公开(公告)号：US07090081B2

公开(公告)日：2006-08-15

申请号：US10656673

申请日：2003-09-05

申请人： Stephen Neil Vaughn ,  Kenneth Ray Clem ,  Keith Holroyd Kuechler ,  James R. Lattner

发明人： Stephen Neil Vaughn ,  Kenneth Ray Clem ,  Keith Holroyd Kuechler ,  James R. Lattner

IPC分类号： B07B7/00 ,  C07C1/00

CPC分类号： B01J8/0065 ,  B01J8/0055 ,  C07C1/20 ,  C10G3/49 ,  C10G3/62 ,  C10G2300/4093 ,  C10G2400/20 ,  Y02P30/20 ,  C07C11/02

摘要： The present invention provides various processes for selectively removing undesirably sized catalyst particles from a reaction system. In one embodiment, a plurality of catalyst particles, having a first median particle diameter, is withdrawn from the reaction system and is directed to a separation unit such as a counter flow cyclone separator. In the separation unit, the particles are separated into a small catalyst stream and a large catalyst stream, the small catalyst stream having a second median particle diameter less than the first median particle diameter, and the large catalyst stream having a third median particle diameter greater than the first median particle diameter. At least a portion of the small or large catalyst stream is then directed back to the reaction system in order to maintain a desirable particle size distribution therein.

摘要翻译： 本发明提供了用于从反应体系中选择性除去不期望的尺寸的催化剂颗粒的各种方法。 在一个实施方案中，具有第一中值粒径的多个催化剂颗粒从反应体系中排出并被引导至分离单元如逆流旋风分离器。 在分离单元中，将颗粒分离成小的催化剂流和大的催化剂流，小的催化剂流具有小于第一中值粒径的第二中值粒径，并且大的催化剂流具有较大的第三中值粒径 比第一个中值粒径。 然后将至少一部分小或大的催化剂流引导回反应体系，以便在其中保持所需的粒度分布。

公开(公告)号：US07057083B2

公开(公告)日：2006-06-06

申请号：US10712952

申请日：2003-11-12

申请人： Teng Xu ,  Nicolas P. Coute ,  Kenneth Ray Clem ,  Keith H. Kuechler

发明人： Teng Xu ,  Nicolas P. Coute ,  Kenneth Ray Clem ,  Keith H. Kuechler

IPC分类号： C07C1/00

CPC分类号： C07C1/20 ,  B01J29/85 ,  C07C2529/84 ,  C07C2529/85 ,  Y02P30/42 ,  C07C11/02 ,  C07C11/08

摘要： This invention relates to processes for converting oxygenates to olefins that include a step of pretreating molecular sieve used in the conversion reaction with a C4–C7 olefin composition, which contains one or more C4–C7 olefins. Fresh or regenerated molecular sieve, which is low in carbon content, is contacted or pretreated with the olefin composition to form a hydrocarbon co-catalyst within the pore structure of the molecular sieve, and the pretreated molecular sieve containing the co-catalyst is used to convert oxygenate to a lighter olefin product.

摘要翻译： 本发明涉及将含氧化合物转化为烯烃的方法，其包括用C 4 -C 7烯烃组合物预处理转化反应中使用的分子筛的步骤，其中含有一个 或更多的C 4 -C 7烯烃。 碳含量低的新鲜或再生分子筛与烯烃组合物接触或预处理，以在分子筛的孔结构内形成烃助催化剂，并将含有助催化剂的预处理分子筛用于 将含氧化合物转化为较轻的烯烃产物。

公开(公告)号：US07053260B2

公开(公告)日：2006-05-30

申请号：US10170939

申请日：2002-06-13

申请人： Teng Xu ,  Paul N. Chisholm ,  Stephen Neil Vaughn ,  Shun Chong Fung ,  Keith Holroyd Kuechler ,  James R. Lattner ,  Kenneth Ray Clem ,  Patrick J. Maher ,  Dean C. Draemel

发明人： Teng Xu ,  Paul N. Chisholm ,  Stephen Neil Vaughn ,  Shun Chong Fung ,  Keith Holroyd Kuechler ,  James R. Lattner ,  Kenneth Ray Clem ,  Patrick J. Maher ,  Dean C. Draemel

