公开(公告)号：US4816233A

公开(公告)日：1989-03-28

申请号：US95367

申请日：1987-09-11

Applicant: William J. Rourke ,  Wen-Chao Lai ,  Samuel Natansohn

Inventor： William J. Rourke ,  Wen-Chao Lai ,  Samuel Natansohn

IPC: B01J39/18 ,  B01J45/00 ,  C01F17/00 ,  C22B59/00 ,  F02B75/02 ,  C01G17/00

CPC classification number: C01F17/0043 ,  C01F17/0006 ,  C22B3/42 ,  F02B2075/027 ,  Y02P10/234 ,  Y10S423/14

Abstract: A method of recovering quantitatively trace amounts of scandium from aqueous solutions containing large amounts of other metals consists of reducing any manganese and iron in the solution to the divalent states of manganese and iron. The solution is then adjusted to a pH from about 1.9 to about 2.1 and passed through a column of the ion exchange resin in the hydrogen form having an iminodiacetic acid functionality. The scandium is absorbed on the column and any base metals and rare earth metals which were also absorbed are removed by eluting with a dilute acid without removing the scandium. The scandium is subsequently removed from the column by eluting with a solution containing a chelating agent such as diglycolic acid. The scandium is then recovered from the solution by precipitation, filtering, washing, drying and calcined to the oxide.

公开(公告)号：US4786481A

公开(公告)日：1988-11-22

申请号：US759104

申请日：1985-07-25

Applicant: Yushin Kataoka ,  Masaaki Matsuda ,  Masahiro Aoi

Inventor： Yushin Kataoka ,  Masaaki Matsuda ,  Masahiro Aoi

IPC: B01J45/00 ,  B01D1/04 ,  B01D15/00 ,  B01D15/08 ,  B01J20060101 ,  B01J20/34 ,  B01J39/04 ,  B01J49/00 ,  C01G7/00 ,  C01G15/00 ,  C01G17/00 ,  C01G43/00 ,  C01G55/00 ,  C07B63/00 ,  C22B3/00 ,  C22B3/16 ,  C22B9/10

CPC classification number: C22B3/24 ,  Y02P10/234

Abstract: A method for eluting a metal adsorbed on a chelating agent with an eluent, which comprises using as the eluent an aqueous solution containing a water-soluble inorganic sulfide and a basic compound at concentrations of 0.005 to 3N and 0.1N or more, respectively.

Abstract translation: 一种用洗脱剂洗脱吸附在螯合剂上的金属的方法，该方法包括分别使用浓度为0.005至3N和0.1N或更高的水溶性无机硫化物和碱性化合物的水溶液作为洗脱剂。

公开(公告)号：US4714556A

公开(公告)日：1987-12-22

申请号：US711304

申请日：1985-03-13

Applicant: Clara M. Ambrus ,  Csaba Horvath

Inventor： Clara M. Ambrus ,  Csaba Horvath

IPC: A61M1/34 ,  B01D15/00 ,  B01J45/00 ,  B01D13/00

CPC classification number: B01J45/00 ,  A61M1/3472 ,  A61M1/3475 ,  B01D15/00 ,  B01D61/145 ,  B01D63/02 ,  B01D69/144 ,  A61M2205/3606 ,  A61M2205/366 ,  B01D15/3809 ,  B01D2311/2626

Abstract: Extracorporeal apparatus for selective removal of pathogenic factors, i.e. antigens, from blood by circulating the blood through hollow fibers which, exterior to the lumen are in proximity to antibodies, i.e. proteins having strong biospecific activity for the pathogenic factors. In some situations, the antibody is segregated in a liquid medium outside the hollow fiber to improve mass transfer and the antigen penetrates the ultrafilter wall of the fiber to join the antibody.

公开(公告)号：US4652280A

公开(公告)日：1987-03-24

申请号：US741169

申请日：1985-06-04

Applicant: Edward G. Boeren ,  Richard B. van Henegouwen

Inventor： Edward G. Boeren ,  Richard B. van Henegouwen

IPC: B01D15/04 ,  B01J20/26 ,  B01J20/28 ,  B01J20/281 ,  B01J20/285 ,  B01J39/26 ,  B01J45/00 ,  B01J47/00 ,  C07C7/135 ,  G01N30/88 ,  B01D15/08

CPC classification number: B01J47/006 ,  B01J39/26 ,  B01J45/00 ,  C07C7/135

Abstract: This invention relates to an adsorption material for olefins, a gas chromatography column and a method for removing olefins from a mixture with saturated hydrocarbons by gas chromatography. The adsorption material according to the invention is a thermostable, macroporous resin having strongly acid ion exchange groups to which silver ions are linked. The resin has an average pore diameter of 10-100 nm, an internal surface area of 10-100 m.sup.2 /g and 5-15% cross-linking.

