公开(公告)号：US20120222552A1

公开(公告)日：2012-09-06

申请号：US13406019

申请日：2012-02-27

申请人： Peter I. Ravikovitch ,  Robert A. Johnson ,  Harry W. Deckman ,  Thomas N. Anderson

发明人： Peter I. Ravikovitch ,  Robert A. Johnson ,  Harry W. Deckman ,  Thomas N. Anderson

IPC分类号： B01D53/047

CPC分类号： B01D53/047 ,  B01D53/0438 ,  B01D53/0462 ,  B01D53/0473 ,  B01D53/526 ,  B01D2252/20431 ,  B01D2252/20436 ,  B01D2252/20489 ,  B01D2253/102 ,  B01D2253/106 ,  B01D2253/108 ,  B01D2253/1085 ,  B01D2253/116 ,  B01D2253/204 ,  B01D2253/25 ,  B01D2253/304 ,  B01D2253/306 ,  B01D2253/311 ,  B01D2253/34 ,  B01D2256/24 ,  B01D2256/245 ,  B01D2257/102 ,  B01D2257/304 ,  B01D2257/504 ,  B01D2257/7022 ,  B01D2259/40022 ,  B01D2259/40052 ,  B01D2259/402 ,  B01D2259/41 ,  B01J20/18 ,  B01J20/186 ,  B01J20/20 ,  B01J20/226 ,  B01J20/28016 ,  B01J20/28019 ,  B01J20/28042 ,  B01J20/28057 ,  B01J20/28078 ,  B01J20/28095 ,  B01J20/3408 ,  B01J20/3416 ,  B01J20/3483 ,  B01J20/3491 ,  B01J2220/42 ,  B01J2220/46 ,  B01J2220/56 ,  C01B17/0408 ,  C01B17/167 ,  C10L3/103 ,  C10L3/104 ,  C10L3/105 ,  Y02C10/08 ,  Y02P20/152 ,  Y10T428/2991

摘要： The present invention relates to a pressure-temperature swing adsorption process wherein gaseous components that have been adsorbed can be recovered from the adsorbent bed at elevated pressures. In particular, the present invention relates to a pressure-temperature swing adsorption process for the separation of C2+ hydrocarbons (hydrocarbons with at least 2 carbon atoms) from natural gas streams to obtain a high purity methane product stream. In more preferred embodiments of the present processes, the processes may be used to obtain multiple, high purity hydrocarbon product streams from natural gas stream feeds resulting in a chromatographic-like fractionation with recovery of high purity individual gaseous component streams.

摘要翻译： 本发明涉及压力 - 温度变化吸附方法，其中可以在升高的压力下从吸附剂床中回收吸附的气体成分。 特别地，本发明涉及用于从天然气流中分离C2 +烃（具有至少2个碳原子的烃）获得高纯度甲烷产物流的压力 - 温度变化吸附方法。 在本方法的更优选实施方案中，该方法可用于从天然气流进料中获得多种高纯度烃产物流，从而进行色谱分离，并回收高纯度单独的气态组分流。

公开(公告)号：US07947120B2

公开(公告)日：2011-05-24

申请号：US12152875

申请日：2008-05-16

申请人： Harry W. Deckman ,  Bruce T. Kelley ,  Frank Hershkowitz ,  Ronald R. Chance ,  Paul S. Northrop ,  Edward W. Corcoran, Jr.

发明人： Harry W. Deckman ,  Bruce T. Kelley ,  Frank Hershkowitz ,  Ronald R. Chance ,  Paul S. Northrop ,  Edward W. Corcoran, Jr.

IPC分类号： B01D53/02

CPC分类号： B01D53/0423 ,  B01D53/02 ,  B01D53/0462 ,  B01D2253/108 ,  B01D2253/311 ,  B01D2253/342 ,  B01D2257/504 ,  B01D2259/4143 ,  Y02C10/04 ,  Y02C10/08

摘要： The adsorption of CO2 from flue gas streams using temperature swing adsorption. Adsorbent contactors are used in the temperature swing adsorption unit that contain a plurality of substantially parallel channels comprised of or coated with an adsorbent material that is selective for adsorbing CO2 from flue gas.