IPC分类号： C07C1/20

CPC分类号： C10G3/49 ,  B01J29/061 ,  B01J29/068 ,  B01J29/85 ,  B01J29/90 ,  B01J35/0006 ,  B01J38/36 ,  B01J2229/186 ,  C07C2523/42 ,  C07C2529/40 ,  C07C2529/54 ,  C07C2529/85 ,  C10G3/44 ,  C10G3/45 ,  C10G3/47 ,  C10G3/62 ,  C10G2300/708 ,  C10G2400/20 ,  Y02P20/584 ,  Y02P30/20 ,  Y02P30/42

摘要： The present invention provides a process for making an olefin product from an oxygenate feedstock which comprises:a) contacting the feedstock in a reaction zone with a catalyst comprising i) a molecular sieve having defined pore openings and ii) a CO oxidation metal, under conditions effective to convert the feedstock into an olefin product stream comprising C2–C3 olefins and to form carbonaceous deposits on the catalyst so as to provide a carbon-containing catalyst;b) contacting at least a portion of the carbon-containing catalyst with a regeneration medium comprising oxygen in a regeneration zone comprising a fluid bed regenerator having a dense fluid phase and a dilute fluid phase under conditions effective to obtain a regenerated catalyst portion, wherein the difference between the temperature of the dilute phase and the temperature of the dense phase is no greater than 100° C.;c) introducing said regenerated catalyst portion into said reaction zone; andd) repeating steps a)–c).

摘要翻译： 本发明提供了一种从含氧化合物原料制备烯烃产物的方法，其包括：a）使反应区中的原料与催化剂接触，所述催化剂包括：i）具有确定的孔开口的分子筛和ii）CO氧化金属， 有效地将原料转化成包含C 2 -C 3烯烃的烯烃产物流，并在催化剂上形成碳质沉积物，以提供含碳催化剂; b）在有效获得再生催化剂部分的条件下，使至少一部分含碳催化剂与包含氧的再生介质在再生区中接触，所述再生区包括具有致密流体相和稀液相的流化床再生器，其中， 稀相温度与致密相温度之差不大于100℃。 c）将所述再生催化剂部分引入所述反应区; 和d）重复步骤a）-c）。

公开(公告)号：US07045672B2

公开(公告)日：2006-05-16

申请号：US10712668

申请日：2003-11-12

申请人： Teng Xu ,  Kenneth Ray Clem ,  Keith H. Kuechler

发明人： Teng Xu ,  Kenneth Ray Clem ,  Keith H. Kuechler

IPC分类号： C07C1/00

CPC分类号： C07C1/20 ,  B01J29/85 ,  C07C2529/84 ,  C07C2529/85 ,  Y02P20/52 ,  Y02P30/42 ,  C07C11/06 ,  C07C11/04 ,  C07C11/02

摘要： This invention relates to processes for converting oxygenates to olefins and olefins to polyolefins. The processes include a step of pretreating molecular sieve used in the conversion of oxygenate to olefin with a dimethyl ether composition. Fresh or regenerated molecular sieve, which is low in carbon content, is contacted or pretreated with the dimethyl ether composition to form a hydrocarbon co-catalyst within the pore structure of the molecular sieve, and the pretreated molecular sieve containing the co-catalyst is used to convert oxygenate to a lighter olefin product.

摘要翻译： 本发明涉及将含氧化合物转化为烯烃和烯烃到聚烯烃的方法。 该方法包括用二甲基醚组合物预处理用于将含氧化合物转化为烯烃的分子筛的步骤。 碳含量低的新鲜或再生分子筛与二甲醚组合物接触或预处理，以在分子筛的孔结构内形成烃助催化剂，并使用含有助催化剂的预处理分子筛 将含氧化合物转化为较轻的烯烃产物。

公开(公告)号：US06737556B2

公开(公告)日：2004-05-18

申请号：US10274739

申请日：2002-10-21

申请人： Jeffrey P. Jones ,  Kenneth Ray Clem ,  Stephen N. Vaughn ,  Teng Xu ,  Jeffrey L. White

发明人： Jeffrey P. Jones ,  Kenneth Ray Clem ,  Stephen N. Vaughn ,  Teng Xu ,  Jeffrey L. White

IPC分类号： C07C1207

CPC分类号： C22C19/05 ,  B01J4/002 ,  B01J19/02 ,  B01J19/26 ,  B01J2219/00119 ,  B01J2219/00155 ,  B01J2219/00252 ,  B01J2219/0218 ,  B01J2219/0236 ,  C07C1/20 ,  C22C19/058 ,  C22C30/00 ,  C22C38/02 ,  C22C38/04 ,  C22C38/06 ,  C22C38/50 ,  Y02P30/42 ,  Y10S585/92 ,  Y10S585/923 ,  C07C11/02

