公开(公告)号：US09586828B2

公开(公告)日：2017-03-07

申请号：US13057821

申请日：2009-07-29

申请人： Christophe Bouchy ,  Emmanuelle Guillon

发明人： Christophe Bouchy ,  Emmanuelle Guillon

IPC分类号： C01B39/48 ,  B01J29/74 ,  B01J29/76 ,  B01J29/78 ,  B01J35/00 ,  B01J37/02 ,  B01J37/03 ,  B01J37/08 ,  C10G2/00 ,  C10G45/62 ,  C10G45/64 ,  C10G47/16 ,  C10G47/18 ,  C10G47/20 ,  C10G65/04 ,  C10G65/12

CPC分类号： C01B39/48 ,  B01J29/74 ,  B01J29/76 ,  B01J29/78 ,  B01J35/0006 ,  B01J35/0066 ,  B01J37/0201 ,  B01J37/033 ,  B01J37/08 ,  B01J2229/42 ,  C10G2/30 ,  C10G45/62 ,  C10G45/64 ,  C10G47/16 ,  C10G47/18 ,  C10G47/20 ,  C10G65/043 ,  C10G65/12 ,  C10G2300/1022 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2400/04

摘要： The invention relates to a process for producing middle distillates from a paraffinic feedstock produced by Fischer-Tropsch synthesis, implementing a hydrocracking/hydroisomerization catalyst comprising at least one hydro-dehydrogenating metal selected from the group formed by the metals from group VIB and from group VIII of the periodic table and a substrate comprising at least one crystallized IZM-2 solid having a chemical composition, expressed on an anhydrous base, in terms of oxide moles, by the following general formula: XO2:aY2O3:bM2/nO, wherein X represents at least one tetravalent element, Y represents at least one trivalent element and M is at least one alkali metal and/or an alkaline earth metal of valency n, a and b representing respectively the number of moles of Y2O3 and M2/nO and a is between 0 and 0.5 and b is between 0 and 1.

摘要翻译： 本发明涉及一种由费 - 托合成生产的石蜡原料生产中间馏分的方法，其实施加氢裂化/加氢异构化催化剂，该加氢裂化/加氢异构化催化剂包含至少一种选自VIB族金属和VIII族金属形成的氢化脱氢金属 和包含至少一种具有化学组成的结晶的IZM-2固体的底物，其以无水碱表示，以氧化物摩尔数表示，通过以下通式：XO 2：aY 2 O 3 :bM 2 / nO，其中X表示 至少一种四价元素，Y表示至少一种三价元素，M是至少一种碱金属和/或碱土金属的化合价n，a和b分别代表Y2O3和M2 / nO的摩尔数，a是 在0和0.5之间，b在0和1之间。

公开(公告)号：US20110042270A1

公开(公告)日：2011-02-24

申请号：US12811636

申请日：2008-12-10

申请人： Emmanuelle Guillon ,  Christophe Bouchy ,  Johan Martens

发明人： Emmanuelle Guillon ,  Christophe Bouchy ,  Johan Martens

IPC分类号： B01J29/06 ,  C10G11/05

CPC分类号： B01J29/80 ,  B01J21/12 ,  B01J29/04 ,  B01J29/65 ,  B01J29/70 ,  B01J29/7042 ,  B01J29/7046 ,  B01J29/72 ,  B01J29/74 ,  B01J29/76 ,  B01J29/78 ,  B01J35/10 ,  B01J37/0009 ,  B01J2229/20 ,  B01J2229/42 ,  C10G47/20

摘要： The invention describes a catalyst comprising at least one hydrodehydrogenating metal selected from the group formed by metals from group VIB and metals from group VIII and a support comprising at least one silica-alumina, and at least one COK-7 zeolite alone, or mixed with at least one ZBM-30 zeolite, as well as a process for hydrocracking hydrocarbon feeds employing said catalyst.

摘要翻译： 本发明描述了一种催化剂，其包含至少一种选自组VIB的金属和来自VIII族的金属形成的氢化金属和包含至少一种二氧化硅 - 氧化铝的载体和至少一种单独的COK-7沸石或与 至少一种ZBM-30沸石，以及使用所述催化剂加氢裂解烃进料的方法。