摘要翻译： 使用变温吸附从烟气流吸附CO2。 吸附剂接触器用于变温吸附单元，其包含多个基本上平行的通道，该通道由吸附剂材料组成或涂覆，所述吸附材料可选择性地从烟道气中吸附二氧化碳。

公开(公告)号：US20110059001A1

公开(公告)日：2011-03-10

申请号：US12990932

申请日：2009-04-09

申请人： Bruce T. Kelley ,  Harry W. Deckman ,  Stephen Mark Davis ,  Frank Hershkowitz

发明人： Bruce T. Kelley ,  Harry W. Deckman ,  Stephen Mark Davis ,  Frank Hershkowitz

IPC分类号： C01B35/10 ,  G06Q90/00 ,  C01F5/02 ,  B01J8/00

CPC分类号： C01B31/02 ,  C01B3/26 ,  C01B3/34 ,  C01B32/05 ,  C01B33/02 ,  C01B35/02 ,  C01B2203/0233 ,  C01B2203/0266 ,  C01B2203/0277 ,  C01B2203/1241 ,  G06Q99/00

摘要： The present application is directed to a method and system for monetizing energy. More specifically, the invention is directed to the economically efficient utilization of remote or stranded natural gas resources. The invention includes importing a high energy density material into an energy market and distributing the high energy density material (HEDM) therein. The HEDM is produced from reduction of a material oxide such as boria into the HEDM, which may be boron. The reduction utilizes remote hydrocarbon resources such as stranded natural gas resources.

摘要翻译： 本申请涉及一种用于从能量获利的方法和系统。 更具体地，本发明涉及经济上有效利用远程或搁浅天然气资源。 本发明包括将高能量密度材料输入能源市场并在其中分配高能量密度材料（HEDM）。 HEDM通过将诸如氧化硼的材料氧化物还原成可以是硼的HEDM来制备。 减少利用遥远的碳氢化合物资源，如搁浅的天然气资源。

公开(公告)号：US20110008226A1

公开(公告)日：2011-01-13

申请号：US12886336

申请日：2010-09-20

申请人： Frank Hershkowitz ,  John Scott Buchanan ,  Harry W. Deckman ,  Jeffrey W. Frederick

发明人： Frank Hershkowitz ,  John Scott Buchanan ,  Harry W. Deckman ,  Jeffrey W. Frederick

IPC分类号： B01J8/00

CPC分类号： B01J8/02 ,  B01F3/02 ,  B01F5/0603 ,  B01F2215/0431 ,  B01J4/002 ,  B01J8/0278 ,  B01J8/04 ,  B01J8/0438 ,  B01J8/0442 ,  B01J8/0492 ,  B01J8/0496 ,  B01J19/2485 ,  B01J19/26 ,  B01J2208/00132 ,  B01J2208/00309 ,  B01J2208/00504 ,  B01J2208/0053 ,  B01J2208/00831 ,  B01J2208/0084 ,  B01J2208/00849 ,  B01J2219/0004 ,  B01J2219/00081 ,  B01J2219/00117 ,  B01J2219/00157 ,  B01J2219/00159 ,  B01J2219/182 ,  B01J2219/1943 ,  C01B3/46 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/0244 ,  C01B2203/0261 ,  C01B2203/0277 ,  C01B2203/0811 ,  C01B2203/0844 ,  C01B2203/1235 ,  C01B2203/1241 ,  C01B2203/142 ,  C07C2/78 ,  C07C5/327 ,  C08G18/10 ,  C08G18/4825 ,  C08G18/73 ,  C08G18/792 ,  C08G2101/005 ,  Y02P20/132 ,  Y10S585/943 ,  C07C11/24 ,  C08G18/3203 ,  C08G18/48

摘要： The present invention provides a process for the manufacture of acetylene and other higher hydrocarbons from methane feed using a reverse-flow reactor system, wherein the reactor system includes (i) a first reactor and (ii) a second reactor, the first and second reactors oriented in a series relationship with respect to each other, the process comprising supplying each of first and second reactant through separate channels in the first reactor bed of a reverse-flow reactor such that both of the first and second reactants serve to quench the first reactor bed, without the first and second reactants substantially reacting with each other until reaching the core of the reactor system.

公开(公告)号：US20090214407A1

公开(公告)日：2009-08-27

申请号：US12321751

申请日：2009-01-23

申请人： Sebastian C. Reyes ,  Jose G. Santiesteban ,  Zheng Ni ,  Charanjit S. Paur ,  Pavel Kortunov ,  John Zengel ,  Harry W. Deckman

发明人： Sebastian C. Reyes ,  Jose G. Santiesteban ,  Zheng Ni ,  Charanjit S. Paur ,  Pavel Kortunov ,  John Zengel ,  Harry W. Deckman

IPC分类号： B01D53/62 ,  B01D53/047 ,  B01D53/22 ,  C01B31/20

CPC分类号： B01D53/02 ,  B01D53/228 ,  B01D67/0051 ,  B01D69/141 ,  B01D71/028 ,  B01D2253/204 ,  B01D2256/10 ,  B01D2257/504 ,  B01D2325/12 ,  B01D2325/20 ,  B01J20/226 ,  Y02C10/04 ,  Y02C10/08 ,  Y02C10/10

摘要： The present invention relates to the selective separation of carbon dioxide (“CO2”) from nitrogen (“N2”) in streams containing both carbon dioxide and nitrogen utilizing a zeolitic imidazolate framework (“ZIF”) material. Preferably, the stream to be separated is fed to the present process in a substantially gaseous phase. In preferred embodiments, the current invention is utilized in a process to separate carbon dioxide from combustion gas (e.g., flue gas) streams preferably for sequestration of at least a portion of the carbon dioxide produced in combustion processes.

