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公开(公告)号：US06093865A
公开(公告)日：2000-07-25
申请号：US98237
申请日：1998-06-16
CPC分类号： C07C2/52 , C07C4/04 , C07C2102/42 , C07C2103/68 , Y10S585/905
摘要： The present invention relates to a method for using a single distillation column to recover the reactants and products from the reaction of a cyclic diolefin and an olefin to produce an alkenyl bridged ring compound.
摘要翻译： 本发明涉及使用单一蒸馏塔从环状二烯烃与烯烃的反应中回收反应物和产物以产生链烯基桥环化合物的方法。
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公开(公告)号：US09365467B2
公开(公告)日：2016-06-14
申请号：US13883742
申请日：2011-12-02
CPC分类号： C07C2/74 , C07C5/367 , C07C6/126 , C07C2521/08 , C07C2523/14 , C07C2523/42 , C07C2601/08 , C07C2601/14 , C07C13/28
摘要： In a process for producing cyclohexylbenzene, benzene is contacted with hydrogen under hydroalkylation conditions effective to form a first effluent stream comprising cyclohexylbenzene, cyclohexane, methylcyclopentane, and unreacted benzene. At least a portion of the first effluent stream is contacted with a dehydrogenation catalyst under dehydrogenation conditions to convert at least a portion of the cyclohexane to benzene thereby forming a second effluent stream. The amount of methylcyclopentane in the second effluent stream is different by no more than 65% of the total amount of the portion of the first effluent stream, said amounts being on a weight basis. A methylcyclopentane-containing stream is removed from either the first or the second effluent stream and at least a portion of the second effluent stream containing benzene is recycled to the hydroalkylation step.
摘要翻译： 在生产环己基苯的方法中，苯在有效形成包含环己基苯，环己烷，甲基环戊烷和未反应苯的第一流出物流的加氢烷基化条件下与氢气接触。 在脱氢条件下，将至少一部分第一流出物流与脱氢催化剂接触以将至少一部分环己烷转化为苯，从而形成第二流出物流。 第二流出物流中的甲基环戊烷的量不同于第一流出物流的部分总量的不超过65％，所述量基于重量。 从第一或第二流出物流中除去含甲基环戊烷的物流，并将含有苯的第二流出物流的至少一部分再循环至加氢烷基化步骤。
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公开(公告)号：US09181146B2
公开(公告)日：2015-11-10
申请号：US13465721
申请日：2012-05-07
CPC分类号： C07C2/864 , C10G9/005 , C10G9/36 , C10G11/00 , C10G29/205 , C10G35/00 , C10G57/005 , C10G2300/1092 , C10G2300/1096 , C10G2400/30 , C07C15/08
摘要： In a hydrocarbon upgrading process, a hydrocarbon feed is treated in at least one of a steam cracker, catalytic cracker, coker, hydrocracker, and reformer under suitable conditions to produce a first stream comprising olefinic and aromatic hydrocarbons. A second stream composed mainly of C4 to C12 olefinic and aromatic hydrocarbons is recovered from the first stream and at least part of the second stream is contacted with a catalyst in the absence of added hydrogen under reaction conditions including a temperature of about 450° C. to about 70° C. effective to dealkylate, transalkylate, crack and aromatize components of the second stream to produce a third stream having an increased benzene and/or toluene content compared with the second stream and a C3− olefin by-product. The C3− olefin by-product and a fourth stream comprising toluene are then recovered from the third stream.
摘要翻译： 在烃改质方法中，在合适条件下，在蒸汽裂化器，催化裂化器，焦化器，加氢裂化器和重整器中的至少一种中处理烃进料以产生包含烯烃和芳族烃的第一流。 在第一料流中回收主要由C4至C12烯属和芳烃组成的第二料流，并且在包括约450℃的温度的反应条件下，至少部分第二料流在不加入氢气的情况下与催化剂接触。 至约70℃有效地使第二物流的烷基化，烷基转移，裂解和芳构化成分，以产生与第二物流和C3-烯烃副产物相比具有增加的苯和/或甲苯含量的第三物流。 然后从第三流中回收C3-烯烃副产物和包含甲苯的第四料流。
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公开(公告)号：US09115105B2
公开(公告)日：2015-08-25
申请号：US14348414
申请日：2012-08-30
IPC分类号： C07D301/03 , C07C37/08 , C07D301/19 , C09K11/61 , C09K11/77 , H01J61/44 , H01L33/50 , C07C1/24 , C07C5/03 , C07C29/132 , C07C407/00
CPC分类号： C07D301/19 , C07C1/24 , C07C5/03 , C07C29/132 , C07C407/00 , C07C2601/14 , C09K11/617 , C09K11/7721 , C09K11/7734 , C09K11/7774 , C09K11/7792 , H01J61/44 , H01L33/502 , H01L2224/32245 , H01L2224/32257 , H01L2224/48091 , H01L2224/48247 , H01L2224/48257 , H01L2224/49107 , H01L2224/73265 , H01L2224/8592 , H01L2924/181 , H01L2924/00014 , H01L2924/00012 , H01L2924/00
摘要： In a process for producing propylene oxide, cyclohexylbenzene is contacted with an oxygen-containing compound under oxidation conditions with or without a suitable catalyst to produce an oxidation reaction effluent comprising cyclohexylbenzene hydroperoxide. At least a portion of the cyclohexylbenzene hydroperoxide is then reacted with propylene in the presence of an epoxidation catalyst under conditions effective to produce an epoxidation reaction effluent comprising phenylcyclohexanol and propylene oxide.
