摘要:
Silicon doping of GaAs epitaxial layers grown using the AsCl.sub.3 /H.sub.2 /GaAs:Ga CVD system is accomplished using AsCl.sub.3 :SiCl.sub.4 liquid doping solutions. These solutions can be readily prepared with reproducible compositions and provide excellent doping control. Fine adjustments in the doping level can be achieved by adjusting the H.sub.2 flow rate and by varying the temperature of the doping solution. Doping levels may range from about 5.times.10.sup.15 to 5.times.10.sup.19 cm.sup.-3 by adjusting the mole fraction of SiCl.sub.4 in the doping solution and the H.sub.2 flow rate to change the mole fraction of P.sub.HCl. The epitaxial layers doped using this technique have excellent room temperature and liquid nitrogen mobilities for electron concentrations between 1.times.10.sup.16 cm.sup.-3 and 8.times.10.sup.18 cm.sup.-3. This doping method is particularly useful for the growth of GaAs epitaxial layers for FET devices.
摘要翻译:使用AsCl3 / H2 / GaAs:Ga CVD系统生长的GaAs外延层的硅掺杂使用AsCl 3:SiCl 4液体掺杂溶液来实现。 这些溶液可以容易地用可重复组合物制备并提供优异的掺杂控制。 可以通过调节H2流速和改变掺杂溶液的温度来实现掺杂水平的微调。 通过调节掺杂溶液中SiCl 4的摩尔分数和H 2流速来改变PHCl的摩尔分数,掺杂量可以在约5×10 15至5×10 19 cm -3的范围内。 使用该技术掺杂的外延层对于1×10 16 cm -3和8×10 18 cm -3之间的电子浓度具有优异的室温和液氮迁移率。 该掺杂方法对于用于FET器件的GaAs外延层的生长特别有用。
摘要:
A process for the oxidation of carbon monoxide to carbon dioxide in the presence of elemental nitrogen with minimal oxidation thereof which comprises combining the carbon monoxide with a predetermined amount of oxygen containing gas to give at least 1% stoichiometric excess of oxygen for the oxidation of carbon monoxide to carbon dioxide and passing the resulting mixture over a ceramic catalyst of the following empirical formula at a temperature between about 100.degree. C and about 1,000.degree. C;w.sub.k X.sub.n J(1-k-n).sup.ZO (3.+-.m)WhereinW is Zirconium, Tin or Thorium or mixtures thereof;X is an alkaline earth metal or mixture thereof;J is scandium, ytrrium, a rare-earth element or mixture thereof;Z is a metal of the first transition series or a mixture thereof, at least 0.01% of said metal having an oxidation state other than +3;k is a number having a value between 0 and about 0.1;m is a number having a value of from 0 to about 0.26; andn is a number having a value from 0 to about 0.51, provided when n has a value of 0, k has a value between 0 and about 0.05.
摘要:
A process for the oxidation of hydrogen to water in the presence of elemental nitrogen with minimal oxidation thereof which comprises combining the hydrogen with a predetermined amount of oxygen containing gas to give at least 1% stoichiometric excess of oxygen for the oxidation of hydrogen to water and passing the resulting mixture over a ceramic catalyst of the following empirical formula at a temperature between about 100.degree. C and about 1,000.degree. C;w.sub.k X.sub.n J(1-k-n).sup.ZO (3.+-.m)WhereinW is Zirconium, Tin or Thorium or mixtures thereof;X is an alkaline earth metal or mixture thereof;J is scandium, yttrium, a rare-earth element or mixture thereof;Z is a metal of the first transition series of a mixture thereof, at least 0.01% of said metal having an oxidation state other then +3;k is a number having a value between 0 and about 0.1;m is a number having a value of from 0 to about 0.26; andn is a number having a value from 0 to about 0.51, provided when n has a value of 0, k has a value between 0 and about 0.05.
摘要:
A process for the oxidation of carbon monoxide to carbon dioxide with sulfur dioxide and water which comprises combining the carbon monoxide with a predetermined amount of sulfur dioxide and water to produce hydrogen sulfide and carbon dioxide; and passing the resulting mixture over a ceramic catalyst of the following empirical formula above about 200.degree. C.:w.sub.k X.sub.n J.sub.(1-k-n) ZO.sub.(3.+-.m')Wherein:W is zirconium, tin or thorium, or a mixture thereof;X is an alkaline earth metal or mixture thereof;J is scandium, yttrium, a rare-earth element or mixture thereof;Z is a metal of the first transition series or a mixture thereof, at least 0.01% of said metal having an oxidation state other than +3;k is a number having a value of between 0 and about 0.1;m' is a number having a value of from 0 to about 0.25, provided m' has a value other than 0 when n has a value of 0; andn is a number having a value from 0 to about 0.51, provided when n has a value of 0, k has a value of between 0 and about 0.05.
