摘要:
Conducting the hydrodesulphurization of gasoline cuts in the presence of a catalyst comprising at least one support, at least one element of group VIII and tungsten, in which the atomic ratio (element of group VIII)/(element of group VIII+tungsten) is greater than 0.15 and less than 0.50, preferably 0.35–0.40 inclusive.
摘要:
A novel process is described which allows selective hydrodesulphurizing gasoline cuts containing sulphur-containing compounds and olefins. The process employs a catalyst comprising a support selected, for example, from refractory oxides such as aluminas, silicas, silica-aluminas or magnesia, used alone or as a mixture, a group VI metal, preferably Mo or W which may or may not be promoted by a group VIII metal, Co or Ni. The catalyst is characterized by a mean pore diameter of more than 22 nm. The process may comprise one or more steps.
摘要:
The invention is about a catalyst comprising at least one support, at least one group VIII element, at least one group VIB element and phosphorus, in which the density of group VIB elements per unit surface area of the support is in the range (limits included) 2×10−4 to 18×10−4 of oxides of group VIB elements per m2 of support, in which the molar ratio of phosphorus to the group VIB element is in the range 0.27 to 2.00, and in which the amount of group VIB elements is in the range (limits included) 1% to 20% by weight of oxides of group VIB elements and in which the support has a specific surface area of less than 135 m2/g. The invention is also about a process for hydrodesulphurizing gasoline cuts containing sulphur and olefins in the presence of this catalyst.
摘要:
The invention relates to a catalyst for the selective hydrodesulfurization of hydrocarbon-containing feedstocks that comprise sulfur-containing compounds and olefins. This catalyst comes in a sulfurized form and comprises a substrate that is selected from among the refractory oxides, at least one metal that is selected from the group that consists of the metals of groups VI and VII of the periodic table and carbon, whereby the carbon content is less than or equal to 2.8% by weight. The invention also relates to a method for the production of the catalyst that is described above, as well as a process that uses this catalyst for the selective hydrodesulfurization of hydrocarbon-containing feedstocks that contain sulfur-containing compounds and olefins.
摘要:
The invention is about a catalyst comprising at least one support, at least one group VIII element, at least one group VIB element and phosphorus, in which the density of group VIB elements per unit surface area of the support is in the range (limits included) 2×10−4 to 18×10−4 of oxides of group VIB elements per m2 of support, in which the molar ratio of phosphorus to the group VIB element is in the range 0.27 to 2.00, and in which the amount of group VIB elements is in the range (limits included) 1% to 20% by weight of oxides of group VIB elements and in which the support has a specific surface area of less than 135 m2/g. The invention is also about a process for hydrodesulphurizing gasoline cuts containing sulphur and olefins in the presence of this catalyst.
摘要:
A process for jointly carrying out selective hydrogenation of polyunsaturated compounds into mono unsaturated compounds contained in gasolines, and for transforming light sulphur-containing compounds into heavier compounds by reaction with unsaturated compounds, said process employing a supported catalyst comprising at least one metal from group VIB and at least one non-noble metal from group VIII used in the sulphurized form deposited on a support and having a specific composition and comprising bringing the feed into contact with the catalyst at a temperature in the range of 80° C. to 220° C. at a liquid hourly space velocity in the range of 1 h−1 to 10 h−1 and at a pressure in the range of 0.5 to 5 MPa.
摘要:
A process for hydrodesulphurizing gasoline cuts is carried out in the presence of a catalyst comprising at least one group VIII element, at least one group VIB element, and a support with a specific surface area of less than about 200 m2/g, wherein the density of the group VIB elements per unit surface area of the support is in the range 4×10−4 to 36×10−4 g of group VIB element oxides per m2 of the support.
摘要:
The invention concerns a process for hydrodesulphurizing a gasoline containing less than 0.1% by weight of sulphur derived from a catalytic cracking unit or other conversion units, said process comprising at least one hydrodesulphurization reactor using a bimetallic catalyst operating at a HSV in the range 0.1 h−1 to 20 h−1, a temperature in the range 220° C. to 350° C. and a pressure in the range 0.1 MPa to 5 MPa, and comprising recycling a fraction of the desulphurized gasoline to the inlet to the hydrodesulphurization reactor with a recycle ratio in the range 0.1 to 3 times the flow rate of the gasoline to be desulphurized.
摘要:
The invention relates to a process for producing middle distillates from a paraffinic feedstock produced by Fischer-Tropsch synthesis, implementing a hydrocracking/hydroisomerization catalyst comprising at least one hydro-dehydrogenating metal selected from the group formed by the metals from group VIB and from group VIII of the periodic table and a substrate comprising at least one crystallized IZM-2 solid having a chemical composition, expressed on an anhydrous base, in terms of oxide moles, by the following general formula: XO2:aY2O3:bM2/nO, wherein X represents at least one tetravalent element, Y represents at least one trivalent element and M is at least one alkali metal and/or an alkaline earth metal of valency n, a and b representing respectively the number of moles of Y2O3 and M2/nO and a is between 0 and 0.5 and b is between 0 and 1.
摘要:
The invention describes a catalyst comprising at least one hydrodehydrogenating metal selected from the group formed by metals from group VIB and metals from group VIII and a support comprising at least one silica-alumina, and at least one COK-7 zeolite alone, or mixed with at least one ZBM-30 zeolite, as well as a process for hydrocracking hydrocarbon feeds employing said catalyst.