摘要翻译： 本发明涉及使用沸石咪唑化物骨架（“ZIF”）材料在含有二氧化碳和氮气的物流中从氮气（“N2”）中选择性分离二氧化碳（“CO 2”）。 优选地，待分离的物流以基本上气相的方式进料到本方法中。 在优选的实施方案中，本发明用于将二氧化碳从燃烧气体（例如烟道气）流中分离出来，优选用于封存燃烧过程中产生的二氧化碳的至少一部分。

公开(公告)号：US20090211440A1

公开(公告)日：2009-08-27

申请号：US12322363

申请日：2009-01-30

申请人： Sebastian C. Reyes ,  Jose G. Santiesteban ,  Zheng Ni ,  Charanjit S. Paur ,  Pavel Kortunov ,  John Zengel ,  Harry W. Deckman

发明人： Sebastian C. Reyes ,  Jose G. Santiesteban ,  Zheng Ni ,  Charanjit S. Paur ,  Pavel Kortunov ,  John Zengel ,  Harry W. Deckman

IPC分类号： B01D53/00 ,  B01D53/04 ,  B01D53/22

CPC分类号： B01D53/228 ,  B01D53/02 ,  B01D53/0462 ,  B01D53/047 ,  B01D67/0051 ,  B01D69/141 ,  B01D71/028 ,  B01D2253/108 ,  B01D2253/204 ,  B01D2256/16 ,  B01D2256/24 ,  B01D2257/702 ,  B01D2325/12 ,  B01J20/226 ,  C01B3/503 ,  C01B3/56 ,  C01B2203/0233 ,  C01B2203/0283 ,  C01B2203/0405 ,  C01B2203/043 ,  C01B2203/0445 ,  C01B2203/048 ,  Y10S95/902

摘要： The present invention relates to the selective separation of hydrogen (“H2”) hydrocarbons in streams containing both hydrogen and hydrocarbons (e.g. methane, ethylene, ethane, propylene, propane, etc.) utilizing a zeolitic imidazolate framework (“ZIF”) material. Preferably, the stream to be separated is fed to the present process in a substantially gaseous phase. In preferred embodiments, the current invention is utilized in either a pressure swing adsorption process, a temperature swing adsorption process, or a membrane separations process to separate hydrogen from hydrocarbons present in hydrogen production streams or petrochemical/petroleum refining product streams and intermediate streams.

摘要翻译： 本发明涉及使用沸石咪唑化物骨架（“ZIF”）材料选择性分离含氢和烃（例如甲烷，乙烯，乙烷，丙烯，丙烷等）的物流中的氢（“H 2”）烃。 优选地，待分离的物流以基本上气相的方式进料到本方法中。 在优选实施方案中，本发明用于变压吸附法，变温吸附法或膜分离方法，以将氢气与存在于氢生产流或石化/石油精炼产物流和中间物流中的烃分离。

公开(公告)号：US06632266B2

公开(公告)日：2003-10-14

申请号：US10234920

申请日：2002-09-04

申请人： Eugene R. Thomas ,  Harry W. Deckman ,  Donald J. Victory ,  Ronald R. Chance ,  Russell H. Oelfke

发明人： Eugene R. Thomas ,  Harry W. Deckman ,  Donald J. Victory ,  Ronald R. Chance ,  Russell H. Oelfke

IPC分类号： B01D5322

CPC分类号： E21B43/164 ,  B01D53/22 ,  B01D53/226 ,  Y02C10/10 ,  Y02P90/70

摘要： The invention relates to a method of separating one or more components from a multi-component gas stream comprising at least one non-acid gas component and at least one acid gas component. A multi-component gas stream at a pressure above 1,200 psia (82.8 bar) and a temperature above 120° F. (48.9° C.) with the concentration of at least one acid gas component in the gas stream being at least 20 mole percent is passed to a membrane system that selectively separates at least one acid gas component from the multi-component gas stream as a permeate stream. The permeate stream has a pressure at least 20% of the pressure of the feed pressure.

