公开(公告)号：US06203865B1

公开(公告)日：2001-03-20

申请号：US09357621

申请日：1999-07-20

Applicant: Andrzej R. Badzian ,  Rustum N. Roy ,  Pravin Mistry ,  Manuel C. Turchan

Inventor： Andrzej R. Badzian ,  Rustum N. Roy ,  Pravin Mistry ,  Manuel C. Turchan

IPC: C23C1648

CPC classification number: C23C16/27 ,  C23C16/483

Abstract: A method for producing well-crystallized adherent diamond layers on WC—Co substrates. An array of focused laser beams is scanned across the WC—Co sample. Useful lasers include the excimer, YAG:Nd, and carbon dioxide types. The process is conducted in open air with carbon dioxide and nitrogen gases delivered for shrouding the substrate. A luminous plasma is found a few mm above the WC—Co insert. The duration of the deposition process in a typical case is approximately 40 s. This typically gives 20-40 &mgr;m thick coatings. The vertical growth rate is about 1 &mgr;m/s.

Abstract translation: 一种用于在WC-Co基底上生产良好结晶的粘附金刚石层的方法。 在WC-Co样品上扫描聚焦激光束阵列。 有用的激光器包括准分子，YAG：Nd和二氧化碳类型。 该过程在露天进行，二氧化碳和氮气输送用于覆盖基材。 发现等离子体在WC-Co插入物上方几毫米。 在典型情况下，沉积过程的持续时间约为40秒。 这通常会给出20-40毫米厚的涂层。 垂直生长速度约为1mum / s。

公开(公告)号：US20130001204A1

公开(公告)日：2013-01-03

申请号：US13536257

申请日：2012-06-28

Applicant: Pravin Mistry ,  Jahr Turchan

Inventor： Pravin Mistry ,  Jahr Turchan

IPC: B23K10/00 ,  B05C9/12 ,  B05D3/10

CPC classification number: D06M10/025 ,  B05D1/60 ,  B05D3/06 ,  B05D3/142 ,  B05D3/145 ,  D06M10/005 ,  H01H1/24 ,  H05H1/34

Abstract: Material treatment is effected in a treatment region by at least two energy sources, such as (i) an atmospheric pressure plasma and (ii) an ultraviolet laser directed into the plasma and optionally onto the material being treated. Precursor materials may be dispensed before, and finishing material may be dispensed after treatment. Electrodes for generating the plasma may comprise two spaced-apart rollers. Nip rollers adjacent the electrode rollers define a semi-airtight cavity, and may have a metallic outer layer.

Abstract translation: 材料处理在处理区域通过至少两种能量源进行，例如（i）大气压等离子体和（ii）引导到等离子体中的紫外线激光和任选地被引导到待处理的材料上。 前体材料可以在之前分配，并且整理材料可以在处理后分配。 用于产生等离子体的电极可以包括两个间隔开的辊。 邻近电极辊的压辊定义了半气密腔，并且可以具有金属外层。

公开(公告)号：US5731046A

公开(公告)日：1998-03-24

申请号：US241930

申请日：1994-05-12

Applicant: Pravin Mistry ,  Manuel C. Turchan

Inventor： Pravin Mistry ,  Manuel C. Turchan

IPC: C04B41/80 ,  B01J19/12 ,  B23K26/06 ,  B81C99/00 ,  C21D1/09 ,  C23C14/06 ,  C23C14/22 ,  C23C14/28 ,  C23C16/26 ,  C23C16/27 ,  C23C16/44 ,  C23C20/06 ,  C23C26/00 ,  C30B23/02 ,  C30B25/02 ,  C30B25/10 ,  C30B25/18 ,  C30B29/04 ,  H01S3/00 ,  B05D3/06

CPC classification number: B23K26/0604 ,  B23K26/0622 ,  C23C14/0605 ,  C23C14/22 ,  C23C14/28 ,  C23C16/26 ,  C23C16/27 ,  C23C16/4418 ,  C30B23/02 ,  C30B25/105 ,  C30B25/18

Abstract: Energy, such as from three different lasers, is directed at the surface of a substrate to mobilize and vaporize a carbon constituent element (e.g., carbide) within the substrate (e.g., steel). The vaporized constituent element is reacted by the energy to alter its physical structure (e.g., from carbon to diamond) to that of a composite material which is diffused back into the substrate as a composite material. An additional secondary element, which also contains carbon, may optionally be directed (e.g., sprayed) onto the substrate to augment, enhance and/or modify the formation of the composite material, as well as to supply sufficient or additional material for fabricating a diamond or diamond-like coating on the surface of the substrate. The process can be carried out in an ambient environment (e.g., without a vacuum), and without pre-heating or post-cooling of the substrate.