摘要:
An elastomeric mounting comprises a body of elastomeric material having end regions the surfaces which are bonded to respective confronting surfaces of a pair of rigid end members for compression therebetween. A first of the rigid end members (32) extends radially outwardly from a longitudinal compression axis (19) of the mounting to lie beyond the bonded interface (35). The first end member has outwards of the bonded interface an abutment face (34) which is contacted by the elastomeric body when subject to compression loading, and a discontinuity is defined by the first rigid end member whereby the interface and abutment face depart from a wholly co-planar form.
摘要:
Chemically pure mercuric iodide is purified to form detector-grade mercuric iodide and mercuric iodide semi-conductor crystals by vaporization in an inert gas stream containing deliberate addition of oxygen and iodine vapor and crystallizing the vaporized mercuric iodide in order to remove undesired metallic iodides and organic residues, followed by the elimination of undesired oxides of mercury by the revaporization in a second inert gas stream in the presence of reducing vapors such as carbon monoxide, hydrogen iodide or iodine and recrystallization to produce detector-grade mercuric iodide, and crystal growth in such a reducing atmosphere produces semi-conductor crystals.
摘要:
A polycrystalline article is densified to provide either a nonporous body or a body with controlled interconnected porosity. A mixture of fine powders of the polycrystalline material and a sintering aid is compacted and outgassed under reduced pressure. The outgassed compact is then subjected to a permeation anneal step in which it is heated in a closed chamber to a temperature sufficient to form a liquid of the sintering aid, but under pressure conditions which inhibit evaporation of the sintering aid. The sintering aid can then be leached out to provide a densified article having interconnected porosity. Alternatively, the sintering aid can be leached out at elevated temperature, further densifying the compact to form a substantially nonporous body. Alternatively, the sintering aid can be removed by subjecting the densified article to an evaporation anneal step in which the article is heated to evaporate the sintering aid, further densifying the compact to form a substantially nonporous article. Apparatus is provided containing interconnected sections to accomplish the foregoing process. When applied to magnesium fluoride, a transparent polycrystalline body is obtained as a new article of manufacture which is substantially uniformly transparent to infrared radiation throughout the entire range of 0.7-8 microns.
摘要:
A process for the oxidation of hydrogen sulfide to sulfur trioxide in the presence of elemental nitrogen with minimal oxidation thereof which comprises combining the hydrogen sulfide with a predetermined amount of oxygen containing gas to give at least 1% stoichiometric excess of oxygen for the oxidation of hydrogen sulfide to sulfur trioxide and passing the resulting mixture over a ceramic catalyst of the following empirical formula at a temperature between about 100.degree. C and about 700.degree. C.;w.sub.k X.sub.n J(1-k-n).sup.ZO (3.+-.m)whereinW is Zirconium, Tin or Thorium or mixtures thereof;X is an alkaline earth metal or mixture thereof;J is scandium, yttrium, a rare-earth element or mixture thereof;Z is a metal of the first transition series orA mixture thereof, at least 0.01% of said metalHaving an oxidation state other than +3;k is a number having a value between 0 and about 0.1;m is a number having a value of from 0 to 0.26; andn is a number having a value from 0 to about 0.51,Provided when n has a value of 0, k has a value between 0 and about 0.05.
摘要:
A class of ceramic mixed oxide, nonstoichiometric electrically neutral, rare-earth-type catalyst containing rare-earth-type elements, elements of the first transition metal series and Zirconium, Tin or Thorium and optionally the alkaline earth metals. The catalyst has the following formula:W.sub.k X.sub.n Y.sub.(1-k-n) ZO.sub.(3.sub.+-m.sub.') (I)wherein:W is Zirconium, Tin or Thorium or mixture thereof;X is an alkaline earth metal or mixture thereof;J is a rare-earth-type element or mixture thereof;Z is a metal of the first transition series or a mixture thereof, at least 0.01% of said metal having an oxidation state other than +3;k is a number having a value of between 0 and about 0.1;m' is a number having a value of from 0 to about 0.26, provided m has a value other than 0 when n has a value of 0; andn is a number having a value from 0 to about 0.51, provided when n has a value of 0, k has a value of between 0 and about 0.05.
摘要:
A class of ceramic mixed oxide, nonstoichiometric electrically neutral rare-earth-type catalyst containing rare-earth-type elements and elements of the first transition metal series and optionally the alkaline earth metals. The catalyst has the following formula: X.sub.n Y.sub.(1.sub.-n) ZO.sub.(3