摘要翻译： 本发明涉及从包含至少一种非酸性气体组分和至少一种酸性气体组分的多组分气流中分离一种或多种组分的方法。 压力高于1,200psia（82.8bar）和高于120°F（48.9℃）的多组分气流，气流中至少一种酸性气体组分的浓度为至少20摩尔％ 被传递到膜系统，其选择性地将至少一种酸性气体组分与作为渗透物流的多组分气流分离。 渗透物流的压力至少为进料压力的20％

公开(公告)号：US5980596A

公开(公告)日：1999-11-09

申请号：US845706

申请日：1997-04-25

申请人： Frank Hershkowitz ,  Harry W. Deckman ,  Robert P. Reynolds ,  Constantine P. Gonatas ,  John W. Fulton ,  Leonard Schoenman ,  Jack I. Ito ,  Russell J. Koveal ,  Costas A. Coulaloglou

发明人： Frank Hershkowitz ,  Harry W. Deckman ,  Robert P. Reynolds ,  Constantine P. Gonatas ,  John W. Fulton ,  Leonard Schoenman ,  Jack I. Ito ,  Russell J. Koveal ,  Costas A. Coulaloglou

IPC分类号： B01F5/00 ,  B01F5/06 ,  B01J4/00 ,  B01J8/02 ,  B01J19/24 ,  C01B3/36 ,  C01B3/38 ,  C10G2/00 ,  F23D14/22 ,  F23D14/62 ,  B01J8/00 ,  B01J8/04 ,  C07C27/00

CPC分类号： F23D14/62 ,  B01J19/249 ,  B01J8/0278 ,  C01B3/36 ,  C01B3/382 ,  C10G2/30 ,  F23D14/22 ,  B01J2208/022 ,  B01J2219/2453 ,  B01J2219/2462 ,  B01J2219/247 ,  B01J2219/2477 ,  B01J2219/2481 ,  B01J2219/2485 ,  C01B2203/142 ,  C01B2203/82

摘要： A novel injector/reactor apparatus and an efficient process for the partial oxidation of light hydrocarbon gases, such as methane, to convert such gases to useful synthesis gas for subsequent hydrocarbon synthesis. Sources of a light hydrocarbon gas, such as methane, and oxygen or an oxygen-containing gas are preheated and pressurized and injected through an injector means at high velocity into admixture with each other in the desired proportions, preferably at comparable momentums, at a plurality of mixing nozzles which are open to the reaction zone of a reactor and are spaced over the face of the injector, to form a reactant gas premix having a pressure drop equal to at least 1% of the lowest upstream pressure of either of said gas streams. The gas premix is ejected in a time period which preferably is less than 9 milliseconds, at a velocity between about 25 to 1000 feet/second, into a reaction zone comprising a partial oxidation zone, so that the gas mixture reacts therein. The partially-oxidized effluent is then passed into a steam reforming catalyst zone to reduce the amounts of CO.sub.2, H.sub.2 O and heat produced by the partial oxidation reaction to form the useful syngas, which is cooled, recovered and/or further processed.

摘要翻译： 一种新型的注射器/反应器装置和用于轻质烃气体（例如甲烷）的部分氧化的有效方法，以将这种气体转化成有用的合成气以用于随后的烃合成。 来自诸如甲烷和氧气或含氧气体的轻质烃气体被预热和加压，并通过注射器装置以高速度以所需比例（优选在可比较的动量）以多种方式彼此混合，多个 的混合喷嘴，其对反应器的反应区开放并且在喷射器的表面上间隔开，以形成反应气体预混合物，该反应物气体预混合物的压降等于任一气流的最低上游压力的至少1％ 。 气体预混物在优选小于9毫秒的时间内以约25至1000英尺/秒的速度喷射到包含部分氧化区的反应区中，使得气体混合物在其中反应。 然后将部分氧化的流出物进入蒸汽重整催化剂区域以减少CO 2，H 2 O的量和通过部分氧化反应产生的热量，以形成有用的合成气，其被冷却，回收和/或进一步处理。

公开(公告)号：US5886056A

公开(公告)日：1999-03-23

申请号：US845701

申请日：1997-04-25

申请人： Frank Hershkowitz ,  Harry W. Deckman ,  Robert P. Reynolds ,  Constantine P. Gonatas ,  John W. Fulton ,  Leonard Schoenman ,  Jack I. Ito

发明人： Frank Hershkowitz ,  Harry W. Deckman ,  Robert P. Reynolds ,  Constantine P. Gonatas ,  John W. Fulton ,  Leonard Schoenman ,  Jack I. Ito