摘要： Disclosed is a method and system for reducing the formation of metal catalyzed side-reaction byproducts formed in the feed vaporization and introduction system of a methanol to olefin reactor system by forming and/or coating one or more of the heating devices, feed lines or feed introduction nozzles of/with a material that is resistant to the formation of metal catalyzed side reaction byproducts. The invention also may include monitoring and/or maintaining the temperature of at least a portion of the feed vaporization and introduction system and/or of the feedstock contained therein below about 400° C., 350° C., 300° C., 250° C., 200° C. or below about 150° C. The temperature can be maintained in the desired range by jacketing at least a portion of the feed vaporization and introduction system, such as at least a portion of the feed introduction nozzle, with a thermally insulating material or by implementing a cooling system.

公开(公告)号：US06699811B1

公开(公告)日：2004-03-02

申请号：US09565975

申请日：2000-05-05

申请人： Gary David Mohr ,  Kenneth Ray Clem ,  Wilfried Jozef Mortier ,  Machteld Maria Mertens ,  Xiaobing Feng ,  Marc H. Anthonis ,  Bart Schoofs

发明人： Gary David Mohr ,  Kenneth Ray Clem ,  Wilfried Jozef Mortier ,  Machteld Maria Mertens ,  Xiaobing Feng ,  Marc H. Anthonis ,  Bart Schoofs

IPC分类号： B01J2906

CPC分类号： B01J29/7042 ,  B01J29/06 ,  B01J29/40 ,  B01J29/80 ,  B01J29/87 ,  B01J29/89 ,  B01J37/0009 ,  B01J2229/42 ,  B01J2229/62 ,  C10G11/05 ,  C10G29/205 ,  C10G45/64

摘要： There is provided a zeolite bound zeolite catalyst which does not contain significant amount of non-zeolitic binder and can be tailored to optimize its performance and a process for converting hydrocarbons utilizing the zeolite bound zeolite catalyst. The zeolite bound zeolite catalyst comprises core crystals containing first crystals of a first zeolite and optionally second crystals of a second zeolite having a composition, structure type, or both that is different from said first zeolite and binder crystals containing third crystals of a third zeolite and optionally fourth crystals of a fourth zeolite having a composition, structure type, or both that is different from said third zeolite. If the core crystals do not contain the second crystals of the second zeolite, then the binder crystals must contain the fourth crystals of the fourth zeolite. The zeolite bound zeolite finds application in hydrocarbon conversion processes, e.g., catalytic cracking, alkylation, disproportional of toluene, isomerization, and transalkylation reactions.

公开(公告)号：US06198013B1

公开(公告)日：2001-03-06

申请号：US09058751

申请日：1998-04-10

申请人： Gary David Mohr ,  Tan Jen Chen ,  Kenneth Ray Clem ,  Mechilium Johannes Gerardus Janssen ,  Philip Andrew Ruziska ,  Johannes Petrus Verduijn

发明人： Gary David Mohr ,  Tan Jen Chen ,  Kenneth Ray Clem ,  Mechilium Johannes Gerardus Janssen ,  Philip Andrew Ruziska ,  Johannes Petrus Verduijn

IPC分类号： C07C522

CPC分类号： C10G45/64 ,  B01J29/40 ,  B01J29/70 ,  B01J29/80 ,  B01J37/0009 ,  B01J37/0246 ,  B01J2229/26 ,  B01J2229/42 ,  C07C1/20 ,  C07C2/00 ,  C07C2/66 ,  C07C5/2708 ,  C07C5/2724 ,  C07C6/123 ,  C07C6/126 ,  C07C2529/08 ,  C07C2529/40 ,  C07C2529/65 ,  C07C2529/70 ,  C07C2529/80 ,  C07C2529/87 ,  C07C2529/89 ,  C10G11/05 ,  C10G35/095 ,  Y02P20/52 ,  Y02P30/20 ,  Y02P30/42 ,  C07C15/00 ,  C07C15/02 ,  C07C15/067

摘要： There is provided a process for converting hydrocarbons which utilizes a zeolite bound zeolite catalyst that has enhanced performance when utilized in hydrocarbon conversion processes, e.g., catalytic cracking, alkylation, disproportionation of toluene, isomerization, and transalkylation reactions. The catalyst comprises a first zeolite having particles of greater than about 0.1 micron average particle size and a binder comprising second zeolite particles having an average particle size less than said first particles.

