摘要:
An after-treatment system includes, in series along an exhaust gas flow direction through the after-treatment system: a diesel oxidation catalyst (DOC) or a passive NOx adsorber (PNA), a diesel exhaust fluid (DEF) delivery device, a soot-reducing device and a selective catalytic reduction (SCR) catalyst, which may also include an additional PNA.
摘要:
A catalyst device has a wall flow-type substrate. The substrate is formed of a porous base material. An SCR catalyst for reduction of NOx is supported in pores in the interior of the base material. The surface of the base material on a diesel engine side is coated with a trapping layer that traps PM in an exhaust gas. The surface of the substrate on a side opposite to the diesel engine side is coated with an oxidation catalyst layer that is formed of an oxidation catalyst.
摘要:
An exhaust gas purification material according to the present invention is provided with a particulate filter 10 that traps particulate matter in exhaust gas and contains an SCR catalyst for adsorbing ammonia and reducing NOx in the exhaust gas. A maximum allowable adsorption amount of ammonia adsorbable by the filter 10 differs between an upstream portion 10a of the filter 10 including an exhaust gas inlet-side end 10c, and a downstream portion 10b of the filter 10 including an exhaust gas outlet-side end 10d. The SCR catalyst contained in the upstream portion 10a and the SCR catalyst contained in the downstream portion 10b are qualitatively different. A ratio (B/A) of a maximum allowable adsorption amount of ammonia A in the upstream portion 10a and a maximum allowable adsorption amount of ammonia B in the downstream portion 10b satisfies the relationship 1.1≤(B/A)≤2.
摘要:
A method for treatment of a gas having 10 to 0.5% by volume of at least one of COS and CS2, and 30 ppm to 5% by volume of unsaturated hydrocarbons: a) hydrogenation of organic compounds unsaturated with respect to paraffins by contacting the gas with a hydrogenation catalyst in the presence of hydrogen at 100 to 400° C., to provide an effluent that is low in unsaturated hydrocarbon compounds, the hydrogenation catalyst having at least one metal that is palladium, platinum, nickel, or cobalt deposited on a porous substrate. b) catalytic hydrolysis-hydrogenation in the presence of water of COS and/or CS2 present in the effluent of a) to provide an H2S-rich effluent by bringing the effluent from a) into contact with a hydrolysis-hydrogenation catalyst.
摘要:
The invention relates to an ammonia gas generator for producing ammonia from an ammonia precursor substance as well as the use thereof in exhaust aftertreatment systems. The invention further relates to a method for producing ammonia gas to reduce nitrogen oxides in exhaust gases, in particular combustion gases from internal combustion engines such as diesel engines.
摘要:
The present invention relates to a method for generating ammonia from an ammonia precursor substance and to the use thereof for reducing nitrogen oxides in exhaust from industrial facilities, from combustion engines, from gas engines, from diesel engines or from petrol engines.
摘要:
The present invention relates to a process for treating a gas containing from 10 ppm by volume to 0.5 volume % of at least one of the compounds COS and CS2 and from 30 ppm by volume to 5 volume % of unsaturated hydrocarbon compounds, the said process comprising the following stages:(a) a hydrogenation of the unsaturated organic compounds to paraffins is carried out by contacting the said gas with a hydrogenation catalyst in the presence of hydrogen, (b) a catalytic hydrolysis of COS and/or CS2 present in the gaseous effluent from stage a) is carried out in the presence of water and a hydrolysis catalyst.
摘要:
An exhaust gas purification method which is capable of purifying nitrogen oxide to be included in exhaust gas from a lean burn engine such as a boiler, a gas turbine or a lean-burn-type gasoline engine, a diesel engine, effectively, in particular, even at low temperature, with spray-supplying an aqueous solution of urea as the reducing component to the selective reduction catalyst.The exhaust gas purification method for reducing selectively NOx in exhaust gas, which is exhausted from a lean burn engine, with a selective reduction catalyst and ammonia, characterized in that an aqueous solution of urea is spray-supplied to the selective reduction catalyst, comprising at least the following zeolite (A) and the hydrolysis promotion component of urea (B), and it is contacted at 150 to 600° C., and ammonia is generated in a ratio of [NH3/NOx=0.5 to 1.5] to NOx in exhaust gas, as converted to ammonia, and a nitrogen oxide is decomposed into nitrogen and water. zeolite (A): zeolite comprising an iron element hydrolysis promotion component (B): a complex oxide comprising at least one kind selected from titania or titanium, zirconium, tungsten, silicon or alumina
摘要翻译:一种排气净化方法,其特征在于,能够从诸如锅炉,燃气轮机或稀燃型汽油发动机的柴油发动机,柴油发动机中净化包含在废气中的氮氧化物, 即使在低温下也可以向选择还原催化剂喷雾供应尿素水溶液作为还原组分。 一种废气净化方法,用于选择性还原催化剂和氨,从贫燃发动机排出的废气中选择性地还原NOx,其特征在于向选择性还原催化剂喷射供给尿素水溶液, 至少以下的沸石(A)和尿素(B)的水解促进成分,并且在150〜600℃下接触,以[NH 3 / NO x = 0.5〜1.5]的比例生成氨与NOx 废气转化为氨,氮氧化物分解成氮和水。 沸石(A):包含铁元素水解促进组分的沸石(B):包含选自二氧化钛或钛,锆,钨,硅或氧化铝中的至少一种的复合氧化物
摘要:
Exhaust gas aftertreatment system for internal combustion engines operated with a lean mixture, wherein nitrogen oxides are reduced by an SCR catalyst, and particulates are removed by a particle separator or filter. A thermolysis catalyst is located near the engine in the exhaust gas split stream downstream of the supply point of the reducing agent. At temperatures above 135° C., this thermolysis catalyst vaporizes the water component of the aqueous urea solution. It contains a catalyst material that is thermally stable at exhaust gas temperatures occurring near the engine and preferentially reacts with the urea to form isocyanic acid. A hydrolysis catalyst is located in the exhaust gas stream downstream of the return of the split stream into the main stream of exhaust gas. The hydrolysis catalyst converts the isocyanic acid formed during thermolysis to ammonia and carbon dioxide using water vapor formed in the thermolysis catalyst.