IPC分类号： B01F3/02 ,  B01F5/06 ,  B01J4/00 ,  B01J8/02 ,  B01J8/44 ,  B01J10/00 ,  B01J19/24 ,  B05B1/14 ,  C01B3/36 ,  C01B3/38 ,  C10G2/00 ,  F23D14/22 ,  C07C27/00 ,  C07C1/02

CPC分类号： F23D14/22 ,  B01F5/0682 ,  B01J10/00 ,  B01J19/2485 ,  B01J19/249 ,  B01J8/0278 ,  B01J8/44 ,  C01B3/36 ,  C01B3/363 ,  C01B3/382 ,  C10G2/30 ,  B01F3/02 ,  B01J2208/022 ,  B01J2219/2453 ,  B01J2219/2462 ,  B01J2219/247 ,  B01J2219/2481 ,  B01J2219/2485 ,  B01J2219/2498 ,  C01B2203/142 ,  C01B2203/82

摘要： A novel injector/reactor apparatus and an efficient process for the partial oxidation of light hydrocarbon gases, such as methane, to convert such gases to useful synthesis gas for recovery and/or subsequent hydrocarbon synthesis. Sources of a light hydrocarbon gas, such as methane, and oxygen or an oxygen-containing gas are preheated and pressurized and injected through an injector means at high velocity into admixture with each other in the desired relating proportions, at a plurality of mixing nozzles which are open to the partial oxidation zone of a reactor and are uniformly-spaced over the face of the injector means, to form a gaseous premix having a pressure drop through the injector. The gaseous premix is injected in a time period which is less than 5 milliseconds, preferably at a velocity between about 25 to 1000 feet/second, into a partial oxidation reaction zone so that the gaseous premix reacts therein, to reduce the amounts of CO.sub.2, H.sub.2 O and heat produced by the partial oxidation reaction and form, cool and recover a useful syngas.

摘要翻译： 一种新颖的注射器/反应器装置以及用于部分氧化轻质烃气体（例如甲烷）的有效方法，以将这种气体转化成有用的合成气以用于回收和/或随后的烃合成。 来自诸如甲烷，氧气或含氧气体的轻质烃气体在多个混合喷嘴处被预热和加压并通过喷射器装置以高速度以所需的相关比例彼此混合注入 对反应器的部分氧化区开放，并且在喷射器装置的表面上均匀间隔开，以形成具有通过喷射器的压降的气态预混物。 气体预混物在小于5毫秒（优选以约25至1000英尺/秒的速度）的时间段内注入部分氧化反应区中，使得气态预混物在其中反应以减少CO 2的量， H2O和通过部​​分氧化反应产生的热量形成，冷却并回收有用的合成气。

公开(公告)号：US5395979A

公开(公告)日：1995-03-07

申请号：US23235

申请日：1993-02-25

申请人： Harry W. Deckman ,  Edward Kantner ,  Joel R. Livingston, Jr. ,  Michael G. Matturro ,  Edmund J. Mozeleski

发明人： Harry W. Deckman ,  Edward Kantner ,  Joel R. Livingston, Jr. ,  Michael G. Matturro ,  Edmund J. Mozeleski

IPC分类号： B01J31/24 ,  B01J31/40 ,  B01J38/48 ,  C07B61/00 ,  C07C45/50 ,  C07C47/02 ,  C07C45/78

CPC分类号： B01J31/2404 ,  B01J31/24 ,  B01J31/4038 ,  B01J31/4046 ,  B01J31/4053 ,  B01J31/4061 ,  B01J38/48 ,  C07C45/50 ,  B01J2231/321 ,  B01J2531/80 ,  B01J2531/822 ,  Y02P20/584

摘要： A catalyst for use in hydroformylation of olefins which comprises a Group VIII noble metal complexed with a phosphine ligand having at least one alkyl or aryl group bonded thereto, such as tris-4-propylphenyl phosphines and tris-4-octylphenyl phosphines. These and other triphenylphosphine catalysts can be separated from a crude reaction product of a noble metal-catalyzed hydroformylation reaction by contacting the crude reaction product with a dense polymeric, nonpolar membrane, preferably nonpolar polyolefin membranes.

摘要翻译： 用于烯烃加氢甲酰化的催化剂，其包含与其上键合有至少一个烷基或芳基的膦配体络合的VIII族贵金属，例如三-4-丙基苯基膦和三-4-辛基苯基膦。 这些和其它三苯基膦催化剂可以通过使粗反应产物与致密的聚合非极性膜，优选非极性聚烯烃膜接触，从贵金属催化的加氢甲酰基化反应的粗反应产物中分离出来。