公开(公告)号：US20110120910A1

公开(公告)日：2011-05-26

申请号：US12942315

申请日：2010-11-09

申请人： Laurent Simon ,  Emmanuelle Guillon ,  Christophe Bouchy

发明人： Laurent Simon ,  Emmanuelle Guillon ,  Christophe Bouchy

IPC分类号： C10G69/02 ,  C10G47/20 ,  C10G35/04

CPC分类号： C10G45/62 ,  B01J29/106 ,  B01J29/126 ,  B01J29/166 ,  B01J35/002 ,  B01J35/1023 ,  B01J35/108 ,  B01J37/0009 ,  B01J2229/16 ,  B01J2229/20 ,  B01J2229/36 ,  B01J2229/37 ,  B01J2229/38 ,  B01J2229/42 ,  C10G45/64 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2400/04 ,  C10G2400/08 ,  Y02P30/20

摘要： This invention describes a process for the production of middle distillates from a paraffinic feedstock that is produced by Fischer-Tropsch synthesis, implementing a hydrocracking/hydroisomerization catalyst that comprises at least one hydro-dehydrogenating metal that is selected from the group that is formed by the metals of group VIB and group VIII of the periodic table and a substrate that comprises at least one dealuminified Y zeolite that has an initial overall atomic ratio of silicon to aluminum of between 2.5 and 20, a starting extra-lattice aluminum atom fraction by weight that is greater than 10%, relative to the total mass of aluminum that is present in the zeolite, a starting mesopore volume that is measured by nitrogen porosimetry that is greater than 0.07 ml.g−1, and a starting crystalline parameter ao of the elementary mesh of between 24.38 Å and 24.30 Å, whereby said zeolite is modified by a) a basic treatment stage consisting in mixing said dealuminified Y zeolite with a basic aqueous solution, and at least one heat treatment stage c).

摘要翻译： 本发明描述了一种由费 - 托合成生产的石蜡原料生产中间馏分的方法，其实施加氢裂化/加氢异构化催化剂，其包含至少一种加氢脱氢金属，其选自由 元素周期表VIB族和VIII族的金属以及包含至少一种脱铝Y沸石的底物，其具有硅与铝的初始总原子比为2.5至20，起始晶格间铝原子级分的重量比为 相对于存在于沸石中的铝的总质量大于10％，通过氮气孔率法测量的起始中孔体积大于0.07ml.g-1，并且初级晶体参数ao为初级 筛网在24.38埃至24.30埃之间，由此所述沸石通过以下步骤进行改性：a）将所述脱铝Y沸石w 碱性水溶液和至少一个热处理阶段c）。

公开(公告)号：US08791313B2

公开(公告)日：2014-07-29

申请号：US13530186

申请日：2012-06-22

申请人： Emmanuelle Guillon ,  Christophe Bouchy ,  Eric Sanchez

发明人： Emmanuelle Guillon ,  Christophe Bouchy ,  Eric Sanchez

IPC分类号： C07C5/27 ,  B01J29/74 ,  B01J37/20 ,  B01J35/00 ,  B01J37/16

CPC分类号： C07C5/2775 ,  B01J29/7446 ,  B01J35/0066 ,  B01J37/16 ,  B01J37/20 ,  B01J2229/20 ,  B01J2229/42 ,  C07C2529/72 ,  Y02P20/52 ,  C07C15/08

摘要： The invention concerns a process for the isomerization of aromatic compounds containing 8 carbon atoms per molecule in the presence of a catalyst comprising at least one zeolite with structure type EUO, wherein said process is operated in the presence of water in the feed at the end of a catalyst activation period.

摘要翻译： 本发明涉及一种在包含至少一种结构类型为EUO的沸石的催化剂存在下，每分子含有8个碳原子的芳族化合物异构化的方法，其中所述方法在进料中在水存在下在进料中在 催化剂活化期。

公开(公告)号：US08399373B2

公开(公告)日：2013-03-19

申请号：US12541540

申请日：2009-08-14

申请人： Simone Goergen ,  Loic Rouleau ,  Emmanuelle Guillon ,  Florent Guillou ,  Laurent Simon ,  Christophe Bouchy ,  Joël Patarin

发明人： Simone Goergen ,  Loic Rouleau ,  Emmanuelle Guillon ,  Florent Guillou ,  Laurent Simon ,  Christophe Bouchy ,  Joël Patarin

IPC分类号： C07C5/22 ,  B01J29/06 ,  C10G47/02

CPC分类号： B01J29/06 ,  B01J29/084 ,  B01J29/166 ,  B01J29/40 ,  B01J29/70 ,  B01J29/7023 ,  B01J29/7446 ,  B01J35/002 ,  B01J35/10 ,  B01J35/1038 ,  B01J35/1066 ,  B01J2229/186 ,  B01J2229/64 ,  C10G47/16 ,  C10G49/08

摘要： The invention describes a porous composite material that comprises a porous substrate based on a refractory inorganic oxide in which said substrate has a zeolite crystal content that is less than 25% by mass, whereby said crystals are dispersed homogeneously in the pores of said substrate, and the distribution coefficient that is measured by Castaing microprobe is between 0.75 and 1.25, and in which the total pore volume of said substrate represents at least 40% of the initial total pore volume of the substrate, and the mean diameter of the pores represents at least 50% of the mean diameter of the pores of the initial substrate, its process for preparation and its use as catalyst in the hydrocarbon feedstock conversion reactions.

