0.6，优选0.1至0.5，更优选0.15至0.3。 本发明还提供了包含聚合物的组合物，其包含衍生自苯乙烯和1,3-丁二烯的单体单元，并且其中所述聚合物具有至少以下特征：A）乙烯基含量为12至40重量％，基于聚合 聚合物中的丁二烯，B）基于聚合物中苯乙烯的重量，苯乙烯含量小于8重量％，C）苯乙烯含量为10至50重量％，基于聚合物的重量。