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公开(公告)号:US11773198B2
公开(公告)日:2023-10-03
申请号:US17931103
申请日:2022-09-09
IPC分类号: C08F210/16 , C08F2/00
CPC分类号: C08F210/16 , C08F2400/02
摘要: Methods of controlling olefin polymerization reactor systems may include a) selecting n input variables, each input variable corresponding to a process condition for an olefin polymerization process; b) identifying m response variables corresponding to a measurable polymer property; c) adjusting one of more of the n input variables using the olefin polymerization reactor system and measuring each of the m response variables as a function of the input variables for olefin polymers; d) analyzing the change in each of the response variables as a function of the input variables to determine coefficients; e) calculating a Response Surface Model (RSM) for each response variable determined in step d); f) applying n selected input variables to the calculated RSM to predict one or more of m target response variables; and g) using the n selected input variables to operate the olefin polymerization reactor system and provide a polyolefin product.
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公开(公告)号:US20230295524A1
公开(公告)日:2023-09-21
申请号:US17655051
申请日:2022-03-16
发明人: Steven R. Horlacher
CPC分类号: C10G67/00 , C10G7/12 , C10G47/16 , C10G49/002 , C10G45/00 , B01D3/009 , B01D3/32 , C10G2300/4006 , C10G2300/4012 , C10G2300/301 , C10G2400/02 , C10G2400/26
摘要: A pyrolysis oil fractionation system for treating a pyrolysis oil feed includes a fractionation column, at least one treatment catalyst bed, and a plurality of distillation trays. The system further includes a condenser to receive a light fraction and produce a condensed gasoline product and a vapor, a receiver coupled to the condenser, a knockout drum, and a distillate stripper coupled to the fractionation column. A method for treating a pyrolysis oil feed includes, in a fractionating column, dehydrohalogenating, decontaminating, and/or dehydrating a pyrolysis oil feed in at least one treatment catalyst bed, and distilling the treated pyrolysis oil feed into a light fraction, a middle fraction, a heavy fraction, and a bottom fraction. The method further includes condensing the light fraction and producing a condensed gasoline product and a vapor, separating a fuel gas product from the vapor, and stripping the middle fraction to produce a distillate product.
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33.
公开(公告)号:US11753356B2
公开(公告)日:2023-09-12
申请号:US18057803
申请日:2022-11-22
发明人: Bruce E. Kreischer , Kendall M. Hurst , Eric D. Schwerdtfeger , Steven M. Bischof , Jared Fern , Kent E. Mitchell , James Hillier
CPC分类号: C07C2/32 , B01J8/10 , B01J8/1809 , B01J8/1854 , C12M41/30 , C12M41/32 , B01J8/001 , B01J19/0006 , B01J19/0013 , B01J2208/00548 , B01J2208/00663 , B01J8/001 , B01J19/0006 , B01J19/0013
摘要: Methods for determining ethylene concentration in an ethylene oligomerization reactor using an ultrasonic flow meter are described, and these methods are integrated into ethylene oligomerization processes and related oligomerization reactor systems.
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公开(公告)号:US11746297B2
公开(公告)日:2023-09-05
申请号:US18173196
申请日:2023-02-23
发明人: Ronald G. Abbott , Scott G. Morrison , Steven R. Horlacher , Jamie N. Sutherland , Bruce D. Murray , Jacob M. Hilbrich , Charles T. Polito
CPC分类号: C10B53/07 , C10G45/26 , C10G45/50 , C10G51/023 , C10G57/02 , C10G2300/1003 , C10G2400/04 , C10G2400/06 , C10G2400/20 , C10G2400/22 , C10G2400/28 , C10G2400/30
摘要: This disclosure relates to the production of chemicals and plastics using pyrolysis oil from the pyrolysis of plastic waste as a co-feedstock along with a petroleum-based, fossil fuel-based, or bio-based feedstock. In an aspect, the polymers and chemicals produced according to this disclosure can be certified under International Sustainability and Carbon Certification (ISCC) provisions as circular polymers and chemicals at any point along complex chemical reaction pathways. The use of a mass balance approach which attributes the pounds of pyrolyzed plastic products derived from pyrolysis oil to any output stream of a given unit has been developed, which permits ISCC certification agency approval.
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35.
公开(公告)号:US11735293B2
公开(公告)日:2023-08-22
申请号:US17460400
申请日:2021-08-30
发明人: Richard M. Buck , Qing Yang
IPC分类号: G16C20/10 , G16C20/20 , C08F4/6592 , B01J31/22 , G01N21/31 , G06F17/17 , C08F2/01 , C08F2/00 , G05B13/04 , B01J19/24 , B01J19/18 , B01J19/00 , C08F4/659 , C08F10/02 , G01N21/33 , C08F6/02
CPC分类号: G16C20/10 , B01J19/0006 , B01J19/0033 , B01J19/1837 , B01J19/2435 , B01J31/2295 , C08F2/00 , C08F2/01 , C08F4/65912 , C08F4/65916 , G01N21/31 , G01N21/314 , G05B13/042 , G06F17/17 , G16C20/20 , B01J2219/00164 , B01J2219/00186 , B01J2219/00198 , B01J2219/00213 , B01J2219/00218 , B01J2219/00231 , C08F6/02 , C08F10/02 , G01N21/33 , G01N2021/3129 , G01N2021/3155 , G01N2201/129 , C08F10/00 , C08F2/01 , C08F10/00 , C08F2/00 , C08F6/02 , C08L23/00
摘要: Methods for simultaneously determining the concentrations of transition metal compounds in solutions containing two or more transition metal compounds are described. Polymerization reactor systems providing real-time monitoring and control of the concentrations of the transition metal components of a multicomponent catalyst system are disclosed, as well as methods for operating such polymerization reactor systems, and for improving methods of preparing the multicomponent catalyst system.
