公开(公告)号：US08741127B2

公开(公告)日：2014-06-03

申请号：US12967199

申请日：2010-12-14

申请人： Omer Refa Koseoglu ,  Abdennour Bourane ,  Farhan M. Al-Shahrani ,  Emad Al-Shafi

发明人： Omer Refa Koseoglu ,  Abdennour Bourane ,  Farhan M. Al-Shahrani ,  Emad Al-Shafi

IPC分类号： C10G45/00

CPC分类号： C10G45/22 ,  B01J19/006 ,  B01J19/18 ,  B01J2219/00768 ,  B01J2219/00777 ,  C10G21/00 ,  C10G21/16 ,  C10G21/20 ,  C10G21/27 ,  C10G27/04 ,  C10G27/12 ,  C10G27/14 ,  C10G45/02 ,  C10G53/04 ,  C10G53/14 ,  C10G67/04 ,  C10G67/0418 ,  C10G67/12 ,  C10G67/14 ,  C10G2300/1096 ,  C10G2300/202 ,  C10G2300/44

摘要： Reduction of sulfur-containing and nitrogen-containing compounds from hydrocarbon feeds is achieved by first contacting the entire feed with a hydrotreating catalyst in a hydrotreating reaction zone operating under mild conditions to convert the labile organosulfur and organonitrogen compounds. An extraction zone downstream of the hydrotreating reaction zone separates an aromatic-rich fraction that contains a substantial amount of the remaining refractory organosulfur and organonitrogen compounds. The aromatic-lean fraction is substantially free of organosulfur and organonitrogen compounds, since the non-aromatic organosulfur and organonitrogen compounds were the labile organosulfur and organonitrogen compounds which were initially removed by mild hydrotreating. The aromatic-rich fraction is oxidized to convert the refractory organosulfur and organonitrogen compounds to oxidized sulfur-containing and nitrogen-containing hydrocarbon compounds. These oxidized organosulfur and organonitrogen compounds are subsequently removed.

摘要翻译： 通过在温和条件下操作的加氢处理反应区中首先使整个进料与加氢处理催化剂接触，以使不稳定的有机硫和有机氮化合物转化，从而进一步从烃进料中还原含硫和含氮化合物。 在加氢处理反应区下游的萃取区分离富含芳烃的级分，其中含有大量剩余的难熔有机硫和有机氮化合物。 芳香族贫馏分基本上不含有机硫和有机氮化合物，因为非芳族有机硫和有机氮化合物是不稳定的有机硫和有机氮化合物，最初通过轻度加氢处理除去。 氧化富含芳烃的级分将难熔有机硫和有机氮化合物转化为氧化的含硫和含氮烃化合物。 随后除去这些氧化的有机硫和有机氮化合物。

公开(公告)号：US20130026068A1

公开(公告)日：2013-01-31

申请号：US13556343

申请日：2012-07-24

申请人： Omer Refa KOSEOGLU

发明人： Omer Refa KOSEOGLU

IPC分类号： C10G47/02

CPC分类号： C10G67/14 ,  B01J8/22 ,  B01J2208/00283 ,  B01J2208/00539 ,  C10G45/04 ,  C10G45/16 ,  C10G45/20 ,  C10G45/22 ,  C10G47/00 ,  C10G47/26 ,  C10G47/30 ,  C10G49/12 ,  C10G2300/4081 ,  C10G2400/02 ,  C10G2400/04

摘要： An improved system and method for processing feedstocks in an ebullated-bed hydroprocessing reactor is provided in which hydrogen gas is dissolved in the fresh and recycled liquid feedstock by mixing and/or diffusion of an excess of hydrogen, followed by flashing of the undissolved hydrogen upstream of the reactor inlet, introduction of the feed containing dissolved hydrogen into the ebullated-bed hydroprocessing reactor whereby the dissolved hydrogen eliminates or minimizes the prior art problems of gas hold-up and reduced operational efficiency of the recycle pump due to the presence of excess gas in the recycle stream when hydrogen gas was introduced as a separate phase into the reactor.

