Photopolymerizable compositions for electroless plating methods
    11.
    发明授权
    Photopolymerizable compositions for electroless plating methods 有权
    用于化学镀方法的光聚合组合物

    公开(公告)号:US09207533B2

    公开(公告)日:2015-12-08

    申请号:US14174879

    申请日:2014-02-07

    CPC classification number: G03F7/038 G03F7/0045 G03F7/0047 G03F7/028

    Abstract: A photopolymerizable composition has seven essential components: (a) a photopolymerizable epoxy material, (b) a photoacid generator such as an onium salt, (c) electron acceptor photosensitizer, (d) an electron donor co-initiator having an oxidation potential of 0.1 V to 3 V vs. SCE, (e) metal particles, and in some embodiments, (f) one or more free radically polymerizable compounds, and (g) one or more free radical photoinitiators. This photopolymerizable composition can be applied or printed onto one or both sides of various substrates to form articles that can be used to form electrically conductive materials. Methods for using the photopolymerizable compositions include electroless plating methods that can be carried out in roll-to-roll printing and plating systems once various photocured patterns are formed from the photopolymerizable compositions.

    Abstract translation: 可光聚合组合物具有七个基本组分:(a)可光聚合的环氧材料,(b)光酸产生剂如鎓盐,(c)电子受体光敏剂,(d)电子给体共引发剂,其氧化电位为0.1 V至3V对SCE,(e)金属颗粒,在一些实施方案中,(f)一种或多种可自由基自由基化合物,和(g)一种或多种自由基光引发剂。 该可光聚合组合物可以施加或印刷在各种基材的一面或两面上,以形成可用于形成导电材料的制品。 使用可光聚合组合物的方法包括一旦从光聚合组合物形成各种光固化图案,可以在辊对印刷和电镀系统中进行的化学镀方法。

    PRECURSOR DIELECTRIC COMPOSITION WITH THIOSULFATE-CONTAINING POLYMERS
    13.
    发明申请
    PRECURSOR DIELECTRIC COMPOSITION WITH THIOSULFATE-CONTAINING POLYMERS 有权
    含有含硫聚合物聚合物的前驱体电介质组合物

    公开(公告)号:US20150364688A1

    公开(公告)日:2015-12-17

    申请号:US14301385

    申请日:2014-06-11

    Abstract: A precursor dielectric composition comprises: (1) a photocurable or thermally curable thiosulfate-containing polymer that has a Tg of at least 50° C. and comprises: an organic polymer backbone comprising (a) recurring units comprising pendant thiosulfate groups; and organic charge balancing cations, (2) optionally, an electron-accepting photosensitizer component, and (3) one or more organic solvents in which the photocurable or thermally curable thiosulfate-containing polymer is dissolved or dispersed. These precursor dielectric compositions can be applied to various substrates and eventually cured to form dielectric compositions or layers for various types of electronic devices.

    Abstract translation: 前体电介质组合物包含:(1)Tg至少为50℃的可光固化或可热固化的含硫代硫酸盐的聚合物,包括:有机聚合物主链,其包含(a)包含硫代硫酸盐基团的重复单元; 和有机电荷平衡阳离子,(2)任选的电子接受光敏剂组分,和(3)其中溶解或分散有可光固化或可热固化的含硫代硫酸盐的聚合物的一种或多种有机溶剂。 这些前体介电组合物可以施加到各种基底上,并且最终固化以形成用于各种类型的电子器件的电介质组合物或层。

    THIOSULFATE POLYMERS
    14.
    发明申请
    THIOSULFATE POLYMERS 有权
    硫代聚合物

    公开(公告)号:US20140288253A1

    公开(公告)日:2014-09-25

    申请号:US14158897

    申请日:2014-01-20

    Abstract: A thiosulfate polymer includes both an electron-accepting photosensitizer component and thiosulfate groups in the same molecule, arranged in random order along the backbone. The thiosulfate polymer composition can be formulated into compositions and applied to various articles, or used to form a predetermined polymeric pattern after photothermal reaction to form crosslinked disulfide bonds, removing non-crosslinked polymer, and reaction with a disulfide-reactive material. Such thiosulfate polymer compositions can also be used to sequester metals in nanoparticulate form, and as a way for shaping human hair in hairdressing operations.