Abstract translation: 本发明涉及一种用于烯烃的吸附材料，气相色谱柱和通过气相色谱从饱和烃的混合物中除去烯烃的方法。 根据本发明的吸附材料是具有强酸性离子交换基团的稳定的大孔树脂，其中银离子被连接。 该树脂的平均孔径为10-100nm，内表面积为10-100m2 / g，交联度为5-15％。

公开(公告)号：US4500494A

公开(公告)日：1985-02-19

申请号：US560771

申请日：1983-12-12

Applicant: Herbert B. Scher

Inventor： Herbert B. Scher

IPC: B01D61/40 ,  B01J13/18 ,  B01J45/00 ,  C01G3/00 ,  C02F1/68 ,  C22B3/26 ,  C22B3/34 ,  C22B3/36 ,  B01D15/00 ,  C01G5/00

CPC classification number: B01D61/40 ,  B01J13/18 ,  B01J45/00 ,  C01G3/003 ,  C02F1/683 ,  C22B3/0021 ,  C22B3/0031 ,  C22B3/0037 ,  Y02P10/234 ,  Y10S423/14 ,  Y10T428/2985

Abstract: Novel polyurea and urea-formaldehyde microcapsules are disclosed which enclose a chelsating agent selected from .beta.-diketones, 8-hydroxyquinolines and their thiol analogs, and oximes. The microcapsules are capable of removing metal ions from water.

Abstract translation: 公开了新型聚脲和脲甲醛微胶囊，其包围选自β-二酮，8-羟基喹啉及其硫醇类似物和肟的切丝剂。 微胶囊能够从水中除去金属离子。

公开(公告)号：US4448694A

公开(公告)日：1984-05-15

申请号：US299416

申请日：1981-09-04

Applicant: Edwin P. Plueddemann

Inventor： Edwin P. Plueddemann

IPC: B01J45/00 ,  C01F17/00 ,  C01G3/00 ,  C01G7/00 ,  C01G23/00 ,  C01G39/00 ,  C01G45/00 ,  C01G49/00 ,  C01G51/00 ,  C01G53/00 ,  C01G55/00 ,  C01G56/00 ,  C02F1/28 ,  C02F1/42 ,  C02F1/62 ,  C07F7/10 ,  C07F7/18 ,  C22B60/02 ,  B01D15/04 ,  C08L83/06

CPC classification number: C22B60/0265 ,  B01J45/00 ,  C01F17/0006 ,  C01G23/001 ,  C01G3/003 ,  C01G39/003 ,  C01G45/003 ,  C01G49/0009 ,  C01G51/003 ,  C01G53/003 ,  C01G55/001 ,  C01G56/001 ,  C01G7/003 ,  C02F1/288 ,  C07F7/1836 ,  C22B3/24 ,  Y02P10/234

Abstract: What is disclosed are novel metal chelating agents which are bonded to inorganic substrates to immobilize them. An example of such a metal chelating agent is (CH.sub.3 O).sub.3 Si(CH.sub.2).sub.3 NH(CH.sub.2 CH.sub.2 NH).sub.2 (CH.sub.2).sub.3 Si(OCH.sub.3). An example of an inorganic substrate is a silica gel.

Abstract translation: 公开的是新的金属螯合剂，其结合到无机基底上以固定它们。 这种金属螯合剂的实例是（CH 3 O）3 Si（CH 2）3 NH（CH 2 CH 2 NH）2（CH 2）3 Si（OCH 3）。 无机底物的实例是硅胶。

公开(公告)号：US4415631A

公开(公告)日：1983-11-15

申请号：US278864

申请日：1981-06-29

Applicant: Jan A. J. Schutijser

Inventor： Jan A. J. Schutijser

IPC: C08F2/00 ,  B01J20/281 ,  B01J20/283 ,  B01J20/286 ,  B01J20/32 ,  B01J41/08 ,  B01J45/00 ,  C08F2/44 ,  C08F292/00 ,  C12N11/00 ,  G01N30/88 ,  B32B5/16 ,  B01J3/02 ,  B32B9/00

CPC classification number: B01J20/286 ,  B01J20/261 ,  B01J20/264 ,  B01J20/267 ,  B01J20/28057 ,  B01J20/28078 ,  B01J20/289 ,  B01J20/3092 ,  B01J20/3204 ,  B01J20/3217 ,  B01J20/3219 ,  B01J20/3257 ,  B01J20/3263 ,  B01J20/327 ,  B01J20/3276 ,  B01J20/3282 ,  C08F292/00 ,  B01J2220/54 ,  B01J2220/58 ,  Y10T428/2993 ,  Y10T428/2995 ,  Y10T428/31663

Abstract: The invention relates to support material usable as such in chromatography or as a starting material which, upon linkage to it of compounds containing ionic groups, ligands or biomacromolecules, can be used as ion exchanger, as a medium in affinity chromatography or in enzymatic reactions and consists of porous, inorganic silanized particles onto which there is covalently bonded an organic, stationary phase built up of (co)polymerized vinyl monomers containing amide groups, said inorganic particles having been silanized with an organo silane.

