公开(公告)号：US06224639B1

公开(公告)日：2001-05-01

申请号：US09348757

申请日：1999-07-07

申请人： Takahiro Hamada ,  Emiko Igaki ,  Masakazu Tanahashi ,  Yasunobu Tsuji ,  Chiharu Hayashi ,  Yoshihiko Tsujikawa

发明人： Takahiro Hamada ,  Emiko Igaki ,  Masakazu Tanahashi ,  Yasunobu Tsuji ,  Chiharu Hayashi ,  Yoshihiko Tsujikawa

IPC分类号： H01G9025

CPC分类号： H01G9/025 ,  H01G9/028 ,  H01G11/48 ,  H01G11/56 ,  Y02E60/13 ,  Y10T29/417

摘要： The present invention provides a method of producing an electrolytic capacitor including a porous anode and a solid electrolyte made of a conductive polymer, which can improve coating properties of the conductive polymer on an external surface of the porous anode and productivity. By controlling a polymerization rate, it is possible to sufficiently coat the external surface of the porous anode and fill inner spaces of a lot of pores of the porous anode with the conductive polymer with less numbers of polymerization in comparison with a method of the prior art, thereby obtaining an electrolytic capacitor with small leak current and high reliability.

摘要翻译： 本发明提供一种电解电容器的制造方法，该电解电容器包括多孔阳极和由导电聚合物制成的固体电解质，其可以改善多孔阳极的外表面上的导电聚合物的涂层性能和生产率。 通过控制聚合速度，与现有技术的方法相比，可以充分地涂覆多孔阳极的外表面并且填充多孔阳极的许多孔的内部空间与具有较少聚合数的导电聚合物 从而获得漏电流小且可靠性高的电解电容器。

公开(公告)号：US06174589B1

公开(公告)日：2001-01-16

申请号：US09159376

申请日：1998-09-23

申请人： Yoshihiro Kawakita ,  Seiichi Nakatani ,  Masakazu Tanahashi

发明人： Yoshihiro Kawakita ,  Seiichi Nakatani ,  Masakazu Tanahashi

IPC分类号： B32B300

CPC分类号： H05K1/0373 ,  H05K2201/0769 ,  H05K2203/121 ,  Y10S428/901 ,  Y10T29/49155 ,  Y10T428/24802 ,  Y10T428/24917

摘要： A printed circuit board includes insulating layers formed by impregnating a base material with a resin and a metal foil pattern formed on a desired layer of the insulating layers. Ions for forming a hardly soluble metal salt by combining with metal ions free from a portion of the board or a sulfur-containing compound for reacting with the metal ion are present in the insulating layer or on a surface of the metal foil pattern. Furthermore, a method for producing the printed circuit board includes any one of the steps of adding the ions or the sulfur-containing compound to the resin varnish, impregnating a base material with the solution of the ions or the sulfur-containing compound, or applying the solution onto the surface of the metal foil pattern, in order to allow the ions or the sulfur-containing compound to exist in the printed circuit board.

摘要翻译： 印刷电路板包括通过用树脂浸渍基材而形成的绝缘层和形成在所述绝缘层的所需层上的金属箔图案。 在绝缘层或金属箔图案的表面上存在用于通过与不含板的金属离子结合形成难溶金属盐的离子或与金属离子反应的含硫化合物。 此外，制造印刷电路板的方法包括以下步骤之一：将离子或含硫化合物加入到树脂清漆中，用离子或含硫化合物的溶液浸渍基材或施加 溶液到金属箔图案的表面上，以便允许离子或含硫化合物存在于印刷电路板中。

公开(公告)号：US6088218A

公开(公告)日：2000-07-11

申请号：US179710

申请日：1998-10-27

申请人： Takahiro Hamada ,  Emiko Igaki ,  Masakazu Tanahashi ,  Chiharu Hayashi ,  Yasunobu Tsuji

发明人： Takahiro Hamada ,  Emiko Igaki ,  Masakazu Tanahashi ,  Chiharu Hayashi ,  Yasunobu Tsuji

IPC分类号： H01G9/00 ,  H01G9/02 ,  H01G9/025

CPC分类号： H01G9/0036 ,  H01G9/025 ,  Y10T29/417

摘要： The present invention provides a method for producing an electrolytic capacitor including a porous body of a valve metal, an oxide film on a surface of the valve metal, and a conductive polymer layer on a surface of the oxide film. The step of forming the conductive polymer layer on the surface of the oxide film includes the steps of dipping the porous body in a monomer solution; lifting the porous body from the monomer solution and dipping the porous body in an oxidizing solution; and lifting the porous body from the oxidizing solution and allowing the porous body to stand. In the step of dipping the porous body in the oxidizing solution, a period for which the porous body is dipped in the oxidizing solution is equal to or shorter than a period in which 30% of the monomer contained in pores of the porous body diffuses and flows into the oxidizing solution. Alternatively, the volume of the oxidizing solution can be less than three times that of the porous body. The above method can be performed by replacing the monomer solution and the oxidizing solution with each other. Furthermore, a temperature of the porous body is maintained at a low temperature (e.g., 10.degree. C. or less) in the step of dipping the porous body in the oxidizing solution.