公开(公告)号：US20130026067A1

公开(公告)日：2013-01-31

申请号：US13493270

申请日：2012-06-11

申请人： Omer Refa KOSEOGLU

发明人： Omer Refa KOSEOGLU

IPC分类号： C10G47/00 ,  C10G1/00

CPC分类号： C10G11/18 ,  C10G45/20 ,  C10G45/22 ,  C10G47/30 ,  C10G49/007 ,  C10G2300/202 ,  C10G2300/207 ,  C10G2400/02

摘要： A process for catalytically cracking a hydrocarbon oil containing sulfur and/or nitrogen hydrocarbon constituents by dissolving excess hydrogen in the liquid hydrocarbon feedstock in a mixing zone at a temperature of 420° C. to 500° C. and a hydrogen-to-feedstock oil volumetric ratio of 300:1 to 3000:1, flashing the mixture to remove remaining hydrogen and any light components in the feed, introducing the hydrogen saturated hydrocarbon feed into an FCC reactor for contact with a catalyst suspension in a riser or downflow reactor to produce lower boiling hydrocarbon components which can be more efficiently and economically separated into lower molecular weight hydrocarbon products, hydrogen sulfide and ammonia gas and unreacted hydrogen in a separation zone. Hydrogen present in the liquid phase enhances the desulfurization and denitrification reactions which occur during the conversion process and allows for the removal of significantly more sulfur- and/or nitrogen-containing contaminants from the feedstock in an economical fashion.

摘要翻译： 一种通过在420℃至500℃的温度下将过量的氢溶解在液态烃原料的混合区中，将含硫和/或氮烃成分的烃油催化裂解的方法，以及氢至原料油 体积比为300:1至3000:1，闪蒸混合物以除去进料中的剩余氢气和任何轻组分，将氢饱和烃进料引入FCC反应器中以与提升管或下流式反应器中的催化剂悬浮液接触以产生 较低沸点的烃组分可以更有效和经济地分离成较低分子量的烃产物，硫化氢和氨气以及分离区中的未反应的氢。 存在于液相中的氢增强了在转化过程中发生的脱硫和脱氮反应，并允许以经济的方式从原料中除去显着更多的含硫和/或含氮污染物。

公开(公告)号：US08350108B2

公开(公告)日：2013-01-08

申请号：US12548963

申请日：2009-08-27

申请人： Randy D. Cortright ,  Paul G. Blommel ,  Michael J. Werner ,  Matthew R. Vanstraten

发明人： Randy D. Cortright ,  Paul G. Blommel ,  Michael J. Werner ,  Matthew R. Vanstraten

IPC分类号： C07C2/54 ,  C07C1/24

CPC分类号： C07C27/12 ,  B01J21/06 ,  B01J21/066 ,  B01J23/6567 ,  B01J29/46 ,  B01J2229/20 ,  B01J2229/42 ,  C01B3/323 ,  C01B2203/0233 ,  C01B2203/062 ,  C01B2203/1211 ,  C10G3/45 ,  C10G3/46 ,  C10G3/47 ,  C10G3/48 ,  C10G3/49 ,  C10G3/52 ,  C10G29/205 ,  C10G45/02 ,  C10G45/06 ,  C10G45/08 ,  C10G45/22 ,  C10G45/60 ,  C10G45/62 ,  C10G45/64 ,  C10G69/123 ,  C10G2300/1011 ,  C10G2300/1014 ,  C10G2300/42 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  C10G2400/20 ,  C10G2400/22 ,  Y02P20/52 ,  Y02P20/588

摘要： Processes and reactor systems are provided for the conversion of oxygenated hydrocarbons to paraffins useful as liquid fuels. The process involves the conversion of water soluble oxygenated hydrocarbons to oxygenates, such as alcohols, furans, ketones, aldehydes, carboxylic acids, diols, triols, and/or other polyols, followed by the subsequent conversion of the oxygenates to paraffins by dehydration and alkylation. The oxygenated hydrocarbons may originate from any source, but are preferably derived from biomass.

摘要翻译： 提供了将氧化烃转化为可用作液体燃料的石蜡的方法和反应器系统。 该方法包括将水溶性氧化烃转化为含氧化合物，例如醇，呋喃，酮，醛，羧酸，二醇，三醇和/或其它多元醇，随后通过脱水和烷基化将含氧化合物转化为链烷烃 。 氧化烃可以源于任何来源，但优选来自生物质。

公开(公告)号：US20120047793A1

公开(公告)日：2012-03-01

申请号：US12872762

申请日：2010-08-31

申请人： Vedula Kasipati Murty ,  Donald Eizenga ,  Charles P. Luebke ,  Samarjit Singh

发明人： Vedula Kasipati Murty ,  Donald Eizenga ,  Charles P. Luebke ,  Samarjit Singh

IPC分类号： C10L1/10 ,  B01J8/00

CPC分类号： B01D53/1487 ,  B01D2252/205 ,  B01D2257/7022 ,  B01D2257/7025 ,  C10G3/42 ,  C10G3/52 ,  C10G45/22 ,  C10G49/007 ,  Y02C20/20 ,  Y02E50/13 ,  Y02P30/20

摘要： Systems and methods for treating hydrogen recycle gas in a process for converting biorenewable feedstock into green diesel fuel are provided. Sponge oil is provided. Hydrogen recycle gas produced during the process is contacted with the sponge oil. The sponge oil and hydrogen recycle gas are contacted in a contact drum and propane and other light hydrocarbons from the hydrogen recycle gas are absorbed into the sponge oil producing purified recycle gas and propane-rich sponge oil. The purified recycle gas is recycled into the process and the propane-rich sponge oil is fractionated to recover propane. The sponge oil may be sour sponge oil to also sulfide a deoxygenation catalyst used in the process.

