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    PROCESS FOR PRODUCING HYDROGEN AND GENERATING POWER
    132.
    发明申请
    PROCESS FOR PRODUCING HYDROGEN AND GENERATING POWER 审中-公开
    生产氢和发电的方法

    公开(公告)号：US20150233290A1

    公开(公告)日：2015-08-20

    申请号：US14433074

    申请日：2013-10-03

    申请人： SHELL OIL COMPANY

    发明人： Salvador Aldrett Lee ,  Nikunj Gupta ,  Karel Martin Kapoun

    IPC分类号： F02C3/22 ,  C01B3/50 ,  F02C3/28 ,  C01B3/34

    CPC分类号： F02C3/22 ,  C01B3/346 ,  C01B3/384 ,  C01B3/50 ,  C01B2203/0216 ,  C01B2203/0233 ,  C01B2203/0283 ,  C01B2203/043 ,  C01B2203/0475 ,  C01B2203/0811 ,  C01B2203/0872 ,  C01B2203/1235 ,  C01B2203/1241 ,  C01B2203/84 ,  F02C3/28 ,  F02C6/18

    摘要： A process for producing hydrogen and power comprises subjecting a gaseous hydrocarbon feedstock to an endothermic steam reforming reaction by contacting the feedstock, in a reaction zone, in the presence of steam, with catalyst to obtain a mixture comprising hydrogen and carbon monoxide; recovering hydrogen from the mixture; feeding fuel and oxidant to a turbine system comprising a compressor, combustion chamber and expansion turbine, wherein the compressor is coupled to the turbine, the oxidant is compressed in the compressor to obtain compressed oxidant, and the fuel is combusted with the compressed oxidant in the chamber to obtain a stream of combusted gas; feeding at least part of the stream to the turbine to generate power and to obtain a turbine flue gas; and providing heat for the reforming reaction from the combusted gas and/or the flue gas; and liquefaction of the recovered hydrogen by subjecting it to a liquefaction cycle.

    摘要翻译： 用于生产氢气和动力的方法包括使气态烃原料经历吸热蒸汽重整反应，在反应区中，在蒸汽存在下与催化剂接触，以获得包含氢气和一氧化碳的混合物; 从混合物中回收氢气; 将燃料和氧化剂供给到包括压缩机，燃烧室和膨胀涡轮机的涡轮机系统，其中压缩机联接到涡轮机，氧化剂在压缩机中被压缩以获得压缩的氧化剂，并且燃料与压缩的氧化剂在 室以获得燃烧气体流; 将至少一部分流供应到涡轮机以产生动力并获得涡轮机烟道气; 并从燃烧气体和/或烟道气提供重整反应的热量; 并通过使回收的氢气经受液化循环而液化。

    Method for producing synthesis gas for methanol production
    134.
    发明授权
    Method for producing synthesis gas for methanol production 有权
    生产甲醇合成气的方法

    公开(公告)号：US09102532B2

    公开(公告)日：2015-08-11

    申请号：US14354536

    申请日：2012-10-26

    申请人： STAMICARBON B.V.

    发明人： Gaetano Iaquaniello ,  Elena Antonetti ,  Palma Contaldo

    IPC分类号： C01B3/26 ,  C01B3/30 ,  C07C29/151 ,  C07C29/00

    CPC分类号： C01B3/26 ,  C01B3/30 ,  C01B3/38 ,  C01B3/386 ,  C01B3/48 ,  C01B2203/0233 ,  C01B2203/0261 ,  C01B2203/0283 ,  C01B2203/043 ,  C01B2203/0475 ,  C01B2203/061 ,  C01B2203/1235 ,  C01B2203/141 ,  C01B2203/142 ,  C07C29/00 ,  C07C29/1518

    摘要： Method for producing synthesis gas for methanol production The present invention relates to a method for producing synthesis gas from a hydrocarbon containing feed, which synthesis gas is particularly suitable for subsequent use in methanol production. In this method, a feed (100) is divided into two streams, wherein one stream is subjected to catalytic partial oxidation (CPO) (2) and the other stream is subjected to steam reforming (5) followed by a water gas shift reaction (51). The two streams are then recombined and can be used further in methanol synthesis (6). The recombined stream preferably has an R ratio, being a molar ratio (H2−C02)/(CO+C02), in the range of 1.9-2.2 and preferably about 2. The invention further relates to a method for producing methanol from a hydrocarbon containing feed, wherein first synthesis gas is obtained according to the method of the invention, which synthesis gas is further used to produce methanol. Also, the invention relates to a method of adapting an existing methanol plant to the methanol production process of the invention.

