Process For Hydrodesulphurizing Gasoline Employing A Catalyst With Controlled Porosity
    12.
    发明申请
    Process For Hydrodesulphurizing Gasoline Employing A Catalyst With Controlled Porosity 有权
    使用具有可控孔隙率的催化剂加氢脱硫汽油的方法

    公开(公告)号:US20120067780A1

    公开(公告)日:2012-03-22

    申请号:US13305527

    申请日:2011-11-28

    IPC分类号: C10G45/06

    摘要: A novel process is described which allows selective hydrodesulphurizing gasoline cuts containing sulphur-containing compounds and olefins. The process employs a catalyst comprising a support selected, for example, from refractory oxides such as aluminas, silicas, silica-aluminas or magnesia, used alone or as a mixture, a group VI metal, preferably Mo or W which may or may not be promoted by a group VIII metal, Co or Ni. The catalyst is characterized by a mean pore diameter of more than 22 nm. The process may comprise one or more steps.

    摘要翻译: 描述了允许选择性加氢脱硫含有含硫化合物和烯烃的汽油馏分的新方法。 该方法使用包含例如单独使用或作为混合物使用的例如氧化铝,二氧化硅,二氧化硅 - 氧化铝或氧化镁的难熔氧化物的载体的催化剂,VI族金属,优选Mo或W,其可以是或可以不是 由VIII族金属,Co或Ni促进。 催化剂的特征在于平均孔径大于22nm。 该过程可以包括一个或多个步骤。

    Selective hydrogenation process employing a sulphurized catalyst
    16.
    发明授权
    Selective hydrogenation process employing a sulphurized catalyst 失效
    使用硫化催化剂的选择性氢化方法

    公开(公告)号:US07645376B2

    公开(公告)日:2010-01-12

    申请号:US11642973

    申请日:2006-12-21

    IPC分类号: C07C7/163

    摘要: A process for jointly carrying out selective hydrogenation of polyunsaturated compounds into mono unsaturated compounds contained in gasolines, and for transforming light sulphur-containing compounds into heavier compounds by reaction with unsaturated compounds, said process employing a supported catalyst comprising at least one metal from group VIB and at least one non-noble metal from group VIII used in the sulphurized form deposited on a support and having a specific composition and comprising bringing the feed into contact with the catalyst at a temperature in the range of 80° C. to 220° C. at a liquid hourly space velocity in the range of 1 h−1 to 10 h−1 and at a pressure in the range of 0.5 to 5 MPa.

    摘要翻译: 一种将多不饱和化合物选择氢化成汽油中所含的单不饱和化合物的方法,以及通过与不饱和化合物反应将轻质含硫化合物转化成较重的化合物的方法,所述方法采用负载型催化剂,其包含至少一种VIB族金属 和至少一种用于硫化形式的第VIII族的非贵金属沉积在载体上并具有特定组成,并且包括使进料在80℃至220℃的温度范围内与催化剂接触 在1小时-1至10小时-1的范围内的液时空速和0.5-5MPa的压力下。

    Novel process for desulphurizing olefinic gasolines to limit the mercaptans content
    18.
    发明申请
    Novel process for desulphurizing olefinic gasolines to limit the mercaptans content 有权
    用于脱硫烯烃汽油以限制硫醇含量的新方法

    公开(公告)号:US20070012596A1

    公开(公告)日:2007-01-18

    申请号:US11487605

    申请日:2006-07-17

    IPC分类号: C10G47/04 C10G47/02

    摘要: The invention concerns a process for hydrodesulphurizing a gasoline containing less than 0.1% by weight of sulphur derived from a catalytic cracking unit or other conversion units, said process comprising at least one hydrodesulphurization reactor using a bimetallic catalyst operating at a HSV in the range 0.1 h−1 to 20 h−1, a temperature in the range 220° C. to 350° C. and a pressure in the range 0.1 MPa to 5 MPa, and comprising recycling a fraction of the desulphurized gasoline to the inlet to the hydrodesulphurization reactor with a recycle ratio in the range 0.1 to 3 times the flow rate of the gasoline to be desulphurized.

    摘要翻译: 本发明涉及一种加氢脱硫含有少于0.1重量%的衍生自催化裂化装置或其它转化装置的硫的汽油的方法,所述方法包括至少一个加氢脱硫反应器,该反应器使用在HSV下操作的双金属催化剂,范围为0.1h -100℃至20小时-1,温度范围为220℃至350℃,压力为0.1MPa至5MPa,并且包括 将脱硫汽油的一部分循环到加氢脱硫反应器的入口,再循环比例在待脱硫汽油流量的0.1至3倍的范围内。