摘要翻译： 本发明提供一种电解电容器的制造方法，该电解电容器包括阀金属多孔体，阀金属表面的氧化膜，氧化膜表面的导电性聚合物层。 在氧化膜的表面上形成导电聚合物层的步骤包括将多孔体浸渍在单体溶液中的步骤; 将多孔体从单体溶液中提起并将多孔体浸入氧化溶液中; 并且从氧化溶液中提起多孔体并允许多孔体静置。 在将多孔体浸渍在氧化液中的步骤中，多孔体浸渍在氧化液中的时间等于或短于多孔体的孔中含有30％的单体的时间， 流入氧化溶液。 或者，氧化溶液的体积可以小于多孔体的体积。 上述方法可以通过将单体溶液和氧化溶液相互替代来进行。 此外，在将多孔体浸入氧化溶液的步骤中，多孔体的温度保持在低温（例如10℃以下）。

公开(公告)号：US20050078154A1

公开(公告)日：2005-04-14

申请号：US10497348

申请日：2003-01-14

申请人： Takanori Nakano ,  Shogo Matsubara ,  Shintaro Hara ,  Kazuo Nishimura ,  Masaichiro Tatekawa ,  Masakazu Tanahashi ,  Hiroyuki Matsuo

发明人： Takanori Nakano ,  Shogo Matsubara ,  Shintaro Hara ,  Kazuo Nishimura ,  Masaichiro Tatekawa ,  Masakazu Tanahashi ,  Hiroyuki Matsuo

IPC分类号： B41J2/14 ,  H01L41/09 ,  B41J2/045

CPC分类号： B41J2/14233 ,  B41J2202/03 ,  H01L41/0973

摘要： A piezoelectric actuator is constructed by forming a common electrode 27 of Cr, a piezoelectric layer 29 of Pb(Zr,Ti)O3, a cover layer 31 of BaTiO3, and an individual electrode 33 of Pt in this order into a laminate. The thickness of the piezoelectric layer 29 in the lamination direction (T1) and the thickness of the cover layer 31 in the lamination direction (T2) satisfy the relationship of 0.08≦T2/T1≦1. The relative dielectric constant of the piezoelectric layer 29 (εr1) and the relative dielectric constant of the cover layer 31 (εr2) satisfy the relationship of εr2/εr1≧0.2.

摘要翻译： 通过将Cr的公共电极27，Pb（Zr，Ti）O 3的压电层29，BaTiO 3的覆盖层31和Pt的单个电极33依次形成为层叠体来构成压电致动器。 层叠方向（T1）的压电体层29的厚度和层叠方向（T2）的覆盖层31的厚度满足0.08 <= T2 / T1 <= 1的关系。 压电层29的相对介电常数（ε1r1）和覆盖层31的相对介电常数（ε2r2）满足ε2r2/ε1r1≥0.2的关系。

公开(公告)号：US06580601B2

公开(公告)日：2003-06-17

申请号：US10284658

申请日：2002-10-30

申请人： Takahiro Hamada ,  Emiko Igaki ,  Masakazu Tanahashi

发明人： Takahiro Hamada ,  Emiko Igaki ,  Masakazu Tanahashi

IPC分类号： H01G900

CPC分类号： H01G9/15 ,  H01G9/0425 ,  H01G11/48 ,  H01G11/56 ,  H01L2224/32245 ,  H01L2924/181 ,  Y02E60/13 ,  Y10T29/417 ,  H01L2924/00012

摘要： A solid electrolyte capacitor includes an anode made of a valve metal on whose surface a dielectric oxide film layer is formed, a solid electrolyte layer formed on the dielectric oxide film, a cathode layer formed on the solid electrolyte layer, a cathode contact terminal electrically connected to the cathode layer, and an anode contact terminal electrically connected to the anode layer. The cathode layer includes a carbon layer containing carbon particles, and a conductive paste layer containing conductive metal particles and having numerous pores, formed in that order from the solid electrolyte layer side. The solid electrolyte capacitor further includes a conductive polymer layer formed through the numerous pores of the conductive paste layer and connecting the carbon particles of the carbon layer and the conductive metal particles of the conductive paste layer. Thus, the interface resistance between the carbon layer and the conductive paste layer is lowered, and a solid electrolyte capacitor with small equivalent series resistance can be provided.