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公开(公告)号:US20230183400A1
公开(公告)日:2023-06-15
申请号:US18165969
申请日:2023-02-08
IPC分类号: C08F210/02
CPC分类号: C08F210/02
摘要: Techniques are provided for catalyst preparation. A method includes heating a mixture of one or more transition metal compounds and an oxide support or a chromium containing oxide support to a temperature or a set of temperatures that enables the a transition metal compound of the one or more transition metal compounds to sublime, melt, or thermally decompose, such that a transition metal of the one or more transition metal compounds reacts with and is deposited onto a surface of the oxide support or the chromium containing oxide support to form a catalyst, and activating the catalyst. The catalyst is configured to facilitate a reaction that produces a target inorganic material.
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公开(公告)号:US20230183390A1
公开(公告)日:2023-06-15
申请号:US17551273
申请日:2021-12-15
摘要: Processes for producing ethylene-based polymers and oligomers from ethanol include the steps of contacting the ethanol and a catalyst to produce a reaction mixture containing ethylene, wherein a first portion of the ethanol is derived from a biomass and a second portion of the ethanol is derived from a plastic, a mixed solid waste stream, or a combination thereof, separating at least a portion of the ethylene from the reaction mixture, and contacting ethylene with a suitable polymerization or oligomerization catalyst composition to produce the ethylene polymer or ethylene oligomers. A related process for producing ethylene-based polymers and oligomers uses a first ethylene feed derived from ethanol and a second ethylene feed derived from a plastic, a mixed solid waste stream, or a combination thereof.
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公开(公告)号:US11667590B2
公开(公告)日:2023-06-06
申请号:US17330523
申请日:2021-05-26
CPC分类号: C07C2/30 , B01J31/12 , B01J31/128 , B01J31/143 , C07C2531/14 , C07C2531/22
摘要: Process for producing alpha olefins comprising contacting ethylene, a zirconium based catalyst system comprising, a hydrocarbylmetal compound, a chain transfer agent, and optionally an organic reaction medium. Chain transfer agents which can be utilized include a) hydrogen, b) a compound comprising a hydrogen silicon bond, a compound having a hydrogen sulfur bond, a compound having a hydrogen phosphorus bond, or c) a transition metal compound chain transfer agent.
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公开(公告)号:US11648541B2
公开(公告)日:2023-05-16
申请号:US17552959
申请日:2021-12-16
发明人: An-Hsiang Wu , Joseph Bergmeister
IPC分类号: B01J29/62 , B01J21/08 , B01J35/00 , B01J35/02 , B01J37/08 , B01J37/26 , B01J37/24 , B01J37/02 , C07C5/41 , B01J37/06 , B01J23/42 , B01J27/12 , B01J27/10 , B01J37/00 , B01J27/128 , B01J29/068 , B01J29/072 , B01J37/22 , B01J29/63
CPC分类号: B01J29/62 , B01J21/08 , B01J23/42 , B01J27/10 , B01J27/12 , B01J27/128 , B01J29/068 , B01J29/072 , B01J29/63 , B01J35/002 , B01J35/0006 , B01J35/026 , B01J37/0009 , B01J37/0201 , B01J37/0207 , B01J37/0209 , B01J37/0236 , B01J37/06 , B01J37/08 , B01J37/22 , B01J37/24 , B01J37/26 , C07C5/417 , B01J2229/18 , B01J2229/186 , B01J2229/20 , B01J2229/42 , C07C2521/08 , C07C2523/42 , C07C2527/08 , C07C2527/10 , C07C2527/12 , C07C2527/13 , C07C2529/068 , C07C2529/072 , C07C2529/62
摘要: Catalysts and method of preparing the catalysts are disclosed. One of the catalysts includes a zeolite support, a Group VIII metal on the zeolite support, and at least two halides bound to the zeolite support, to the Group VIII metal, or to both, and can have an average crush strength greater than 11.25 lb based on at least two samples of pellets of the catalyst measured in accordance with ASTM D4179.
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公开(公告)号:US20230146088A1
公开(公告)日:2023-05-11
申请号:US17890364
申请日:2022-08-18
CPC分类号: C07C2/36 , B01J31/2447 , B01J31/143 , C07C2531/24 , B01J2231/20 , C07C2531/14
摘要: The present disclosure relates to a catalyst system comprising i) (a) a bicyclic 2-[(phosphinyl)aminyl] cyclic imine chromium salt or (b) a chromium salt and a bicyclic 2-[(phosphinyl)aminyl] cyclic imine and ii) an organoaluminum compound. The present disclosure also relates to a process comprising: a) contacting i) ethylene; ii) a catalyst system comprising (a) a 2-[(phosphinyl)aminyl] cyclic imine chromium salt complex or (b) a chromium salt and a bicyclic 2-[(phosphinyl)aminyl] cyclic imine; ii) an organoaluminum compound, and iii) optionally an organic reaction medium; and b) forming an oligomer product in a reaction zone.
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