Abstract translation: 本发明涉及在色谱法或起始材料中可以使用的载体材料，其在连接到其上含有离子基团的化合物，配体或生物大分子时可用作离子交换剂，作为亲和层析或酶促反应中的介质， 由多孔无机硅烷化颗粒组成，其上共价键合由含有酰胺基团的（共）聚合的乙烯基单体组成的有机固定相，所述无机颗粒已用有机硅烷硅烷化。

公开(公告)号：US4384025A

公开(公告)日：1983-05-17

申请号：US721268

申请日：1976-09-08

Applicant: Bruno Hilti ,  Carl W. Mayer

Inventor： Bruno Hilti ,  Carl W. Mayer

IPC: B01J45/00 ,  C07D495/06 ,  C08F4/00 ,  H01B1/12 ,  B32B9/04 ,  H01B1/00

CPC classification number: C07D495/06 ,  C08F4/00 ,  H01B1/121

Abstract: A novel metallically conducting charge-transfer complex derived from 5,6,11,12-tetrathiotetracene and iodine is described. This complex is preferably produced by reacting 5,6,11,12-tetrathiotetracene and iodine together in the gas phase in an inert-gas atmosphere. The novel complex is characterized by a very high electrical conductivity, and it can be used, for example, as an organic conductor element.

Abstract translation: 描述了衍生自5,6,11,12-四硫代四烯和碘的新型金属导电电荷转移络合物。 该络合物优选通过在惰性气体气氛中在气相中使5,6,11,12-四硫代四烯和碘一起反应来制备。 该新型复合物的特征在于非常高的导电性，并且可以用作例如有机导体元件。

公开(公告)号：US4383924A

公开(公告)日：1983-05-17

申请号：US194022

申请日：1980-10-06

Applicant: Gunter Ritter

Inventor： Gunter Ritter

IPC: A01K63/04 ,  B01J45/00 ,  C02F1/42

CPC classification number: B01J45/00 ,  A01K63/04

Abstract: Treatment of water for selective and quantitative removal of all cations of the transition elements, with simultaneous adjustment of a definite mole ratio of calcium, magnesium, and the alkali metals, with a cation exchanger which, towards the ions of the I. transition elements, II. alkaline earth metals, III. alkali metals, shows a markedly gradually decreasing affinity from I. to III.; and which cation exchanger is loaded with calcium and magnesium ions in a predetermined mole ratio, or with hydrogen or sodium ions to obtain a water corresponding to the desired type of water in a vessel made of a water-resistant material and having at least one water-permeable wall.

Abstract translation: 处理水以选择性和定量地除去过渡元素的所有阳离子，同时利用阳离子交换剂调节钙，镁和碱金属的确定摩尔比，该阳离子交换剂朝向I.过渡元素的离子， 二， 碱土金属，III。 碱金属显示出从I到III显着逐渐降低的亲和力。 并且哪个阳离子交换剂以预定的摩尔比装载钙离子和镁离子，或用氢或钠离子负载，以在由耐水材料制成的容器中获得对应于所需类型的水的水，并且具有至少一种水 不渗透墙

公开(公告)号：US4351933A

公开(公告)日：1982-09-28

申请号：US271745

申请日：1981-06-08

Applicant: Thomas A. Chamberlin ,  Donald A. Tomalia

Inventor： Thomas A. Chamberlin ,  Donald A. Tomalia

IPC: B01D53/14 ,  B01J45/00 ,  C02F1/28 ,  C07D323/00 ,  C08F16/26 ,  C08F20/28 ,  C08F20/22 ,  C08F20/26

CPC classification number: B01J45/00 ,  B01D53/1493 ,  C02F1/285 ,  C07D323/00 ,  C08F16/26 ,  C08F20/28

Abstract: Compounds represented by the formula: ##STR1## and addition polymers thereof where m is an integer from 2 to about 10, X-- is chlorine, hydroxy, carboxy or:--AC--R).dbd.CH.sub.2--R is hydrogen or methyl, --R--' is an ethylene or propylene group and--AC--R).dbd.CH.sub.2is one of: ##STR2## These compounds and their addition polymers form complexes with alkali metal or alkaline earth metal salts and permit the concentration of aqueous solutions of said salts. For example, a compound of the formula: ##STR3## is polymerized with an azobis (isobutyronitrile) catalyst to form addition polymers of the repeating unit ##STR4## When cross-linked, rendering it water-insoluble, such an addition polymer concentrates an aqueous solution of sodium chloride when contacted with same at about 0.degree. C.

Abstract translation: 由下式表示的化合物及其加成聚合物，其中m为2至约10的整数，X-为氯，羟基，羧基或：-AC-R）= CH 2 -R为氢或甲基，-R - '是乙烯或丙烯基，-AC-R）= CH 2是以下之一：这些化合物及其加成聚合物与碱金属或碱土金属盐形成络合物，并允许浓度为 说盐。 例如，下式的化合物与偶氮二（异丁腈）催化剂聚合以形成重复单元的加成聚合物。当交联时，使其不溶于水，这种加成聚合物将水 氯化钠在约0℃下与其接触时的溶液