摘要翻译： 一种固体电解质电容器包括：由其表面形成有电介质氧化膜层的阀金属制成的阳极，形成在电介质氧化膜上的固体电解质层，形成在固体电解质层上的阴极层，电连接的阴极接触端子 与阳极层电连接的阳极接触端子。 阴极层包括含有碳颗粒的碳层和从固体电解质层侧依次形成含有导电金属颗粒并具有许多孔的导电浆料层。 固体电解质电容器还包括通过导电膏层的多个孔形成并连接碳层​​的碳颗粒和导电糊层的导电金属颗粒的导电聚合物层。 因此，碳层和导电糊层之间的界面电阻降低，并且可以提供具有小的等效串联电阻的固体电解电容器。

公开(公告)号：US06558616B2

公开(公告)日：2003-05-06

申请号：US09776989

申请日：2001-02-05

申请人： Masahiro Ito ,  Masakazu Tanahashi ,  Toshiro Kume ,  Kouichi Morimoto ,  Junji Kojima ,  Emiko Igaki

发明人： Masahiro Ito ,  Masakazu Tanahashi ,  Toshiro Kume ,  Kouichi Morimoto ,  Junji Kojima ,  Emiko Igaki

IPC分类号： B22F704

CPC分类号： H01C1/1406 ,  H01C7/027 ,  Y10T428/12028 ,  Y10T428/12493

摘要： An electrode for a PTC thermistor of the present invention includes a base layer having electrical conductivity and a sintered layer formed on the base layer. The sintered layer is formed by sintering a conductive powder and has electrical conductivity, and has roughness on a surface thereof. Thus, the present invention can provide an electrode for a PTC thermistor that has a large adhesion to the conductive polymer and can be produced easily.

公开(公告)号：US06493210B2

公开(公告)日：2002-12-10

申请号：US10035164

申请日：2002-01-04

申请人： Seiji Nonaka ,  Masakazu Tanahashi ,  Mikinari Shimada ,  Tamao Kojima ,  Munehiro Tabata

发明人： Seiji Nonaka ,  Masakazu Tanahashi ,  Mikinari Shimada ,  Tamao Kojima ,  Munehiro Tabata

IPC分类号： H01G900

CPC分类号： H01G9/04 ,  H01G11/24 ,  H01G11/30 ,  H01G11/38 ,  H01G11/42 ,  H01M4/13 ,  H01M4/625 ,  H01M4/661 ,  H01M4/663 ,  H01M4/667 ,  H01M10/052 ,  H01M2004/027 ,  Y02E60/13 ,  Y10T29/417

摘要： The present invention relates to an electrode metal material for batteries, capacitors, etc., used in contact with non-aqueous electrolyte, and particularly to a capacitor formed of the electrode metal material, and provides a valve metal material capable of decreasing the internal resistance of the capacitor. The electrode metal material includes a valve metal material and numerous carbon particles included in the surface of the valve metal material. The carbon particles are further fixed in the surface of the valve metal material so as to expose to the surface. The electrode metal material is coated with an activated carbon layer and used as a double-layer electrode for an electric double-layer capacitor. The carbon particles included in the surface ensure conduction between the activated carbon layer and the valve metal material. With this configuration, even if the surface of the valve metal material is oxidized, the internal resistance of the electrode is not decreased, the internal resistance of the capacitor is decreased, and the capacitance of the capacitor is increased.

摘要翻译： 本发明涉及用于与非水电解质接触的电池，电容器等的电极金属材料，特别涉及由电极金属材料形成的电容器，并提供能够降低内阻的阀金属材料 的电容器。 电极金属材料包括阀金属材料和包括在阀金属材料表面中的许多碳颗粒。 碳颗粒进一步固定在阀金属材料的表面上以暴露于表面。 电极金属材料涂覆有活性炭层，并用作双层电容器的双层电极。 包含在表面中的碳颗粒确保活性炭层和阀金属材料之间的导电。 利用这种结构，即使阀金属材料的表面被氧化，电极的内部电阻也不会降低，电容器的内部电阻降低，并且电容器的电容增大。

公开(公告)号：US06392869B2

公开(公告)日：2002-05-21

申请号：US09864661

申请日：2001-05-23

申请人： Seigo Shiraishi ,  Emiko Igaki ,  Masakazu Tanahashi ,  Mikinari Shimada ,  Norihisa Takahara ,  Yasuhiko Nakada ,  Keizou Nakagawa ,  Hideki Masumi ,  Eiji Yamashita

发明人： Seigo Shiraishi ,  Emiko Igaki ,  Masakazu Tanahashi ,  Mikinari Shimada ,  Norihisa Takahara ,  Yasuhiko Nakada ,  Keizou Nakagawa ,  Hideki Masumi ,  Eiji Yamashita

IPC分类号： H01G900

CPC分类号： H01G9/012 ,  H01G9/15 ,  H01G9/26

摘要： A solid electrolytic capacitor capable of realizing miniaturization and large capacitance and obtaining the connection, in particular electric connection between the anodes, with low resistance and high reliability. A solid electrolytic capacitor includes: a laminate including a plurality of capacitor units in which a dielectric layer and a solid electrolytic layer are laminated in this order on a predetermined surface of an anode made of a valve metal; a sealing body for sealing the laminate; and an anodic conductive elastic body formed outside the sealing body and electrically connected to the anode. The anodes are adhered to each other via the conductive elastic body. In the solid electrolytic capacitor, a part of the anode is exposed to the outside of the sealing portion and the exposed portion is covered with a plating layer, and electrically connected to the anodic conductive elastic body via the covered exposed portion.