摘要翻译： 在生产环氧丙烷的方法中，环己基苯在含或不含合适催化剂的氧化条件下与含氧化合物接触以产生包含环己基苯氢过氧化物的氧化反应流出物。 然后在有效产生包含苯基环己醇和环氧丙烷的环氧化反应流出物的条件下，至少一部分环己基苯氢过氧化物在环氧化催化剂存在下与丙烯反应。
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公开(公告)号：US09115060B2
公开(公告)日：2015-08-25
申请号：US14347279
申请日：2012-08-29
IPC分类号： C07C45/53 , C07C37/08 , C07C37/07 , C07C2/74 , C07C407/00 , C07C49/403
CPC分类号： C07C37/07 , C07C2/74 , C07C37/08 , C07C45/53 , C07C49/403 , C07C407/00 , C07C2529/70 , C07C2601/14 , C07C13/28 , C07C409/14 , C07C39/04
摘要： In a process for producing phenol, cyclohexylbenzene hydroperoxide is cleaved to produce a cleavage effluent stream comprising phenol and cyclohexanone and at least a portion of the cleavage effluent stream is fractionated to produce a first fraction richer in cyclohexanone than the cleavage effluent stream portion and a second fraction richer in phenol and depleted in cyclohexanone as compared with said cleavage effluent stream portion. At least a portion of the second fraction is then contacted with a dehydrogenation catalyst in a dehydrogenation reaction zone under dehydrogenation conditions effective to convert at least a portion of the cyclohexanone in said second fraction portion into phenol and cyclohexanol.
摘要翻译： 在生产苯酚的方法中，将环己基苯氢过氧化物切割以产生包含苯酚和环己酮的裂解流出料流，并将至少一部分裂解流出物流分馏以产生比裂解流出物流部分富含环己酮的第一馏分，第二馏分 与所述裂解流出物流部分相比，苯酚中的馏分比较富含，耗尽环己酮。 然后在有效将至少一部分所述第二级分部分中的环己酮转化成苯酚和环己醇的脱氢条件下，至少部分第二馏分与脱氢催化剂在脱氢反应区中接触。
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公开(公告)号：US09017641B2
公开(公告)日：2015-04-28
申请号：US13983974
申请日：2011-11-21
CPC分类号： C01B3/22 , B01D53/1406 , B01D53/1418 , B01D53/263 , C01B3/52 , C07C37/08
摘要： In a process for purifying a hydrogen stream, the stream is contacted with a first washing fluid in a first purification zone under conditions effective to transfer at least some water from the hydrogen stream to the first washing fluid, thereby transforming the hydrogen stream into a water-depleted hydrogen stream. At least a portion of the water-depleted hydrogen stream may then be transferred from the first purification zone to a second purification zone, where it is contacted with a second washing fluid under conditions effective to transfer at least some oxygenates from the water-depleted hydrogen stream to the second washing fluid.
摘要翻译： 在纯化氢气流的方法中，在有效地将至少一些水从氢气流转移到第一洗涤流体的条件下，使该物流与第一净化区中的第一洗涤流体接触，从而将氢气流转化为水 分离的氢气流。 然后可以将至少一部分的贫水氢气流从第一纯化区转移到第二纯化区，在第二纯化区中，在有效从至少一些含氧化合物转移至水中的氢的条件下与第二洗涤流体接触 流到第二洗涤液。
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公开(公告)号：US20140371498A1
公开(公告)日：2014-12-18
申请号：US13883742
申请日：2011-12-02
CPC分类号： C07C2/74 , C07C5/367 , C07C6/126 , C07C2521/08 , C07C2523/14 , C07C2523/42 , C07C2601/08 , C07C2601/14 , C07C13/28
摘要： In a process for producing cyclohexylbenzene, benzene is contacted with hydrogen under hydroalkylation conditions effective to form a first effluent stream comprising cyclohexylbenzene, cyclohexane, methylcyclopentane, and unreacted benzene. At least a portion of the first effluent stream is contacted with a dehydrogenation catalyst under dehydrogenation conditions to convert at least a portion of the cyclohexane to benzene thereby forming a second effluent stream. The amount of methylcyclopentane in the second effluent stream is different by no more than 65% of the total amount of the portion of the first effluent stream, said amounts being on a weight basis. A methylcyclopentane-containing stream is removed from either the first or the second effluent stream and at least a portion of the second effluent stream containing benzene is recycled to the hydroalkylation step.
