摘要:
This invention concerns a time-effective method of manufacture for a sodium ferrierite precursor of a hydrogen ferrierite catalytic composition of matter by crystallizing an aqueous mixture of sodium hydroxide, an aluminum compound, a silicon compound and a nitrogen-containing compound, which mixture possesses 1.60 to 3.40 moles of sodium oxide and 0.70 to 1.60 moles of aluminum oxide per 25 moles of silicon oxide. The ultimate use of the resultant catalyst is for removing wax from a lubricating oil (preferably a light lubricating oil) with or without the metals of Group VIII and/or Group VIB used in association with the catalyst.
摘要:
New ferrierites are disclosed as well as their process of manufacture.According to the invention, these new ferrierites are characterized by:(a) The following approximate formula:M.sub.x/n (T.sup.III O.sub.2).sub.x (Si.sup.IV O.sub.2).sub.36-xwherein T.sup.III is at least one element selected from the group formed of boron (B.sup.III),aluminum (Al.sup.III),gallium (Ga.sup.III) and iron (Fe.sup.III)x ranges from 0.05 and 6.6M is a compensation cationn is the valence of M.(b) A particular X-ray diagram,(c) A fluorine content after synthesis ranging from about 0.01 to 1.6% by weight, and(d) A Si.sup.IV /T.sup.III molar ratio of at least 4.75.
摘要:
A new crystalline zeolite, designated ZSM-35, a method of making same and the use thereof in catalytic conversion of hydrocarbons is the subject of this application. The new zeolite has a composition, in the anhydrous state, expressed in terms of mole ratios of oxides as follows:(0.3-2.5)R.sub.2 O:(0-0.8)M.sub.2 O:Al.sub.2 O.sub.3 :>8 SiO.sub.2wherein R is an organic nitrogen-containing cation and M is an alkali metal cation, and is characterized by a specified X-ray powder diffraction pattern.
摘要:
Disclosed are a tandem catalyst for synthesizing methyl acetate from carbon dioxide, a method for preparing the same, and a method for preparing methyl acetate using the same. The tandem catalyst of the present invention includes a first catalyst having a core-shell structure including a composite metal oxide core and a silica shell surrounding a surface of the composite metal oxide core, and a second catalyst including nano-ferrierite (N-FER) zeolite.
摘要:
Process for the co-production of acetic acid and dimethyl ether by contacting methyl acetate and methanol in the presence of a catalyst containing a crystalline zeolite having a FER framework type. The zeolite has crystallites having a dimension of about 500 nm or less in the c-axis.
摘要:
The present disclosure comprises a new method for hydrothermal synthesis of ferrierite zeolite, using tetramethylammonium and benzylmethylpyrrodlidine as directional structure agents, and does not require a subsequent process in order to obtain the acid form of the material. This aspect is very important as it avoids subject treatments of calcination and successive interchanges which degrade the structure of the zeolite. The synthetic ferrierite obtained by means disclosed processes has uses in catalytic processes of transformation of hydrocarbons, such as cracking, isomerization, alkylation, and polymerization. Specifically, it can be used in the isomerization of butene to isobutene. To be used in catalytic processes, the zeolite ferrierite must be heated in an oxidant atmosphere in conditions such that the organic material occluded in the interior is eliminated.
摘要:
Colloidal crystalline molecular sieve seeds are used in phosphorus-containing crystalline molecular sieve manufacture. Certain of the products have enhanced utility in oxygenate conversions.
摘要:
Crystalline molecular sieve particles of a size suitable for use as seeds in molecular sieve manufacture are obtained by washing larger particle sized product to dislodge smaller particles from the larger.
摘要:
This invention relates to a new and improved form of crystalline silicate identified as zeolite ZSM-35, to a new and useful improvement in synthesizing said crystalline silicate and to use of said crystalline silicate prepared in accordance herewith as a catalyst for organic compound, e.g. hydrocarbon compound, conversion.
摘要:
An improved process is disclosed for producing alumino-silicates having a porous structure, of the zeolite class, the process essentially comprising the step of preparing a homogeneous aqueous mixture containing a source of alumina, a source of silica and alkali metal bases and/or alkaline earth metal bases, the improvement consisting in adding to said mixture at least one substance which contains at least a hydroxyl group in its molecule. The advantages are that the use of nitrogenous organic substances, universally used heretofore for the preparation of certain zeolites, can be dispensed with inasmuch as the alkali metal ion is capable, alone, of displaying the counter-ion function.