    Abstract translation: 硫代硫酸盐聚合物包括同一分子中的电子接受光敏剂组分和硫代硫酸盐基团,其沿主链以随机顺序排列。 硫代硫酸盐聚合物组合物可以配制成组合物并施加到各种制品上,或者用于在光热反应后形成预定的聚合物图案以形成交联的二硫键,除去非交联的聚合物和与二硫化物反应性材料的反应。 这样的硫代硫酸盐聚合物组合物也可以用于螯合纳米颗粒形式的金属,并且作为在理发操作中塑造人的头发的方法。

    METAL CATALYTIC COMPOSITION WITH SILVER-OXIME COMPLEX
    17.
    发明申请
    METAL CATALYTIC COMPOSITION WITH SILVER-OXIME COMPLEX 有权
    金属催化组合物与银 - 氧复合物

    公开(公告)号:US20160167021A1

    公开(公告)日:2016-06-16

    申请号:US14571419

    申请日:2014-12-16

    Applicant: Deepak Shukla

    Inventor: Deepak Shukla

    Abstract: A non-aqueous metal catalytic composition includes (a) a complex of silver and an oxime comprising reducible silver ions in an amount of at least 2 weight %, (b) a silver ion photoreducing composition in an amount of at least 1 weight %, and (c) a photocurable component, a non-curable polymer, or a combination of a photocurable component and a non-curable polymer. This non-aqueous metal catalytic composition can be used to form silver metal particles in situ during suitable reducing conditions. The silver metal can be provided in a suitable layer or pattern on a substrate, which can then be subsequently subjected to electroless plating to form electrically-conductive layers or patterns for use in various articles or as touch screen displays in electronic devices.

    Abstract translation: 非水性金属催化剂组合物包括(a)含有至少2重量%量的可还原银离子的银和肟的配合物,(b)至少1重量%的银离子光还原组合物, 和(c)可光固化组分,不可固化聚合物,或光固化性组分和不可固化聚合物的组合。 该非水金属催化剂组合物可用于在合适的还原条件下原位形成银金属颗粒。 银金属可以以合适的层或图案提供在基底上,然后可随后对其进行化学镀以形成用于各种制品的导电层或图案或用作电子设备中的触摸屏显示器。

    FORMING SILVER CATALYTIC SITES FROM SILVER PHOSPHITE CARBOXYLATES
    18.
    发明申请
    FORMING SILVER CATALYTIC SITES FROM SILVER PHOSPHITE CARBOXYLATES 有权
    从银磷酸酯形成银催化场

    公开(公告)号:US20160167019A1

    公开(公告)日:2016-06-16

    申请号:US14571375

    申请日:2014-12-16

    Abstract: A non-aqueous metal catalytic composition includes (a) a silver carboxylate-trialkyl(triaryl)phosphite complex comprising reducible silver ions in an amount of at least 2 weight %, (b) a silver ion photoreducing composition in an amount of at least 1 weight %, and (c) a photocurable component or a non-curable polymer or a combination of a photocurable component and a non-curable polymer. This non-aqueous metal catalytic composition can be used to form silver metal particles in situ during suitable reducing conditions. The silver metal can be provided in a suitable layer or pattern on a substrate, which can then be subsequently subjected to electroless plating to form electrically-conductive layers or patterns for use in various articles or as touch screen displays in electronic devices.

    Abstract translation: 非水性金属催化剂组合物包括(a)含有至少2重量%量的可还原银离子的羧酸银 - 三烷基(三芳基)亚磷酸酯络合物,(b)银离子光还原组合物的量至少为1 重量%,(c)可光固化成分或非固化性聚合物,或光固化性成分与不可固化聚合物的组合。 该非水金属催化剂组合物可用于在合适的还原条件下原位形成银金属颗粒。 银金属可以以合适的层或图案提供在基底上,然后可随后对其进行化学镀以形成用于各种制品的导电层或图案或用作电子设备中的触摸屏显示器。

    Method of photocuring acrylate compositions
    19.
    发明授权
    Method of photocuring acrylate compositions 有权
    光固化丙烯酸酯组合物的方法

    公开(公告)号:US09365658B2

    公开(公告)日:2016-06-14

    申请号:US14507024

    申请日:2014-10-06

    Applicant: Deepak Shukla

    Inventor: Deepak Shukla

    Abstract: Acrylate-containing compositions are photocured by mixing at least one N-oxyazinium salt photoinitiator, a photosensitizer for the N-oxyazinium salt, an N-oxyazinium salt efficiency amplifier, an aromatic heterocyclic, nitrogen-containing base, and one or more photocurable acrylates to form a photocurable composition. This photocurable composition is then irradiated to effect polymerization of the one or more acrylates. This method can be carried out in oxygen-containing environments.

    Abstract translation: 含有丙烯酸酯的组合物通过将至少一种N-氧嗪鎓盐引发剂,N-氧嗪鎓盐的光敏剂,N-氧嗪嗪盐效率放大器,芳族杂环,含氮碱和一种或多种光固化性丙烯酸酯混合至 形成光固化组合物。 然后照射该可光固化组合物以实现一种或多种丙烯酸酯的聚合。 这种方法可以在含氧环境中进行。

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