METAL PASSIVATION OF HEAT-EXCHANGER EXPOSED TO SYNTHESIS GAS
    23.
    发明申请
    METAL PASSIVATION OF HEAT-EXCHANGER EXPOSED TO SYNTHESIS GAS 审中-公开
    接触合成气体的换热器的金属钝化

    公开(公告)号:US20130248769A1

    公开(公告)日:2013-09-26

    申请号:US13821768

    申请日:2011-08-19

    Abstract: A process is described for the passivation of the surfaces of heat exchange apparatus exposed to a synthesis gas containing carbon monoxide and hydrogen, including the steps of: (i) adding an arsenic compound to the synthesis gas at a temperature ≧850° C. to generate volatile arsenic passivation species, (ii) exposing the mixture of hot synthesis gas and arsenic passivation species to surfaces on the shell-side of said heat exchange apparatus to reduce the interaction between the carbon monoxide present in said gas and metals said in said surfaces, (iii) recovering a cooled synthesis gas from the shell-side of said apparatus, and (iv) passing the cooled synthesis gas, optionally after further cooling, through a sorbent bed to remove arsenic compounds from the synthesis gas.

    Abstract translation: 描述了暴露于含有一氧化碳和氢气的合成气体的热交换装置的表面钝化的方法,包括以下步骤:(i)在温度≥850℃下向合成气中加入砷化合物。 以产生挥发性砷钝化物质,(ii)将热合成气和砷钝化物质的混合物暴露于所述热交换装置的壳侧上的表面,以减少所述气体中存在的一氧化碳和所述气体中所述的金属之间的相互作用 表面,(iii)从所述装置的壳侧回收冷却的合成气,和(iv)任选地在冷却后通过吸附剂床将冷却的合成气通过,以从合成气中除去砷化合物。

    Ni-based corrosion resistant alloy and corrosion resistant member for supercritical ammonia reactor made of the alloy
    24.
    发明授权
    Ni-based corrosion resistant alloy and corrosion resistant member for supercritical ammonia reactor made of the alloy 有权
    Ni合金耐腐蚀合金和超临界氨反应器耐腐蚀材料

    公开(公告)号:US08414828B2

    公开(公告)日:2013-04-09

    申请号:US12064297

    申请日:2006-08-22

    Abstract: A material is presented that exhibits excellent corrosion resistance to supercritical ammonia and is suitable for a supercritical ammonia reactor. An Ni-based corrosion resistant alloy includes from 15% or more to 50% or less by mass of Cr and any one or both of Mo and W, wherein a [(content of Mo)+0.5×(content of W)] is from 1.5% or more to 8.5% or less by mass, a value of 1.8×[% content of Cr]/{[% content of Mo]+0.5×[% content of W]} is from 3.0 or more to 70.0 or less and the balance is Ni and an unavoidable impurity. The alloy may be used to configure a supercritical ammonia reactor or the material is coated on a surface that contacts with a supercritical ammonia fluid. The alloy exhibits excellent corrosion resistance to supercritical ammonia and a mineralizer added the supercritical ammonia. The safety and reliability of an apparatus can be improved, the producing cost can be reduced, the apparatus lifetime can be extended and the running cost can be reduced.

    Abstract translation: 对超临界氨表现出优异的耐腐蚀性,适用于超临界氨反应器的材料。 镍基耐腐蚀合金包含15质量%以上至50质量%以下的Cr和Mo和W中的任一种或两种,其中[(Mo含量)+ 0.5×(W含量)]为 从1.5%以上至8.5%以下,1.8×[Cr含量%] [{Mo含量] + 0.5×[W含量%]的值为3.0以上〜70.0以上 较少,平衡是Ni和不可避免的杂质。 该合金可用于构造超临界氨反应器,或者该材料涂覆在与超临界氨流体接触的表面上。 该合金对超临界氨表现出优异的耐腐蚀性,并且矿化剂加入超临界氨。 可以提高设备的安全性和可靠性,可以降低生产成本,延长设备使用寿命,降低运行成本。

    REACTOR SYSTEM AND METHOD OF POLYCRYSTALLINE SILICON PRODUCTION THEREWITH
    25.
    发明申请
    REACTOR SYSTEM AND METHOD OF POLYCRYSTALLINE SILICON PRODUCTION THEREWITH 审中-公开
    多晶硅生产的反应器系统和方法

    公开(公告)号:US20120183686A1

    公开(公告)日:2012-07-19

    申请号:US13350570

    申请日:2012-01-13

    Applicant: Daniel Ohs

    Inventor: Daniel Ohs

    Abstract: Embodiments of a method for reducing or mitigating metal contamination of polycrystalline silicon are disclosed. In particular the disclosure relates to a method of mitigating metal contamination of granulate polycrystalline silicon, during its manufacture in a fluidized bed reactor unit, resulting from contact with a metal surface of components of the supporting transportation and auxiliary infrastructure by use of a protective coating comprising silicon or a silicon-containing material.