摘要翻译： 本发明描述了一种多孔复合材料，其包括基于难熔无机氧化物的多孔基材，其中所述基材的沸石晶体含量小于25质量％，由此所述晶体均匀地分散在所述基材的孔中，以及 由Castaing微探针测量的分布系数在0.75和1.25之间，其中所述基材的总孔体积占基材初始总孔体积的至少40％，孔的平均直径至少表示 初始底物的孔的平均直径的50％，其制备方法及其作为烃原料转化反应中的催化剂。

公开(公告)号：US08282815B2

公开(公告)日：2012-10-09

申请号：US12490647

申请日：2009-06-24

申请人： Christophe Bouchy ,  Antoíne Daudin ,  Emmanuelle Guillon ,  Nathalie Dupassieux ,  Thierry Chapus

发明人： Christophe Bouchy ,  Antoíne Daudin ,  Emmanuelle Guillon ,  Nathalie Dupassieux ,  Thierry Chapus

IPC分类号： C10G35/09 ,  C10G35/095

CPC分类号： C10G65/043 ,  C10G3/46 ,  C10G3/50 ,  C10G3/54 ,  C10G45/02 ,  C10G45/08 ,  C10G45/64 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/202 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2300/4018 ,  Y02P30/20

摘要： The invention relates to a method of treating feedstocks from renewable sources without intermediate gas-liquid separation in order to produce diesel fuel bases of excellent quality. The feedstocks used can be raw vegetable oils or such oils that have been previously subjected to a prerefining stage, animal fats, or mixtures of such feedstocks. The invention relates to a method allowing high diesel fuel base yields to be obtained from such feedstocks.

摘要翻译： 本发明涉及一种从可再生能源处理原料而不进行中间气液分离的方法，以生产质量优良的柴油燃料基料。 所使用的原料可以是先前经受预精制阶段，动物脂肪或这些原料的混合物的生植物油或这种油。 本发明涉及允许从这些原料获得高柴油燃料碱产率的方法。

公开(公告)号：US20090326290A1

公开(公告)日：2009-12-31

申请号：US12490647

申请日：2009-06-24

申请人： Christophe Bouchy ,  Antoine Daudin ,  Emmanuelle Guillon ,  Nathalie Dupassieux ,  Thierry Chapus

发明人： Christophe Bouchy ,  Antoine Daudin ,  Emmanuelle Guillon ,  Nathalie Dupassieux ,  Thierry Chapus

IPC分类号： C07C5/13

CPC分类号： C10G65/043 ,  C10G3/46 ,  C10G3/50 ,  C10G3/54 ,  C10G45/02 ,  C10G45/08 ,  C10G45/64 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/202 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2300/4018 ,  Y02P30/20

摘要： The invention relates to a method of treating feedstocks from renewable sources without intermediate gas-liquid separation in order to produce diesel fuel bases of excellent quality. The feedstocks used can be raw vegetable oils or such oils that have been previously subjected to a prerefining stage, animal fats, or mixtures of such feedstocks. The invention relates to a method allowing high diesel fuel base yields to be obtained from such feedstocks.

摘要翻译： 本发明涉及一种从可再生能源处理原料而不进行中间气液分离的方法，以生产质量优良的柴油燃料基料。 所使用的原料可以是先前经受预精制阶段，动物脂肪或这些原料的混合物的生植物油或这种油。 本发明涉及允许从这些原料获得高柴油燃料碱产率的方法。

公开(公告)号：US20120330077A1

公开(公告)日：2012-12-27

申请号：US13530186

申请日：2012-06-22

申请人： Emmanuelle Guillon ,  Christophe Bouchy ,  Bric Sanchez

发明人： Emmanuelle Guillon ,  Christophe Bouchy ,  Bric Sanchez

IPC分类号： C07C5/27

CPC分类号： C07C5/2775 ,  B01J29/7446 ,  B01J35/0066 ,  B01J37/16 ,  B01J37/20 ,  B01J2229/20 ,  B01J2229/42 ,  C07C2529/72 ,  Y02P20/52 ,  C07C15/08

摘要： The invention concerns a process for the isomerization of aromatic compounds containing 8 carbon atoms per molecule in the presence of a catalyst comprising at least one zeolite with structure type EUO, wherein said process is operated in the presence of water in the feed at the end of a catalyst activation period.