Abstract translation: 诸如来自三种不同激光器的能量被引导到衬底的表面以便在衬底（例如，钢）内移动和汽化碳构成元件（例如碳化物）。 蒸发的构成元素通过能量反应以改变其物理结构（例如，从碳到金刚石）到​​作为复合材料漫反射到基底中的复合材料的物理结构。 另外还含有碳的次要元素可以任选地被引导（例如喷涂）到基底上以增强，增强和/或改变复合材料的形成，以及提供用于制造金刚石的足够的或附加的材料 或金刚石样涂层。 该方法可以在周围环境（例如，没有真空）中进行，并且不需要对基材进行预热或后冷却。

公开(公告)号：US5643641A

公开(公告)日：1997-07-01

申请号：US465583

申请日：1995-06-05

Applicant: Manuel C. Turchan ,  Pravin Mistry

Inventor： Manuel C. Turchan ,  Pravin Mistry

IPC: B81C99/00 ,  C23C14/06 ,  C23C14/22 ,  C23C14/28 ,  C23C16/26 ,  C23C16/27 ,  C23C16/44 ,  C23C26/00 ,  C30B23/02 ,  C30B25/10 ,  C30B25/18 ,  C23C16/48

CPC classification number: C30B25/18 ,  C23C14/0605 ,  C23C14/22 ,  C23C14/28 ,  C23C16/26 ,  C23C16/27 ,  C23C16/4418 ,  C23C26/00 ,  C30B23/02 ,  C30B25/105 ,  F41A21/04 ,  F16C33/62 ,  Y10S427/103 ,  Y10S427/104

Abstract: Energy, such as from one or more lasers, is directed at the surface of a substrate to mobilize and vaporize a constituent element (e.g., carbide) within the substrate (e.g., steel). The vaporized constituent element is reacted by the energy to alter its physical structure (e.g., from carbon to diamond) to that of a composite material which is diffused back into the substrate as a composite material. The method of the present invention includes the additional steps of using the energy to move a carbon constituent element in a sub-surface zone of the substrate towards the surface of the substrate, vaporizing selected amounts of the carbon constituent element to produce a vaporized carbon constituent element, reacting the vaporized carbon constituent element to modify its physical structure and properties, reacting the vaporized carbon constituent element to modify its physical structure and properties, and fabricating the diamond coating from the reacted vaporized carbon constituent element.

Abstract translation: 诸如来自一个或多个激光器的能量被引导到衬底的表面以便移动和汽化衬底（例如钢）内的构成元件（例如，碳化物）。 蒸发的构成元素通过能量反应以改变其物理结构（例如，从碳到金刚石）到​​作为复合材料漫反射到基底中的复合材料的物理结构。 本发明的方法包括使用能量将基底的亚表面区域中的碳构成元素朝向基底的表面移动的附加步骤，蒸发选定量的碳构成元素以产生气化碳成分 使蒸发的碳组成元件反应以改变其物理结构和性质，使蒸发的碳组成元素反应以改变其物理结构和性质，以及从反应的气化碳构成元素制备金刚石涂层。

公开(公告)号：US5168742A

公开(公告)日：1992-12-08

申请号：US634194

申请日：1991-01-17

Applicant: Peter J. Heyes ,  Stephen J. Digby ,  Steven P. Williams ,  Kevin M. Ambrose ,  Pravin Mistry

Inventor： Peter J. Heyes ,  Stephen J. Digby ,  Steven P. Williams ,  Kevin M. Ambrose ,  Pravin Mistry