    摘要翻译： 用于生产甲醇生产合成气的方法本发明涉及一种由含烃进料生产合成气的方法，该合成气特别适用于随后用于甲醇生产。 在该方法中，将进料（100）分成两股料流，其中一条料流进行催化部分氧化（CPO）（2），另一条料流进行蒸汽重整（5），随后进行水煤气变换反应 51）。 然后将两种物流重组，并可以进一步用于甲醇合成（6）。 重组流优选具有在1.9-2.2，优选约2的范围内的摩尔比（H 2 -CO 2）/（CO + CO 2）的R比。本发明还涉及一种从烃生产甲醇的方法 其中根据本发明的方法获得第一合成气，该合成气被进一步用于生产甲醇。 本发明还涉及使现有的甲醇装置适应本发明的甲醇生产方法。

    Synthesis gas and Fischer Tropsch integrated process
    140.
    发明授权
    Synthesis gas and Fischer Tropsch integrated process 有权
    合成气和费托综合工艺

    公开(公告)号：US09067850B2

    公开(公告)日：2015-06-30

    申请号：US14345554

    申请日：2012-07-23

    申请人： Peter Edward James Abbott

    发明人： Peter Edward James Abbott

    IPC分类号： C07C27/06 ,  C07C1/04 ,  C07C29/151 ,  C10K1/00 ,  C10K1/04 ,  C10K3/04 ,  C10G2/00 ,  C01B3/16 ,  C01B3/38 ,  B01D53/22

    CPC分类号： C07C1/0485 ,  B01D53/229 ,  C01B3/16 ,  C01B3/38 ,  C01B2203/0233 ,  C01B2203/0244 ,  C01B2203/0255 ,  C01B2203/0261 ,  C01B2203/0283 ,  C01B2203/0405 ,  C01B2203/0415 ,  C01B2203/043 ,  C01B2203/0475 ,  C01B2203/0495 ,  C01B2203/062 ,  C07C29/1518 ,  C10G2/30 ,  C10K1/005 ,  C10K1/04 ,  C10K3/04 ,  Y02P20/125

    摘要： Process for synthesizing hydrocarbons includes: reforming a hydrocarbon feedstock containing inert gases in reforming stages to generate a synthesis gas including the inert gases, steam, hydrogen and carbon monoxide; cooling the synthesis gas below the dew point to obtain a dewatered synthesis gas; synthesizing hydrocarbons from the dewatered synthesis gas by the Fischer-Tropsch reaction and separating at least part of the synthesized hydrocarbons, to give a tail gas; subjecting a mixture of at least part of the tail gas and steam to the water-gas shift reaction, to form shifted tail gas having increased hydrogen and carbon dioxide contents; subjecting the shifted tail gas to one or more membrane separation stages thereby generating an inert gas-containing gas mixture and one or more of a hydrogen-, carbon dioxide- and a hydrocarbon-containing gas mixture; and using one or more of the hydrogen-, carbon dioxide- and hydrocarbon-containing gas mixture in a reformer feed stream.

    摘要翻译： 合成烃的方法包括：在重整阶段重整含有惰性气体的烃原料以产生包括惰性气体，蒸汽，氢气和一氧化碳的合成气; 冷却低于露点的合成气，得到脱水合成气; 通过费 - 托反应从脱水合成气中合成烃，并分离至少部分合成的烃，得到尾气; 使至少部分尾气和蒸汽的混合物进行水煤气变换反应，形成具有增加的氢和二氧化碳含量的转移尾气; 将转移的尾气经受一个或多个膜分离阶段，从而产生含惰性气体的气体混合物和一种或多种含氢气，二氧化碳和含烃气体混合物; 并在重整器进料流中使用一种或多种含氢气，二氧化碳和含烃气体混合物。