摘要翻译： 提供了在生物可再生原料转化为绿色柴油燃料的方法中处理氢循环气体的系统和方法。 提供海绵油。 在该过程中产生的氢循环气体与海绵油接触。 海绵油和氢气再循环气体在接触鼓中接触，丙烷和来自氢循环气体的其它轻烃被吸收到海绵油中产生纯化的再循环气体和富含丙烷的海绵油中。 将纯化的循环气体再循环到该方法中，并将富丙烷海绵油分馏以回收丙烷。 海绵油可以是酸性海绵油，也可以是硫化物，在该过程中使用脱氧催化剂。

公开(公告)号：US07429318B2

公开(公告)日：2008-09-30

申请号：US11438059

申请日：2006-05-18

申请人： Ian A. Cody ,  William J. Murphy ,  Sylvain Hantzer ,  David W. Larkin ,  John E. Gallagher, Jr. ,  Jeenok T. Kim

发明人： Ian A. Cody ,  William J. Murphy ,  Sylvain Hantzer ,  David W. Larkin ,  John E. Gallagher, Jr. ,  Jeenok T. Kim

IPC分类号： C10G71/00 ,  C10G47/02

CPC分类号： B01J29/7461 ,  B01J29/041 ,  B01J29/068 ,  B01J29/74 ,  B01J37/12 ,  B01J2229/12 ,  B01J2229/34 ,  B01J2229/42 ,  C10G45/02 ,  C10G45/22 ,  C10G45/58 ,  C10G45/60 ,  C10G45/62 ,  C10G45/64 ,  C10G65/043

摘要： A process for preparing high VI lubricating oil basestocks comprising hydrotreating, hydrodewaxing and optionally hydrofinishing. The hydrotreated feedstock is hydrodewaxed using a dewaxing catalyst that has been selectively activated by oxygenate treatment. The hydrodewaxed product may then be hydrofinished.

摘要翻译： 一种制备高VI润滑油基础油料的方法，包括加氢处理，加氢脱蜡和任选加氢精制。 加氢处理的原料使用已经通过含氧化合物处理选择性活化的脱蜡催化剂进行加氢脱蜡。 然后将加氢脱蜡产品加氢处理。

公开(公告)号：US20050040073A1

公开(公告)日：2005-02-24

申请号：US10678680

申请日：2003-10-03

申请人： Ian Cody ,  William Murphy ,  Sylvain Hantzer ,  David Larkin ,  John Gallagher ,  Jeenok Kim

发明人： Ian Cody ,  William Murphy ,  Sylvain Hantzer ,  David Larkin ,  John Gallagher ,  Jeenok Kim

IPC分类号： B01J29/04 ,  B01J29/74 ,  C10G45/02 ,  C10G45/22 ,  C10G45/58 ,  C10G45/60 ,  C10G45/62 ,  C10G45/64 ,  C10G65/04 ,  C10G69/02

CPC分类号： B01J29/7461 ,  B01J29/041 ,  B01J29/068 ,  B01J29/74 ,  B01J37/12 ,  B01J2229/12 ,  B01J2229/34 ,  B01J2229/42 ,  C10G45/02 ,  C10G45/22 ,  C10G45/58 ,  C10G45/60 ,  C10G45/62 ,  C10G45/64 ,  C10G65/043

摘要： A process for preparing high VI lubricating oil basestocks comprising hydrotreating, hydrodewaxing and optionally hydrofinishing. The hydrotreated feedstock is hydrodewaxed using a dewaxing catalyst that has been selectively activated by oxygenate treatment. The hydrodewaxed product may then be hydrofinished.

摘要翻译： 一种制备高VI润滑油基础油料的方法，包括加氢处理，加氢脱蜡和任选加氢精制。 加氢处理的原料使用已经通过含氧化合物处理选择性活化的脱蜡催化剂进行加氢脱蜡。 然后将加氢脱蜡产品加氢处理。

公开(公告)号：US3714028A

公开(公告)日：1973-01-30

申请号：US3714028D

申请日：1970-11-23

申请人： UNIVERSAL OIL PROD CO

发明人： HALLMAN N

IPC分类号： C10G45/22 ,  C10G13/02 ,  C10G13/04

CPC分类号： C10G45/22

摘要： Hydroprocessing is effected by contacting the hydrocarbon with hydrogen in a low pressure, vapor-liquid contacting zone maintained under conditions sufficient to dissolve at least a portion of the hydrogen, with the resultant hydrocarbon liquid containing dissolved hydrogen being passed to a high temperature, high pressure reaction zone.