摘要翻译： 本发明涉及一种在包含至少一种结构类型为EUO的沸石的催化剂存在下，每分子含有8个碳原子的芳族化合物异构化的方法，其中所述方法在进料中在水存在下在进料中在 催化剂活化期。

公开(公告)号：US20110180455A1

公开(公告)日：2011-07-28

申请号：US13057821

申请日：2009-07-29

申请人： Christophe Bouchy ,  Emmanuelle Guillon

发明人： Christophe Bouchy ,  Emmanuelle Guillon

IPC分类号： C10G65/02

CPC分类号： C01B39/48 ,  B01J29/74 ,  B01J29/76 ,  B01J29/78 ,  B01J35/0006 ,  B01J35/0066 ,  B01J37/0201 ,  B01J37/033 ,  B01J37/08 ,  B01J2229/42 ,  C10G2/30 ,  C10G45/62 ,  C10G45/64 ,  C10G47/16 ,  C10G47/18 ,  C10G47/20 ,  C10G65/043 ,  C10G65/12 ,  C10G2300/1022 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2400/04

摘要： The invention relates to a process for producing middle distillates from a paraffinic feedstock produced by Fischer-Tropsch synthesis, implementing a hydrocracking/hydroisomerisation catalyst comprising at least one hydro-dehydrogenating metal selected from the group formed by the metals from group VIB and from group VIII of the periodic table and a substrate comprising at least one crystallised IZM-2 solid having a chemical composition, expressed on an anhydrous base, in terms of oxide moles, by the following general formula: XO2:aY2O3:bM2/nO, wherein X represents at least one tetravalent element, Y represents at least one trivalent element and M is at least one alkali metal and/or an alkaline earth metal of valency n, a and b representing respectively the number of moles of Y2O3 and M2/nO and a is between 0 and 0.5 and b is between 0 and 1.

摘要翻译： 本发明涉及由费 - 托合成生产的石蜡原料生产中间馏分的方法，其实施加氢裂化/加氢异构化催化剂，其包含至少一种加氢脱氢金属，其选自由VIB族金属和VIII族 和包含至少一种具有化学组成的结晶的IZM-2固体的底物，其以无水碱表示，以氧化物摩尔数表示，通过以下通式：XO 2：aY 2 O 3 :bM 2 / nO，其中X表示 至少一种四价元素，Y表示至少一种三价元素，M是至少一种碱金属和/或碱土金属的化合价n，a和b分别代表Y2O3和M2 / nO的摩尔数，a是 在0和0.5之间，b在0和1之间。

公开(公告)号：US08679323B2

公开(公告)日：2014-03-25

申请号：US12942315

申请日：2010-11-09

申请人： Laurent Simon ,  Emmanuelle Guillon ,  Christophe Bouchy

发明人： Laurent Simon ,  Emmanuelle Guillon ,  Christophe Bouchy

IPC分类号： C10G47/20 ,  B01J29/10

CPC分类号： C10G45/62 ,  B01J29/106 ,  B01J29/126 ,  B01J29/166 ,  B01J35/002 ,  B01J35/1023 ,  B01J35/108 ,  B01J37/0009 ,  B01J2229/16 ,  B01J2229/20 ,  B01J2229/36 ,  B01J2229/37 ,  B01J2229/38 ,  B01J2229/42 ,  C10G45/64 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2400/04 ,  C10G2400/08 ,  Y02P30/20

摘要： A process is described for the production of middle distillates from a paraffinic feedstock wherein the feedstock is subjected to hydrocracking and/or hydro-isomerization in the presence of a hydrocracking/hydro-isomerization catalyst. The catalyst comprises at least one hydro-dehydrogenating metal selected from metals of groups VIB and VIII, and a substrate that comprises at least one dealuminified Y zeolite. The dealuminified Y zeolite is modified by a basic treatment stage wherein the dealuminified Y zeolite is mixed with a basic aqueous solution, and at least one heat treatment stage.

摘要翻译： 描述了从石蜡原料生产中间馏分的方法，其中原料在加氢裂化/加氢异构化催化剂存在下进行加氢裂化和/或加氢异构化。 该催化剂包含至少一种选自VIB和VIII族金属的氢化脱氢金属，以及包含至少一种脱铝Y沸石的底物。 脱铝Y沸石通过碱处理阶段进行改性，其中脱铝Y沸石与碱性水溶液和至少一个热处理阶段混合。