摘要翻译： 提供了一种用于转化烃的方法，其利用沸石结合的沸石催化剂，当用于烃转化过程（例如催化裂化，烷基化，甲苯歧化，异构化和烷基转移反应）时，具有增强的性能。 催化剂包括具有大于约0.1微米平均粒度的颗粒的第一沸石和包含平均粒度小于所述第一颗粒的第二沸石颗粒的粘合剂。

公开(公告)号：US5993642A

公开(公告)日：1999-11-30

申请号：US561674

申请日：1995-11-22

申请人： Gary David Mohr ,  Tan Jen Chen ,  Kenneth Ray Clem ,  Mechilium Johannes Geradus Janssen ,  Phillip Andrew Ruziska ,  Johannes Petrus Verduijn ,  Jannetje Maatje van den Berge

发明人： Gary David Mohr ,  Tan Jen Chen ,  Kenneth Ray Clem ,  Mechilium Johannes Geradus Janssen ,  Phillip Andrew Ruziska ,  Johannes Petrus Verduijn ,  Jannetje Maatje van den Berge

IPC分类号： B01J29/06 ,  B01J29/40 ,  B01J29/70 ,  B01J29/80 ,  B01J37/00 ,  B01J37/02 ,  C07B61/00 ,  C07C1/20 ,  C07C2/00 ,  C07C2/66 ,  C07C5/22 ,  C07C5/27 ,  C07C6/12 ,  C07C15/08 ,  C10G3/00 ,  C10G11/05 ,  C10G35/095 ,  C10G45/64 ,  C10G45/68 ,  C10G47/16 ,  C01B33/36 ,  C07C15/00

CPC分类号： C10G45/64 ,  B01J29/80 ,  B01J37/0246 ,  C07C1/20 ,  C07C2/00 ,  C07C2/66 ,  C07C5/2708 ,  C07C5/2724 ,  C07C6/123 ,  C07C6/126 ,  C10G11/05 ,  C10G35/095 ,  B01J2229/26 ,  B01J2229/42 ,  B01J29/40 ,  B01J29/70 ,  B01J37/0009 ,  C07C2529/08 ,  C07C2529/40 ,  C07C2529/65 ,  C07C2529/70 ,  C07C2529/80 ,  C07C2529/87 ,  C07C2529/89 ,  Y02P20/52 ,  Y02P30/20 ,  Y02P30/42

摘要： There is provided a process for converting hydrocarbons which utilizes a zeolite bound zeolite catalyst that has enhanced performance when utilized in hydrocarbon conversion processes, e.g., catalytic cracking, alkylation, disproportionation of toluene, isomerization, and transalkylation reactions. The catalyst comprises a first zeolite having particles of greater than about 0.1 micron average particle size and a binder comprising second zeolite particles having an average particle size less than said first particles.

公开(公告)号：US5756414A

公开(公告)日：1998-05-26

申请号：US940579

申请日：1992-09-04

申请人： Yao-Jyh Robert Huang ,  Shun Chong Fung ,  Gary Brice McVicker ,  Jar-lin Kao ,  John Francis Walsh ,  Kenneth Ray Clem

发明人： Yao-Jyh Robert Huang ,  Shun Chong Fung ,  Gary Brice McVicker ,  Jar-lin Kao ,  John Francis Walsh ,  Kenneth Ray Clem

IPC分类号： B01J29/62 ,  B01J29/90 ,  B01J38/44 ,  C07B61/00 ,  C07C5/387 ,  C07C5/41 ,  C07C15/04 ,  C10G35/095 ,  B01J29/38 ,  B01J38/42

CPC分类号： B01J29/62 ,  B01J29/90 ,  B01J38/44 ,  C10G35/095 ,  B01J2229/26 ,  B01J2229/36 ,  B01J2229/40 ,  B01J2229/42

摘要： The present invention is a process for regenerating deactivated catalyst or redispersing catalytic metal in a fresh catalyst comprising at least one Group VIII catalytic metal, zeolite, an inert binder. The process comprises coke burn, hydrogen reduction, catalyst conditioning, oxychlorination, low pressure stripping, and low pressure final hydrogen reduction.

摘要翻译： 本发明是一种在包含至少一种VIII族催化金属，沸石，惰性粘合剂的新鲜催化剂中再生失活催化剂或再分散催化金属的方法。 该方法包括焦炭燃烧，氢还原，催化剂调节，氧氯化，低压汽提和低压最终氢还原。