摘要翻译： 通过在保持在足以溶解至少一部分氢气的条件下保持的低压气 - 液接触区中使烃与氢接触来进行加氢处理，所得到的含有溶解氢的烃液体通过高温高压 反应区。

公开(公告)号：US20240150662A1

公开(公告)日：2024-05-09

申请号：US18417569

申请日：2024-01-19

申请人： Magema Technology LLC

发明人： Michael Joseph Moore ,  Bertrand Ray Klussmann ,  Carter James White

IPC分类号： C10G45/04 ,  B01D3/34 ,  B01D53/14 ,  B01J8/00 ,  B01J8/02 ,  B01J8/04 ,  B01J21/04 ,  B01J23/24 ,  B01J23/40 ,  B01J23/74 ,  C10G7/00 ,  C10G25/00 ,  C10G25/02 ,  C10G45/02 ,  C10G45/06 ,  C10G45/08 ,  C10G45/22 ,  C10G47/02 ,  C10G65/04 ,  C10G65/16 ,  C10G67/02 ,  C10G67/06 ,  C10G69/02 ,  C10L1/04 ,  C10L1/12 ,  C10L1/14 ,  C10L1/16

CPC分类号： C10G45/04 ,  B01D3/343 ,  B01D53/1481 ,  B01J8/008 ,  B01J8/0278 ,  B01J8/0292 ,  B01J8/0457 ,  B01J8/0492 ,  B01J21/04 ,  B01J23/24 ,  B01J23/40 ,  B01J23/74 ,  C10G7/00 ,  C10G25/003 ,  C10G25/02 ,  C10G45/02 ,  C10G45/06 ,  C10G45/08 ,  C10G45/22 ,  C10G47/02 ,  C10G65/04 ,  C10G65/16 ,  C10G67/02 ,  C10G67/06 ,  C10G69/02 ,  C10L1/04 ,  C10L1/12 ,  C10L1/14 ,  C10L1/1608 ,  B01J2208/00557 ,  B01J2208/02 ,  B01J2208/025 ,  C10G2300/1037 ,  C10G2300/1044 ,  C10G2300/1048 ,  C10G2300/1059 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/201 ,  C10G2300/202 ,  C10G2300/205 ,  C10G2300/206 ,  C10G2300/207 ,  C10G2300/208 ,  C10G2300/30 ,  C10G2300/302 ,  C10G2300/308 ,  C10G2300/4012 ,  C10G2300/4018 ,  C10G2300/4062 ,  C10G2300/70 ,  C10G2300/80 ,  C10G2400/04 ,  C10G2400/06 ,  C10L2200/0263 ,  C10L2200/0438 ,  C10L2270/02 ,  C10L2270/026

摘要： A multi-stage process for transforming a high sulfur ISO 8217 compliant Feedstock Heavy Marine Fuel Oil involving a core desulfurizing process that produces a Product Heavy Marine Fuel Oil that can be used as a feedstock for subsequent refinery process such as anode grade coking, needle coking and fluid catalytic cracking. The Product Heavy Marine Fuel Oil exhibits multiple properties desirable as a feedstock for those processes including a sulfur level has a maximum sulfur content (ISO 14596 or ISO 8754) between the range of 0.05 mass % to 1.0 mass. A process plant for conducting the process is also disclosed.

公开(公告)号：US20230347332A1

公开(公告)日：2023-11-02

申请号：US18128919

申请日：2023-03-30

申请人： Instituo Mexicano del Petróleo

发明人： Gustavo Jesús Marroquín Sánchez ,  Pedro Martín Vega Merino ,  Carlos Cureño Rodríguez ,  Patricia Rayo Mayoral ,  Salvador Castillo Cervantes ,  José Antonio Toledo Antonio ,  Jorge Ancheyta Juárez ,  Magally Cruz Juárez

IPC分类号： B01J37/08 ,  C10G45/22

CPC分类号： B01J37/08 ,  C10G45/22 ,  B01J2203/00 ,  C10G2300/1048 ,  C10G2300/703

摘要： The present invention deals with activation and start-up procedures of catalysts for the deep HDS of middle distillates for producing ultra low sulfur diesel (ULSD), consisting of two in situ activation stages: at stage 1, TGA is applied, and at stage 2, DMDS is used; kerosene is the transport means at these stages, which are carried out under given temperature and pressure conditions, and feedstock and hydrogen flows at established times. After the activation of the catalyst in situ, the stabilization stage takes place under selected temperature and pressure conditions, feedstock and hydrogen flow at established times, with which the stabilization of the highly dispersed metallic sulfides is achieved and, in this way, the activity of the catalysts removing contaminants for the production of ULSD is increased.