IPC: B32B1/00 ,  B21C3/02 ,  B21D20060101 ,  B21D22/20 ,  B21D22/28 ,  B21D22/30 ,  B32B15/08 ,  B32B15/20

CPC classification number: B21D22/286 ,  B21D22/201 ,  B21D22/28 ,  B21D22/30 ,  Y10T428/131

Abstract: A wall ironing ring (8, 11, 14) for use in cooperation with a punch (1) to reduce the thickness of a sidewall of a cup (17) drawn from a laminate of a polyester film and sheet aluminum or sheet aluminum alloy has a frusto conical entry surface (24) to the ring which converges at an angle between 1.degree. and 4.degree. to a central axis perpendicular to the plane of the ring and terminates at a land of short length, measured at said axis; and divergent exit surface extends from said land at an angle in the range from 5.degree. to 15.degree.. The ironing ring may be made from a material having a thermal conductivity greater than 50 W/m.degree.C. used in cooperation with a like ring of smaller land diameter held apart from the first ring by a spacer (7) in which coolant is applied to the cup.

公开(公告)号：US06370165B1

公开(公告)日：2002-04-09

申请号：US09357623

申请日：1999-07-20

Applicant: Andrzej R. Badzian ,  Rustum N. Roy ,  Theresa Badzian ,  William R. Drawl ,  Pravin Mistry ,  Manuel C. Turchan

Inventor： Andrzej R. Badzian ,  Rustum N. Roy ,  Theresa Badzian ,  William R. Drawl ,  Pravin Mistry ,  Manuel C. Turchan

IPC: H01S330

CPC classification number: C23C16/483 ,  C23C16/27

Abstract: A diamond coating formed on a WC—Co substrate prepared through a process including employing a plasma and a variety of interactions from a multiple laser system demonstrates exceptional adhesion and indicates a durable cubic diamond structure. The coating on the WC—Co substrate is typically between 25 and 40 &mgr;m thick and has an average crystal size of between 10 and 20 &mgr;m. Various methods of confirming the cubic diamond structure of the coatings have been employed. The adhesion of the diamond coating to the substrate is very strong. An electron microprobe analysis shows tungsten and cobalt atoms incorporated into the film and a layer depleted in cobalt exists at the diamond-WC—Co interface. Particulates of WC—Co—C alloy are spread over the top surface, apparently formed by condensation from the vapor phase of metal-containing molecules. Carbon is confirmed as being the main component of the surface layer.

Abstract translation: 通过包括采用等离子体和多种激光系统的相互作用的方法制备的在WC-Co基底上形成的金刚石涂层显示了出色的附着力并且表明了耐久的立方金刚石结构。 WC-Co基底上的涂层通常为25至40μm厚，平均晶体尺寸为10至20μm。 已经采用确认涂层的立方金刚石结构的各种方法。 金刚石涂层对基材的粘附性非常强。 电子探针分析显示结合到膜中的钨和钴原子，在金刚石WC-Co界面存在贫钴层。 WC-Co-C合金的颗粒分散在顶部表面，显然由含金属分子的气相的冷凝形成。 确认碳作为表层的主要成分。

公开(公告)号：US06274206B1

公开(公告)日：2001-08-14

申请号：US08468612

申请日：1995-06-05

Applicant: Manuel C. Turchan ,  Pravin Mistry

Inventor： Manuel C. Turchan ,  Pravin Mistry

IPC: C23C1648

CPC classification number: C23C16/44 ,  C23C14/0605 ,  C23C14/22 ,  C23C14/28 ,  C23C16/26 ,  C23C16/27 ,  C23C16/4418 ,  C23C16/48 ,  C23C26/00 ,  C30B23/02 ,  C30B25/105 ,  C30B25/18 ,  C30B29/04 ,  F16C33/62 ,  F41A21/04 ,  Y10S427/103 ,  Y10S427/104