    Abstract translation: 公开了减少或减轻多晶硅的金属污染的方法的实施例。 特别地,本公开涉及一种减轻颗粒状多晶硅在其流化床反应器单元制造期间的金属污染的方法,其通过使用保护涂层与支撑运输和辅助基础设施的部件的金属表面接触而形成,所述保护涂层包括 硅或含硅材料。

    Apparatus And Methods For Utilizing Heat Exchanger Tubes
    26.
    发明申请
    Apparatus And Methods For Utilizing Heat Exchanger Tubes 有权
    使用热交换器管的装置和方法

    公开(公告)号:US20110257455A1

    公开(公告)日:2011-10-20

    申请号:US12762910

    申请日:2010-04-19

    Abstract: In one aspect, the present techniques include a heat exchange apparatus including: a) a body comprising an interior cavity, the body including: a first surface and a second surface defining at least a portion of the body and the first surface positioned exterior with respect to the second surface and the interior cavity, and the second surface positioned exterior with respect to the interior cavity and interior with respect to the first surface; b) a first conduit for conveying a fluid to the body; c) a second conduit in fluid communication with the first conduit wherein the second conduit is positioned at least partially within the interior cavity of the body; and d) a joint between the first conduit and the second conduit, wherein the joint moves between a first location and a second location based on the temperature within the interior cavity, wherein at least one of said first location and said second location is positioned intermediate the first surface and the second surface.

    Abstract translation: 在一个方面,本技术包括热交换装置,其包括:a)包括内腔的主体,所述主体包括:第一表面和第二表面,所述第一表面和第二表面限定所述主体的至少一部分,并且所述第一表面相对于 并且所述第二表面相对于所述内腔定位在外部并且相对于所述第一表面位于内部; b)用于将流体输送到身体的第一导管; c)与所述第一管道流体连通的第二导管,其中所述第二导管至少部分地定位在所述主体的内腔内; 以及d)所述第一管道和所述第二管道之间的接头,其中所述接头基于所述内部空腔内的温度在第一位置和第二位置之间移动,其中所述第一位置和所述第二位置中的至少一个位于中间 第一表面和第二表面。

    APPARATUS FOR PRODUCING SILICON
    27.
    发明申请
    APPARATUS FOR PRODUCING SILICON 审中-公开
    生产硅胶的设备

    公开(公告)号:US20100290960A1

    公开(公告)日:2010-11-18

    申请号:US12810254

    申请日:2008-12-26

    Abstract: To provide an apparatus for producing silicon capable of recovering silicon sufficiently in a recovery container even if the silicon deposited in a reaction container solidifies in the shape of an anthill.[Means for Solution] The apparatus for producing silicon has means for moving a recovery container 14 in a reaction container body 2. The moving means includes a support shaft 18 for supporting a bottom wall 14b of the recovery container 14 and a drive unit 17 for rotating the support shaft 18, which are provided for the recovery container 14. The support shaft 18 is deviated from the position of the center portion of the opening 7a on the lower end side of the reaction tube 7 so that the support shaft 18 suitably rotates at the time when the silicon is recovered in the recovery container 14 thereby varying the position on where the anthill is formed.

    Abstract translation: 即使沉积在反应容器中的硅固化成一个蚁丘的形状,提供一种能够在回收容器中充分回收硅的硅的装置。 [解决方案]用于制造硅的装置具有用于使反应容器主体2中的回收容器14移动的装置。移动装置包括用于支撑回收容器14的底壁14b的支撑轴18和用于 旋转用于回收容器14的支撑轴18.支撑轴18从反应管7的下端侧上的开口7a的中心部分的位置偏离,使得支撑轴18适当地旋转 在硅在回收容器14中回收,从而改变在形成该止点的位置。

    Fuel gas reformer assemblage
    30.
    发明申请

    公开(公告)号:US20100040511A1

    公开(公告)日:2010-02-18

    申请号:US12586163

    申请日:2004-10-27

    Inventor: Roger R. Lesieur

    Abstract: A fuel gas-steam reformer assembly, preferably an autothermal reformer assembly, for use in a fuel cell power plant, includes a mixing station for intermixing a relatively high molecular weight fuel and an air-steam stream so as to form a homogeneous fuel-air-steam mixture for admission into a catalyst bed. The catalyst bed includes catalyzed alumina pellets, or a monolith such as a foam or honeycomb body which is preferably formed from a high temperature material such as a steel alloy, or from a ceramic material. The catalyst bed is contained in a shell which is preferably formed from stainless steel or some other high temperature alloy. The shell includes an internal peripheral thermal insulation layer of zirconia (ZrO2), either in a felt form, or in a rigidified foam. The zirconia insulation layer provides thermal insulation for the shell and retains heat in the catalyst bed and protects the shell against thermal degradation from the hot catalyst bed; and it also protects the catalyst bed against carbon deposition from the fuel and oxygen mixture flowing through the catalyst bed. The use of an internal zirconia insulation layer obviates the need to provide an alumina washcoat and metal oxide coatings on the inner surface of the shell for inhibiting carbon deposition in the catalyst bed. The zirconia insulation layer is non-acidic and possesses carbon gasification properties which are similar to the carbon gasification properties possessed by calcium and alkali metal oxides. Unlike silica insulation, zirconia insulation does not vaporize in the presence of high temperature steam.

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