公开(公告)号：US06361572B1

公开(公告)日：2002-03-26

申请号：US09616876

申请日：2000-07-14

申请人： Emiko Igaki ,  Masakazu Tanahashi ,  Chiharu Hayashi

发明人： Emiko Igaki ,  Masakazu Tanahashi ,  Chiharu Hayashi

IPC分类号： H01G900

CPC分类号： H01G9/042 ,  H01G9/0036 ,  H01G9/025 ,  H01G9/028 ,  H01G9/0425 ,  H01G11/48 ,  H01G11/56 ,  Y02E60/13 ,  Y10T29/417

摘要： Disclosed is a method of making an electrolytic capacitor including the steps of forming a cathode by depositing a homogeneous and densified conducting polymer on a dielectric layer of a valvular metal porous anode. The conducting polymer is formed of two layers by chemical oxidation polymerization. The first conductive polymer layer is formed in the pretreatment step using a solution excluding an organic acid-type dopant, the polymer is efficiently formed on the inner surface of the pores of the anode and the second conductive polymer layer is formed in the primary treatment step on the first conductive polymer layer, using a solution containing an organic acid-type dopant. The resultant capacitor obtains a high capacitance, a low impedance, and a high responsiveness at high frequencies.

摘要翻译： 公开了一种制造电解电容器的方法，包括以下步骤：通过在瓦楞金属多孔阳极的电介质层上沉积均质且致密化的导电聚合物来形成阴极。 导电聚合物通过化学氧化聚合由两层形成。 在预处理步骤中，使用不含有机酸型掺杂剂的溶液形成第一导电聚合物层，在阳极的孔的内表面上有效地形成聚合物，并且在第一处理步骤中形成第二导电聚合物层 在第一导电聚合物层上，使用含有机酸型掺杂剂的溶液。 所得电容器在高频下获得高电容，低阻抗和高响应性。

公开(公告)号：US6113755A

公开(公告)日：2000-09-05

申请号：US760722

申请日：1996-12-05

申请人： Masakazu Tanahashi ,  Kounosuke Hashio ,  Mitsuhisa Yoshimura ,  Daisuke Suzuki ,  Masanori Okabayashi ,  Shinji Kabeya

发明人： Masakazu Tanahashi ,  Kounosuke Hashio ,  Mitsuhisa Yoshimura ,  Daisuke Suzuki ,  Masanori Okabayashi ,  Shinji Kabeya

IPC分类号： H01G9/04 ,  C25D7/06 ,  C25D11/04 ,  C25D17/10 ,  H01G9/00 ,  H01G13/00

CPC分类号： H01G9/0029 ,  C25D11/04 ,  C25D17/10 ,  C25D7/0628 ,  C25D7/0642 ,  H01G13/00 ,  Y10S204/07

摘要： This invention provides an apparatus for producing an electrode foil for use in aluminum electrolytic capacitors with which a high capacitance is obtained while the distortion of the foil and the leakage current can be controlled. At least two electrode plates as cathode are disposed in an electrolytic tank containing an electrolytic solution, and a direct current is supplied between an aluminum foil as anode and the electrode plates. Anodization is conducted continuously by turning the direction of the aluminum foil via rollers and conveying the foil between the electrode plates. During this treatment, the length and the position of the effective sections of the electrode plates are adjusted to keep the length to be at most two-thirds of the distance between an area near the surface of the electrolytic solution and the upper part of the bottom roller, so that the peak value of the anodizing current density appears not at the surface of the electrolytic solution but in the electrolytic solution.

摘要翻译： 本发明提供一种用于制造用于铝电解电容器的电极箔的设备，其中可以获得高电容，同时可以控制箔的变形和泄漏电流。 将至少两个作为阴极的电极板设置在包含电解液的电解槽中，并且在作为阳极的铝箔和电极板之间提供直流电流。 通过辊转动铝箔的方向并在电极板之间输送箔片来连续进行阳极氧化。 在这种处理过程中，调节电极板的有效部分的长度和位置，使其长度保持在电解液表面附近与底部上部之间的距离的三分之二以上 使得阳极氧化电流密度的峰值不出现在电解液的表面，而在电解液中。