摘要翻译： 在生产环己基苯的方法中，苯在有效形成包含环己基苯，环己烷，甲基环戊烷和未反应苯的第一流出物流的加氢烷基化条件下与氢气接触。 在脱氢条件下，将至少一部分第一流出物流与脱氢催化剂接触以将至少一部分环己烷转化为苯，从而形成第二流出物流。 第二流出物流中的甲基环戊烷的量不同于第一流出物流的部分总量的不超过65％，所述量基于重量。 从第一或第二流出物流中除去含甲基环戊烷的物流，并将含有苯的第二流出物流的至少一部分再循环至加氢烷基化步骤。
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公开(公告)号：US08658834B2
公开(公告)日：2014-02-25
申请号：US13516414
申请日：2010-11-23
摘要： The present invention relates to a hydrogenation process that may be used in connection with the production of phenol. In the process, a composition comprising: (i) cyclohexylbenzene; and (ii) a hydrogenable component are contacted with hydrogen in the presence of a hydrogenation catalyst under hydrogenation conditions. The hydrogenable component can be one or more of an olefin, a ketone or phenol. The hydrogenation catalyst has hydrogenation component and a support.
摘要翻译： 本发明涉及可用于生产苯酚的氢化方法。 在该方法中，组合物包含：（i）环己基苯; 和（ii）可氢化组分在氢化条件下在氢化催化剂存在下与氢气接触。 可氢化组分可以是烯烃，酮或苯酚中的一种或多种。 氢化催化剂具有氢化组分和载体。
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29.发明授权公开(公告)号：US08344197B2
公开(公告)日：2013-01-01
申请号：US12894778
申请日：2010-09-30
申请人： James R. Lattner , Mark P. Hagemeister , Jon Edmond Randolph Stanat , John Di-Yi Ou , Xiaobo Zheng , Lu Han
发明人： James R. Lattner , Mark P. Hagemeister , Jon Edmond Randolph Stanat , John Di-Yi Ou , Xiaobo Zheng , Lu Han
IPC分类号： C07C2/66
CPC分类号： C07C2/864 , C07C2529/40 , Y02P20/52 , C07C15/08
摘要： In a process for the production of para-xylene, methanol is preheated to a first temperature, an aromatic feedstock comprising toluene and/or benzene is preheated to a second temperature and the preheated methanol and aromatic feedstocks are fed to a reactor at a first methanol to aromatic feedstock molar ratio. The preheated aromatic feedstock is contacted with the preheated methanol under alkylation conditions in the reactor in the presence of a catalyst so that the methanol reacts with the aromatic feedstock to produce an effluent comprising para-xylene. During the reaction, a temperature is measured within the reactor and is compared with a predetermined optimal temperature. The methanol to aromatic feedstock molar ratio is then adjusted in a manner to reduce any difference between the measured and predetermined optimal temperatures in the reactor.
摘要翻译： 在制备对二甲苯的方法中，将甲醇预热至第一温度，将包含甲苯和/或苯的芳族原料预热至第二温度，并将预热的甲醇和芳族原料以第一个甲醇 与芳烃原料摩尔比。 预热的芳族原料在催化剂存在下在反应器中在烷基化条件下与预热的甲醇接触，使得甲醇与芳族原料反应以产生包含对二甲苯的流出物。 在反应期间，在反应器内测量温度并与预定的最佳温度进行比较。 然后以降低反应器中测量的和预定的最佳温度之间的任何差异的方式调节甲醇与芳族原料的摩尔比。
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公开(公告)号：US08084648B2
公开(公告)日：2011-12-27
申请号：US12747295
申请日：2009-01-13
CPC分类号： C07C409/14 , C07C13/28 , C07C37/08 , C07C45/53 , C07C407/00 , C07C2601/14 , C07C49/08 , C07C39/04
摘要： In a process for producing cyclohexylbenzene, hydrogen and a liquid feed comprising benzene are introduced into a reaction zone and are contacted in the reaction zone under hydroalkylation conditions to produce cyclohexylbenzene. An effluent stream comprising cyclohexylbenzene and unreacted benzene is removed from the reaction zone and is divided into at least first and second portions, wherein the mass ratio of the effluent stream first portion to the effluent stream second portion is at least 2:1. The effluent stream first portion is then cooled and the cooled effluent stream first portion is recycled to the reaction zone.
摘要翻译： 在生产环己基苯的方法中，将氢和含苯的液体原料引入反应区，并在加氢烷基化条件下在反应区中接触以制备环己基苯。 将包含环己基苯和未反应苯的流出物流从反应区除去，并分成至少第一和第二部分，其中流出物流第一部分与流出物流第二部分的质量比至少为2:1。 然后将流出物流第一部分冷却，将冷却的流出物流第一部分再循环至反应区。
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