Abstract: Energy, such as from one or more lasers, is directed at the surface of a substrate to mobilize and vaporize a constituent element (e.g., carbide) within the substrate (e.g., steel). The vaporized constituent element is reacted by the energy to alter its physical structure (e.g., from carbon to diamond) to that of a composite material which is diffused back into the substrate as a composite material. An additional secondary element, which can be the same as or different from the constituent element, may optionally be directed (e.g., sprayed) onto the substrate to augment, enhance and/or modify the formation of the composite material, as well as to supply sufficient or additional material for fabricating one or more coatings on the surface of the substrate. The process can be carried out in an ambient environment (e.g., without a vacuum), and without pre-heating or post-cooling of the substrate. The process is truly heteroepitaxial, and is suitable for treating substrates of complex geometries, and coating all sides of such substrates either evenly or selectively. The process may also be used as an adjunct to conventional CVD-type processes, to eliminate the need for heating the substrate to high temperatures. Articles formed by the disclosed processes are described, including three-dimensional objects.

Abstract translation: 诸如来自一个或多个激光器的能量被引导到衬底的表面以便移动和汽化衬底（例如钢）内的构成元件（例如，碳化物）。 蒸发的构成元素通过能量反应以改变其物理结构（例如，从碳到金刚石）到​​作为复合材料漫反射到基底中的复合材料的物理结构。 另外可以与构成元件相同或不同的次要元件可任选地被引导（例如喷涂）到基底上以增强，增强和/或改变复合材料的形成，以及供应 用于在衬底的表面上制造一个或多个涂层的足够的或附加的材料。 该方法可以在周围环境（例如，没有真空）中进行，并且不需要对基材进行预热或后冷却。 该工艺是真正的异质外延，适用于处理复杂几何形状的基材，并均匀或选择性地涂覆这些基材的所有面。 该方法也可以用作常规CVD型工艺的辅助装置，以消除将衬底加热到​​高温的需要。 描述由所公开的方法形成的物品，包括三维物体。

公开(公告)号：US06200183B1

公开(公告)日：2001-03-13

申请号：US09357622

申请日：1999-07-20

Applicant: Andrzej R. Badzian ,  Rustum N. Roy ,  Theresa Badzian ,  William R. Drawl ,  Pravin Mistry ,  Manuel C. Turchan

Inventor： Andrzej R. Badzian ,  Rustum N. Roy ,  Theresa Badzian ,  William R. Drawl ,  Pravin Mistry ,  Manuel C. Turchan

IPC: H01J902

CPC classification number: C23C16/27 ,  C23C16/277 ,  C23C16/483 ,  H01J2201/30457

Abstract: The preparation and use of diamond as an electron emission material is disclosed. Satisfactory measurements were conducted on diamond coatings deposited on WC-Co alloy by a multiple pulsed laser process. The electron emission was measured in a diode configuration with a diamond surface-anode spacing of 20 and 50 &mgr;m in vacuum at P=10−7 Torr. Current densities of 6 mA/cm were calculated at an applied of voltage of 3000 V (for 20 &mgr;m). Analysis proved that electron field emission provided by a diamond grown by a multiple pulsed laser process proved to satisfactorily meet the specified demands.

Abstract translation: 公开了金刚石作为电子发射材料的制备和使用。 对通过多脉冲激光工艺沉积在WC-Co合金上的金刚石涂层进行了令人满意的测量。 在二极管配置中测量电子发射，金刚石表面 - 阳极间距为20和50微米，真空度为P = 10-7乇。 在施加的电压为3000V（20mum）下计算出6mA / cm 2的电流密度。 分析证明，通过多脉冲激光工艺生长的金刚石提供的电子场发射证明满足了特定的要求。

公开(公告)号：US5635243A

公开(公告)日：1997-06-03

申请号：US464448

申请日：1995-06-05

Applicant: Manuel C. Turchan ,  Pravin Mistry

Inventor： Manuel C. Turchan ,  Pravin Mistry

IPC: B81C99/00 ,  C23C14/06 ,  C23C14/22 ,  C23C14/28 ,  C23C16/26 ,  C23C16/27 ,  C23C16/44 ,  C23C26/00 ,  C30B23/02 ,  C30B25/10 ,  C30B25/18 ,  C08J7/18

