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    High performance monolith treater for gasoline upgrade
    11.
    发明授权
    High performance monolith treater for gasoline upgrade 失效
    用于汽油升级的高性能整料处理器

    公开(公告)号：US06673237B2

    公开(公告)日：2004-01-06

    申请号：US09996499

    申请日：2001-11-28

    申请人： Wei Liu ,  Tinghong Tao

    发明人： Wei Liu ,  Tinghong Tao

    IPC分类号： C10G4500

    CPC分类号： B01J35/04 ,  B01J19/2485 ,  B01J21/04 ,  B01J23/85 ,  B01J23/882 ,  B01J35/10 ,  B01J37/0203 ,  C10G2400/02

    摘要： A method of increasing the selective desulfurization of naphtha feed streams that includes: combining a naphtha feed stream with a hydrogen containing gas to form a combined feed stream and reacting the combined feed stream over a monolithic honeycomb catalyst bed containing hydrodesulfurization catalyst components to give a desulfurized naphtha. In conducting such an illustrative embodiment, the percent desulfurization of the naphtha is preferably greater than about 50% and the percent olefin hydrogenation of the naphtha is preferably less than about 50%. The monolithic honeycomb catalyst bed of one alternative and illustrative embodiment preferably has a channel density of about 25 to 1600 cells per square inch; a channel size from about 0.1 to 10 mm; and a channel wall thickness of about 0.01 to about 2.0 mm. The illustrative method should be carried out such that the octane number (R+M/2) of the naphtha feed stream is reduced by no more than 3.0 at 95% desulfurization and preferably no more than 1.5. The hydrodesulfurization catalyst components include a powdered refractory oxide and transition metal catalyst compounds. Alternatively the hydrodesulfurization catalyst components may be impregnated into the monolithic honeycomb catalyst bed itself. Preferable hydrodesulfurization catalyst components include a Group VIII metal containing compound and a Group VIB metal containing compound. Alternatively the hydrodesulfurization catalyst components may further include a phosphorous promoter.

    摘要翻译： 一种增加石脑油进料流的选择性脱硫的方法，其包括：将石脑油进料流与含氢气体组合以形成组合的进料流，并将组合的进料流在含有加氢脱硫催化剂组分的整体式蜂窝催化剂床上反应，得到脱硫 石脑油 在进行这样的说明性实施例中，石脑油的脱硫百分比优选大于约50％，并且石脑油的烯烃氢化百分比优选小于约50％。 一个替代和说明性实施方案的整体蜂窝催化剂床优选具有约25至1600个细胞/平方英寸的通道密度; 通道尺寸约0.1至10mm; 并且通道壁厚度为约0.01至约2.0mm。 应进行说明性的方法，使得石脑油进料流的辛烷值（R + M / 2）在95％脱硫时减少不超过3.0，优选不超过1.5。 加氢脱硫催化剂组分包括粉末难熔氧化物和过渡金属催化剂化合物。 或者，加氢脱硫催化剂组分可以浸渍到整体蜂窝催化剂床本身中。 优选的加氢脱硫催化剂组分包括含Ⅷ族金属的化合物和含VIB族金属的化合物。 或者，加氢脱硫催化剂组分可以进一步包括磷促进剂。

    Device for liquid or gas process streams and method of making and using same
    12.
    发明授权
    Device for liquid or gas process streams and method of making and using same 有权
    液体或气体工艺流的装置及其制造和使用方法

    公开(公告)号：US06303368B1

    公开(公告)日：2001-10-16

    申请号：US09413716

    申请日：1999-10-05

    申请人： Willard A. Cutler ,  Tinghong Tao

    发明人： Willard A. Cutler ,  Tinghong Tao

    IPC分类号： C12M112

    CPC分类号： B01J19/2485 ,  B01J20/0288 ,  B01J20/04 ,  B01J20/06 ,  B01J20/08 ,  B01J20/10 ,  B01J20/18 ,  B01J20/20 ,  B01J20/28004 ,  B01J20/28045 ,  B01J20/28085 ,  B01J35/04 ,  B01J2219/2424 ,  B01J2219/2428 ,  B01J2219/243 ,  B01J2219/2432 ,  B01J2219/2445 ,  B01J2219/2446

    摘要： A device for use in processing of a liquid and/or gas stream. The device is made up of a monolithic structure having active powder for treating streams. The structure has an inlet end and an outlet end and a multiplicity of cells extending from inlet end to outlet end. The cells are separated from one another by porous walls, a portion of the total number of cells being plugged in a pattern such that a stream enters the device through the unplugged cells at the inlet end and passes through at least two porous walls and the active powder in-between, and thereafter passes out of the device through unplugged cells at the outlet end. The device finds use in a number of applications including ion exchange, adsorption, biological and chemical reactions, and catalytic applications.

    摘要翻译： 一种用于处理液体和/或气流的装置。 该装置由具有用于处理流的活性粉末的整体结构构成。 该结构具有入口端和出口端以及从入口端延伸到出口端的多个单元。 细胞通过多孔壁彼此分开，细胞总数的一部分被插入图案中，使得流在入口端通过未插入的细胞进入装置并且通过至少两个多孔壁并且活性物质 之间的粉末，然后在出口端通过未插入的电池从设备中流出。 该设备可用于许多应用，包括离子交换，吸附，生物和化学反应以及催化应用。

    Structured materials for purification of liquid streams and method of making and using same
    13.
    发明授权
    Structured materials for purification of liquid streams and method of making and using same 失效
    用于液体流净化的结构材料及其制造和使用方法

    公开(公告)号：US06200483B1

    公开(公告)日：2001-03-13

    申请号：US09413717

    申请日：1999-10-05

    申请人： Willard A. Cutler ,  Tinghong Tao ,  Jennifer M. Torns

    发明人： Willard A. Cutler ,  Tinghong Tao ,  Jennifer M. Torns

    IPC分类号： C02F142

    CPC分类号： B01J47/00 ,  C02F1/42

    摘要： A monolithic structure having active material that includes at least inorganic ion exchange material, for purifying a liquid stream of contaminants such as heavy metals, chlorine, volatile organics, pesticides, herbicides, and/or parasites, etc. The structure has an inlet end and an outlet end and a multiplicity of cells extending from inlet to outlet end. The cells are separated from one another by porous walls that are alternatively plugged at each end such that a liquid stream that enters the structure, enters through the unplugged cells at the inlet end and passes through porous walls to be purified by the active material, and thereafter passes out of the structure through unplugged cells at the outlet end. One method of making the structure involves applying active material as a coating on an alternately plugged substrate. The average particle size of the active material after calcination is greater than the average cell wall pore size of the substrate. The coated substrate is dried at no greater than 200° C., and calcined at no greater than 650° C., to bond the active material to the substrate. The structure can be shaped from a forming mixture of the active materials.

    摘要翻译： 具有至少包含无机离子交换材料的活性材料的整体结构，用于净化诸如重金属，氯，挥发性有机物，杀虫剂，除草剂和/或寄生虫等杂质的液体流。该结构具有入口端和 出口端和从入口到出口端延伸的多个单元。 细胞通过多孔壁彼此分开，多孔壁可替代地插入每一端，使得进入结构的液体流通过入口端处的未堵塞的细胞进入并穿过多孔壁以被活性物质净化，以及 然后通过出口端的未插入电池从结构中流出。 制造该结构的一种方法包括将活性材料作为涂层施加在交替堵塞的基底上。 煅烧后的活性物质的平均粒径大于基材的平均泡孔壁孔径。 将涂覆的基材在不超过200℃下干燥，并在不高于650℃下煅烧以将活性材料粘合到基材上。 该结构可以由活性材料的形成混合物成型。

    Metallic catalysts for non-neutral liquid media
    18.
    发明授权
    Metallic catalysts for non-neutral liquid media 失效
    用于非中性液体介质的金属催化剂

    公开(公告)号：US06455023B1

    公开(公告)日：2002-09-24

    申请号：US09686555

    申请日：2000-10-11

    申请人： Kishor P. Gadkaree ,  Tinghong Tao

    发明人： Kishor P. Gadkaree ,  Tinghong Tao

    IPC分类号： C07C500

    CPC分类号： C07B61/00 ,  B01J21/18 ,  B01J23/42 ,  B01J35/04 ,  C07C5/03 ,  C07C13/18

    摘要： Carbon monolith-supported catalysts with high leach resistance used in catalytic applications involving strong acidic and basic conditions in a pH range of from 0 to 6.5 and from 7.5 to 14, are respectively described. The leach resistance of the catalyst system originates from strong interaction between the catalyst and the unsaturated valence of the carbon surface. In addition to surprisingly high resistance to leach out, the catalysts also have substantial differential advantages in catalyst performance: catalyst activity, selectivity, and stability.

    摘要翻译： 分别描述了在0至6.5和7.5至14的pH范围内涉及强酸性和碱性条件的催化应用中具有高浸出性的碳整料负载型催化剂。 催化剂体系的浸出电阻起始于催化剂与碳表面的不饱和化合价之间的强相互作用。 除了令人惊讶的高耐渗出性之外，催化剂在催化剂性能方面也具有显着的差异优势：催化剂活性，选择性和稳定性。

    Water filtration apparatus
    20.
    发明授权
    Water filtration apparatus 失效
    水过滤装置

    公开(公告)号：US06227382B1

    公开(公告)日：2001-05-08

    申请号：US09211134

    申请日：1998-12-14

    申请人： Willard A. Cutler ,  Kishor P. Gadkaree ,  Tinghong Tao

    发明人： Willard A. Cutler ,  Kishor P. Gadkaree ,  Tinghong Tao

    IPC分类号： B01D2937

    CPC分类号： C02F1/003 ,  A47J31/605 ,  B01D29/31 ,  B01D29/52 ,  B01D39/2068 ,  B01D61/18 ,  B01D63/066 ,  B01D69/02 ,  B01D71/02 ,  B01D71/021 ,  B01D2325/02 ,  C02F1/281 ,  C02F1/283 ,  C02F1/444 ,  C02F2307/04

    摘要： A cyst reduction water filter and a method and carafe system for using it, wherein the filter incorporates a cellular ceramic honeycomb filter element of a selectively plugged channel configuration wherein all water filtration paths traverse porous channel walls, the walls exhibiting open porosity characterized by a median pore diameter in the range of about 2-8 micrometers and with pores over 10 microns in diameter comprising not more than 10% of the open pore volume, and wherein the filter element has a primed water flux of at least 0.3 ml/min/cm3 under a water pressure of 0.3 psig.

    摘要翻译： 一种囊肿还原水过滤器及其使用的方法和保鲜系统，其中所述过滤器包括选择性堵塞通道构造的蜂窝陶瓷蜂窝过滤器元件，其中所有水过滤路径穿过多孔通道壁，所述壁具有开放孔隙度，其特征在于中值 孔直径在约2-8微米范围内，直径大于10微米，孔径不大于开孔体积的10％，并且其中过滤元件具有至少0.3ml / min / cm3的底漆水通量 在0.3 psig的水压下。