CPC classification number: C30B25/18 ,  C23C14/0605 ,  C23C14/22 ,  C23C14/28 ,  C23C16/26 ,  C23C16/27 ,  C23C16/4418 ,  C23C26/00 ,  C30B23/02 ,  C30B25/105 ,  F41A21/04 ,  F16C33/62 ,  Y10S427/103 ,  Y10S427/104

Abstract: Energy, such as from one or more lasers, is directed at the surface of a substrate to mobilize and vaporize a constituent element (e.g., carbide) within the substrate (e.g., steel). The vaporized constituent element is reacted by the energy to alter its physical structure (e.g., from carbon to diamond) to that of a composite material which is diffused back into the substrate as a composite material. An additional secondary element, which can be the same as or different from the constituent element, may optionally be directed (e.g., sprayed) onto the substrate to augment, enhance and/or modify the formation of the composite material, as well as to supply sufficient or additional material for fabricating one or more coatings on the surface of the substrate. The process can be carried out in an ambient environment (e.g., without a vacuum), and without pre-heating or post-cooling of the substrate. Articles formed by the disclosed processes are described, including three-dimensional objects.

Abstract translation: 诸如来自一个或多个激光器的能量被引导到衬底的表面以便移动和汽化衬底（例如钢）内的构成元件（例如，碳化物）。 蒸发的构成元素通过能量反应以改变其物理结构（例如，从碳到金刚石）到​​作为复合材料漫反射到基底中的复合材料的物理结构。 另外可以与构成元件相同或不同的次要元件可任选地被引导（例如喷涂）到基底上以增强，增强和/或改变复合材料的形成，以及供应 用于在衬底的表面上制造一个或多个涂层的足够的或附加的材料。 该方法可以在周围环境（例如，没有真空）中进行，并且不需要对基材进行预热或后冷却。 描述由所公开的方法形成的物品，包括三维物体。

公开(公告)号：US5554415A

公开(公告)日：1996-09-10

申请号：US182978

申请日：1994-01-18

Applicant: Manuel C. Turchan ,  Pravin Mistry

Inventor： Manuel C. Turchan ,  Pravin Mistry

IPC: B81C99/00 ,  C23C14/06 ,  C23C14/22 ,  C23C14/28 ,  C23C16/26 ,  C23C16/27 ,  C23C16/44 ,  C23C26/00 ,  C30B23/02 ,  C30B25/10 ,  C30B25/18 ,  C08J7/18

CPC classification number: C30B25/18 ,  C23C14/0605 ,  C23C14/22 ,  C23C14/28 ,  C23C16/26 ,  C23C16/27 ,  C23C16/4418 ,  C23C26/00 ,  C30B23/02 ,  C30B25/105 ,  F41A21/04 ,  F16C33/62 ,  Y10S427/103 ,  Y10S427/104

Abstract: Energy, such as from one or more lasers, is directed at the surface of a substrate to mobilize and vaporize a constituent element (e.g., carbide) within the substrate (e.g., steel). The vaporized constituent element is reacted by the energy to alter its physical structure (e.g., from carbon to diamond) to that of a composite material which is diffused back into the substrate as a composite material. An additional secondary element, which can be the same as or different from the constituent element, may optionally be directed (e.g., sprayed) onto the substrate to augment, enhance and/or modify the formation of the composite material, as well as to supply sufficient or additional material for fabricating one or more coatings on the surface of the substrate. The process can be carried out in an ambient environment (e.g., without a vacuum), and without pre-heating or post-cooling of the substrate.

Abstract translation: 诸如来自一个或多个激光器的能量被引导到衬底的表面以便移动和汽化衬底（例如钢）内的构成元件（例如，碳化物）。 蒸发的构成元素通过能量反应以改变其物理结构（例如，从碳到金刚石）到​​作为复合材料漫反射到基底中的复合材料的物理结构。 另外可以与构成元件相同或不同的次要元件可任选地被引导（例如喷涂）到基底上以增强，增强和/或改变复合材料的形成，以及供应 用于在衬底的表面上制造一个或多个涂层的足够的或附加的材料。 该方法可以在周围环境（例如，没有真空）中进行，并且不需要对基材进行预热或后冷却。